Log InRegister
Quick Links : The Mindat ManualThe Rock H. Currier Digital LibraryMindat Newsletter [Free Download]
Home PageAbout MindatThe Mindat ManualHistory of MindatCopyright StatusWho We AreContact UsAdvertise on Mindat
Donate to MindatCorporate SponsorshipSponsor a PageSponsored PagesMindat AdvertisersAdvertise on Mindat
Learning CenterWhat is a mineral?The most common minerals on earthInformation for EducatorsMindat ArticlesThe ElementsThe Rock H. Currier Digital LibraryGeologic Time
Minerals by PropertiesMinerals by ChemistryAdvanced Locality SearchRandom MineralRandom LocalitySearch by minIDLocalities Near MeSearch ArticlesSearch GlossaryMore Search Options
Search For:
Mineral Name:
Locality Name:
Keyword(s):
 
The Mindat ManualAdd a New PhotoRate PhotosLocality Edit ReportCoordinate Completion ReportAdd Glossary Item
Mining CompaniesStatisticsUsersMineral MuseumsClubs & OrganizationsMineral Shows & EventsThe Mindat DirectoryDevice SettingsThe Mineral Quiz
Photo SearchPhoto GalleriesSearch by ColorNew Photos TodayNew Photos YesterdayMembers' Photo GalleriesPast Photo of the Day GalleryPhotography

Dalnegroite

A valid IMA mineral species
This page is currently not sponsored. Click here to sponsor this page.
Hide all sections | Show all sections

About DalnegroiteHide

00234900017058292732322.jpg
Alberto Dal Negro
Formula:
(Tl4Pb2)(As12Sb8)S34
Colour:
Red
Lustre:
Sub-Metallic
Hardness:
3 - 3½
Specific Gravity:
4.82 (Calculated)
Crystal System:
Triclinic
Name:
Named in honor of Alberto Dal Negro (1941 - 1 April 2022, Padua, Veneto, Italy), Professor in Mineralogy and Crystallography, University of Padova, Italy, for "his contribution to the discovery and crystal-structure determination of several new mineral species".
As-dominant analogue of chabournéite.

Structurally related to the Sartorite Group.

Note: Kasatkin et al. (2022) describe a triclinic possible "As analog of protochabournéite («protodalnegroite»)".



Unique IdentifiersHide

Mindat ID:
39758
Long-form identifier:
mindat:1:1:39758:6
GUID
(UUID V4):
af01203e-2bbc-4683-8bcc-44e9030826e8

IMA Classification of DalnegroiteHide

Classification of DalnegroiteHide

2.HD.05e

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
D : With Tl
3.8.12.2

3 : SULFOSALTS
8 : 1 < ø < 2

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
DnrIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of DalnegroiteHide

Sub-Metallic
Transparency:
Opaque
Colour:
Red
Streak:
Brownish-red
Hardness:
3 - 3½ on Mohs scale
Hardness:
VHN25=87 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven
Density:
4.82 g/cm3 (Calculated)

Optical Data of DalnegroiteHide

Anisotropism:
Strong, bluish to green
Bireflectance:
Highly bireflectant
Reflectivity:
WavelengthR1R2
471.1nm45.6% 46.1%
548.3nm46.1% 46.6%
586.6nm46.3% 47.0%
652.3nm46.4% 47.1%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 47.1%.
R1 shown in black, R2 shown in red
Internal Reflections:
Red
Pleochroism:
Weak
Comments:
White to a slightly greenish-grey

Chemistry of DalnegroiteHide

Mindat Formula:
(Tl4Pb2)(As12Sb8)S34

Crystallography of DalnegroiteHide

Crystal System:
Triclinic
Class (H-M):
1 - Pedial
Space Group:
P1
Cell Parameters:
a = 16.217(7) Å, b = 42.544(9) Å, c = 8.557(4) Å
α = 95.72(4)°, β = 90.25(4)°, γ = 96.78(4)°
Ratio:
a:b:c = 0.381 : 1 : 0.201
Unit Cell V:
5,832.53 ų (Calculated from Unit Cell)

Crystal StructureHide

Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
View
CIF File    Best | x | y | z | a | b | c
Rotation
Stop | Start
Labels
Console Off | On | Grey | Yellow
IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0020126DalnegroiteBindi L, Nestola F, Guastoni A, Secco L (2013) The crystal structure of dalnegroite, Tl5-xPb2x(As,Sb)21-xS34: a masterpiece of structural complexity Mineralogical Magazine 74 999-10122013Lengenbach quarry, Binntal, Canton Valais, Switzerland0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.927 Å(100)
3.774 Å(45)
3.685 Å(45)
3.620 Å(50)
3.124 Å(50)
2.929 Å(60)
2.850 Å(70)
2.097 Å(60)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of DalnegroiteHide

Place of Conservation of Type Material:
Museum of Mineralogy of the Department of Geosciences at the University of Padova, catalogue number MMP M762.
Associated Minerals at Type Locality:
Reference:
Nestola, F., A. Guastoni, L. Bindi, and L. Secco (2009) Dalnegroite,Tl^5-xPb^2x(As,Sb)^21-xS^34, a new thallium sulphosalt from Lengenbach quarry, Binntal, Switzerland. Mineralogical Magazine: 73: 1027-1032

Synonyms of DalnegroiteHide

Relationship of Dalnegroite to other SpeciesHide

Other Members of this group:
ChabournéiteAgzTl8-x-zPb4+2xSb40-x-yAsyS68 with 0.00 < x < 0.40(9), 16.15(3)< y < 19.11(10), 0.04(4) < z < 0.11(6)Tric. 1 : P1
DewititeAgzTl10-x-zPb2xSb42-x-yAsyS68Tric. 1 : P1
ProtochabournéiteTl4-xPb2+2xSb20-x-yAsyS34 with 0.02(2) < x < 0.34(2), 5.71(9) < y < 6.69(9)Tric. 1 : P1
ShimeniteTl5Sb21-yAsyS34Tric. 1 : P1
VallouiseiteAg3Tl21.5PbSb63As41.5S170Tric. 1 : P1
Structurally related to group(s):
Sartorite GroupA group of chemically and structurally very complex sulphosalts which are impossible to identify visually.

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Dalnegroite associated with RealgarAs4S4

Related Minerals - Strunz-mindat GroupingHide

2.HD.BoscardiniteTlPb4(Sb7As2)S18Tric. 1 : P1
2.HD.EnneasartoriteTl6Pb32As70S140Mon. 2/m : P21/b
2.HD.GungeriteTlAs5Sb4S13Orth. mmm (2/m 2/m 2/m) : Pbcn
2.HD.ShimeniteTl5Sb21-yAsyS34Tric. 1 : P1
2.HD.DewititeAgzTl10-x-zPb2xSb42-x-yAsyS68Tric. 1 : P1
2.HD.VallouiseiteAg3Tl21.5PbSb63As41.5S170Tric. 1 : P1
2.HD.BuyniteTlPb14As17S40Mon. 2 : P21
2.HD.GiuşcăiteAg2Tl4Pb4As20Sb2S40Mon. m
2.HD.05eChabournéiteAgzTl8-x-zPb4+2xSb40-x-yAsyS68 with 0.00 < x < 0.40(9), 16.15(3)< y < 19.11(10), 0.04(4) < z < 0.11(6)Tric. 1 : P1
2.HD.05LoránditeTlAsS2Mon. 2/m : P21/b
2.HD.05WeissbergiteTlSbS2Tric. 1 : P1
2.HD.15ChristiteTlHgAsS3Orth. mmm (2/m 2/m 2/m) : Cmca
2.HD.15RichardsollyiteTlPbAsS3Mon. 2/m : P21/b
2.HD.20JankovićiteTl5Sb9(As,Sb)4S22Tric. 1 : P1
2.HD.25RebuliteTl5Sb5As8S22Mon. 2/m : P21/b
2.HD.30ImhofiteTl5.8As15.4S26Mon. 2/m
2.HD.35EdenharteritePbTlAs3S6Orth. mm2 : Fdd2
2.HD.40JentschiteTlPbAs2SbS6Mon. 2/m
2.HD.45HutchinsoniteTlPbAs5S9Orth. mmm (2/m 2/m 2/m) : Pbca
2.HD.45ProtochabournéiteTl4-xPb2+2xSb20-x-yAsyS34 with 0.02(2) < x < 0.34(2), 5.71(9) < y < 6.69(9)Tric. 1 : P1
2.HD.50BernarditeTlAs5S8Mon. 2/m : P21/b
2.HD.55SicheriteTlAg2(As,Sb)3S6Orth.
2.HD.55GeueriteAg2Tl4Pb4As22S40Mon. 2/m : P21/b
2.HD.60GabrieliteTl6Ag3Cu6(As,Sb)9S21Tric. 1 : P1
2.HD.65TsygankoiteMn8Tl8Hg2(Sb21Pb2Tl)S48Mon. 2/m : B2/m
2.HD.70DrechsleriteTl4(Sb4-xAsx)S8 (1 < x < 2)Tric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for DalnegroiteHide

References for DalnegroiteHide

Localities for DalnegroiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
China
 
  • Hunan
    • Changde
      • Shimen Co.
        • Shimen deposit
Roth et al. (2017)
Russia
 
  • Sverdlovsk Oblast
    • Serovsky District
      • Turya river
        • Tur'insk
Kasatkin et al. (2018) +5 other references
Switzerland (TL)
 
  • Valais
    • Goms
      • Binn
        • Fäld
Nestola et al. (2009) +1 other reference
 
and/or  
Mindat Discussions Facebook Logo Instagram Logo Discord Logo
Mindat.org is an outreach project of the Hudson Institute of Mineralogy, a 501(c)(3) not-for-profit organization.
Copyright © mindat.org and the Hudson Institute of Mineralogy 1993-2024, except where stated. Most political location boundaries are © OpenStreetMap contributors. Mindat.org relies on the contributions of thousands of members and supporters. Founded in 2000 by Jolyon Ralph.
Privacy Policy - Terms & Conditions - Contact Us / DMCA issues - Report a bug/vulnerability Current server date and time: May 14, 2024 16:31:42 Page updated: March 12, 2024 17:39:06
Go to top of page