Irhtemite
A valid IMA mineral species
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About Irhtemite
Formula:
Ca4Mg(AsO4)2(HAsO4)2 · 4H2O
Colour:
Colorless, white, pale rose
Lustre:
Silky
Specific Gravity:
3.09
Crystal System:
Monoclinic
Name:
Named after the type locality, the Ightem Mine (Irhtem Mine).
This page provides mineralogical data about Irhtemite.
Unique Identifiers
Mindat ID:
2043
Long-form identifier:
mindat:1:1:2043:1
GUID
(UUID V4):
(UUID V4):
2197109b-7874-442a-b386-1af78c562b00
IMA Classification of Irhtemite
Approved
IMA Formula:
Ca4Mg(AsO4)2(AsO3OH)2 · 4H2O
Classification of Irhtemite
8.CG.55
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
G : With large and medium-sized cations, RO4:H2O = 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
G : With large and medium-sized cations, RO4:H2O = 1:1
39.2.5.1
39 : HYDRATED ACID PHOSPHATES,ARSENATES AND VANADATES
2 : (AB)5[HXO4]2[XO4]2.xH2O
39 : HYDRATED ACID PHOSPHATES,ARSENATES AND VANADATES
2 : (AB)5[HXO4]2[XO4]2.xH2O
20.2.19
20 : Arsenates (also arsenates with phosphate, but without other anions)
2 : Arsenates of Be, Mg, Ca or Ba
20 : Arsenates (also arsenates with phosphate, but without other anions)
2 : Arsenates of Be, Mg, Ca or Ba
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Irh | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Irhtemite
Silky
Transparency:
Transparent
Colour:
Colorless, white, pale rose
Streak:
White
Density:
3.09 g/cm3 (Measured) 3,153 g/cm3 (Calculated)
Optical Data of Irhtemite
Type:
Biaxial (+)
RI values:
nα = 1.634 nγ = 1.642
Max Birefringence:
δ = 0.008
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
strong
Optical Extinction:
Extinction angle 25°.
Comments:
Elongation negative.
Chemistry of Irhtemite
Mindat Formula:
Ca4Mg(AsO4)2(HAsO4)2 · 4H2O
Crystallography of Irhtemite
Crystal System:
Monoclinic
Cell Parameters:
a = 16.736(5) Å, b = 9.483(3) Å, c = 10.840(5) Å
β = 97.25°
β = 97.25°
Ratio:
a:b:c = 1.765 : 1 : 1.143
Unit Cell V:
1,706.63 ų (Calculated from Unit Cell)
Z:
4
Comment:
Point Group: n.d.; Space Group: n.d.
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
9.42 Å | (30) |
6.85 Å | (30) |
5.08 Å | (40) |
3.68 Å | (40) |
3.24 Å | (90) |
2.97 Å | (100) |
2.82 Å | (90) |
Comments:
Ightem Mine, Morocco. Data from the type description.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47d : [Arsenates, antimonates, selenates, bismuthinates] |
Type Occurrence of Irhtemite
General Appearance of Type Material:
Spherulites 0.5-1 mm in diameter.
Place of Conservation of Type Material:
National School of Mines, Paris, France.
Geological Setting of Type Material:
Dehydration product of picropharmacolite in hydrothermal veins.
Associated Minerals at Type Locality:
Reference:
Pierrot R, Schubnel H J (1972) L'irhtemite, un nouvel arséniate hydraté de calcium et magnésium. Bulletin de la Société Française de Minéralogie et de Cristallographie 95, 365-370
Synonyms of Irhtemite
Other Language Names for Irhtemite
Common Associates
Associated Minerals Based on Photo Data:
7 photos of Irhtemite associated with Calcite | CaCO3 |
7 photos of Irhtemite associated with Vladimirite | Ca4(AsO4)2(AsO3OH) · 4H2O |
Related Minerals - Strunz-mindat Grouping
8.CG. | Ca-Huréaulite | CaMn5(PO4)4 · 4H2O |
8.CG. | Fluckite | CaMn2+(AsO3OH)2 · 2H2O |
8.CG. | Dondoellite | Ca2Fe(PO4)2 · 2H2O |
8.CG. | Alumolukrahnite | Ca[CuAl](AsO4)2(H2O,OH)2 |
8.CG.05 | Cassidyite | Ca2Ni(PO4)2 · 2H2O |
8.CG.05 | Collinsite | Ca2Mg(PO4)2 · 2H2O |
8.CG.05 | Fairfieldite | Ca2Mn2+(PO4)2 · 2H2O |
8.CG.05 | Gaitite | Ca2Zn(AsO4)2 · 2H2O |
8.CG.05 | Messelite | Ca2Fe2+(PO4)2 · 2H2O |
8.CG.05 | Parabrandtite | Ca2Mn2+(AsO4)2 · 2H2O |
8.CG.05 | Anorthoroselite | Ca2Co(AsO4)2 · 2H2O |
8.CG.05 | Talmessite | Ca2Mg(AsO4)2 · 2H2O |
8.CG.05 | Hillite | Ca2Zn(PO4)2 · 2H2O |
8.CG.05 | Unnamed (Fe2+-analogue of Parabrandtite) | Ca2Fe2+(AsO4)2 · 2H2O |
8.CG.10 | Brandtite | Ca2Mn2+(AsO4)2 · 2H2O |
8.CG.10 | Roselite | Ca2Co(AsO4)2 · 2H2O |
8.CG.10 | Wendwilsonite | Ca2Mg(AsO4)2 · 2H2O |
8.CG.10 | Zincroselite | Ca2Zn(AsO4)2 · 2H2O |
8.CG.10 | Rruffite | Ca2Cu(AsO4)2 · 2H2O |
8.CG.10 | Unnamed (Fe2+-analogue of Brandtite) | Ca2Fe2+(AsO4)2 · 2H2O |
8.CG.15 | Ferrilotharmeyerite | CaZnFe3+(AsO4)2(OH) · H2O |
8.CG.15 | Lotharmeyerite | CaZn2(AsO4)2 · 2H2O |
8.CG.15 | Mawbyite | PbFe3+2(AsO4)2(OH)2 |
8.CG.15 | Mounanaite | PbFe3+2(VO4)2(OH,F)2 |
8.CG.15 | Thometzekite | PbCu2+2(AsO4)2 · 2H2O |
8.CG.15 | Tsumcorite | PbZn2(AsO4)2 · 2H2O |
8.CG.15 | Cobaltlotharmeyerite | CaCo2(AsO4)2 · 2H2O |
8.CG.15 | Cabalzarite | CaMg2(AsO4)2 · 2H2O |
8.CG.15 | Krettnichite | PbMn3+2(VO4)2(OH)2 |
8.CG.15 | Cobalttsumcorite | PbCo2(AsO4)2 · 2H2O |
8.CG.15 | Nickellotharmeyerite | CaNi2(AsO4)2 · 2H2O |
8.CG.15 | Manganlotharmeyerite | CaMn3+2(AsO4)2(OH)2 |
8.CG.15 | Schneebergite | BiCo2(AsO4)2(OH) · H2O |
8.CG.15 | Nickelschneebergite | BiNi2(AsO4)2(OH) · H2O |
8.CG.15 | Yancowinnaite | PbCuAl(AsO4)2OH · H2O |
8.CG.15 | Nickeltsumcorite | Pb(Ni,Fe3+)2(AsO4)2(H2O,OH)2 |
8.CG.15 | Magnesiofluckite | CaMg(AsO3OH)2(H2O)2 |
8.CG.20 | Gartrellite | PbCuFe3+(AsO4)2(OH) · H2O |
8.CG.20 | Helmutwinklerite | PbZn2(AsO4)2 · 2H2O |
8.CG.20 | Zincgartrellite | PbZn2(AsO4)2(H2O,OH)2 |
8.CG.20 | Rappoldite | PbCo2(AsO4)2 · 2H2O |
8.CG.20 | Phosphogartrellite | PbCuFe3+(PO4)2(OH,H2O)2 |
8.CG.20 | Lukrahnite | CaCuFe3+(AsO4)2(OH,H2O)2 |
8.CG.25 | Pottsite | (Pb3xBi4-2x)(VO4)4 · H2O (0.8 < x < 1.0) |
8.CG.25 | Armellinoite-(Ce) | Ca4Ce4+(AsO4)4 · H2O |
8.CG.35 | Nickeltalmessite | Ca2Ni(AsO4)2 · 2H2O |
Other Information
Thermal Behaviour:
DTA curve shows an endothermic break at 300° and an exothermic break at 730°.
Notes:
Dissolved by dilute acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Irhtemite
mindat.org URL:
https://www.mindat.org/min-2043.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Irhtemite
Reference List:
Localities for Irhtemite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Czech Republic | |
| Lapis 2002 (7/8) |
France | |
| Cuchet (2000) |
Germany | |
| Weiß (1990) |
Weiß (1990) | |
Greece | |
| Rieck et al. (2020) |
| Rieck et al. (2020) |
Morocco | |
| Favreau et al. (2006) |
| American Mineralogist: 59: 209 |
USA | |
| Mineral News: 19 (12) |
Quick NavTopAbout IrhtemiteUnique IdentifiersIMA Classification Classification Mineral SymbolsPhysical Properties Optical Data Chemistry Crystallography X-Ray Powder DiffractionGeological EnvironmentType Occurrence SynonymsOther LanguagesCommon AssociatesStrunz-MindatOther InformationInternet Links References Localities Locality List
Ightem Mine, Ightem, Tansifte Caïdat, Agdz Cercle, Zagora Province, Drâa-Tafilalet Region, Morocco