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Parabrandtite

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Gozaisho mine, Iwaki City, Fukushima Prefecture, Tohoku Region, Honshu Island, Japan




Formula:
Ca
 
2
Mn
2+
 
(AsO
 
4
)
 
2
 · 2H
 
2
O
System:TriclinicColour:Colourless
Hardness:3 - 4
Member of:Fairfieldite Group
Name:Named in allusion to its dimorphous relationship with brandtite.


Fairfieldite Group.

Only 3 co-type specimens exist. The material was discovered by Fred Parker, American collector of Franklin Minerals, and a local mineral dealer in Maryland, in a single flat of specimens purchased from a miner, and submitted by Parker for analysis and identification.

Classification of Parabrandtite

IMA status:Approved 1986
Strunz 8th edition ID:7/C.17-70
Nickel-Strunz 10th (pending) edition ID:8.CG.05

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
G : With large and medium-sized cations, RO4:H2O = 1:1
Dana 8th edition ID:40.2.2.8

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
2 : AB2(XO4)2·xH2O
Hey's CIM Ref.:20.8.15

20 : Arsenates (also arsenates with phosphate, but without other anions)
8 : Arsenates of Mn
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Type Occurrence of Parabrandtite

Type Locality:Sterling Mine, Sterling Hill, Ogdensburg, Franklin Mining District, Sussex Co., New Jersey, USA
General Appearance of Type Material:Microscopic gtroups of crystals on the surfaces of the fissures.
Year of Discovery:1986
Geological Setting of type material:Fissures traversing massive willemite-franklinite "red" ore in the Sterling Hill ore body.
Associated Minerals at type locality:
WillemiteSphaleriteFranklinite

Physical Properties of Parabrandtite

Diaphaneity (Transparency):Transparent
Colour:Colourless
Hardness (Mohs):3 - 4

Crystallography of Parabrandtite

Crystal System:Triclinic
Cell Parameters:a = 5.89Å, b = 7.03Å, c = 5.64Å
α = 96.77°, β = 109.32°, γ = 108.47°
Ratio:a:b:c = 0.838 : 1 : 0.802
Unit Cell Volume:V 202.46 ų (Calculated from Unit Cell)
Morphology:Intergrown, parallel, wedge-shaped crystal aggregates to 1.5 mm.

Optical Data of Parabrandtite

Type:Biaxial (+)
RI values: nα = 1.701 nβ = 1.721 nγ = 1.751
2V:Measured: 79° , Calculated: 80°
Maximum Birefringence:δ = 0.050

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:r > v weak

Chemical Properties of Parabrandtite

Formula:
Ca
 
2
Mn
2+
 
(AsO
 
4
)
 
2
 · 2H
 
2
O
Essential elements:As, Ca, H, Mn, O
All elements listed in formula:As, Ca, H, Mn, O

Relationship of Parabrandtite to other Species

Member of:Fairfieldite Group
Other Members of Group:

- +
Cassidyite
Ca
 
2
(Ni
2+
 
,Mg)(PO
 
4
)
 
2
 · 2H
 
2
O
Collinsite
Ca
 
2
(Mg,Fe
2+
 
)(PO
 
4
)
 
2
 · 2H
 
2
O
Fairfieldite
Ca
 
2
(Mn
2+
 
,Fe
2+
 
)(PO
 
4
)
 
2
 · 2H
 
2
O
Gaitite
Ca
 
2
Zn(AsO
 
4
)
 
2
 · 2H
 
2
O
Messelite
Ca
 
2
(Fe
2+
 
,Mn
2+
 
)(PO
 
4
)
 
2
 · 2H
 
2
O
Nickeltalmessite
Ca
 
2
Ni(AsO
 
4
)
 
2
 · 2H
 
2
O
Talmessite
Ca
 
2
Mg(AsO
 
4
)
 
2
 · 2H
 
2
O
β-Roselite
Ca
 
2
(Co
2+
 
,Mg)(AsO
 
4
)
 
2
 · 2H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
8.CG.05Cassidyite
Ca
 
2
(Ni
2+
 
,Mg)(PO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Collinsite
Ca
 
2
(Mg,Fe
2+
 
)(PO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Fairfieldite
Ca
 
2
(Mn
2+
 
,Fe
2+
 
)(PO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Gaitite
Ca
 
2
Zn(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Messelite
Ca
 
2
(Fe
2+
 
,Mn
2+
 
)(PO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Talmessite
Ca
 
2
Mg(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.05Hillite
Ca
 
2
(Zn,Mg)(PO
 
4
)
 
2
 · 2 H
 
2
O
8.CG.10Brandtite
Ca
 
2
(Mn
2+
 
,Mg)(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.10Roselite
Ca
 
2
(Co
2+
 
,Mg)(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.10Wendwilsonite
Ca
 
2
(Mg,Co
2+
 
)(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.10Zincroselite
Ca
 
2
Zn(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.10Rruffite
Ca
 
2
Cu(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.15Ferrilotharmeyerite
Ca(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Lotharmeyerite
Ca(Zn,Mn
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Mawbyite
Pb(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Mounanaite
PbFe
3+
2
(VO
 
4
)
 
2
 · 2(OH,F)
8.CG.15Thometzekite
Pb(Cu,Zn)
 
2
(AsO
 
4
,SO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Tsumcorite
Pb(Zn,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Cobaltlotharmeyerite
Ca(Co,Fe
3+
 
,Ni)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Cabalzarite
Ca(Mg,Al,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Krettnichite
(Pb,Sr)(Mn
3+
 
,Co)
 
2
(VO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Cobalttsumcorite
Pb(Co,Fe
3+
 
,Ni)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Nickellotharmeyerite
Ca(Ni,Fe
3+
 
,Co)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.15Manganlotharmeyerite
Ca(Mn
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Schneebergite
(Bi
3+
 
,Ca)(Co,Ni,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.15Nickelschneebergite
(Bi
3+
 
,Ca)(Ni,Co,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
 · 2(OH,H
 
2
O)
8.CG.20Gartrellite
Pb(Cu,Fe
3+
 
,Zn)
 
2
(AsO
 
4
,SO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.20Helmutwinklerite
Pb(Zn,Cu)
 
2
(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.20Zincgartrellite
Pb(Zn,Fe
3+
 
,Cu)
 
2
(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.20Rappoldite
Pb(Co,Ni,Zn)
 
2
(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CG.20Phosphogartrellite
Pb(Cu,Fe
3+
 
)
 
2
(PO
 
4
,AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.20Lukrahnite
Ca(Cu,Zn)(Fe
3+
 
,Zn)(AsO
 
4
)
 
2
 · 2(H
 
2
O,OH)
8.CG.25Pottsite
HPbBi(VO
 
4
)
 
2
 · 2H
 
2
O
8.CG.35Nickeltalmessite
Ca
 
2
Ni(AsO
 
4
)
 
2
 · 2H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
20.8.1Sarkinite
Mn
2+
2
(AsO
 
4
)(OH)
20.8.2Eveite
Mn
2+
2
(AsO
 
4
)(OH)
20.8.3Arsenoclasite
Mn
2+
5
(AsO
 
4
)
 
2
(OH)
 
4
20.8.4Flinkite
Mn
2+
2
Mn
3+
 
(AsO
 
4
)(OH)
 
4
20.8.5Jarosewichite
Mn
2+
3
Mn
3+
 
(AsO
 
4
)(OH)
 
6
20.8.6Allactite
Mn
2+
7
(AsO
 
4
)
 
2
(OH)
 
8
20.8.7Krautite
Mn(HAsO
 
4
) · H
 
2
O
20.8.8Synadelphite
Mn
2+
9
(As
5+
 
O
 
4
)
 
2
(As
3+
 
O
 
3
)(OH)
 
9
 · 2H
 
2
O
20.8.9Sterlinghillite
Mn
 
3
(AsO
 
4
)
 
2
 · 4H
 
2
O
20.8.10Geigerite
Mn
2+
5
(AsO
 
4
)
 
2
(HAsO
 
4
)
 
2
 · 10H
 
2
O
20.8.11Akrochordite
(Mn
2+
 
,Mg)
 
5
(AsO
 
4
)
 
2
(OH)
 
4
 · 4H
 
2
O
20.8.12Manganohörnesite
(Mn,Mg)
 
3
(AsO
 
4
)
 
2
 · 8H
 
2
O
20.8.13Fluckite
CaMn
2+
 
(HAsO
 
4
)
 
2
 · 2H
 
2
O
20.8.14Brandtite
Ca
 
2
(Mn
2+
 
,Mg)(AsO
 
4
)
 
2
 · 2H
 
2
O
20.8.16Wallkilldellite-(Mn)
Ca
 
2
Mn
2+
3
(AsO
 
4
)
 
2
(OH)
 
4
 · 9H
 
2
O
20.8.17Berzeliite
NaCa
 
2
(Mg,Mn
2+
 
)
 
2
(AsO
 
4
)
 
3
20.8.18Manganberzeliite
(Ca,Na)
 
3
(Mn
2+
 
,Mg)
 
2
(AsO
 
4
)
 
3
20.8.19Magnesiochlorophoenicite
(Mg,Mn)
 
3
Zn
 
2
(AsO
 
4
)(OH,O)
 
6
20.8.20Villyaellenite
MnMn
 
2
Ca
 
2
(AsO
 
4
)
 
2
(HAsO
 
4
)
 
2
 · 4H
 
2
O
20.8.21Hematolite
(Mn,Mg,Al)
 
15
(As
5+
 
O
 
4
)
 
2
(As
3+
 
O
 
3
)(OH)
 
23
20.8.22Grischunite
NaCa
 
2
Mn
2+
5
Fe
3+
 
(AsO
 
4
)
 
6
 · 2H
 
2
O

Other Names for Parabrandtite

Synonyms:
IMA1986-009
Other Languages:
German:Parabrandtit
Russian:Парабрандтит
Spanish:Parabrandtita

Other Information

Fluorescence in UV light:None.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Parabrandtite

Reference List:

- +
Dunn, P.J., et al (1987), Neues Jahrbuch für Mineralogie, Monatshefte: 2: 113-119.

American Mineralogist (1988): 73: 1496.

Dunn, Pete J. (1995): Franklin and Sterling Hill New Jersey: the world's most magnificent mineral deposits, part 5: 675.

Internet Links for Parabrandtite

Search Engines:
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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Parabrandtite details from Handbook of Mineralogy (PDF)
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    • Localities for Parabrandtite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Japan
     
    • Honshu Island
      • Tohoku Region
        • Fukushima Prefecture
          • Iwaki City
    		Alfredo Petrov collection (named parabrandtite on original japanese label, but no analytical data presented). Feb. 2010: Single crystal XRD identification, G. Giester & F. Neuhold
    USA
     
    • New Jersey
      • Sussex Co.
        • Franklin Mining District
          • Ogdensburg
            • Sterling Hill
    		Dunn, P.J., et al: Neues Jahrbuch für Min. Abhandlungen:157:113-119 (1987); Dunn(1995):Pt5:675.
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