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Oscarkempffite

A valid IMA mineral species
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Formula:
Ag10Pb4(Sb17Bi9)S48
Colour:
Greyish black
Lustre:
Metallic
Hardness:
3 - 3½
Specific Gravity:
5.8 (Calculated)
Crystal System:
Orthorhombic
Name:
Named in honour of Oscar Kempff Bacigalupo (b. 1948), Bolivian engineering geologist and mineralogist who discovered several large mineral deposits in Bolivia.
Lillianite homologue with N = 4. Chemically similar to clino-oscarkempffite, holubite, lazerckerite, and staročeskéite; and somewhat resembling borodaevite and terrywallaceite.

Found in old material (1929-1930).




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Unique IdentifiersHide

Mindat ID:
41958
Long-form identifier:
mindat:1:1:41958:7
GUID
(UUID V4):
b1c9169a-d962-4391-9003-89ac8574fe3f

IMA Classification of OscarkempffiteHide

Classification of OscarkempffiteHide

2.JB.

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
B : Galena derivatives, with Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
OkpIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of OscarkempffiteHide

Metallic
Transparency:
Opaque
Colour:
Greyish black
Hardness:
3 - 3½ on Mohs scale
Hardness:
VHN100=189 - 208 - Vickers
Tenacity:
Brittle
Cleavage:
None Observed
Without any discernible cleavage
Density:
5.8 g/cm3 (Calculated)

Optical Data of OscarkempffiteHide

Anisotropism:
grey rotation tints
Reflectivity:
WavelengthR1R2
470nm39.9%42.6%
546nm38.6%41.7%
589nm38.1%41.2%
650nm37.3%40.6%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 42.6%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Grayish white
Internal Reflections:
not present
Pleochroism:
Visible
Comments:
White to dark grey

Chemistry of OscarkempffiteHide

Mindat Formula:
Ag10Pb4(Sb17Bi9)S48
Common Impurities:
Cu

Crystallography of OscarkempffiteHide

Crystal System:
Orthorhombic
Class (H-M):
mm2 - Pyramidal
Cell Parameters:
a = 13.199(2) Å, b = 19.332(3) Å, c = 8.294(1) Å
Ratio:
a:b:c = 0.683 : 1 : 0.429
Unit Cell V:
2,116.32 ų (Calculated from Unit Cell)
Morphology:
Anhedral grains; grain aggregates up to 10 mm.
Comment:
Space group: Pnca

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.354 Å(100)
2.988 Å(40)
2.889 Å(80)
2.263 Å(40)
2.066 Å(60)
1.766 Å(50)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of OscarkempffiteHide

General Appearance of Type Material:
Found in old material (1929-30), as anhedral grains, and grain aggregates up to 10 mm across.
Place of Conservation of Type Material:
Department of Materials Engineering and Physics, University of Salzburg, Salzburg,Austria, specimen number 15000, and the Natural History Museum, London, United Kingdom, specimen number BM 20, 3
Associated Minerals at Type Locality:
Reference:
Topa, D., Paar, W.H., Makovicky, E., Stanley, C.J., Roberts, A.C. (2016) Oscarkempffite, Ag10Pb4(Sb17Bi9)Σ26S48, a new Sb-Bi member of the lillianite homologous series. Mineralogical Magazine: 80: 809-817.

Synonyms of OscarkempffiteHide

Other Language Names for OscarkempffiteHide

Relationship of Oscarkempffite to other SpeciesHide

Other Members of this group:
AndreadiniiteCuHgAg7Pb7Sb24S48Mon. 2/m : P21/b
ArsenquatrandoriteAg17.6Pb12.8Sb38.1As11.5S96Mon. 2/m : P21/b
AschamalmitePb6-3xBi2+xS9Mon. 2/m : B2/m
Clino-oscarkempffiteAg15Pb6Sb21Bi18S72Mon. 2/m : P21/b
ErzwiesiteAg8Pb12Bi16S40Orth. mmm (2/m 2/m 2/m) : Cmcm
EskimoiteAg7Pb10Bi15S36Mon.
FizélyiteAg5Pb14Sb21S48 Mon. 2/m
GustaviteAgPbBi3S6Orth. mmm (2/m 2/m 2/m)
HeyrovskýitePb6Bi2S9Orth. mmm (2/m 2/m 2/m) : Cccm
HolubiteAg3Pb6(Sb8Bi3)S24Mon. 2/m
JasrouxiteAg16Pb4(Sb24As16)S72Tric. 1 : P1
LasmanisiteAg12Pb13Mn11Sb44S96Orth. 2 2 2 : P21 21 21
LillianitePb3-2xAgxBi2+xS6Orth. mmm (2/m 2/m 2/m)
MenchettiiteAgPb2.40Mn1.60Sb3As2S12Mon. 2/m : P21/b
OurayiteAg3Pb4Bi5S13Orth.
OyoniteAg3Mn2Pb4Sb7As4S24Mon. 2/m
QuatrandoriteAgPbSb3S6Mon. 2/m : P21/b
RamdohritePb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24Mon. 2/m
RoshchiniteAg19Pb10Sb51S96Orth. mmm (2/m 2/m 2/m) : Pnma
SchirmeritePbAgBi3S6 - Pb3Ag1.5Bi3.5S9Orth.
SenandoriteAgPbSb3S6Orth. mm2 : Pmn21
StaročeskéiteAg0.70Pb1.60(Bi1.35Sb1.35)Σ2.70S6Orth. mmm (2/m 2/m 2/m) : Cmcm
TerrywallaceiteAgPb(Sb,Bi)3S6 Mon. 2/m : P21/b
TreasuriteAg7Pb6Bi15S32Mon.
UchucchacuaiteAgMnPb3Sb5S12Orth. mmm (2/m 2/m 2/m) : Pmmm
UstarasitePb(Bi,Sb)6S10 (?)
VikingiteAg5Pb8Bi13S30Mon. 2/m : B2/m
XilingolitePb3Bi2S6Mon.

Related Minerals - Strunz-mindat GroupingHide

2.JB.SenandoriteAgPbSb3S6Orth. mm2 : Pmn21
2.JB.ChukotkaiteAgPb7Sb5S15Mon. 2/m : P21/b
2.JB.ArsenquatrandoriteAg17.6Pb12.8Sb38.1As11.5S96Mon. 2/m : P21/b
2.JB.Clino-oscarkempffiteAg15Pb6Sb21Bi18S72Mon. 2/m : P21/b
2.JB.AndreadiniiteCuHgAg7Pb7Sb24S48Mon. 2/m : P21/b
2.JB.GinelfiteAg2(Ag0.5Fe)TlPb23.5(Sb,As)33.5S76Tric. 1 : P1
2.JB.LazerckeriteAg3.75Pb4.50(Sb7.75Bi4)S24Mon. 2/m
2.JB.LasmanisiteAg12Pb13Mn11Sb44S96Orth. 2 2 2 : P21 21 21
2.JB.MontpelvouxiteAgPb16Sb27As18S84Tric. 1 : P1
2.JB.SelenojunoiteCu2Pb3Bi8Se16Mon. 2/m : B2/m
2.JB.05DiaphoriteAg3Pb2Sb3S8Mon. 2/m : P21/b
2.JB.10CosalitePb2Bi2S5Orth. mmm (2/m 2/m 2/m)
2.JB.15FreieslebeniteAgPbSbS3Mon. 2/m : P21/b
2.JB.15MarriteAgPbAsS3Mon. 2/m : P21/b
2.JB.20CannizzaritePb48Bi56S132Mon. 2/m : P21/m
2.JB.20WittitePb9Bi12(S,Se)27Mon.
2.JB.25aJunoiteCu2Pb3Bi8(S,Se)16Mon. 2/m : B2/m
2.JB.25iNeyiteAg2Cu6Pb25Bi26S68Mon. 2/m : B2/m
2.JB.25cNordströmiteCuPb3Bi7(Se4S10)Mon. 2/m : P21/m
2.JB.25gNuffielditeCu1.4Pb2.4Bi2.4Sb0.2S7Orth. mmm (2/m 2/m 2/m)
2.JB.25dProuditeCuPb7.5Bi9.33(S,Se)22Mon. 2/m : B2/m
2.JB.25hWeibullitePb5Bi8Se7S11Orth. mmm (2/m 2/m 2/m) : Pnma
2.JB.25bFelbertaliteCu2Pb6Bi8S19Mon. 2/m : B2/m
2.JB.25jRouxeliteCu2HgPb23Sb27S65.5Mon. 2/m : B2/m
2.JB.25fÁngelaiteCu2AgPbBiS4Orth. mmm (2/m 2/m 2/m) : Pnma
2.JB.25iCuproneyiteCu7Pb27Bi25S68Mon. 2/m : B2/m
2.JB.30aGeocronitePb14Sb6S23Mon. 2/m : P21/m
2.JB.30aJordanitePb14As6S23Mon. 2/m : P21/m
2.JB.30bKirkiitePb10Bi3As3S19Mon. 2/m : P21/m
2.JB.30cTsugaruitePb28As15S50ClOrth. mm2 : Pnn2
2.JB.30aMarcobaldiitePb12(Sb3As2Bi)Σ6S21Tric. 1 : P1
2.JB.30aArsenmarcobaldiitePb12(As3.2Sb2.8)Σ6S21Tric. 1 : P1
2.JB.35cPillaitePb9Sb10S23ClO0.5Mon. 2/m : B2/m
2.JB.35aZinkenitePb9Sb22S42Hex. 6 : P63
2.JB.35bScainiitePb14Sb30S54O5Mon. 2/m : B2/m
2.JB.35dPellouxite(Cu,Ag)Pb10Sb12S27O(Cl,S)0.6Mon. 2/m : B2/m
2.JB.35fTubuliteAg2Pb22Sb20S53 Mon. m : Pb
2.JB.35eChovanitePb15-2xSb14+2xS36Ox (x ~ 0.2)Mon. 2/m : B2/m
2.JB.40bAschamalmitePb6-3xBi2+xS9Mon. 2/m : B2/m
2.JB.40aBursaitePb5Bi4S11 (?)Orth.
2.JB.40bEskimoiteAg7Pb10Bi15S36Mon.
2.JB.40aFizélyiteAg5Pb14Sb21S48 Mon. 2/m
2.JB.40aGustaviteAgPbBi3S6Orth. mmm (2/m 2/m 2/m)
2.JB.40aLillianitePb3-2xAgxBi2+xS6Orth. mmm (2/m 2/m 2/m)
2.JB.40cOurayiteAg3Pb4Bi5S13Orth.
2.JB.40aRamdohritePb5.9Fe0.1Mn0.1In0.1Cd0.2Ag2.8Sb10.8S24Mon. 2/m
2.JB.40aRoshchiniteAg19Pb10Sb51S96Orth. mmm (2/m 2/m 2/m) : Pnma
2.JB.40dSchirmeritePbAgBi3S6 - Pb3Ag1.5Bi3.5S9Orth.
2.JB.40aTreasuriteAg7Pb6Bi15S32Mon.
2.JB.40aUchucchacuaiteAgMnPb3Sb5S12Orth. mmm (2/m 2/m 2/m) : Pmmm
2.JB.40eUstarasitePb(Bi,Sb)6S10 (?)
2.JB.40aVikingiteAg5Pb8Bi13S30Mon. 2/m : B2/m
2.JB.40aXilingolitePb3Bi2S6Mon.
2.JB.40bHeyrovskýitePb6Bi2S9Orth. mmm (2/m 2/m 2/m) : Cccm
2.JB.40UM1988-05-S:AgBiCuHgPb(Hg,Ag,Cu,Pb)5Pb5Bi11S27
2.JB.40UM1988-06-S:AgBiCuHgPb(Pb,Hg)12(Cu,Ag)3(Bi,Sb)10(S,Te)27
2.JB.40aQuatrandoriteAgPbSb3S6Mon. 2/m : P21/b
2.JB.40aMenchettiiteAgPb2.40Mn1.60Sb3As2S12Mon. 2/m : P21/b
2.JB.40aTerrywallaceiteAgPb(Sb,Bi)3S6 Mon. 2/m : P21/b
2.JB.40aJasrouxiteAg16Pb4(Sb24As16)S72Tric. 1 : P1
2.JB.40aErzwiesiteAg8Pb12Bi16S40Orth. mmm (2/m 2/m 2/m) : Cmcm
2.JB.40aStaročeskéiteAg0.70Pb1.60(Bi1.35Sb1.35)Σ2.70S6Orth. mmm (2/m 2/m 2/m) : Cmcm
2.JB.40aOyoniteAg3Mn2Pb4Sb7As4S24Mon. 2/m
2.JB.40aHolubiteAg3Pb6(Sb8Bi3)S24Mon. 2/m
2.JB.40bBaiamareiteAg4Pb12Fe4Sb20S48Mon. 2/m
2.JB.55GratonitePb9As4S15Trig. 3m : R3m
2.JB.60MarrucciiteHg3Pb16Sb18S46Mon. 2/m : B2/m
2.JB.65VurroitePb20Sn2(Bi,As)22S54Cl6Mon. 2/m : B2/b
2.JB.65TazieffitePb20Cd2(As,Bi)22S50Cl10Mon. 2/m : B2/b
2.JB.70DaliranitePbHgAs2S5Mon.

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for OscarkempffiteHide

References for OscarkempffiteHide

Localities for OscarkempffiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Bolivia
 
  • Potosí
    • Sud Chichas Province
      • Atocha Municipality
Cazorla Martínez et al. (2019)
Torró et al. (2019)
            • Colorada vein
Williams et al. (2011) +1 other reference
 
and/or  
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