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Carpathite

A valid IMA mineral species - grandfathered
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About CarpathiteHide

Formula:
C24H12
structural formula: [(CH)2C2]6 (7 fused benzene rings)
Colour:
Yellow, yellowish brown
Lustre:
Vitreous
Hardness:
Specific Gravity:
1.35 - 1.40
Crystal System:
Monoclinic
Name:
Originally appears in the literature, translated from Russian as karpatite, apparently unclear on the origin of the name. Later appears as carpathite, but there does seem to be an IMA notice of the change. The new name is clearly for the Carpathian mountains. The name pendletonite also occurs in the literature, but was shown to be identical to carpathite
(CNMMN, 1971).
Chemically identical to coronene, a polycyclic aromatic hydrocarbon (PAH).



Unique IdentifiersHide

Mindat ID:
2162
Long-form identifier:
mindat:1:1:2162:9
GUID
(UUID V4):
ed5aa46b-1fe7-4bb8-8922-b52c6c8ac0dc

IMA Classification of CarpathiteHide

Approved, 'Grandfathered' (first described prior to 1959)
First published:
1955

Classification of CarpathiteHide

10.BA.30

10 : ORGANIC COMPOUNDS
B : Hydrocarbons
A : Hydrocarbons
50.3.7.1

50 : ORGANIC COMPOUNDS
3 : Hydrocarbons
32.6

32 : Hydrocarbons, Resins and other Organic Compounds

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
CpaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CarpathiteHide

Vitreous
Transparency:
Translucent
Colour:
Yellow, yellowish brown
Hardness:
1½ on Mohs scale
Tenacity:
Flexible
Cleavage:
Perfect
on {001}, {100}, {201}
Fracture:
Splintery
Density:
1.35 - 1.40 g/cm3 (Measured)    1.29 g/cm3 (Calculated)

Optical Data of CarpathiteHide

Type:
Biaxial (+/-)
RI values:
nα = 1.760 - 1.780 nβ = 1.977 - 1.982 nγ = 2.050 - 2.150
2V:
Measured: 96° to 115°
Max Birefringence:
δ = 0.290 - 0.370
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
r > v, relatively strong

Chemistry of CarpathiteHide

Mindat Formula:
C24H12

structural formula: [(CH)2C2]6 (7 fused benzene rings)
CAS Registry number:
191-07-1

CAS Registry numbers are published by the American Chemical Society

Crystallography of CarpathiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 10.035 Å, b = 4.695 Å, c = 16.014 Å
β = 112°
Ratio:
a:b:c = 2.137 : 1 : 3.411
Unit Cell V:
699.55 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals are acicular, thin tabular parallel to [001], showing {001}, {100}, {201}, many other forms, to 1 cm; typically in bladed groups and fibrous radiating aggregates.
Comment:
sp gr. P21/c or P2/c (synthetic)

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0004412CarpathiteEchigo T, Kimata M, Maruoka T (2007) Crystal-chemical and carbon-isotopic characteristics of karpatite (C24H12) from the Picacho Peak Area, San Benito County, California: Evidences for the hydrothermal formation American Mineralogist 92 1262-12692007Picacho Peak Area, San Benito County, California, USA0293
0015361CarpathiteFawcett J K, Trotter J (1966) The crystal and molecular structure of coronene Proceedings of the Royal Society of London A289 366-3761966synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.40 Å(100)
7.52 Å(80)
7.25 Å(50)
3.97 Å(70)
3.52 Å(90)
3.43 Å(40)
3.05 Å(60)
Comments:
Olenevo, Ukraine.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3b: Earth’s earliest hydrosphere>4.45
14 : Hot springs, geysers, and other subaerial geothermal minerals
Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere<0.6
53 : Other minerals with taphonomic origins<0.4

Type Occurrence of CarpathiteHide

Geological Setting of Type Material:
In cavities at the contact of diorite porphyry with argillites.
Associated Minerals at Type Locality:
Reference:
Piotrovsky, G.L. (1955) Karpatite – a new organic mineral from Transcarpathia. Lvovskoe geol. Obshch., Mineralogicheskii Sbornik: 9: 120–127.

Synonyms of CarpathiteHide

Other Language Names for CarpathiteHide

Common AssociatesHide

Associated Minerals Based on Photo Data:
34 photos of Carpathite associated with CinnabarHgS
29 photos of Carpathite associated with QuartzSiO2
21 photos of Carpathite associated with GoldAu
3 photos of Carpathite associated with IdrialiteC22H14
3 photos of Carpathite associated with MetacinnabarHgS
2 photos of Carpathite associated with ChalcedonySiO2
2 photos of Carpathite associated with Goethiteα-Fe3+O(OH)

Related Minerals - Strunz-mindat GroupingHide

10.BA.FreitaliteC14H10Mon. 2/m : P21/b
10.BA.05FichteliteC19H34Mon. 2 : P21
10.BA.10BranchiteC20H34Tric. 1 : P1
10.BA.15DiniteC20H36Orth. 2 2 2 : P21 21 21
10.BA.20IdrialiteC22H14Orth.
10.BA.25KratochvíliteC13H10Orth. mmm (2/m 2/m 2/m)
10.BA.35PhylloretineC18H18Orth.
10.BA.40RavatiteC14H10Mon. 2 : P21
10.BA.45SimonelliteC19H24Orth. mmm (2/m 2/m 2/m) : Pnna
10.BA.50EvenkiteC21H44Orth. mmm (2/m 2/m 2/m) : Pbcm
10.BA.55WampeniteC18H16Mon. 2/m : P21/b
10.BA.60Scharizerite

Fluorescence of CarpathiteHide

Fluoresces sky-blue under LW and SW UV.

Other InformationHide

Notes:
Flammable.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for CarpathiteHide

References for CarpathiteHide

Reference List:

Localities for CarpathiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia
 
  • Chukotka Autonomous Okrug
    • Anadyrsky District
      • Tamvatnei massif
Pavel.M. Kartashov (n.d.)
Slovakia
 
  • Prešov Region
    • Prešov District
      • Červenica
Duda
    • Vranov nad Topľou District
      • Juskova Voľa
Koděra (1986)
      • Komárany
Ďuďa
Ukraine (TL)
 
  • Zakarpattia Oblast
    • Mukachevo Raion
American Mineralogist (1957) +1 other reference
USA
 
  • California
    • San Benito County
Chuck Trantham specimen
      • Picacho Peak
        • Flint group
Robbins (1994)
Van Nostrand Reinholt Press: 343 +4 other references
 
Mineral and/or Locality  
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