Jasonsmithite
A valid IMA mineral species
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About Jasonsmithite
Formula:
Mn2+4ZnAl(PO4)4(OH)(H2O)7 · 3.5H2O
Colour:
Colorless to light brown (indistinct color boundaries)
Lustre:
Vitreous
Hardness:
2
Specific Gravity:
2.63
Crystal System:
Monoclinic
Name:
Named by Anthony R. Kampf, Aaron J. Celestian, Barbara P., Nash, in honor of Jason Boyd Smith (b. 1977), geologist and mineral collector from Charlotte, North Carolina, USA. He found the type specimen.
Chemically a bit similar to ferraioloite.
New structure type.
Found in the east dump.
From type description:
"With H2O groups removed, the framework has a void space of 70.2% per unit cell, and a framework density of 14.5 polyhedral atoms/1000 Å3, which would place jasonsmithite among the most porous minerals."
New structure type.
Found in the east dump.
From type description:
"With H2O groups removed, the framework has a void space of 70.2% per unit cell, and a framework density of 14.5 polyhedral atoms/1000 Å3, which would place jasonsmithite among the most porous minerals."
Unique Identifiers
Mindat ID:
54363
Long-form identifier:
mindat:1:1:54363:5
GUID
(UUID V4):
(UUID V4):
94d7e7ba-daaa-4a53-97ae-d0a5226769fa
IMA Classification of Jasonsmithite
Approved
First published:
2021
Classification of Jasonsmithite
8.DG.
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
G : With large and medium-sized cations, (OH, etc.):RO4< 0.5:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
G : With large and medium-sized cations, (OH, etc.):RO4< 0.5:1
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Jsm | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Jasonsmithite
Vitreous
Transparency:
Transparent
Colour:
Colorless to light brown (indistinct color boundaries)
Comment:
Possibly from submicroscopic inclusions
Streak:
White
Hardness:
2 on Mohs scale
Hardness Data:
Measured
Comment:
Based on scratch tests
Tenacity:
Brittle
Cleavage:
Perfect
{001}
{001}
Fracture:
Irregular/Uneven
Density:
2.63(2) g/cm3 (Measured) 2.630 g/cm3 (Calculated)
Comment:
Measured by floatation. Calculated from empirical formula; 2.627 g/cm3 when calculated from ideal formula.
Optical Data of Jasonsmithite
Type:
Biaxial (-)
RI values:
nα = 1.561(2) nβ = 1.580(2) nγ = 1.581(2)
2V:
Measured: 25° (5), Calculated: 25.6°
Max Birefringence:
δ = 0.020
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
moderate, r < v
Pleochroism:
Not Visible
Comments:
Y = b, X ^ c = 18° in obtuse β
Chemistry of Jasonsmithite
Mindat Formula:
Mn2+4ZnAl(PO4)4(OH)(H2O)7 · 3.5H2O
Crystallography of Jasonsmithite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 8.5822(3) Å, b = 13.1770(6) Å, c = 20.304(1) Å
β = 98.485(7)°
β = 98.485(7)°
Ratio:
a:b:c = 0.651 : 1 : 1.541
Unit Cell V:
2271 ų
Z:
4
Morphology:
Slightly flattened prisms with wedge-shaped terminations. Elongation parallel to [100] and flattening on {001}. The crystal forms are {010}, {001}, {011), and {11-1}.
Twinning:
None observed
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
10.98 Å | (43) |
10.08 Å | (100) |
7.95 Å | (18) |
4.074 Å | (19) |
3.029 Å | (30) |
2.846 Å | (18) |
2.605 Å | (29) |
2.543 Å | (24) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Near-surface Processes | |
22 : Hydration and low-𝑇 subsurface aqueous alteration (see also #23) |
Type Occurrence of Jasonsmithite
General Appearance of Type Material:
Colorless to light brown, slightly flattened prisms to about 1 mm in length with wedge-shaped terminations. Commonly in subparallel intergrowths.
Place of Conservation of Type Material:
mineralogical collections of the Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA, catalogue numbers 74374 (holotype), 74375 (cotype) and 74376 (cotype)
Geological Setting of Type Material:
Pegmatite; late stage, low temperature alteration.
Associated Minerals at Type Locality:
Reference:
Kampf, A.R., Celestian, A.J., Nash, B.P. (2021) Jasonsmithite, a new phosphate mineral with a complex microporous framework, from the Foote mine, North Carolina, U.S.A.. American Mineralogist: 106: 174–179.
Synonyms of Jasonsmithite
Common Associates
Related Minerals - Strunz-mindat Grouping
8.DG. | Davidbrownite-(NH4) | (NH4)5(V4+O)2(C2O4)[PO2.75(OH)1.25]4 · 3H2O |
8.DG. | Relianceite-(K) | K4Mg(V4+O)2(C2O4)(PO3OH)4(H2O)10 |
8.DG. | Pleysteinite | [(H2O)0.5K0.5]2Mn2Al3(PO4)4F2 · 14H2O |
8.DG. | Rewitzerite | [K(H2O)]Mn2Al3(PO4)4(OH)2 · 14H2O |
8.DG.05 | Lavendulan | NaCaCu5(AsO4)4Cl · 5H2O |
8.DG.05 | Sampleite | NaCaCu5(PO4)4Cl · 5H2O |
8.DG.05 | Shubnikovite | Ca2Cu8(AsO4)6(OH)Cl · 7H2O |
8.DG.05 | Zdenĕkite | NaPbCu5(AsO4)4Cl · 5H2O |
8.DG.05 | Lemanskiite | NaCaCu5(AsO4)4Cl · 3H2O |
Fluorescence of Jasonsmithite
Does not fluoresce under LW or SW UV
Other Information
Notes:
Easily soluble in dilute HCl at room temperature
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Jasonsmithite
mindat.org URL:
https://www.mindat.org/min-54363.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Jasonsmithite
Reference List:
Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2020) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) - Newsletter 54. European Journal of Mineralogy, 32 (2) 275-283 doi:10.5194/ejm-32-275-2020
Localities for Jasonsmithite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
USA (TL) | |
| Miyawaki et al. (2020) +1 other reference |
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Foote Lithium Co. Mine, Kings Mountain, Cleveland County, North Carolina, USA