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Magnesioastrophyllite

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Formula:
(Na,K)
 
4
Mg
 
2
(Fe,Fe,Mn)
 
5
Ti
 
2
Si
 
8
O
 
24
(O,OH,F)
 
7
System:MonoclinicColour:Yellow
Lustre:VitreousHardness:3
Member of:Astrophyllite Group
Name:Named for the relationship to astrophyllite.

Classification of Magnesioastrophyllite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Nickel-Strunz 10th (pending) edition ID:9.DC.05

9 : SILICATES (Germanates)
D : Inosilicates
C : Inosilicates with branched 2-periodic single chains; Si2O6 + 2SiO3 Si4O12
Dana 8th edition ID:69.1.1.7

69 : INOSILICATES Chains with Side Branches or Loops
1 : Chains with Side Branches or Loops with (P=2, and N=4, 2 branches)
Hey's CIM Ref.:14.9.31

14 : Silicates not Containing Aluminum
9 : Silicates of Ti
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Type Occurrence of Magnesioastrophyllite

Co-type Localities:Kukisvumchorr Mt, Khibiny Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
Yukspor Mt, Khibiny Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia

Physical Properties of Magnesioastrophyllite

Lustre:Vitreous
Colour:Yellow
Hardness (Mohs):3

Crystallography of Magnesioastrophyllite

Crystal System:Monoclinic

Optical Data of Magnesioastrophyllite

Type:Biaxial (-)
RI values: nα = 1.658 nβ = 1.687 nγ = 1.710
2V:Measured: 81° to 83°, Calculated: 82°
Maximum Birefringence:δ = 0.052

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:r < v strong

Chemical Properties of Magnesioastrophyllite

Formula:
(Na,K)
 
4
Mg
 
2
(Fe,Fe,Mn)
 
5
Ti
 
2
Si
 
8
O
 
24
(O,OH,F)
 
7
Essential elements:Fe, Mg, Na, O, Si, Ti
All elements listed in formula:F, Fe, H, K, Mg, Mn, Na, O, Si, Ti

Relationship of Magnesioastrophyllite to other Species

Member of:Astrophyllite Group
Other Members of Group:

- +
Astrophyllite
(K,Na)
 
3
(Fe,Mn)
 
7
Ti
 
2
Si
 
8
O
 
24
(O,OH)
 
7
Hydroastrophyllite
(H
 
3
O,K,Ca)
 
3
(Fe,Mn)
 
5-65
Ti
 
2
Si
 
8
(O,OH)
 
31
Kupletskite
(K,Na)
 
3
(Mn,Fe)
 
7
Ti
 
2
Si
 
8
O
 
26
(OH)
 
4
F
Kupletskite-(Cs)
(Cs,K,Na)
 
3
(Mn,Fe
2+
 
)
 
7
(Ti,Nb)
 
2
Si
 
8
O
 
24
(O,OH,F)
 
7
Nalivkinite
Li
 
2
Na(Fe
2+
 
,Mn
2+
 
)
 
7
Ti
 
2
Si
 
8
O
 
26
(OH)
 
4
F
Niobokupletskite
K
 
2
Na(Mn,Zn,Fe)
 
7
(Nb,Zr,Ti)
 
2
Si
 
8
O
 
26
(OH)
 
4
(O,F)
Niobophyllite
(K,Na)
 
3
(Fe,Mn)
 
6
(Nb,Ti)
 
2
Si
 
8
(O,OH,F)
 
31
Sveinbergeite
Ca(Fe
2+
6
Fe
3+
 
)Ti
 
2
(Si
 
4
O
 
12
)
 
2
O
 
2
(OH)
 
5
(H
 
2
O)
 
4
Tarbagataite
(K□)Ca(Fe
2+
 
,Mn)
 
7
Ti
 
2
(Si
 
4
O
 
12
)
 
2
O
 
2
(OH)
 
5
Zircophyllite
(K,Na)
 
3
(Mn,Fe
2+
 
)
 
7
(Zr,Ti)
 
2
Si
 
8
O
 
24
(O,OH,F)
 
7
Related Minerals - Nickel-Strunz Grouping):

- +
9.DC.05Astrophyllite
(K,Na)
 
3
(Fe,Mn)
 
7
Ti
 
2
Si
 
8
O
 
24
(O,OH)
 
7
9.DC.05Hydroastrophyllite
(H
 
3
O,K,Ca)
 
3
(Fe,Mn)
 
5-65
Ti
 
2
Si
 
8
(O,OH)
 
31
9.DC.05Kupletskite
(K,Na)
 
3
(Mn,Fe)
 
7
Ti
 
2
Si
 
8
O
 
26
(OH)
 
4
F
9.DC.05Niobophyllite
(K,Na)
 
3
(Fe,Mn)
 
6
(Nb,Ti)
 
2
Si
 
8
(O,OH,F)
 
31
9.DC.05Zircophyllite
(K,Na)
 
3
(Mn,Fe
2+
 
)
 
7
(Zr,Ti)
 
2
Si
 
8
O
 
24
(O,OH,F)
 
7
9.DC.05Kupletskite-(Cs)
(Cs,K,Na)
 
3
(Mn,Fe
2+
 
)
 
7
(Ti,Nb)
 
2
Si
 
8
O
 
24
(O,OH,F)
 
7
9.DC.05Niobokupletskite
K
 
2
Na(Mn,Zn,Fe)
 
7
(Nb,Zr,Ti)
 
2
Si
 
8
O
 
26
(OH)
 
4
(O,F)
9.DC.05Nalivkinite
Li
 
2
Na(Fe
2+
 
,Mn
2+
 
)
 
7
Ti
 
2
Si
 
8
O
 
26
(OH)
 
4
F
9.DC.05Sveinbergeite
Ca(Fe
2+
6
Fe
3+
 
)Ti
 
2
(Si
 
4
O
 
12
)
 
2
O
 
2
(OH)
 
5
(H
 
2
O)
 
4
Related Minerals - Hey's Index Grouping:

- +
14.9.1Natisite
Na
 
2
Ti(SiO
 
4
)O
14.9.2Lorenzenite
Na
 
2
Ti
 
2
(Si
 
2
O
 
6
)O
 
3
14.9.3Lintisite
LiNa
 
3
Ti
 
2
(Si
 
2
O
 
6
)
 
2
O
 
2
· 2H
 
2
O
14.9.4Davanite
K
 
2
TiSi
 
6
O
 
15
14.9.5Kazakovite
Na
 
6
Mn
2+
 
Ti(Si
 
6
O
 
18
)
14.9.6Titanite
CaTi(SiO
 
4
)O
14.9.7Ohmilite
Sr
 
3
(Ti,Fe
3+
 
)(Si
 
4
O
 
12
)(O,OH) · 2-3H
 
2
O
14.9.8Lamprophyllite
(Sr,K,Ba)
 
2
(Na,Ti,Mn
2+
 
,Fe
3+
 
)
 
4
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O(O,OH,F)
14.9.9Benitoite
BaTi(Si
 
3
O
 
9
)
14.9.10Batisite
BaNaNaTi
 
2
(Si
 
4
O
 
12
)O
 
2
14.9.11Fresnoite
Ba
 
2
Ti(Si
 
2
O
 
7
)O
14.9.12Joaquinite-(Ce)
NaBa
 
2
Ce
 
2
FeTi
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(OH,F) · H
 
2
O
14.9.13Orthojoaquinite-(Ce)
NaBa
 
2
Ce
 
2
FeTi
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(O,OH) · H
 
2
O
14.9.14Strontiojoaquinite
Sr
 
2
Ba
 
2
(Na,Fe)
 
2
Ti
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(O,OH)
 
2
· H
 
2
O
14.9.15Bario-orthojoaquinite
(Ba,Sr)
 
4
Fe
 
2
Ti
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
· H
 
2
O
14.9.16Strontio-orthojoaquinite
(Na,Fe)
 
2
Sr
 
2
Ba
 
2
Ti
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(O,OH)
 
2
· H
 
2
O
14.9.17Bafertisite
Ba(Fe
3+
 
,Mn
2+
 
)
 
2
Ti(Si
 
2
O
 
7
)O(O,OH)
 
2
14.9.18Hejtmanite
Ba(Mn
2+
 
,Fe
2+
 
)
 
2
Ti(Si
 
2
O
 
7
)O(OH,F)
14.9.19Delindeite
(Na,K)
 
2
(Ba,Ca)
 
2
(Ti,Fe,Al)
 
3
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH)
 
2
· 2H
 
2
O
14.9.20Barytolamprophyllite
(Ba,Na)
 
2
(Na,Ti,Fe
3+
 
)
 
4
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O(OH,F)
14.9.21Trimounsite-(Y)
Y
 
2
Ti
 
2
(SiO
 
4
)O
 
5
14.9.22Perrierite-(Ce)
(Ce,Ca,Th)
 
4
(Fe
2+
 
,Mg)Fe
3+
2
(Ti,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
14.9.23Chevkinite
(Ca,Ce,Th)
 
4
(Fe,Mn)
 
2
(Ti,Fe)
 
3
Si
 
4
O
 
22
14.9.24Strontiochevkinite
(Sr,La,Ce,Ca)
 
4
Fe
2+
 
(Ti,Zr)
 
2
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
14.9.25Tisinalite
Na
 
3
H
 
3
(Mn,Ca,Fe)TiSi
 
6
(O,OH)
 
18
· 2H
 
2
O
14.9.26Neptunite
Na
 
2
KLi(Fe
2+
 
,Mn
2+
 
)
 
2
Ti
 
2
(Si
 
8
O
 
24
)
14.9.27Manganoneptunite
Na
 
2
KLi(Mn
2+
 
,Fe
2+
 
)
 
2
Ti
 
2
[Si
 
8
O
 
24
]
14.9.28Kupletskite
(K,Na)
 
3
(Mn,Fe)
 
7
Ti
 
2
Si
 
8
O
 
26
(OH)
 
4
F
14.9.29Astrophyllite
(K,Na)
 
3
(Fe,Mn)
 
7
Ti
 
2
Si
 
8
O
 
24
(O,OH)
 
7
14.9.30Hydroastrophyllite
(H
 
3
O,K,Ca)
 
3
(Fe,Mn)
 
5-65
Ti
 
2
Si
 
8
(O,OH)
 
31
14.9.32Baratovite
KCa
 
7
(Ti,Zr)
 
2
Li
 
3
Si
 
12
O
 
36
F
 
2
14.9.34Aenigmatite
Na
 
2
Fe
2+
5
Ti(Si
 
6
O
 
18
)O
 
2
14.9.35Schorlomite
Ca
 
3
(Ti,Fe
3+
 
)
 
2
((Si,Fe
3+
 
)O
 
4
)
 
3
14.9.36Tinaksite
K
 
2
Na(Ca,Mn
2+
 
)
 
2
Ti[O|Si
 
7
O
 
18
(OH)]
14.9.37Janhaugite
(Na,Ca)
 
3
(Mn
2+
 
,Fe
2+
 
)
 
3
(Ti,Zr,Nb)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH,F)
 
2
14.9.38Koashvite
Na
 
6
(Ca,Mn)(Ti,Fe)Si
 
6
O
 
18
· H
 
2
O

Other Names for Magnesioastrophyllite

Synonyms:
Magnesium Astrophyllite
Other Languages:

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Magnesioastrophyllite

Reference List:

- +
American Mineralogist (1975): 60: 737.

Scientia Sinica: 12: 272-276 (in Russian).

Canadian Mineralogist (2003): 41: 1-26.

Sokolova, E. & Cámara, F. (2008): Re-investigation of the crystal structure of magnesium astrophyllite(sic!). European Journal of Mineralogy, 20, 253-260.

Buke, E.A.J. (2008): Tidying up Mineral Names: an IMA-CNMNC scheme for suffixes, hyphens and diacritical marks, Mineralogical Record 39,131(2008)

Internet Links for Magnesioastrophyllite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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  • Localities for Magnesioastrophyllite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Russia
     
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
          • Khibiny Massif
    Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    Takai, Y., Uehara, S., Inoo, T. (2011) Minerals from Khibiny, Kola, Russia. Chigaku Kenkyu, 60 (1), 41-46.
    [Mandarino, 1997]
    Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    www.koeln.netsurf.de/~w.steffens/lovo.htm
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