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Kelsey, C. H., McKie, Duncan (1964) The unit-cell of aenigmatite. Mineralogical Magazine and Journal of the Mineralogical Society, 33 (266) 986-1001 doi:10.1180/minmag.1964.033.266.06

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Reference TypeJournal (article/letter/editorial)
TitleThe unit-cell of aenigmatite
JournalMineralogical Magazine and Journal of the Mineralogical Society
AuthorsKelsey, C. H.Author
McKie, DuncanAuthor
Year1964 (September)Volume33
Issue266
PublisherMineralogical Society
Download URLhttps://rruff.info/doclib/MinMag/Volume_33/33-266-986.pdf+
DOIdoi:10.1180/minmag.1964.033.266.06Search in ResearchGate
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Mindat Ref. ID5815Long-form Identifiermindat:1:5:5815:9
GUID0
Full ReferenceKelsey, C. H., McKie, Duncan (1964) The unit-cell of aenigmatite. Mineralogical Magazine and Journal of the Mineralogical Society, 33 (266) 986-1001 doi:10.1180/minmag.1964.033.266.06
Plain TextKelsey, C. H., McKie, Duncan (1964) The unit-cell of aenigmatite. Mineralogical Magazine and Journal of the Mineralogical Society, 33 (266) 986-1001 doi:10.1180/minmag.1964.033.266.06
In(1962) Mineralogical Magazine Vol. 33 (266) Mineralogical Society
Abstract/NotesSummaryRedetermination of the unit-cell dimensions as a 10·406 Å, b 10·813 Å, c 8·926 Å, α 104° 56′, β 96° 52′, γ 125° 19′, has shown that the hitherto accepted unit-cell of Gossner and Spielberger (1929) is in error. The morphological unit-cell of Palache (1933) is related to the new unit-cell, to a high degree of precision, by the transformation Palache → Kelsey-MeKie [001∕01½½∕½00]. Fifteen published and two new analyses indicate that the unit-cell contents approach Na+4 [Fe2-10- Ti4+2] Si4+12O2-40. The common twin axis constitutes the diad of a pseudo-monoclinic cell, the (010) plane of which is dimensionally closely related to that of pyroxenes and amphiboles. It is suggested that the aenigmatite structure is based on silicate chains of pyroxene type cross-linked by Ti4+ and Fe2+ on distinct 6-fold sites, with Na+ on sites of higher coordination number. Aenigmatite from volcanic in contrast to that from plutonic parageneses is often submicroscopically twinned and may be inverted from a high temperature monoclinic polymorph.

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