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Michailidis, K. M., Nicholson, K., Nimfopoulos, M. K., Pattrick, R. A. D. (1997) An EPMA and SEM study of the Mn-oxide mineralization of Kato Nevrokopi, Macedonia, northern Greece: Controls on formation of the Mn4+ oxides, in Manganese Mineralization: Geochemistry and Mineralogy of Terrestrial and Marine Deposits. Special Publication, 119. Geological Society of London. 265-280 doi:10.1144/gsl.sp.1997.119.01.17

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Reference TypeReport (article/chapter)
TitleAn EPMA and SEM study of the Mn-oxide mineralization of Kato Nevrokopi, Macedonia, northern Greece: Controls on formation of the Mn4+ oxides
ReportSpecial Publication
AuthorsMichailidis, K. M.Author
Nicholson, K.Author
Nimfopoulos, M. K.Author
Pattrick, R. A. D.Author
Year1997Volume119
Page(s)265-280
PublisherGeological Society of London
DOIdoi:10.1144/gsl.sp.1997.119.01.17Search in ResearchGate
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Mindat Ref. ID428127Long-form Identifiermindat:1:5:428127:0
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Full ReferenceMichailidis, K. M., Nicholson, K., Nimfopoulos, M. K., Pattrick, R. A. D. (1997) An EPMA and SEM study of the Mn-oxide mineralization of Kato Nevrokopi, Macedonia, northern Greece: Controls on formation of the Mn4+ oxides, in Manganese Mineralization: Geochemistry and Mineralogy of Terrestrial and Marine Deposits. Special Publication, 119. Geological Society of London. 265-280 doi:10.1144/gsl.sp.1997.119.01.17
Plain TextMichailidis, K. M., Nicholson, K., Nimfopoulos, M. K., Pattrick, R. A. D. (1997) An EPMA and SEM study of the Mn-oxide mineralization of Kato Nevrokopi, Macedonia, northern Greece: Controls on formation of the Mn4+ oxides, in Manganese Mineralization: Geochemistry and Mineralogy of Terrestrial and Marine Deposits. Special Publication, 119. Geological Society of London. 265-280 doi:10.1144/gsl.sp.1997.119.01.17
InNicholson, K., Hein, J. R., BĂĽhn, B., Dasgupta, S. - Eds. (1997) Manganese Mineralization: Geochemistry and Mineralogy of Terrestrial and Marine Deposits. Special Publication Vol. 119. Geological Society of London
Abstract/NotesEPMA and SEM studies of tunnel-structured todorokite and nsutite and layerstructured chalcophanite and birnessite from the Kato Nevrokopi battery grade Mnmineralization were performed. The chemistry of todorokite, formed at hypogene and supergene environments in an increasing order of weathering, reflects different pH and
oxidation conditions. The data also point to a clear dependence of the development of late stage hypogene and early supergene Mna+-oxide paragenesis on the host rock and protore composition and the mobilities of base metals (mainly Zn), alkalis and alkaline earths (mainly Ca).

The chemistry and development of (large cation-bearing) nsutite as in situ oxidations and banded poorly crystalline (with structural defects) aggregates in veins and associated karstic cavities, together with birnessite, indicates the influence of climate, oxidation and water table fluctuations. The data on chalcophanite revealed a deposition, under low fo2 conditions, from acid meteoric fluids produced by weathering of vein sulphides. Birnessite formation reflects a prevalence of higher fo2 in weathered veins and the karstic cavities.

The evolution of well developed layer structures through poorly crystalline to amorphous
tunnel-structured nsutite is probably controlled by a Zn-saturation of the ore fluids.

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LocalityCitation Details
Kato Nevrokopi village, Kato Nevrokopi, Drama, Eastern Macedonia and Thrace, Greece

Mineral Occurrences

LocalityMineral(s)
Kato Nevrokopi village, Kato Nevrokopi, Drama, Eastern Macedonia and Thrace, Greece Birnessite, Chalcophanite, Nsutite, Pyrite, Rhodochrosite, Todorokite


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