 | Brigatti, Maria Franca, Affronte, Marco, Elmi, Chiara, Malferrari, Daniele, Laurora, Angela (2015) Trioctahedral Fe-rich micas: Relationships between magnetic behavior and crystal chemistry. American Mineralogist, 100 (10) 2231-2241 doi:10.2138/am-2015-5145 | Journal (article/letter/editorial) | | belong to the phlogopite-annite join (space group C2/m), two are Mg-rich annite and two are Fe-rich phlogopite...mica join from phlogopite [KMg32+AlSi3O10(OH)2] to annite [KFe2+ 3 AlSi3O10(OH)2] (Bailey1984). Tetrahedral...phlogopite, 2+ and tetra-ferri-annite [KFe3 Fe3+Si3O10(OH)2] from annite. In 4+ [vi] trioctahedral lithian...M1 site in trioctahedral micas of the phlogopite-annite join, whereas it can be partially ordered in trioctahedral...and specifically for trioctahedral micas close to annite in composition, are remarkably anisotropic, with |  | Namur, Olivier, Hatert, Frédéric Grandjean, Long, Gary J., Krins, Natacha, Fransolet, André-Mathieu Vander Auwera, Charlier, Bernard (2009) Ti substitution mechanisms in phlogopites from the Suwalki massif-type anorthosite, NE Poland. European Journal of Mineralogy, 21 (2) 397-406 doi:10.1127/0935-1221/2009/0021-1894 | Journal (article/letter/editorial) | | University of Missouri-Rolla, Missouri 65409-0010, USA 5 Département de Chimie, Laboratoire de Chimie inorganique...the infrared spectra of synthetic micas on the annite-siderophyllite solid solution, is affected by the...data set of phlogopites from metapelites from West Maine and SouthCentral Massachusetts. It can be written:...Mineral., 76, 1174-1183. Cesare, B., Cruciani, G., Russo, U. (2003): Hydrogen deficiency in Ti-rich biotite... vol. 1, G.J. Long, ed. Plenum Press, New-York, USA. 443-510. Cruciani, G. & Zanazzi, P.F. (1994): Cation |  | Balassone, Giuseppina, Scordari, Fernando, Lacalamita, Maria, Schingaro, Emanuela, Mormone, Angela, Piochi, Monica, Petti, Carmela, Mondillo, Nicola (2013) Trioctahedral micas in xenolithic ejecta from recent volcanism of the Somma-Vesuvius (Italy): Crystal chemistry and genetic inferences. Lithos, 160. 84-97 doi:10.1016/j.lithos.2012.12.004 | Journal (article/letter/editorial) | | phenomena. T Although ubiquitous in their products (Russo and Punzo, 2004), trioctahedral micas of the RI...phlogopites (Joron et al., 1987). RI P According to Russo and Punzo (2004), the only mica species occurring...olivine, nepheline, spinel, galena and amphibole (Russo and Punzo, 2004). The mica crystals also occur in... MA NU Figure 6 shows that in the phlogopite-annite-siderophyllite-eastonite plane, the study micas...Madison, Wisconsin, USA. Bruker, 2003b. APEX2. Bruker AXS Inc., Madison, Wisconsin, USA. Cesare, B., Cruciani |  | | Journal (article/letter/editorial) | | VVP. The mica megacryst was found in the Borcola quarry (Val d’Adige, north-eastern Italy) in a dyke intruding...co-ordination in mica compositions along the phlogopite-annite join. Both biotite generations studied here have...contents in mica composition on the phlogopite-annite join can be very low (Fe3+/Fetot = 0.02–0.03) under...the octahedral sites of mica along the phlogopite-annite join (Cesare et al., 2003 and reference therein)...Mineral., 81, 913-927. Cesare, B., Cruciani, G., Russo, U. (2003): Hydrogen deficiency in Ti-rich biotite |  | | Journal (article/letter/editorial) | | Sassetto (Italy) and in granite of Oquossoc, western Maine (Bigi and Brigatti 1994; Laurora et al. 2007; Brigatti...Table 1). All the samples belong to the phlogopite-annite solid solution and have high TiO2 (*4.9 wt%) and...dioctahedral micas in metamorphic sequences from western Maine. Am Mineral 93:396–408 Bruker (2003a) COSMO (Version...Inc., Madison, Wisconsin Cesare B, Cruciani G, Russo U (2003) Hydrogen deficiency in Ti-rich biotite...crystal structures of one-layer phlogopite and annite. Am Mineral 58:889–900 Kogure T (2002) Investigation |  | | Journal (article/letter/editorial) | | investigated in this study are from kimberlites, Tongren County, Guizhou Province, China. The chromites were checked...minerals include phlogopite-annite series (Rancourt et al. 1994a), synthetic annite (Rancourt et al. 1994b)...1994b), (OH, F) annite (Rancourt et al. 1996), mica (Redhammer 1998a; Redhammer et al. 2000), synthetic ferritschermak’s...Contrib Mineral Petrol 104: 453–462 Carbonin S, Russo U, Guista Adella (1996) Cation distribution in some...quadrupole splitting distributions in the phlogopite-annite series. Phys Chem Miner 21: 258–267 494 Rancourt |  | | Journal (article/letter/editorial) | | Ti, or Fe3+) relative to the simple phlogopite–annite system investigated by Ferry & Spear (1978). The...the simplest remedy is to adjust the enthalpy of annite (as this end-member is less well constrained by...Petrology, 120, 270–291. Cesare, B., Cruciani, G. & Russo, U., 2003. Hydrogen deficiency in Ti-rich biotite...The stability of annite + quartz: reversed experimental data for the reaction 2 annite + 3 quartz ¼ 2 sanidine...melting of pelitic rock from Morton Pass, Wyoming, USA. Journal of Metamorphic Geology, 22, 65–78. Guidotti |  | Chukanov, Nikita V., Aksenov, Sergey M., Kasatkin, Anatoly V., Škoda, Radek, Nestola, Fabrizio, Nodari, Luca, Ryanskaya, Anastasia D., Rastsvetaeva, Ramiza K. (2019) 3T polytype of an iron-rich oxyphlogopite from the Bartoy volcanic field, Transbaikalia: Mössbauer, infrared, Raman spectroscopy, and crystal structure. Physics and Chemistry of Minerals, 46 (10) 899-908 doi:10.1007/s00269-019-01049-7 | Journal (article/letter/editorial) | | “Protolithionite-3T” was found at Brook Mountain (USA), granitic rocks from Kymi stock (Finland) (Weiss...pegmatites of the anorogenic Pikes Peak batholith (USA) (Brigatti et al. 2003). Phlogopite-3T was described... Acta Cryst A 29:266–271 Cesare B, Cruciani G, Russo U (2003) Hydrogen deficiency in Ti-rich biotite...Mineral 88:583–595 Cesare B, Meli S, Nodari L, Russo U (2005) Fe3+ reduction during biotite melting...9:1183–1190 Pavese A, Curetti N, Ferraris G, Ivaldi G, Russo U, Ibberson R (2003) Deprotonation and order-disorder |  | Ventruti, Gennaro, Levy, Davide, Pavese, Alessandro, Scordari, Fernando, Suard, Emmanuelle (2009) High-temperature treatment, hydrogen behaviour and cation partitioning of a FeTi bearing volcanic phlogopite by in situ neutron powder diffraction and FTIR spectroscopy. European Journal of Mineralogy, 21 (2) 385-396 doi:10.1127/0935-1221/2009/0021-1903 | Journal (article/letter/editorial) | | trioctahedral micas studied belong to the phlogopite-annite solid solution [annitic component Fetot/(Fetot...Crystallogr., 17, 142–146. Cesare, B., Cruciani, G., Russo, U. (2003): Hydrogen deficiency in Ti-rich biotite...Rieder, M., Drábek, M. (1999): Cs-tetra-ferri-annite:’’ High-pressure and high-temperature behavior...crystal structures of one layer phlogopite and annite. Am. Mineral., 58, 889–900. Henry, D.J. & Guidotti...Curetti, N., Diella, V., Levy, D., Dapiaggi, M., Russo, U. (2007): P–V and T–V Equations of State of natural |  | Schingaro, E., Scordari, F., Matarrese, S., Mesto, E., Stoppa, F., Rosatelli, G., Pedrazzi, G. (2007) Phlogopite from the Ventaruolo subsynthem volcanics (Mt Vulture, Italy): a multi-method study. Mineralogical Magazine, 71 (5) 519-537 doi:10.1180/minmag.2007.071.5.519 | Journal (article/letter/editorial) | | this geohygrometer. Indeed, the choice of a proper annite activity model depends on a full understanding...true trioctahedral micas between, or close to, the annite [ K F e 23 + A l S i 3 O 1 0 ( O H ) 2 ] phlogopite...respect to those measured in close-to-end-member annite (10.3235(4) Å, Redhammer and Roth, 2002) and phlogopite...Madison, Wisconsin, USA. Bruker (2003b) SAINT. Bruker AXS Inc., Madison, Wisconsin, USA. Burkhard, D.J.M...Mineralogist, 84, 493 505. Cesare, B., Cruciani, G. and Russo, U. (2003) Hydrogen deficiency in Ti-rich biotite |  | | Journal (article/letter/editorial) | | defined by the Ni-NiO buffer. The synthesis of the annite-fluoroannite series (Table 1) is described by Rancourt...buffer (Eugster and Wones 1962). Samples of the annite-oxyannite-ferrioxyannite series are described by...(2001). The starting sample was the same synthetic annite sample (labeled IKO-Ann in the present work) that...of dissolved K. To ensure K stoichiometry of the annite product, therefore, the water was replaced by a...measured not measured not measured not measured annite-fluoroannite series ‡‡ {K}[Fe3]O10F0.0(OH)2 |  | Schingaro, E., Lacalamita, M., Scordari, F., Brigatti, M. F., Pedrazzi, G. (2011) Crystal chemistry of Ti-rich fluorophlogopite from Presidente Olegario, Alto Paranaiba igneous province, Brazil. American Mineralogist, 96 (5) 732-743 doi:10.2138/am.2011.3666 | Journal (article/letter/editorial) | | 2009); open symbols with cross = natural end-member annite and synthetic near end-member phlogopite (circle:...chemistry of fluorannite and its relationships to annite. Mineralogical Magazine, 71, 683–690. Bruker (2003a)...Madison, Wisconsin, USA. ——— (2003b) APEX2. Bruker AXS Inc., Madison, Wisconsin, USA. Cesare, B., Cruciani...Cruciani, G., and Russo, U. (2003) Hydrogen deficiency in Ti-rich biotite from anatectic metapelites (El...crystal structures of one-layer phlogopite and annite. American Mineralogist, 58, 889–900. Hazen, R.M |  | Mesto, Ernesto, Schingaro, Emanuela, Scordari, Fernando, Ottolini, Luisa (2006) An electron microprobe analysis, secondary ion mass spectrometry, and single-crystal X-ray diffraction study of phlogopites from Mt. Vulture, Potenza, Italy: Consideration of cation partitioning. American Mineralogist, 91 (1) 182-190 doi:10.2138/am.2006.1882 | Journal (article/letter/editorial) | | trioctahedral micas-1M mainly consist of phlogopite-annite solid solutions with a minor component of brittle...INTRODUCTION Trioctahedral micas along the phlogopite-annite join are of widespread occurrence and of importance...trioctahedral micas-1M mainly consist of phlogopite-annite solid solutions with a minor component of brittle...affected by Ti content in micas along the phlogopite-annite join. Figure 1 (modiÞed from Brigatti et al. 2003)...occur at Mt. Vulture. The micas are phlogopite-annite solid solutions with a minor component of brittle |  | Laurora, A., Brigatti, M. F., Mottana, A., Malferrari, D., Caprilli, E. (2007) Crystal chemistry of trioctahedral micas in alkaline and subalkaline volcanic rocks: A case study from Mt. Sassetto (Tolfa district, Latium, central Italy) American Mineralogist, 92 (4) 468-480 doi:10.2138/am.2007.2339 | Journal (article/letter/editorial) | | composition from ferroan phlogopite to magnesian annite. Heterovalent octahedral substitutions are mainly...00/DOI: 10.2138/am.2007.2339 468 the phlogopite–annite join are affected by different substitution processes...composition from ferroan phlogopite to magnesian annite (Fig. 4a, Table 31). The mean value of Mg/(Mg +...and among the lowest refined for the phlogopite–annite join micas (Brigatti and Guggenheim 2002; Cruciani...crystal-chemical mechanisms associated with Fe oxidation in annite was provided by Rancourt et al. (2001) and by Virgo |  | Schingaro, E., Lacalamita, M., Scordari, F., Mesto, E. (2013) 3T-phlogopite from Kasenyi kamafugite (SW Uganda): EPMA, XPS, FTIR, and SCXRD study. American Mineralogist, 98 (4) 709-717 doi:10.2138/am.2013.4283 | Journal (article/letter/editorial) | | mostly belonging to the muscovite-polylithionite-annite system. X‑ray diffraction studies were carried...lithian siderophyllite. More recently, 3T Mg-rich annite has been revealed by TEM investigations as coexisting...structural study on a 3T mica of the phlogopite-annite solid solution. All the analyses were carried out...Wisconsin, U.S.A. Cesare, B., Cruciani, G., and Russo, U. (2003) Hydrogen deficiency in Ti-rich biotite...crystal structures of one-layer phlogopite and annite. American Mineralogist, 58, 889–900. Hendricks |  | Matarrese, S., Schingaro, E., Scordari, F., Stoppa, F., Rosatelli, G., Pedrazzi, G., Ottolini, L. (2008) Crystal chemistry of phlogopite from Vulture-S. Michele Subsynthem volcanic rocks (Mt. Vulture, Italy) and volcanological implications. American Mineralogist, 93 (2) 426-437 doi:10.2138/am.2008.2587 | Journal (article/letter/editorial) | | solutions between phlogopite [KMg3AlSi3O10(OH)2] and annite [KFe32+AlSi3O10(OH)2] with Ti 0.10–0.38 apfu, Ba...crystal chemistry below. Figure 1 is a plot of the annite component [Fetot/(Fetot + Mg)], vs. the Ti content...Ventaruolo Subsynthem, the VUT191 phlogopite has an annite component that spans almost the whole interval...Fe/(Fe + Mg), thought to represent the amount of the annite component vs. Ti content for micas from Monte Vulture...when compared with those of close-to-end-member annite [10.3235(4) Å, Redhammer and Roth (2002)] and close-to-end-member |  | | Journal (article/letter/editorial) | | end-members phlogopite, annite, eastonite and ordered biotite (obi) 2 3 phlogopite þ 13 annite ¼ obi; ð1Þ with...Magazine, 61, 15–27. Cesare, B., Cruciani, G. & Russo, U., 2003. Hydrogen deficiency in Ti-rich biotite...88, 583–595. Cesare, B., Meli, S., Nodari, L. & Russo, U., 2005. Fe36+ reduction during biotite melting |  | Scordari, Fernando, Ventruti, Gennaro, Sabato, Anna, Bellatreccia, Fabio, Ventura, Giancarlo Della, Pedrazzi, Giuseppe (2006) Ti-rich phlogopite from Mt. Vulture (Potenza, Italy) investigated by a multianalytical approach: substitutional mechanisms and orientation of the OH dipoles. European Journal of Mineralogy, 18 (3) 379-391 doi:10.1127/0935-1221/2006/0018-0379 | Journal (article/letter/editorial) | | Madison, Wisconsin, USA. – (2003): APEX2. Bruker AXS Inc., Madison, Wisconsin, USA. Caggianelli, A., De...Petrol., 41, 215-227. Cesare, B., Cruciani, G., Russo, U. (2003): Hydrogen deficiency in Ti-rich biotite...The crystal structure of one layer phlogopite and annite. Am. Mineral., 58, 889-900. Johnston, C.T., Agnew...Quadrupole Splitting Distributions in the phlogopite-annite series Phys. Chem. Minerals, 21, 258-267. Redhammer...structural properties of synthetic micas on the annite-siderophyllite binary: Synthesis, crystal structure |  | | Journal (article/letter/editorial) | | pyrrhotites in some sulphide ores from Norway, 303 Annite (Fe-bearing), from Mont Saint-Hilaire, Quebec... and cervelleite: new occurrences from Montana, USA, 871 Beryllium, lithium and boron in ocean island...Pala pegmatite district, San Diego Co., California, USA, 387 Bismuth-bearing assemblages, from the Northern...from Juab County, Utah, 653 Cervelleite, and benleonardite: new occurrences from Montana, USA, 871 CHALAPATHIRAO...pegmatite district, San Diego Co., California, 997 USA, 387 Clinopyroxene, in-situ differentiation within |  | | Journal (article/letter/editorial) | | more readily than trans sites (M1) in synthetic annite and ferriannite. Diffraction techniques were used...micas from the SA sample belong to the phlogopite-annite solid solution [XFe = Fetot/(Fetot+Mg) ≈ 0.25]...Mineralogist, 85, 480–488. Cesare, B., Cruciani, G., and Russo, U. (2003) Hydrogen deficiency in Ti-rich biotite...Rieder, M., and Drábek, M. (1999) “Cs-tetraferri-annite:” High-pressure and high-temperature behavior of...Mössbauer and X-ray studies on the oxidation of annite and ferriannite. Physics and Chemistry of Minerals |  | Lacalamita, M., Schingaro, E., Scordari, F., Ventruti, G., Fabbrizio, A., Pedrazzi, G. (2011) Substitution mechanisms and implications for the estimate of water fugacity for Ti-rich phlogopite from Mt. Vulture, Potenza, Italy. American Mineralogist, 96 (8) 1381-1391 doi:10.2138/am.2011.3772 | Journal (article/letter/editorial) | | 0.82. A partly ionic model was used to estimate annite activity, starting from experimentally determined...this geohygrometer critically depends on a proper annite activity model and a full understanding of substitution...Chantilly, Virginia. Cesare, B., Cruciani, G., and Russo, U. (2003) Hydrogen deficiency in Ti-rich biotite...crystal structures of one-layer phlogopite and annite. American Mineralogist, 58, 889–900. Henry, D.J...[6]Fe3+, and [6]Fe2+ site populations in synthetic annite by Mössbauer spectroscopy. American Mineralogist |  | Pavese, A., Curetti, N., Diella, V., Levy, D., Dapiaggi, M., Russo, U. (2007) P-V and T-V Equations of State of natural biotite: An in-situ high-pressure and high-temperature powder diffraction study, combined with Mossbauer spectroscopy. American Mineralogist, 92 (7) 1158-1164 doi:10.2138/am.2007.2359 | Journal (article/letter/editorial) | | 1625–1630. Cesare, B., Meli, S., Nodali, L., and Russo, U. (2005) Fe3+ reduction during biotite melting...Pavese, A., Curetti, N., Ferraris, G., Ivaldi, G., Russo, U., and Ibberson, R. (2003b) Deprotonation and...Analysis of Fe K-edge XANES spectra in the phlogopite–annite and phlogopite–tetraferriphlogopite joins on the |  | | Journal (article/letter/editorial) | | 81, 913-927. na Cesare, B., Cruciani, G., and Russo, U. (2003) Hydrogen deficiency in Ti-rich biotite...583-595. Jo Cesare, B., Meli, S., Nodari, L., and Russo, U. (2005) Fe 3+ reduction during biotite melting...Mössbauer and X-ray studies on the oxidation of annite and ferriannite. Physics and Chemistry of Minerals...structural properties of synthetic micas on the annite-siderophyllite binary: Synthesis, crystal structure |  | Scordari, F., Schingaro, E., Ventruti, G., Nicotra, E., Viccaro, M., Tagliani, S. M. (2013) Fluorophlogopite from Piano delle Concazze (Mt. Etna, Italy): Crystal chemistry and implications for the crystallization conditions. American Mineralogist, 98 (5) 1017-1025 doi:10.2138/am.2013.4225 | Journal (article/letter/editorial) | | structural changes due to F content with respect to annite. Schingaro et al. (2011) studying various F-rich...chemistry of fluorannite and its relationships to annite. Mineralogical Magazine, 71, 683–690. Bruker (2008a)...Research, 79, 47–61. Cesare, B., Cruciani, G., and Russo, U. (2003) Hydrogen deficiency in Ti-rich biotite...crystal structures of one-layer phlogopite and annite. American Mineralogist, 58, 889–900. Joswig, V |  | Scordari, Fernando, Schingaro, Emanuela, Ventruti, Gennaro, Lacalamita, Maria, Ottolini, Luisa (2008) Red micas from basal ignimbrites of Mt. Vulture (Italy): interlayer content appraisal by a multi-methodic approach. Physics and Chemistry of Minerals, 35 (3) 163-174 doi:10.1007/s00269-007-0208-0 | Journal (article/letter/editorial) | | ignimbrites of Mt. Vulture. Those minerals are phlogopite-annite solid solutions with a minor component of brittle...(phlogopite) composition within a matrix of Fe-rich (annite) and Ti-rich composition. The largest domain is...Mineral Petrol 41:215–227 Cesare B, Cruciani G, Russo U (2003) Hydrogen deficiency in Ti-rich biotite...The crystal structure of one layer phlogopite and annite. Am Mineral 58:889–900 Henry DJ, Guidotti CV, Thompson |
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