Reference Type | Journal (article/letter/editorial) |
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Title | Crystal Chemistry of an Erythrite-Köttigite Solid Solution (Co3–xZnx) (AsO4)2·8H2O |
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Journal | Minerals |
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Authors | Ciesielczuk, Justyna | Author |
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Dulski, Mateusz | Author |
Janeczek, Janusz | Author |
Krzykawski, Tomasz | Author |
Kusz, Joachim | Author |
Szełęg, Eligiusz | Author |
Year | 2020 (June 17) | Volume | 10 |
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Page(s) | 548 | Issue | 6 |
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Publisher | MDPI AG |
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DOI | doi:10.3390/min10060548Search in ResearchGate |
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Classification | Not set | LoC | Not set |
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Mindat Ref. ID | 13423273 | Long-form Identifier | mindat:1:5:13423273:9 |
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GUID | eb7d7fbc-f5fe-4306-b6ce-3bd729f39dea |
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Full Reference | Ciesielczuk, Justyna, Dulski, Mateusz, Janeczek, Janusz, Krzykawski, Tomasz, Kusz, Joachim, Szełęg, Eligiusz (2020) Crystal Chemistry of an Erythrite-Köttigite Solid Solution (Co3–xZnx) (AsO4)2·8H2O. Minerals, 10 (6) 548 doi:10.3390/min10060548 |
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Plain Text | Ciesielczuk, Justyna, Dulski, Mateusz, Janeczek, Janusz, Krzykawski, Tomasz, Kusz, Joachim, Szełęg, Eligiusz (2020) Crystal Chemistry of an Erythrite-Köttigite Solid Solution (Co3–xZnx) (AsO4)2·8H2O. Minerals, 10 (6) 548 doi:10.3390/min10060548 |
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In | (2020, June) Minerals Vol. 10 (6) MDPI AG |
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Abstract/Notes | A wide compositional range, covering about 90% of an expected erythrite-köttigite substitutional solid solution with extreme compositions of (Co2.84Mg0.14Zn0.02) (AsO4)2·8H2O and (Zn2.74Co0.27) (AsO4)2·8H2O, was revealed in a suite of samples from a polymetallic ore deposit in Miedzianka, SW Poland. Members of the solid solution series were examined by means of Electron Probe Microanalysis (EPMA), Scanning Electron Microscopy (SEM)/Energy-Dispersive Spectrometer (EDS), X-ray single-crystal and powder diffraction, and Raman spectroscopy. Metal cations were randomly distributed between two special octahedral sites in the erythrite–köttigite structure. In response to Co ↔ Zn substitutions, small but significant changes in bond distances (particularly in [AsO4] tetrahedra), rotation, and distortion of co-ordination polyhedra were observed. Two sub-series of dominant cationic substitutions (Co-Mg-Ni and Co-Fe-Zn) were noted within the arsenate series of vivianite-group minerals linked by erythrite. The paragenetic sequence erythrite → Zn-rich erythrite → Co-rich köttigite → köttigite reflects the evolution of the solution’s pH towards increased acidity and a relative increase in the concentration of Zn ions following precipitation of erythrite. |
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These are the references the publisher has listed as being connected to the article. Please check the article itself for the full list of references which may differ. Not all references are currently linkable within the Digital Library.
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