 | | Journal (article/letter/editorial) | | minerals Review The Lengenbach Quarry in Switzerland: Classic Locality for Rare Thallium Sulfosalts... * † Lengenbach Research Association (Forschungsgemeinschaft Lengenbach, FGL), Gemeinde Binn, Dorfstr...Dorfstr. 11, 3996 Binn, Switzerland Swiss Seismological Service, ETH Zurich, Sonneggstr. 5, 8092 Zurich, Switzerland;...Switzerland; phroth@sunrise.ch Correspondence: thomas.raber@kabelbw.de Anniversary publication—60 years...years of continuous mineral search at Lengenbach and 15 years of FGL. Received: 11 July 2018; Accepted: |  | Meisser, Nicolas, Roth, Philippe, Nestola, Fabrizio, Biagioni, Cristian, Bindi, Luca, Robyr, Martin (2017) Richardsollyite, TlPbAsS3, a new sulfosalt from the Lengenbach quarry, Binn Valley, Switzerland. European Journal of Mineralogy, 29 (4) 679-688 doi:10.1127/ejm/2017/0029-2649 | Journal (article/letter/editorial) | | TlPbAsS3, a new sulfosalt from the Lengenbach quarry, Binn Valley, Switzerland NICOLAS MEISSER1,*, PHILIPPE...discovered in the Lengenbach quarry, Imfeld, Binn Valley, Canton Valais, Switzerland, intimately associated...knowledge of the Lengenbach mineralogy during the first flourishing period of Lengenbach investigations,...thallium; arsenic; crystal structure; Lengenbach; Binn Valley; Switzerland. un 10 Musée cantonal de géologie...Lausanne, Anthropole, Dorigny, 1015 Lausanne, Switzerland *Corresponding author, e-mail: nicolas.meisser@unil |  | | Journal (article/letter/editorial) | | new Te-bearing sulfosalt from Lengenbach quarry, Binn valley, Switzerland: description and crystal structure...Pb-Cu-Ag-As-Tl bearing sulfosalts Lengenbach quarry in the Binn Valley, Valais, Switzerland. Debattistiite has been...identified in two specimens from zone 1 of the quarry in cavities in dolomitic marble with realgar, rutile...>330 °C similar to those reported for the other Lengenbach sulfosalts. The mineral was named for Luca De...mineralogist and expert on the minerals of Lengenbach quarry who collected the specimens of debattistiite |  | Orlandi, P., Biagioni, C., Bonaccorsi, E., Moëlo, Y., Paar, W. H. (2012) Lead-antimony sulfosalts from Tuscany (Italy) XII. Boscardinite, TlPb4(Sb7As2)Σ9S18, a new mineral species from the Monte Arsiccio mine: Occurrence and crystal structure. The Canadian Mineralogist, 50 (2) 235-251 doi:10.3749/canmin.50.2.235 | Journal (article/letter/editorial) | | (2009), benstonite: Biagioni & Orlandi (2010), chabournéite: Bonaccorsi et al. (2010), cymrite: Biagioni...Sant’Olga level: Hg-rich “andorite”, boulangerite, chabournéite, jamesonite, robinsonite, and zinkenite. Boscardinite...mineral species boscardinite and the occurrence of chabournéite (Bonaccorsi et al. 2010), the Monte Arsiccio...recently was the first thallium mineral identified (chabournéite from the Monte Arsiccio mine; Bonaccorsi et...___________________________________________ Chabournéite Tl5-xPb2x(Sb,As)21-xS34 16.346 42.602 8.534 |  | Orlandi, P., Biagioni, C., Moëlo, Y., Bonaccorsi, E., Paar, W. H. (2013) Lead-antimony sulfosalts from Tuscany (Italy) XIII. Protochabournéite, ~Tl2Pb(Sb9–8As1–2)∑10S17, from the Monte Arsiccio mine: Occurrence, crystal structure and relationship with chabournéite. The Canadian Mineralogist, 51 (3) 475-494 doi:10.3749/canmin.51.3.475 | Journal (article/letter/editorial) | | OCCURRENCE, CRYSTAL STRUCTURE AND RELATIONSHIP WITH CHABOURNÉITE Paolo ORLANDI§ and Cristian BIAGIONI Dipartimento...044. It agrees with the general features of chabournéite, but with a primitive unit cell, without any...precluding the 2a × 2c superstructure visible in chabournéite as well as in dalnegroite. Protochabournéite...Protochabournéite, like dalnegroite, belongs to the chabournéite homeotypic series. Keywords: protochabournéite, new...lead, antimony, arsenic, crystal structure, chabournéite series, Monte Arsiccio mine, Apuan Alps, Tuscany |  | | Journal (article/letter/editorial) | | © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed...mineralization, and is distributed in North Macedonia, Switzerland, and France [8–12]. The third one is related...include Apuan Alps; Tuscany in Italy [35], Lengenbach in Switzerland; and Yunfu in Guangdong, China [12,36]...remobilization of Tl [37]. Both Apuan Alps and Lengenbach are well known for the Tl-bearing sulfosalts...are [12,36]. associated with low[35], Lengenbach in Switzerland; Yunfu in Guangdong, China This type of |  | | Journal (article/letter/editorial) | | pyramidal groups. The same configuration occurs in chabournéite from Jas Roux (Biagioni et al., 2015), but the... as discussed by Biagioni et al. (2015) for chabournéite and protochabournéite. The other sites occurring...+ 2Tl) vs. As/(As + Sb) atomic ratio in the chabournéite series and boscardinite is shown in Fig. 4....atomic ratio in the chabournéite series and in boscardinite. Lozenges: chabournéite (data after Mantienne...are discussed in the text). Circles: Pb-excess chabournéite derivative or Asboscardinite derivative (data |  | | Journal (article/letter/editorial) | | rare lillianite homologues, as well as to the chabournéite group. The second one to the hutchinsonite family...happens at the famous locality of Lengenbach (Wallis, Switzerland), where this cocktail upkeeps the local...Parapierrotite synth. synth. protochabournéite chabournéite dalnegroite Tsygankoite rouxelite Simonite Synth...(TlPbAs3 S6 )–jentschite (TlPbAs2 SbS6 ) from Lengenbach, Binntal The structure-derived chemical formula...imhofite, given by [30] is Tl5.6As15S25.3. The (Switzerland) [32–34]. order-disorder model with full occupancies |  | Nestola, F., Guastoni, A., Bindi, L., Secco, L. (2009) Dalnegroite, Tl5–xPb2x(As,Sb)2l–xS34, a new thallium sulphosalt from Lengenbach quarry, Binntal, Switzerland. Mineralogical Magazine, 73 (6) 1027-1032 doi:10.1180/minmag.2009.073.6.1027 | Journal (article/letter/editorial) | | a new thallium sulphosalt from Lengenbach quarry, Binntal, Switzerland F. NESTOLA1,*, A. GUASTONI1, L...Tl4Pb2(As12Sb8)S20S34, is a new mineral from Lengenbach, Binntal, Switzerland. It occurs as anhedral to subhedral...sulphosalt, Lengenbach, Switzerland. Introduction SINCE the late eighteenth century the Lengenbach quarry, in...in Binntal, Switzerland, has been a unique source of a number of exclusive arsenic sulphosalts with additional...additional elements including Tl, Pb, Ag and Cu. The quarry is the type locality for 27 new mineral species |  | | Journal (article/letter/editorial) | | Universität Bern, Freiestrasse 3, CH-3012 Bern, Switzerland Geological Institute, Department of Mineralogy...from a sartorite crystal from Lengenbach (Binntal, Valais, Switzerland), yielded a ninefold superstructure:...known to occur only at the Lengenbach deposit, Binntal (Valais, Switzerland), where it is the most common...the Zuni mine (Colorado) and the Pitone marble quarry (Apuane Alps, Italy). The mineral sartorite was...given below. During routine investigations of Lengenbach minerals found in 1993 we discovered sartorite |  | Stepanov, Sergey Y., Palamarchuk, Roman S., Varlamov, Dmitry A., Kiseleva, Darya V., Sharpyonok, Ludmila N., Škoda, Radek, Kasatkin, Anatoly V. (2021) The Features of Native Gold in Ore-Bearing Breccias with Realgar-Orpiment Cement of the Vorontsovskoe Deposit (Northern Urals, Russia) Minerals, 11 (5) 541 doi:10.3390/min11050541 | Journal (article/letter/editorial) | | © 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed...province [14]. 2.2. Local Geological Setting A quarry in the Vorontsovskoe deposit has exposed a wedge...(b) the photograph of the northern wall of the quarry with a tectonic contact between marmorized limestone...realgar-orpiment cement (sample 2016/2), exposed in one of the quarry layers. The white dotted line shows the boundary...samples were collected in 2016–2019 at the Northern quarry of the Vorontsovskoe deposit at horizons from –40 |  | Orlandi, Paolo, Biagioni, Cristian, Bonaccorsi, Elena, Moëlo, Yves, Paar, Werner H. (2017) Lead-antimony sulfosalts from Tuscany (Italy) XXI. Bernarlottiite, Pb12(As10Sb6)Σ16S36, a new N = 3.5 member of the sartorite homologous series from the Ceragiola marble quarry: occurrence and crystal structure. European Journal of Mineralogy, 29 (4) 713-726 doi:10.1127/ejm/2017/0029-2625 | Journal (article/letter/editorial) | | sartorite homologous series from the Ceragiola marble quarry: occurrence and crystal structure 4 PAOLO ORLANDI1...of the Early Jurassic marbles from the Ceragiola quarry, Seravezza, Apuan Alps, Tuscany, Italy. Its name...most prolific deposit is the Lengenbach quarry, Binn Valley, Switzerland, being the type locality for...sartorite-group members have been known from Lengenbach since the 19th century (e.g., vom Rath, 1864)...Thallium was reported in “baumhauerites” from Lengenbach by Laroussi et al. (1989) in only small amount |  | Bindi, L., Nestola, F., Guastoni, A., Secco, L. (2010) The crystal structure of dalnegroite, Tl5−xPb2x(As,Sb)21−xS34: a masterpiece of structural complexity. Mineralogical Magazine, 74 (6) 999-1012 doi:10.1180/minmag.2010.074.6.999 | Journal (article/letter/editorial) | | was determined for a crystal from Lengenbach, Binn Valley, Switzerland. The structure is triclinic, space...crystal structure, thallium, sulphosalt, Lengenbach, Switzerland. Introduction DALNEGROITE, Tl5 xPb2x(As...described new mineral from the Lengenbach quarry, Binntal, Canton Valais, Switzerland (Nestola et al., 2010)...dalnegroite. Recently, a new sample from Lengenbach quarry was made available to the * E-mail: luca...thallium sulphosalt from Lengenbach quarry, Binntal, Canton Valais, Switzerland. Mineralogical Magazine |  | Topa, Dan, Kolitsch, Uwe, Makovicky, Emil, Stanley, Chris (2017) Écrinsite, AgTl3Pb4As11Sb9S36, a new thallium-rich homeotype of baumhauerite from the Jas Roux sulphosalt deposit, Parc national des Écrins, Hautes-Alpes, France. European Journal of Mineralogy, 29 (4) 689-700 doi:10.1127/ejm/2017/0029-2639 | Journal (article/letter/editorial) | | jasrouxite, stibnite, smithite, guettardite, chabournéite, pierrotite and As-bearing zinkenite. Écrinsite...classical sulphosalt localities of Lengenbach, Binn Valley (Wallis, Switzerland), and Madoc (Ontario, Canada)...aktashite (Znbearing), “andorite” (As-bearing), chabournéite*, getchellite, laffittite*, parapierrotite, pierrotite*...As)S4 (reaction product between smithite and chabournéite). Recently, the new mineral jasrouxite, Ag16Pb4Sb24As16S72...Tl, at the beginning also with Pb, producing chabournéite. The late Tl–As–Hg–Ag minerals of stage III |  | | Journal (article/letter/editorial) | | © 2022 by the author. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed...positions in the crystal structure of Pb–rich chabournéite and for which the authors suggested an empirical...several large sulfosalt structures such as Pb-rich chabournéite (Biagioni et al. [7]), argentoliveingite (Topa...19.225 Å (Topa, personal communication), Pb–chabournéite—Ag0.04Tl2.15Pb0.64Sb5.12As5.05S17.32, P1, a...argentoliveingite (average 0.010, 0.257, 0.311), Pb-rich chabournéite (average 𝐸𝐷𝐸𝑉 : 0.009, 0.254, (average EDEV |  | Moëlo, Yves, Makovicky, Emil, Mozgova, Nadejda N., Jambor, John L., Cook, Nigel, Pring, Allan, Paar, Werner, Nickel, Ernest H., Graeser, Stephan, Karup-Møller, Sven, Balic-unic, Tonči, Mumme, William G., Vurro, Filippo, Topa, Dan (2008) Sulfosalt systematics: a review. Report of the sulfosalt sub-committee of the IMA Commission on Ore Mineralogy. European Journal of Mineralogy, 20 (1) 7-62 doi:10.1127/0935-1221/2008/0020-1778 | Journal (article/letter/editorial) | | Naturhistorisches Museum, Augustinerstraße 2, 4001 Basel, Switzerland 10 Institute of Mineral Industry, Danish Technical...in distinct sites, or in distinct sulfosalts (Lengenbach deposit) jamesonite−benavidesite (e) Fe2+ ↔ Mn2+...Unit-cell-intergrowth derivative of dufrénoysite Chabournéite, Tl5 (Sb, As)21 S34 Def.: Mantienne (1974);...rathite varieties from the deposit of Lengenbach, Switzerland, have been described. A critical review...deposit of Einfisch or Anniviers valley (Wallis, Switzerland) corresponds to a Birich (∼ 5 wt.%) variety of |  | Kasatkin, Anatoly, Nestola, Fabrizio, Agakhanov, Atali, Škoda, Radek, Karpenko, Vladimir, Tsyganko, Mikhail, Plášil, Jakub (2018) Vorontsovite, (Hg5Cu)Σ6TlAs4S12, and Ferrovorontsovite, (Fe5Cu)Σ6TlAs4S12: The Tl- and Tl-Fe-Analogues of Galkhaite from the Vorontsovskoe Gold Deposit, Northern Urals, Russia. Minerals, 8 (5) 185 doi:10.3390/min8050185 | Journal (article/letter/editorial) | | com/journal/minerals Minerals 2018, 8, 185 2 of 13 chabournéite [2], christite [3], dalnegroite [4], parapierrotite...As2 S6 , dalnegroite (Tl4 Pb2 (As,Sb)20 S34 )—chabournéite (Tl4 Pb2 (Sb,As)20 S34 ) and parapierrotite...dalnegroite (As > Sb) is found much more often than chabournéite, while in the second pair, instead, parapierrotite...[CrossRef] Johan, Z.; Mantienne, J.; Picot, P. La chabournéite, un nouveau minéral thallifère. Bull. Minér...a new thallium sulphosalt from Lengenbach quarry, Binntal, Switzerland. Mineral. Mag. 2009, 73, 1027–1032 |  | | Journal (article/letter/editorial) | | a new thallium sulfosalt from Lengenbach quarry, Binntal, Switzerland. Mineral. Mag., 73, 1027–1032....new Tl-sulfosalt from the Lengenbach quarry, Binntal, Switzerland. The quarry is host to 15 Tl-sulfosalts...Dalnegroite is presumed to be isotypic with chabournéite and is its As-analogue. The mineral is named...on a sample from a manganese pod at the Merehead Quarry, near Cranmore, Somerset, England. The mineral |  | George, Luke L., Biagioni, Cristian, Lepore, Giovanni Orazio, Lacalamita, Maria, Agrosì, Giovanna, Capitani, Gian Carlo, Bonaccorsi, Elena, d'Acapito, Francesco (2019) The speciation of thallium in (Tl,Sb,As)-rich pyrite. Ore Geology Reviews, 107. 364-380 doi:10.1016/j.oregeorev.2019.02.031 | Journal (article/letter/editorial) | | and jentschite (TlPbAs2SbS6) from Lengenbach, Binntal (Switzerland). Schweiz. Mineral. Petrogr. Mitt...Tl-bearing sulfosalt from the Lengenbach quarry, Binn valley, Switzerland: Philrothite, TlAs3S5. Mineral...Sb)3S6, a new sulfosalt mineral from Lengenbach (Binntal, Switzerland): Description and structure determination...occurrence, crystal structure and relationship with chabournéite. Can. Mineral. 51, 475-494. Pasava J., Pertlik |  | Kasatkin, Anatoly, Makovicky, Emil, Plášil, Jakub, Škoda, Radek, Agakhanov, Atali, Karpenko, Vladimir, Nestola, Fabrizio (2018) Tsygankoite, Mn8Tl8Hg2(Sb21Pb2Tl)Σ24S48, a New Sulfosalt from the Vorontsovskoe Gold Deposit, Northern Urals, Russia. Minerals, 8 (5) 218 doi:10.3390/min8050218 | Journal (article/letter/editorial) | | Russia, similarly to the famous Lengenbach deposit in Switzerland or Allchar in Macedonia, was found...several very rare minerals—such as bernardite, chabournéite, christite, dalnegroite, hutchinsonite, imhofite...© 2018 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed |  | D’Orazio, Massimo, Biagioni, Cristian, Dini, Andrea, Vezzoni, Simone (2017) Thallium-rich pyrite ores from the Apuan Alps, Tuscany, Italy:constraints for their origin and environmental concerns. Mineralium Deposita, 52 (5) 687-707 doi:10.1007/s00126-016-0697-1 | Journal (article/letter/editorial) | | and/or remobilization processes (e.g., Lengenbach, Switzerland, Hoffman and Knill 1996; Lanmuchang, China...and genesis of the Lengenbach Pb-Zn-As-Tl-Ba mineralization, Binn Valley, Switzerland. Mineral Deposita...occurrence, crystal structure and relationship with chabournéite. Can Mineral 51:475–494 Orlandi P, Moëlo Y, |  | | Book | | indigenous people of the discovery area. Poudrette quarry, Mont Saint-Hilaire, Rouville County, Quebec, Canada...Mineralogy, University of Adelaide, Australia. Moculta quarry, Angaston, South Australia, Australia. From Gk...beryllium, calcium, and silicon. Cherbadung, Valais, Switzerland. Named after its discovery locality, at...Freiberg, Germany. Legenbach quarry, Binntal Valley, Valais, Switzerland. Solly, RH. (1902): Mineral....compound in 1952. Gerstenegg, Grimsel, Bern, Switzerland. Walenta, K. (1976): Schweiz. Mineral. Petrogr |  | Gaines, Richard V., Skinner, H. Catherine W., Foord, Eugene E., Mason, Brian, Rosenzweig, Abraham, King, Vandall T. (1997) Dana's New Mineralogy (8th ed.) Wiley-Interscience. p.1872 | Book (edition) | | Hans A. Stalder: Natural History Museum, Bern, Switzerland. Hugo Strunz: Institute of Mineralogy, Technical...Grasshopper Mt., Tulameen, BC, Canada; Kaltenberg, Valais, Switzerland; Bogota, near Canala, New Caledonia; Mt....intrusion, NWT, Canada; Selva, near Poschiavo, Switzerland; Oko, near Koti, Japan; Red Hills, Wairaw R....France; pic. Ste.-Marie-aux-Mines, Alsace, bach, Binn, SwitzerBlack Forest, and Marienberg, Saxony, Germany;...(1893-1973), professor of mineralogy, ETH, Zurich, Switzerland. Mon C2/m. a=11.066, b = 8.085, c = 7.965, B |  | | Book (volume) | | Editorial Office MDPI St. Alban-Anlage 66 4052 Basel, Switzerland This is a reprint of articles from the Special...© 2021 by the author. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed...© 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed...Petrology and Geochemistry (EMPG-XV), ETH Zurich, Switzerland, 5–8 June 2016. 112. Palyanova, G.A. Gold and...Stoichiometric arsenopyrite, FeAsS, from La Roche–Balue Quarry, Loire–Atlantique, France: Crystal structure and |
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Lengenbach Quarry, Fäld, Binn, Goms, Valais, Switzerland