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Jasonsmithite

A valid IMA mineral species
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About JasonsmithiteHide

05438340016114345247141.jpg
Jason B. Smith
Formula:
Mn2+4ZnAl(PO4)4(OH)(H2O)7 · 3.5H2O
Colour:
Colorless to light brown (indistinct color boundaries)
Lustre:
Vitreous
Hardness:
2
Specific Gravity:
2.63
Crystal System:
Monoclinic
Name:
Named by Anthony R. Kampf, Aaron J. Celestian, Barbara P., Nash, in honor of Jason Boyd Smith (b. 1977), geologist and mineral collector from Charlotte, North Carolina, USA. He found the type specimen.
Chemically a bit similar to ferraioloite.

New structure type.

Found in the east dump.


From type description:
"With H2O groups removed, the framework has a void space of 70.2% per unit cell, and a framework density of 14.5 polyhedral atoms/1000 Å3, which would place jasonsmithite among the most porous minerals."


Unique IdentifiersHide

Mindat ID:
54363
Long-form identifier:
mindat:1:1:54363:5
GUID
(UUID V4):
94d7e7ba-daaa-4a53-97ae-d0a5226769fa

IMA Classification of JasonsmithiteHide

Classification of JasonsmithiteHide

8.DG.

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
G : With large and medium-sized cations, (OH, etc.):RO4< 0.5:1

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
JsmIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of JasonsmithiteHide

Vitreous
Transparency:
Transparent
Colour:
Colorless to light brown (indistinct color boundaries)
Comment:
Possibly from submicroscopic inclusions
Streak:
White
Hardness:
Hardness Data:
Measured
Comment:
Based on scratch tests
Tenacity:
Brittle
Cleavage:
Perfect
{001}
Fracture:
Irregular/Uneven
Density:
2.63(2) g/cm3 (Measured)    2.630 g/cm3 (Calculated)
Comment:
Measured by floatation. Calculated from empirical formula; 2.627 g/cm3 when calculated from ideal formula.

Optical Data of JasonsmithiteHide

Type:
Biaxial (-)
RI values:
nα = 1.561(2) nβ = 1.580(2) nγ = 1.581(2)
2V:
Measured: 25° (5), Calculated: 25.6°
Max Birefringence:
δ = 0.020
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
moderate, r < v
Pleochroism:
Not Visible
Comments:
Y = b, X ^ c = 18° in obtuse β

Chemistry of JasonsmithiteHide

Mindat Formula:
Mn2+4ZnAl(PO4)4(OH)(H2O)7 · 3.5H2O

Crystallography of JasonsmithiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 8.5822(3) Å, b = 13.1770(6) Å, c = 20.304(1) Å
β = 98.485(7)°
Ratio:
a:b:c = 0.651 : 1 : 1.541
Unit Cell V:
2271 ų
Z:
4
Morphology:
Slightly flattened prisms with wedge-shaped terminations. Elongation parallel to [100] and flattening on {001}. The crystal forms are {010}, {001}, {011), and {11-1}.
Twinning:
None observed

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
10.98 Å(43)
10.08 Å(100)
7.95 Å(18)
4.074 Å(19)
3.029 Å(30)
2.846 Å(18)
2.605 Å(29)
2.543 Å(24)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
22 : Hydration and low-𝑇 subsurface aqueous alteration (see also #23)

Type Occurrence of JasonsmithiteHide

General Appearance of Type Material:
Colorless to light brown, slightly flattened prisms to about 1 mm in length with wedge-shaped terminations. Commonly in subparallel intergrowths.
Place of Conservation of Type Material:
mineralogical collections of the Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA, catalogue numbers 74374 (holotype), 74375 (cotype) and 74376 (cotype)
Geological Setting of Type Material:
Pegmatite; late stage, low temperature alteration.
Associated Minerals at Type Locality:
Reference:
Kampf, A.R., Celestian, A.J., Nash, B.P. (2021) Jasonsmithite, a new phosphate mineral with a complex microporous framework, from the Foote mine, North Carolina, U.S.A.. American Mineralogist: 106: 174–179.

Synonyms of JasonsmithiteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Jasonsmithite associated with AlbiteNa(AlSi3O8)

Related Minerals - Strunz-mindat GroupingHide

8.DG.Davidbrownite-(NH4)(NH4)5(V4+O)2(C2O4)[PO2.75(OH)1.25]4 · 3H2OMon. 2/m : P21/b
8.DG.Relianceite-(K)K4Mg(V4+O)2(C2O4)(PO3OH)4(H2O)10Mon. m : Pb
8.DG.Pleysteinite[(H2O)0.5K0.5]2Mn2Al3(PO4)4F2 · 14H2OOrth. mmm (2/m 2/m 2/m) : Pbca
8.DG.Rewitzerite[K(H2O)]Mn2Al3(PO4)4(OH)2 · 14H2OMon. 2/m : P21/b
8.DG.05LavendulanNaCaCu5(AsO4)4Cl · 5H2OMon. 2/m
8.DG.05SampleiteNaCaCu5(PO4)4Cl · 5H2OOrth. mmm (2/m 2/m 2/m) : Cmmm
8.DG.05ShubnikoviteCa2Cu8(AsO4)6(OH)Cl · 7H2OOrth.
8.DG.05ZdenĕkiteNaPbCu5(AsO4)4Cl · 5H2OMon. 2/m : P21/b
8.DG.05LemanskiiteNaCaCu5(AsO4)4Cl · 3H2OTet. 4 2 2 : P41 2 2

Fluorescence of JasonsmithiteHide

Does not fluoresce under LW or SW UV

Other InformationHide

Notes:
Easily soluble in dilute HCl at room temperature
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for JasonsmithiteHide

References for JasonsmithiteHide

Localities for JasonsmithiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
USA (TL)
 
  • North Carolina
    • Cleveland County
      • Kings Mountain
Miyawaki et al. (2020) +1 other reference
 
and/or  
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