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Karwowski, Łukasz, Kusz, Joachim, Muszyński, Andrzej, Kryza, Ryszard, Sitarz, Maciej, Galuskin, Evgeny V. (2015) Moraskoite, Na2Mg(PO4)F, a new mineral from the Morasko IAB-MG iron meteorite (Poland) Mineralogical Magazine, 79 (2) 387-398 doi:10.1180/minmag.2015.079.2.16

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Reference TypeJournal (article/letter/editorial)
TitleMoraskoite, Na2Mg(PO4)F, a new mineral from the Morasko IAB-MG iron meteorite (Poland)
JournalMineralogical Magazine
AuthorsKarwowski, ŁukaszAuthor
Kusz, JoachimAuthor
Muszyński, AndrzejAuthor
Kryza, RyszardAuthor
Sitarz, MaciejAuthor
Galuskin, Evgeny V.Author
Year2015 (April)Volume79
Issue2
PublisherMineralogical Society
DOIdoi:10.1180/minmag.2015.079.2.16Search in ResearchGate
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Mindat Ref. ID244641Long-form Identifiermindat:1:5:244641:1
GUID0
Full ReferenceKarwowski, Łukasz, Kusz, Joachim, Muszyński, Andrzej, Kryza, Ryszard, Sitarz, Maciej, Galuskin, Evgeny V. (2015) Moraskoite, Na2Mg(PO4)F, a new mineral from the Morasko IAB-MG iron meteorite (Poland) Mineralogical Magazine, 79 (2) 387-398 doi:10.1180/minmag.2015.079.2.16
Plain TextKarwowski, Łukasz, Kusz, Joachim, Muszyński, Andrzej, Kryza, Ryszard, Sitarz, Maciej, Galuskin, Evgeny V. (2015) Moraskoite, Na2Mg(PO4)F, a new mineral from the Morasko IAB-MG iron meteorite (Poland) Mineralogical Magazine, 79 (2) 387-398 doi:10.1180/minmag.2015.079.2.16
Abstract/NotesAbstractMoraskoite, a new natural phosphate of composition
Na2Mg(PO4)F, has been found in the Morasko IAB-MG
iron meteorite. The new phosphate occurs in a graphite-troilite inclusion
enclosed in a kamacite-taenite matrix. Associated minerals in the inclusions
are chlorapatite, buchwaldite, brianite, merrillite, a new phosphate phase
of composition Na4MgCa3(PO4)4,
chromite, enstatite (bronzite), kosmochlor, kosmochlor–augite, olivine,
albite, orthoclase, quartz, cohenite, schreibersite, nickelphosphide,
altaite, pyrrhotite, sphalerite, daubreelite, djerfischerite, whitlockite
and native Cu. The inclusions are rimmed by a schreibersite-cohenite halo.
Moraskoite forms aggregates up to 1.5 mm in size, with individual grains
20–300 μm across. It is colourless and transparent, with a white streak and
vitreous lustre; fluorescence is weak blue in ultraviolet radiation (254 and
360 nm); hardness is 4–5; it has irregular, conchoidal fracture and cleavage
is rarely observed. Calculated density (using the empirical formula) is
2.925 g cm–3. The moraskoite structure (Pbcn,
a = 5.2117(10), b = 13.711(3),
c = 11.665(2) Å, V = 833.6(3)
Å3 and Z = 8) is similar to that of its
synthetic analogue. The strongest diffraction lines of the moraskoite powder
diffraction pattern are as follows (dhkl, I): 3.909(75), 3.382(52),
2.955(90), 2.606(100), 2.571(96), 2.545(68), 1.691 (67). In the Raman
spectrum, the following characteristic bands are distinguished
(cm–1, strong bands bold): 1114, 1027, 962, 589, 438, 336,
308, 279, 262, 244, 193, 184, 147 and 131. The Raman data prove the absence
of H2O and CO2. Moraskoite is interpreted as being a
primary phosphate, which crystallized together with graphite, troilite and
other accessories inside the nodule.

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LocalityCitation Details
Morasko meteorite, Poznań, Greater Poland Voivodeship, Poland

Mineral Pages

MineralCitation Details
Moraskoite

Mineral Occurrences

LocalityMineral(s)
Morasko meteorite, Poznań, Greater Poland Voivodeship, Poland Albite, Bronzite, Chlorapatite, Enstatite, Fayalite-Forsterite Series, Merrillite, Moraskoite, Native Copper, Nickelphosphide, Orthoclase, Pyrrhotite, Quartz, Whitlockite


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