Jarosewichite
A valid IMA mineral species
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About Jarosewichite
Formula:
Mn2+3Mn3+(AsO4)(OH)6
Colour:
Dark red brown
Lustre:
Sub-Vitreous, Resinous, Greasy
Hardness:
4
Specific Gravity:
3.66
Crystal System:
Orthorhombic
Member of:
Name:
Named in 1982 by Pete J. Dunn, Donald R. Peacor, Peter B. Leavens, and William B. Simmons in honor of Eugene Jarosewich [January 6, 1926 - April 30, 2007 Washington, District of Columbia, USA] mineral and meteorite chemist, Department of Mineral Sciences, Smithsonian Institution. Jarosewich established analytical standard materials for microprobe analysis and established analytical standard materials for meteorites.
Dark brown tightly intergrown cushion-like to divergent clusters of crystals.
Unique Identifiers
Mindat ID:
2077
Long-form identifier:
mindat:1:1:2077:6
GUID
(UUID V4):
(UUID V4):
e5ad9ad7-0c1e-47e7-8119-b40ec7787850
IMA Classification of Jarosewichite
Approved
IMA Formula:
Mn3+Mn2+3(AsO4)(OH)6
First published:
1982
Classification of Jarosewichite
8.BE.70
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
E : With only medium-sized cations, (OH, etc.):RO4 > 2:1
8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
E : With only medium-sized cations, (OH, etc.):RO4 > 2:1
41.1.1.3
41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p > 4:1
41 : ANHYDROUS PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
1 : (AB)m(XO4)pZq, where m:p > 4:1
20.8.5
20 : Arsenates (also arsenates with phosphate, but without other anions)
8 : Arsenates of Mn
20 : Arsenates (also arsenates with phosphate, but without other anions)
8 : Arsenates of Mn
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Jrw | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Jarosewichite
Sub-Vitreous, Resinous, Greasy
Transparency:
Translucent
Comment:
Subvitreous on fractured surfaces
Colour:
Dark red brown
Streak:
Reddish orange
Hardness:
4 on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven
Density:
3.66(4) g/cm3 (Measured) 3.70 g/cm3 (Calculated)
Optical Data of Jarosewichite
Type:
Biaxial (-)
RI values:
nα = 1.780(5) nβ = 1.795(5) nγ = 1.805(5)
2V:
Measured: 78° , Calculated: 78°
Birefringence:
0.025
Max Birefringence:
δ = 0.025
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Very High
Dispersion:
r > v distinct
Optical Extinction:
Parallel. X = a, Y = b, Z = c.
Pleochroism:
Weak
Comments:
X = medium brownish red; Z = dark brownish red.
Comments:
Reactive with some Refractive index liquids.
Absorption: Z > X.
Absorption: Z > X.
Chemistry of Jarosewichite
Mindat Formula:
Mn2+3Mn3+(AsO4)(OH)6
Elements listed:
Common Impurities:
Mg
Crystallography of Jarosewichite
Crystal System:
Orthorhombic
Class (H-M):
2 2 2 - Disphenoidal
Cell Parameters:
a = 6.563 Å, b = 25.201 Å, c = 10.005 Å
Ratio:
a:b:c = 0.26 : 1 : 0.397
Unit Cell V:
1,654.77 ų (Calculated from Unit Cell)
Z:
8
Morphology:
Rarely in rod-like crystals with crude "hexagonal" cross-section, also in tabular to flattened crystals, usually in slightly divergent groups.
Comment:
Point Group: 2/m 2/m 2/m, 222, or mm2.; Space Group: Cmmm, Cmm2 or C222.
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
6.29 Å | (20) |
5.30 Å | (5) |
3.91 Å | (60) |
3.21 Å | (5) |
3.17 Å | (5) |
2.669 Å | (100) |
2.612 Å | (2) |
2.573 Å | (2) |
2.503 Å | (30) |
2.451 Å | (10) |
2.289 Å | (5) |
2.256 Å | (5) |
1.873 Å | (1) |
1.788 Å | (50) |
1.738 Å | (1) |
1.567 Å | (20) |
1.558 Å | (30) |
1.501 Å | (20) |
1.468 Å | (2) |
1.385 Å | (1) |
1.126 Å | (2) |
Comments:
ICDD 41-580
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47d : [Arsenates, antimonates, selenates, bismuthinates] | |
47e : [Vanadates, chromates, manganates] |
Type Occurrence of Jarosewichite
General Appearance of Type Material:
Etched and vuggy granular dark olive green andradite and franklinite.
Place of Conservation of Type Material:
Harvard University, Cambridge, Massachusetts, USA, 109463.
National Museum of Natural History, Washington, D.C., USA, 148972.
National Museum of Natural History, Washington, D.C., USA, 148972.
Associated Minerals at Type Locality:
Reference:
Dunn, P.J., Peacor, D.R. Leavens, P.B., Simmons, W.B. (1982) Jarosewichite and a related phase: basic manganese arsenates of the chlorophoenicite group from Franklin, New Jersey. American Mineralogist: 67: 1043-1047.
Synonyms of Jarosewichite
Other Language Names for Jarosewichite
German:Jarosewichit
Spanish:Jarosewichita
Relationship of Jarosewichite to other Species
Member of:
Other Members of this group:
Chlorophoenicite | (Mn,Mg)3Zn2(AsO4)(OH,O)6 | Mon. 2/m : B2/m |
Magnesiochlorophoenicite | (Mg,Mn)3Zn2(AsO4)(OH,O)6 | Mon. 2/m : B2/m |
Mineral E (of Dunn, et. al., 1982) | Bright translucent black needles showing typical chlorophoenicite habit. | Orth. mmm (2/m 2/m 2/m) |
Peterchinite | Zn3Zn2(OH)6As[O3(OH)3] | Mon. 2/m : B2/m |
Common Associates
Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
8.BE.05 | Augelite | Al2(PO4)(OH)3 |
8.BE.10 | Grattarolaite | Fe3+3(PO4)O3 |
8.BE.15 | Cornetite | Cu3(PO4)(OH)3 |
8.BE.20 | Clinoclase | Cu3(AsO4)(OH)3 |
8.BE.25 | Arhbarite | Cu2Mg(AsO4)(OH)3 |
8.BE.25 | Gilmarite | Cu3(AsO4)(OH)3 |
8.BE.30 | Allactite | Mn2+7(AsO4)2(OH)8 |
8.BE.30 | Flinkite | Mn2+2Mn3+(AsO4)(OH)4 |
8.BE.30 | Raadeite | Mg7(PO4)2(OH)8 |
8.BE.30 | Argandite | Mn7(VO4)2(OH)8 |
8.BE.35 | Chlorophoenicite | (Mn,Mg)3Zn2(AsO4)(OH,O)6 |
8.BE.35 | Magnesiochlorophoenicite | (Mg,Mn)3Zn2(AsO4)(OH,O)6 |
8.BE.35 | Mineral E (of Dunn, et. al., 1982) | |
8.BE.40 | Gerdtremmelite | (Zn,Fe)(Al,Fe)2(AsO4)(OH)5 |
8.BE.45 | Dixenite | CuMn2+14Fe2+(SiO4)2(As5+O4)(As3+O3)5(OH)6 |
8.BE.45 | Hematolite | (Mn,Mg,Al,Fe3+)15(As5+O4)2(As3+O3)(OH)23 |
8.BE.45 | Kraisslite | Zn3(Mn,Mg)25(Fe3+,Al)(As3+O3)2[(Si,As5+)O4]10(OH)16 |
8.BE.45 | Mcgovernite | Mn19Zn3(AsO4)3(AsO3)(SiO4)3(OH)21 |
8.BE.45 | Arakiite | (Zn,Mn2+)(Mn2+,Mg)12(Fe3+,Al)2(As5+O4)2(As3+O3)(OH)23 |
8.BE.45 | Turtmannite | (Mn,Mg)22.5Mg3-3x((V5+,As5+)O4)3(As3+O3)x(SiO4)3O5-5x(OH)20+x |
8.BE.45 | Carlfrancisite | Mn2+3(Mn2+,Mg,Fe3+,Al)42[As3+O3]2(As5+O4)4[(Si,As5+)O4]6[(As5+,Si)O4]2(OH)42 |
8.BE.50 | Synadelphite | Mn2+9(As5+O4)2(As3+O3)(OH)9 · 2H2O |
8.BE.55 | Holdenite | (Mn2+,Mg)6Zn3(AsO4)2(SiO4)(OH)8 |
8.BE.60 | Kolicite | Mn2+7Zn4(AsO4)2(SiO4)2(OH)8 |
8.BE.65 | Sabelliite | (Cu,Zn)2Zn(AsO4,SbO4)(OH)3 |
8.BE.75 | Theisite | Cu5Zn5(AsO4,SbO4)2(OH)14 |
8.BE.80 | Coparsite | Cu4(AsO4,VO4)O2Cl |
8.BE.85 | Waterhouseite | Mn2+7(PO4)2(OH)8 |
8.BE.90 | Vasilseverginite | Cu9O4(AsO4)2(SO4)2 |
Fluorescence of Jarosewichite
Not fluorescent in UV.
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Jarosewichite
mindat.org URL:
https://www.mindat.org/min-2077.html
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References for Jarosewichite
Localities for Jarosewichite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
USA | |
| King (n.d.) |
| Dunn et al. (1982) +1 other reference |
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Buckwheat pit, Franklin Mine, Franklin, Sussex County, New Jersey, USA