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Cano, Néstor, Camprubí, Antoni, Proenza, Joaquín A., González-Partida, Eduardo (2024) Genesis and evolution of the Natividad Au-Ag(-Ge) epithermal deposit in southern Mexico: Unravelling the final chapters of the Sierra Madre del Sur metallogeny. Ore Geology Reviews, 167. 105979 doi:10.1016/j.oregeorev.2024.105979

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Reference TypeJournal (article/letter/editorial)
TitleGenesis and evolution of the Natividad Au-Ag(-Ge) epithermal deposit in southern Mexico: Unravelling the final chapters of the Sierra Madre del Sur metallogeny
JournalOre Geology Reviews
AuthorsCano, NéstorAuthor
Camprubí, AntoniAuthor
Proenza, Joaquín A.Author
González-Partida, EduardoAuthor
Year2024Volume<   167   >
Page(s)105979
URL
DOIdoi:https://doi.org/10.1016/j.oregeorev.2024.105979Search in ResearchGate
Classification
Not set
LoC
Not set
Mindat Ref. ID17216037Long-form Identifiermindat:1:5:17216037:7
GUID763d111c-b33a-466a-b550-93cd1a1878b3
Full ReferenceCano, Néstor, Camprubí, Antoni, Proenza, Joaquín A., González-Partida, Eduardo (2024) Genesis and evolution of the Natividad Au-Ag(-Ge) epithermal deposit in southern Mexico: Unravelling the final chapters of the Sierra Madre del Sur metallogeny. Ore Geology Reviews, 167. 105979 doi:10.1016/j.oregeorev.2024.105979
Plain TextCano, Néstor, Camprubí, Antoni, Proenza, Joaquín A., González-Partida, Eduardo (2024) Genesis and evolution of the Natividad Au-Ag(-Ge) epithermal deposit in southern Mexico: Unravelling the final chapters of the Sierra Madre del Sur metallogeny. Ore Geology Reviews, 167. 105979 doi:10.1016/j.oregeorev.2024.105979
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Abstract/NotesThe final magmatic arc—Miocene in age—of the long-lived Sierra Madre del Sur igneous province in southern Mexico hosts several epithermal deposits that have hitherto received little attention. The Natividad Au-Ag(-Ge) epithermal deposit is one of them and holds a mining record of > 200 years. Here, we present the first petrogenetic and metallogenic study on the Natividad deposit, in which we use a multi-methodological approach to assess the genesis and evolution of the deposit and its associated igneous rocks. Natividad is mostly hosted by Oligocene–Miocene arc-related dacites (U-Pb zircon dates of 22.8–24.7 Ma), whose geochemical features suggest lower-crustal differentiation (i.e., involvement of garnet) at the base of a thickened continental crust. The mineralization occurs in three multi-stage quartz + carbonate veins and consists of Fe-poor sphalerite (<5 mol. % FeS), galena, chalcopyrite, acanthite, and marcasite (sulfide-dominated stage) overprinted by pearceite-polybasite, pyrargyrite-proustite, tetrahedrite-group minerals, electrum, and argyrodite (Ag8GeS6; Ag-sulfosalt-dominated stage). Geothermometry and fluid inclusion data for ore-bearing assemblages reveal fluid temperatures of 170°–400 °C and salinities of 14.6–19.5 wt% NaCl equiv. δ18O from 0.8 ‰ to 7.5 ‰ in mineralizing fluids suggests mixtures of magmatic brines and meteoric waters, while δ13C from –8.4 ‰ to 2.2 ‰ indicates the recycling of organic carbon from the meta-sedimentary basement. Further, δ34S from –3.2 ‰ to –0.3 ‰ in sulfides attest to magmatic S. These results align with an intermediate-sulfidation epithermal model, whereby upwelling magmatic ore-bearing brines precipitated the ores due to conductive cooling, dilution, and, locally, boiling. Our study highlights the metallogenic potential of Miocene magmatism in the eastern Sierra Madre de Sur.

Map of Localities

Locality Pages

LocalityCitation Details
Dulce Nombre mine, Natividad, Natividad Municipality, Oaxaca, Mexico
El Convento vein, Dulce Nombre mine, Natividad, Natividad Municipality, Oaxaca, Mexico
Natividad vein, Dulce Nombre mine, Natividad, Natividad Municipality, Oaxaca, Mexico
Poder de Dios vein, Dulce Nombre mine, Natividad, Natividad Municipality, Oaxaca, Mexico
Natividad Mine, Natividad, Natividad Municipality, Oaxaca, Mexico

Mineral Occurrences

LocalityMineral(s)
Dulce Nombre mine, Natividad, Natividad Municipality, Oaxaca, Mexico Amphibole Supergroup, Andesite, Biotite, Calcite, Chlorite Group, Dacite, Graphite, Greenschist, Ignimbritic tuff, Marl, Mudstone, Muscovite, Phyllite, Plagioclase, Quartz, Sandstone, Slate, Volcanic breccia, White mica
El Convento vein, Dulce Nombre mine, Natividad, Natividad Municipality, Oaxaca, Mexico Ankerite, Calcite, Chalcopyrite, Dacite, Galena, Muscovite, Pearceite, Polybasite, Proustite, Pyrargyrite, Pyrite, Quartz, Sericite, Slate, Sphalerite, Tetrahedrite Subgroup
Natividad vein, Dulce Nombre mine, Natividad, Natividad Municipality, Oaxaca, Mexico Amethyst, Ankerite, Argyrodite, Calcite, Chalcedony, Chalcopyrite, Dacite, Electrum, Galena, Gold, Marcasite, Muscovite, Pearceite, Polybasite, Proustite, Pyrargyrite, Pyrite, Quartz, Sericite, Slate, Sphalerite, Tetrahedrite Subgroup
Poder de Dios vein, Dulce Nombre mine, Natividad, Natividad Municipality, Oaxaca, Mexico Acanthite, Aguilarite, Amethyst, Ankerite, Breccia, Calcite, Chalcopyrite, Electrum, Galena, Gold, Marcasite, Milky Quartz, Muscovite, Pearceite, Phyllite, Polybasite, Proustite, Pyrargyrite, Pyrite, Quartz, Sericite, Slate, Sphalerite, Tetrahedrite Subgroup


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