Philrothite
A valid IMA mineral species
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About Philrothite
Formula:
TlAs3S5
Lustre:
Metallic
Hardness:
3 - 3½
Specific Gravity:
4.635 (Calculated)
Crystal System:
Monoclinic
Member of:
Name:
Named in honour of Philippe Roth (b. 1963), geophysicist and former head of the 'Forschungsgemeinschaft Lengenbach'. He is a well known expert on the Lengenbach and other Alpine metallic deposits' minerals.
Type Locality:
Unique Identifiers
Mindat ID:
44003
Long-form identifier:
mindat:1:1:44003:7
GUID
(UUID V4):
(UUID V4):
deec2c55-996c-4977-a160-a669eabc3b10
IMA Classification of Philrothite
Approved
Approval year:
2013
First published:
2014
Classification of Philrothite
2.HC.05f
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
C : With only Pb
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
C : With only Pb
Mineral Symbols
As of 2021 there are now IMAâCNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Phr | IMAâCNMNC | Warr, L.N. (2021). IMAâCNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Philrothite
Metallic
Transparency:
Opaque
Streak:
Dark brown streak
Hardness:
3 - 3½ on Mohs scale
Comment:
(VHN25) is 128 kg/mm2 (range: 120â137)
Tenacity:
Brittle
Density:
4.635 g/cm3 (Calculated)
Optical Data of Philrothite
Anisotropism:
Grey to bluish rotation tints (Under crossed polars)
Reflectivity:
Wavelength | R1 | R2 |
---|---|---|
471nm | 26.5% | 28.8% |
548nm | 25.4% | 27.2% |
586nm | 24.6% | 26.3% |
652nm | 24.0% | 25.1% |
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 28.8%.
R1 shown in black, R2 shown in red
Pleochroism:
Weak
Comments:
Weakly pleochroic from dark grey to light grey
Chemistry of Philrothite
Mindat Formula:
TlAs3S5
Elements listed:
Crystallography of Philrothite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 8.013(2) Å, b = 24.829(4) Å, c = 11.762(3) Å
β = 132.84(2)°
β = 132.84(2)°
Ratio:
a:b:c = 0.323 : 1 : 0.474
Unit Cell V:
1715.9 Ă
Âł
Z:
8
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0020025 | Philrothite | Bindi L, Nestola F, Makovicky E, Guastoni A, De Battisti L (2014) Tl-bearing sulfosalt from the Lengenbach quarry, Binn Valley, Switzerland: Philrothite, TlAs3S5 Mineralogical Magazine 78 1-9 | 2014 | Lengenbach quarry, Binn Valley, Switzerland | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
12.4145 Ă | (52) |
3.6768 Ă | (100) |
3.4535 Ă | (45) |
3.0150 Ă | (46) |
2.8941 Ă | (52) |
2.7685 Ă | (76) |
2.7642 Ă | (77) |
2.3239 Ă | (52) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-đ alteration and/or metamorphism | |
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) |
Type Occurrence of Philrothite
General Appearance of Type Material:
Crystals up to 200 ÎŒm across on realgar
Place of Conservation of Type Material:
Museum of Mineralogy, Department of Geosciences, University of Padova, Italy (MMP M12605).
Associated Minerals at Type Locality:
Reference:
Bindi, L., Nestola, F., Makovicky, E., Guastoni, A., de Battisti, L. (2014): Tl-bearing sulfosalt from the Lengenbach quarry, Binn valley, Switzerland: Philrothite, TlAs3S5. Mineralogical Magazine: 78: 1-9.
Synonyms of Philrothite
Relationship of Philrothite to other Species
Member of:
Other Members of this group:
Argentobaumhauerite | Ag1.5Pb22As33.5S72 | Tric. 1 : P1 |
Argentodufrénoysite | Ag3Pb26As35S80 | Tric. 1 : P1 |
Argentoliveingite | Ag3+xPb36-2xAs51+xS112 | Tric. 1 : P1 |
Barikaite | Ag3Pb10(Sb8As11)S40 | Mon. 2/m : P21/b |
Baumhauerite | Pb12As16S36 | Tric. 1 : P1 |
Bernarlottiite | Pb6(As5Sb3)S18 | Tric. 1 : P1 |
Boscardinite | TlPb4(Sb7As2)S18 | Tric. 1 : P1 |
Carducciite | (Ag2Sb2)Pb12(As,Sb)16S40 | Mon. 2/m : P21/b |
Dekatriasartorite | TlPb58As97S204 | Mon. 2/m : P21/b |
Dufrénoysite | Pb2As2S5 | Mon. 2 : P21 |
Ăcrinsite | AgTl3Pb4As11Sb9S36 | Tric. 1 : P1 |
Enneasartorite | Tl6Pb32As70S140 | Mon. 2/m : P21/b |
Guettardite | Pb8(Sb0.56As0.44)16S32 | Mon. 2/m : P21/b |
Hendekasartorite | Tl2Pb48As82S172 | Mon. 2/m : P21/b |
Heptasartorite | Tl7Pb22As55S108 | Mon. 2/m : P21/b |
HyrĆĄlite | Pb8As10Sb6S32 | Mon. 2 : P21 |
Incomsartorite | Tl6Pb144As246S516 | Mon. 2/m |
Interliveingite | AgPb18As25S56 | Mon. 2 : P21 |
Liveingite | Pb9As13S28 | Mon. 2 : P21 |
Parapierrotite | TlSb5S8 | Mon. m |
Pierrotite | Tl2(Sb,As)10S16 | Orth. mm2 : Pna21 |
Polloneite | AgPb46As26Sb23S120 | Mon. 2 : P21 |
Rathite | Ag2Pb12-xTlx/2As18+x/2S40 | Mon. 2/m : P21/b |
Sartorite | PbAs2S4 | Mon. 2/m : P21/m |
Twinnite | Pb0.8Tl0.1Sb1.3As0.8S4 | Mon. 2/m |
Veenite | Pb16Sb9-xAs7+xS40, x ~ 0-0.5 | Mon. 2 : P21 |
Related Minerals - Strunz-mindat Grouping
2.HC. | Bernarlottiite | Pb6(As5Sb3)S18 |
2.HC.05b | Argentobaumhauerite | Ag1.5Pb22As33.5S72 |
2.HC.05b | Baumhauerite | Pb12As16S36 |
2.HC.05d | Dufrénoysite | Pb2As2S5 |
2.HC.05a | Guettardite | Pb8(Sb0.56As0.44)16S32 |
2.HC.05c | Liveingite | Pb9As13S28 |
2.HC.05f | Parapierrotite | TlSb5S8 |
2.HC.05f | Pierrotite | Tl2(Sb,As)10S16 |
2.HC.05d | Rathite | Ag2Pb12-xTlx/2As18+x/2S40 |
2.HC.05a | Sartorite | PbAs2S4 |
2.HC.05a | Twinnite | Pb0.8Tl0.1Sb1.3As0.8S4 |
2.HC.05d | Veenite | Pb16Sb9-xAs7+xS40, x ~ 0-0.5 |
2.HC.05g | Marumoite | Pb32As40S92 |
2.HC.05d | Rathite-IV | PbAs2S4 |
2.HC.05h | Polloneite | AgPb46As26Sb23S120 |
2.HC.05e | Heptasartorite | Tl7Pb22As55S108 |
2.HC.05e | Hendekasartorite | Tl2Pb48As82S172 |
2.HC.05e | Ăcrinsite | AgTl3Pb4As11Sb9S36 |
2.HC.05b | Baumhauerite II | |
2.HC.05c | Argentoliveingite | Ag3+xPb36-2xAs51+xS112 |
2.HC.05e | Incomsartorite | Tl6Pb144As246S516 |
2.HC.05d | Argentodufrénoysite | Ag3Pb26As35S80 |
2.HC.05a | HyrĆĄlite | Pb8As10Sb6S32 |
2.HC.05e | Dekatriasartorite | TlPb58As97S204 |
2.HC.10a | FĂŒlöppite | Pb3Sb8S15 |
2.HC.10c | Heteromorphite | Pb7Sb8S19 |
2.HC.10b | Plagionite | Pb5Sb8S17 |
2.HC.10d | Rayite | Pb8(Ag,Tl)2Sb8S21 |
2.HC.10d | Semseyite | Pb9Sb8S21 |
2.HC.15 | Boulangerite | Pb5Sb4S11 |
2.HC.15 | Falkmanite | Pb3Sb2S6 |
2.HC.20 | Robinsonite | Pb4Sb6S13 |
2.HC.25 | Moëloite | Pb6Sb6S14(S3) |
2.HC.30 | Dadsonite | Pb23Sb25S60Cl |
2.HC.35 | Owyheeite | Ag3Pb10Sb11S28 |
2.HC.35 | Zoubekite | AgPb4Sb4S10 |
2.HC.40 | Parasterryite | Ag4Pb20Sb14As10S58 |
2.HC.50 | Lopatkaite | Pb5Sb3AsS11 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Philrothite
mindat.org URL:
https://www.mindat.org/min-44003.html
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References for Philrothite
Localities for Philrothite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
â - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Russia | |
| Stepanov +9 other references |
Switzerland (TL) | |
| Bindi et al. (2014) |
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Lengenbach Quarry, FĂ€ld, Binn, Goms, Valais, Switzerland