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Brandtite

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Harstigen Mine, Pajsberg, Persberg district, Filipstad, Värmland, Sweden
© M. Burkhardt

Show Brandtite Photos (42)



Formula:
Ca
 
2
(Mn
2+
 
,Mg)(AsO
 
4
)
 
2
 · 2H
 
2
O
System:MonoclinicColour:Colourless, white, pink; ...
Hardness:3½
Member of:Roselite Group
Name:For Swedish chemist Georg Brandt (1694-1768).
Isostructural with:Roselite, Wendwilsonite


Roselite Group

Classification of Brandtite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:7/C.17-110
Nickel-Strunz 10th (pending) edition ID:8.CG.10

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
G : With large and medium-sized cations, RO4:H2O = 1:1
Dana 8th edition ID:40.2.3.2

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
2 : AB2(XO4)2·xH2O
Hey's CIM Ref.:20.8.14

20 : Arsenates (also arsenates with phosphate, but without other anions)
8 : Arsenates of Mn
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Type Occurrence of Brandtite

Type Locality:Harstigen Mine, Pajsberg, Persberg district, Filipstad, Värmland, Sweden
Year of Discovery:1888

Physical Properties of Brandtite

Lustre:Vitreous
Diaphaneity (Transparency):Transparent, Translucent
Colour:Colourless, white, pink; colourless in transmitted light.
Hardness (Mohs):3½
Cleavage:Perfect
On {010}, perfect.
Density (measured):3.67 g/cm3
Density (calculated):3.7 g/cm3

Crystallography of Brandtite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:P21/b {P1 1 21/b} {P21/c} {P1 21/c 1} {P21/a}
Cell Parameters:a = 5.89Å, b = 12.96Å, c = 5.68Å
β = 108.05°
Ratio:a:b:c = 0.454 : 1 : 0.438
Unit Cell Volume:V 412.24 ų (Calculated from Unit Cell)
Morphology:Crystals stout prismatic [001]. {100} striated [001]. Frequently grouped into radiated groups. Rounded or reniform masses with a radial-fibrous structure.
Twinning:On {100}, common.

Optical Data of Brandtite

Type:Biaxial (+)
RI values: nα = 1.707 - 1.709 nβ = 1.711 nγ = 1.724 - 1.729
2V:Measured: 22° to 24°, Calculated: 38° to 60°
Maximum Birefringence:δ = 0.017 - 0.020

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:r < v strong

Chemical Properties of Brandtite

Formula:
Ca
 
2
(Mn
2+
 
,Mg)(AsO
 
4
)
 
2
 · 2H
 
2
O
Essential elements:As, Ca, H, Mn, O
All elements listed in formula:As, Ca, H, Mg, Mn, O

Relationship of Brandtite to other Species

Member of:Roselite Group
Other Members of Group:

- +
Kröhnkite
Na
 
2
Cu(SO
 
4
)
 
2
 · 2H
 
2
O
Roselite
Ca
 
2
(Co
2+
 
,Mg)(AsO
 
4
)
 
2
 · 2H
 
2
O
Rruffite
Ca
 
2
Cu(AsO
 
4
)
 
2
 · 2H
 
2
O
Wendwilsonite
Ca
 
2
(Mg,Co
2+
 
)(AsO
 
4
)
 
2
 · 2H
 
2
O
Zincroselite
Ca
 
2
Zn(AsO
 
4
)
 
2
 · 2H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
8.CG.05Cassidyite
Ca
 
2
(Ni
2+
 
,Mg)(PO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Collinsite
Ca
 
2
(Mg,Fe
2+
 
)(PO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Fairfieldite
Ca
 
2
(Mn
2+
 
,Fe
2+
 
)(PO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Gaitite
Ca
 
2
Zn(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Messelite
Ca
 
2
(Fe
2+
 
,Mn
2+
 
)(PO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Parabrandtite
Ca
 
2
Mn
2+
 
(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Talmessite
Ca
 
2
Mg(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Hillite
Ca
 
2
(Zn,Mg)(PO
 
4
)
 
2
 · 2 H
 
2
O
8.CG.10Roselite
Ca
 
2
(Co
2+
 
,Mg)(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.10Wendwilsonite
Ca
 
2
(Mg,Co
2+
 
)(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.10Zincroselite
Ca
 
2
Zn(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.10Rruffite
Ca
 
2
Cu(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.15Ferrilotharmeyerite
Ca(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Lotharmeyerite
Ca(Zn,Mn
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Mawbyite
Pb(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Mounanaite
PbFe
3+
2
(VO
 
4
)
 
2
 · 2(OH,F)
8.CG.15Thometzekite
Pb(Cu,Zn)
 
2
(AsO
 
4
,SO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Tsumcorite
Pb(Zn,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Cobaltlotharmeyerite
Ca(Co,Fe
3+
 
,Ni)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Cabalzarite
Ca(Mg,Al,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Krettnichite
(Pb,Sr)(Mn
3+
 
,Co)
 
2
(VO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Cobalttsumcorite
Pb(Co,Fe
3+
 
,Ni)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Nickellotharmeyerite
Ca(Ni,Fe
3+
 
,Co)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Manganlotharmeyerite
Ca(Mn
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Schneebergite
(Bi
3+
 
,Ca)(Co,Ni,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Nickelschneebergite
(Bi
3+
 
,Ca)(Ni,Co,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.20Gartrellite
Pb(Cu,Fe
3+
 
,Zn)
 
2
(AsO
 
4
,SO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.20Helmutwinklerite
Pb(Zn,Cu)
 
2
(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.20Zincgartrellite
Pb(Zn,Fe
3+
 
,Cu)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.20Rappoldite
Pb(Co,Ni,Zn)
 
2
(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.20Phosphogartrellite
Pb(Cu,Fe
3+
 
)
 
2
(PO
 
4
,AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.20Lukrahnite
Ca(Cu,Zn)(Fe
3+
 
,Zn)(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.25Pottsite
HPbBi(VO
 
4
)
 
2
 · 2H
 
2
O
8.CG.35Nickeltalmessite
Ca
 
2
Ni(AsO
 
4
)
 
2
 · 2H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
20.8.1Sarkinite
Mn
2+
2
(AsO
 
4
)(OH)
20.8.2Eveite
Mn
2+
2
(AsO
 
4
)(OH)
20.8.3Arsenoclasite
Mn
2+
5
(AsO
 
4
)
 
2
(OH)
 
4
20.8.4Flinkite
Mn
2+
2
Mn
3+
 
(AsO
 
4
)(OH)
 
4
20.8.5Jarosewichite
Mn
2+
3
Mn
3+
 
(AsO
 
4
)(OH)
 
6
20.8.6Allactite
Mn
2+
7
(AsO
 
4
)
 
2
(OH)
 
8
20.8.7Krautite
Mn(HAsO
 
4
) · H
 
2
O
20.8.8Synadelphite
Mn
2+
9
(As
5+
 
O
 
4
)
 
2
(As
3+
 
O
 
3
)(OH)
 
9
 · 2H
 
2
O
20.8.9Sterlinghillite
Mn
 
3
(AsO
 
4
)
 
2
 · 4H
 
2
O
20.8.10Geigerite
Mn
2+
5
(AsO
 
4
)
 
2
(HAsO
 
4
)
 
2
 · 10H
 
2
O
20.8.11Akrochordite
(Mn
2+
 
,Mg)
 
5
(AsO
 
4
)
 
2
(OH)
 
4
 · 4H
 
2
O
20.8.12Manganohörnesite
(Mn,Mg)
 
3
(AsO
 
4
)
 
2
 · 8H
 
2
O
20.8.13Fluckite
CaMn
2+
 
(HAsO
 
4
)
 
2
 · 2H
 
2
O
20.8.15Parabrandtite
Ca
 
2
Mn
2+
 
(AsO
 
4
)
 
2
 · 2H
 
2
O
20.8.16Wallkilldellite-(Mn)
Ca
 
2
Mn
2+
3
(AsO
 
4
)
 
2
(OH)
 
4
 · 9H
 
2
O
20.8.17Berzeliite
NaCa
 
2
(Mg,Mn
2+
 
)
 
2
(AsO
 
4
)
 
3
20.8.18Manganberzeliite
(Ca,Na)
 
3
(Mn
2+
 
,Mg)
 
2
(AsO
 
4
)
 
3
20.8.19Magnesiochlorophoenicite
(Mg,Mn)
 
3
Zn
 
2
(AsO
 
4
)(OH,O)
 
6
20.8.20Villyaellenite
MnMn
 
2
Ca
 
2
(AsO
 
4
)
 
2
(HAsO
 
4
)
 
2
 · 4H
 
2
O
20.8.21Hematolite
(Mn,Mg,Al)
 
15
(As
5+
 
O
 
4
)
 
2
(As
3+
 
O
 
3
)(OH)
 
23
20.8.22Grischunite
NaCa
 
2
Mn
2+
5
Fe
3+
 
(AsO
 
4
)
 
6
 · 2H
 
2
O

Other Names for Brandtite

Other Languages:
German:Brandtit
Russian:Брандтит
Spanish:Brandtita

Other Information

Other Information:Soluble in dilute acids.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Brandtite

Reference List:

- +
Nordenskiöld (1888) Svenska Vetenskapsakademien, Stockholm, Handlingar [Ak. Stockholm Öfv.]: 45: 418.

Lindström (1891) Geologiska Föeningens I Stockholm. Förhandlinger, Stockholm: 13L: 123 (Nordenskiöld description in).

Dana, E.S. (1892) System of Mineralogy, 6th. Edition, New York: 811.

Goldschmidt, V. (1913) Atlas der Krystallformen. 9 volumes, atlas, and text: vol. 1: 228.

Aminoff (1919) Geologiska Föeningens I Stockholm. Förhandlinger, Stockholm: 41: 161.

Larsen, E.S. (1921) The Microscopic Determination of the Nonopaque Minerals, First edition, USGS Bulletin 679: 50.

Wolfe (1940) American Mineralogist: 25: 750.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 725-727.

Dahlman, B. (1952): The crystal structures of kröhnkite, CuNa2(SO4)2.2H2O and brandtite, MnCa2(AsO4)2.2H2O. Arkiv för Mineralogi och Geologi, 1, 339-366.

Hawthorne, F. C. and Ferguson, R. B. (1977): The crystal structure of roselite. Canadian Mineralogist 15, 36-42.

Hejny, C., Giester, G., Wildner, M., Götzinger, M. (1997): Die Kristallstruktur von Brandtit, Ca2Mn(AsO4)2 2H2O. European Journal of Mineralogy, Beih. 1, 150.

Internet Links for Brandtite

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  • Raman and XRD data at RRUFF project
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  • Brandtite details from Handbook of Mineralogy (PDF)
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    • Localities for Brandtite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Chile
     
    • Atacama Region
      • Copiapó Province
        • Pabellón
          • Chinchado-Sacramento district
    		Segerstrom, K.(1960); "Cuadrángulo Quebrada Paipote"; Instituto de Investigaciones Geológicas; Stgo de Chile
    Segerstrom, K.(1959); "Cuadrángulo Los Loros"; Instituto de Investigaciones Geológicas; Stgo de Chile
        • Tierra Amarilla
          • Pampa Larga district
    		maurizio dini collection - quantitative analysis
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Central Bohemia Region
        • Příbram
          • Vrančice
    		[Lapis 1995, 12, p.13-24]
    France
     
    • Languedoc-Roussillon
      • Aude
        • Carcassonne
          • Mas-Cabardès
            • Salsigne
    		 Le Règne Minéral, Hors série (3), 36-54
    Pelison P., Descouens D. (1987), Présence de minéraux de néoformation dans les scories de l'ancienne usine de Villagnère (Aude), Le Cahier des Micromonteurs, n°2, pp: 6-10
    Germany
     
    • Bavaria
      • Franconia
        • Spessart
          • Hösbach
            • Sailauf
              • Hartkoppe
    		Lorenz, J. (1991): Die Mineralien im Rhyolithsteinbruch von Sailauf, Der Aufschluss, Vol. 42, 1-38
    • Saxony
      • Erzgebirge
    		Lapis 30(7/8):78-80 (2005)
    Italy
     
    • Liguria
      • La Spezia Province
        • Rocchetta Vara
    		Balestra, C., Kolitsch, U., Blaß, G., Callegari, A.M., Baiocchi, M., Armellino, G., Ciriotti, M.E., Ambrino, P., Bracco, R.: Mineralogia ligure 2007-2008: novità caratterizzate dal servizio UK dell'AMI. Micro (UK report) 1/2009 pp. 78-99
    • Piedmont
      • Torino Province
        • Sesia-Lanzo zone
          • Lanzo Valley
            • Viù Valley
              • Usseglio
    		Piccoli, G.C., Maletto, G., Bosio, P., Lombardo, B. (2007). Minerali del Piemonte e della Valle d'Aosta. Associazione Amici del Museo "F. Eusebio" Alba, Ed., Alba (Cuneo) 607 pp.
    Japan
     
    • Honshu Island
      • Tohoku Region
        • Fukushima Prefecture
          • Iwaki City
    		Matsubara, S. (2000); R. Marumoto collection; Matsubara, S., Miyawaki, R., Kato, A., Matsuyama, F., Mouri, T. and Suzuki, Y. (2001): Arseniopleite from the Gozaisho mine, Fukushima Prefecture, Japan. Bull. Natn. Sci. Mus., Tokyo, Ser. C, 27, 51-62.
    Kazakhstan
     
    • Karagandy Province (Qaragandy Oblysy; Karaganda Oblast')
      • Zhayrem (Zhairem)
        • Ushkatyn (Ushkatan) deposits
    		Frank Dzubeck
    South Africa
     
    • Northern Cape Province
      • Kalahari manganese fields
        • Hotazel
    		[MinRec 22:480]
    Sweden
     
    • Värmland
      • Filipstad
    		Nysten, P., Holtstam, D. and Jonsson, E. (1999) The Långban minerals. In Långban - The mines,their minerals, geology and explorers (D. Holtstam and J. Langhof, eds.), Swedish Museum of Natural History and Raster Förlag, Stockholm & Chr. Weise Verlag, Munich, pp. 89-183.
        • Persberg district
          • Pajsberg
    		Lindström, G. (1891): Mineralanalyser. 1. Brandtit från Harstigen. Geologiska Föreningens i Stockholm Förhandlingar 13: 123-126; Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 726, 857; Canadian Mineralogist (1977): 15: 36; Mineralogical Record: 8: 517, 900; Mineralogical Record: 22: 49.
    Switzerland
     
    • Grischun (Grisons; Graubünden)
      • Oberhalbstein (Surses; Sursass)
        • Tinizong (Tinzen)
    		Geiger, T. (1948): Brandtit aus dem Oberhalbstein GR. Schweiz. Mineral. Petrogr. Mitt. 28, 468-474.
    UK
     
    • England
      • Devon
        • Okehampton area (Northern Dartmoor)
    USA
     
    • New Jersey
      • Sussex Co.
        • Franklin Mining District
          • Ogdensburg
            • Sterling Hill
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 726; Gaines, R.V. (1959) American Mineralogist: 44: 199-200; Mineralogical Record: 13: 36; Dunn, P.J. (1995): Dunn, Pete J. (1995): Franklin and Sterling Hill New Jersey: the world’s most magnificent mineral deposits, part 5: 659.
    Mineral and/or Locality
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