Dalnegroite
A valid IMA mineral species
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About Dalnegroite
Formula:
(Tl4Pb2)(As12Sb8)S34
Colour:
Red
Lustre:
Sub-Metallic
Hardness:
3 - 3½
Specific Gravity:
4.82 (Calculated)
Crystal System:
Triclinic
Member of:
Name:
Named in honor of Alberto Dal Negro (1941 - 1 April 2022, Padua, Veneto, Italy), Professor in Mineralogy and Crystallography, University of Padova, Italy, for "his contribution to the discovery and crystal-structure determination of several new mineral species".
Type Locality:
As-dominant analogue of chabournéite.
Structurally related to the Sartorite Group.
Note: Kasatkin et al. (2022) describe a triclinic possible "As analog of protochabournéite («protodalnegroite»)".
Structurally related to the Sartorite Group.
Note: Kasatkin et al. (2022) describe a triclinic possible "As analog of protochabournéite («protodalnegroite»)".
Unique Identifiers
Mindat ID:
39758
Long-form identifier:
mindat:1:1:39758:6
GUID
(UUID V4):
(UUID V4):
af01203e-2bbc-4683-8bcc-44e9030826e8
IMA Classification of Dalnegroite
Approved
IMA Formula:
Tl4Pb2(As,Sb)20S34
Approval year:
2009
First published:
2009
Classification of Dalnegroite
2.HD.05e
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
D : With Tl
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
D : With Tl
3.8.12.2
3 : SULFOSALTS
8 : 1 < ø < 2
3 : SULFOSALTS
8 : 1 < ø < 2
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Dnr | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Dalnegroite
Sub-Metallic
Transparency:
Opaque
Colour:
Red
Streak:
Brownish-red
Hardness:
3 - 3½ on Mohs scale
Hardness:
VHN25=87 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven
Density:
4.82 g/cm3 (Calculated)
Optical Data of Dalnegroite
Anisotropism:
Strong, bluish to green
Bireflectance:
Highly bireflectant
Reflectivity:
Wavelength | R1 | R2 |
---|---|---|
471.1nm | 45.6% | 46.1% |
548.3nm | 46.1% | 46.6% |
586.6nm | 46.3% | 47.0% |
652.3nm | 46.4% | 47.1% |
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 47.1%.
R1 shown in black, R2 shown in red
Internal Reflections:
Red
Pleochroism:
Weak
Comments:
White to a slightly greenish-grey
Chemistry of Dalnegroite
Mindat Formula:
(Tl4Pb2)(As12Sb8)S34
Crystallography of Dalnegroite
Crystal System:
Triclinic
Class (H-M):
1 - Pedial
Space Group:
P1
Cell Parameters:
a = 16.217(7) Å, b = 42.544(9) Å, c = 8.557(4) Å
α = 95.72(4)°, β = 90.25(4)°, γ = 96.78(4)°
α = 95.72(4)°, β = 90.25(4)°, γ = 96.78(4)°
Ratio:
a:b:c = 0.381 : 1 : 0.201
Unit Cell V:
5,832.53 ų (Calculated from Unit Cell)
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Show
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Big Balls | Small Balls | Just Balls | Spacefill
Polyhedra Off | Si Polyhedra | All Polyhedra
Remove metal-metal sticks
Display Options
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
Black Background | White Background
Perspective On | Perspective Off
2D | Stereo | Red-Blue | Red-Cyan
View
CIF File Best | x | y | z | a | b | c
CIF File Best | x | y | z | a | b | c
Rotation
Stop | Start
Stop | Start
Labels
Console Off | On | Grey | Yellow
Console Off | On | Grey | Yellow
Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0020126 | Dalnegroite | Bindi L, Nestola F, Guastoni A, Secco L (2013) The crystal structure of dalnegroite, Tl5-xPb2x(As,Sb)21-xS34: a masterpiece of structural complexity Mineralogical Magazine 74 999-1012 | 2013 | Lengenbach quarry, Binntal, Canton Valais, Switzerland | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.927 Å | (100) |
3.774 Å | (45) |
3.685 Å | (45) |
3.620 Å | (50) |
3.124 Å | (50) |
2.929 Å | (60) |
2.850 Å | (70) |
2.097 Å | (60) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-𝑇 alteration and/or metamorphism | |
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Dalnegroite
Place of Conservation of Type Material:
Museum of Mineralogy of the Department of Geosciences at the University of Padova, catalogue number MMP M762.
Associated Minerals at Type Locality:
Reference:
Nestola, F., A. Guastoni, L. Bindi, and L. Secco (2009) Dalnegroite,Tl^5-xPb^2x(As,Sb)^21-xS^34 , a new thallium sulphosalt from Lengenbach quarry, Binntal, Switzerland. Mineralogical Magazine: 73: 1027-1032
Synonyms of Dalnegroite
Relationship of Dalnegroite to other Species
Member of:
Other Members of this group:
Chabournéite | AgzTl8-x-zPb4+2xSb40-x-yAsyS68 with 0.00 < x < 0.40(9), 16.15(3)< y < 19.11(10), 0.04(4) < z < 0.11(6) | Tric. 1 : P1 |
Dewitite | AgzTl10-x-zPb2xSb42-x-yAsyS68 | Tric. 1 : P1 |
Protochabournéite | Tl4-xPb2+2xSb20-x-yAsyS34 with 0.02(2) < x < 0.34(2), 5.71(9) < y < 6.69(9) | Tric. 1 : P1 |
Shimenite | Tl5Sb21-yAsyS34 | Tric. 1 : P1 |
Vallouiseite | Ag3Tl21.5PbSb63As41.5S170 | Tric. 1 : P1 |
Structurally related to group(s):
Sartorite Group | A group of chemically and structurally very complex sulphosalts which are impossible to identify visually. |
Common Associates
Related Minerals - Strunz-mindat Grouping
2.HD. | Boscardinite | TlPb4(Sb7As2)S18 |
2.HD. | Enneasartorite | Tl6Pb32As70S140 |
2.HD. | Gungerite | TlAs5Sb4S13 |
2.HD. | Shimenite | Tl5Sb21-yAsyS34 |
2.HD. | Dewitite | AgzTl10-x-zPb2xSb42-x-yAsyS68 |
2.HD. | Vallouiseite | Ag3Tl21.5PbSb63As41.5S170 |
2.HD. | Buynite | TlPb14As17S40 |
2.HD. | Giuşcăite | Ag2Tl4Pb4As20Sb2S40 |
2.HD.05e | Chabournéite | AgzTl8-x-zPb4+2xSb40-x-yAsyS68 with 0.00 < x < 0.40(9), 16.15(3)< y < 19.11(10), 0.04(4) < z < 0.11(6) |
2.HD.05 | Lorándite | TlAsS2 |
2.HD.05 | Weissbergite | TlSbS2 |
2.HD.15 | Christite | TlHgAsS3 |
2.HD.15 | Richardsollyite | TlPbAsS3 |
2.HD.20 | Jankovićite | Tl5Sb9(As,Sb)4S22 |
2.HD.25 | Rebulite | Tl5Sb5As8S22 |
2.HD.30 | Imhofite | Tl5.8As15.4S26 |
2.HD.35 | Edenharterite | PbTlAs3S6 |
2.HD.40 | Jentschite | TlPbAs2SbS6 |
2.HD.45 | Hutchinsonite | TlPbAs5S9 |
2.HD.45 | Protochabournéite | Tl4-xPb2+2xSb20-x-yAsyS34 with 0.02(2) < x < 0.34(2), 5.71(9) < y < 6.69(9) |
2.HD.50 | Bernardite | TlAs5S8 |
2.HD.55 | Sicherite | TlAg2(As,Sb)3S6 |
2.HD.55 | Geuerite | Ag2Tl4Pb4As22S40 |
2.HD.60 | Gabrielite | Tl6Ag3Cu6(As,Sb)9S21 |
2.HD.65 | Tsygankoite | Mn8Tl8Hg2(Sb21Pb2Tl)S48 |
2.HD.70 | Drechslerite | Tl4(Sb4-xAsx)S8 (1 < x < 2) |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Dalnegroite
mindat.org URL:
https://www.mindat.org/min-39758.html
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References for Dalnegroite
Reference List:
Nestola, F., Guastoni, A., Bindi, L., Secco, L. (2009) Dalnegroite, Tl5–xPb2x(As,Sb)2l–xS34, a new thallium sulphosalt from Lengenbach quarry, Binntal, Switzerland. Mineralogical Magazine, 73 (6) 1027-1032 doi:10.1180/minmag.2009.073.6.1027 [see also Erratum: all refs. to jordanite should be to sartorite]
Bindi, L., Nestola, F., Guastoni, A., Secco, L. (2010) The crystal structure of dalnegroite, Tl5−xPb2x(As,Sb)21−xS34: a masterpiece of structural complexity. Mineralogical Magazine, 74 (6) 999-1012 doi:10.1180/minmag.2010.074.6.999
Nestola, F., Guastoni, A., Bindi, L., Secco, L. (2010) Erratum: Dalnegroite, Tl5–xPb2x(As,Sb)2l–xS34, a new thallium sulphosalt from Lengenbach quarry, Binntal, Switzerland. Mineralogical Magazine, 74 (1) 187 doi:10.1180/s0026461x0005711x
Localities for Dalnegroite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
China | |
| Roth et al. (2017) |
Russia | |
| Kasatkin et al. (2018) +5 other references |
Switzerland (TL) | |
| Nestola et al. (2009) +1 other reference |
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Lengenbach Quarry, Fäld, Binn, Goms, Valais, Switzerland