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Charoite

A valid IMA mineral species
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About CharoiteHide

Formula:
(K,Sr)15-16(Ca,Na)32[Si6O11(O,OH)6]2[Si12O18(O,OH)12]2[Si17O25(O,OH)18]2(OH,F)4 · ~3H2O
Colour:
Violet to deep lilac, whitish-grey to brown
Lustre:
Vitreous, Silky
Hardness:
5 - 6
Specific Gravity:
2.54
Crystal System:
Monoclinic
Name:
For the type locality, near the Chara River, Russia.

Unique IdentifiersHide

Mindat ID:
972
Long-form identifier:
mindat:1:1:972:4
GUID
(UUID V4):
200389f3-2447-4082-b82e-0478b4179623

IMA Classification of CharoiteHide

Approved
IMA Formula:
(K,Sr,Ba,Mn)15-16(Ca,Na)32[Si70(O,OH)180](OH,F)4 · nH2O

Classification of CharoiteHide

9.DG.92

9 : SILICATES (Germanates)
D : Inosilicates
G : Inosilicates with 3-periodic single and multiple chains
70.1.2.3

70 : INOSILICATES Column or Tube Structures
1 : Column or Tube Structures with columnar silicate units
17.1.14

17 : Silicates Containing other Anions
1 : Silicates with fluoride (not containing Al)

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
ChaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CharoiteHide

Vitreous, Silky
Transparency:
Translucent
Colour:
Violet to deep lilac, whitish-grey to brown
Comment:
Material from the type locality is vivid purple, due to trace manganese. Whitish-gray to brown from Patyn Mt.
Hardness:
5 - 6 on Mohs scale
Hardness:
VHN50=412 kg/mm2 - Vickers
Cleavage:
Distinct/Good
Good in three directions.
Density:
2.54 g/cm3 (Measured)    2.77 g/cm3 (Calculated)

Optical Data of CharoiteHide

Type:
Biaxial (+)
RI values:
nα = 1.550 nβ = 1.553 nγ = 1.559
2V:
Measured: 28° to 30°, Calculated: 72°
Max Birefringence:
δ = 0.009
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
r < v strong
Optical Extinction:
X = b, Z ∧ c = 5°.
Pleochroism:
Weak
Comments:
X= rose
Z= colorless

Chemistry of CharoiteHide

Mindat Formula:
(K,Sr)15-16(Ca,Na)32[Si6O11(O,OH)6]2[Si12O18(O,OH)12]2[Si17O25(O,OH)18]2(OH,F)4 · ~3H2O
Common Impurities:
Al,Fe,Mn,Sr,Ba

Crystallography of CharoiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Cell Parameters:
a = 32.296 Å, b = 19.651 Å, c = 7.16 Å
β = 96.3°
Ratio:
a:b:c = 1.643 : 1 : 0.364
Unit Cell V:
4517 ų
Z:
2
Morphology:
Fibrous, massive.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0017698CharoiteRozhdestvenskaya I, Mugnaioli E, Czank M, Depmeier W, Kolb U, Reinholdt A, Weirich T (2010) The structure of charoite, (K,Sr,Ba,Mn)15-16(Ca,Na)32[(Si70(O,OH)180)](OH,F)4.0*nH2O, solved by conventional and automated electron diffraction Mineralogical Magazine 74 159-1772010Murun massif, Yakutiya, Russia0293
0018568CharoiteRozhdestvenskaya I V, Mugnaioli E, Czank M, Depmeier W, Kolb U, Merlino S (2011) Essential features of the polytypic charoite-96 structure compared to charoite-90 Mineralogical Magazine 75 2833-28462011Murun massif in Yakutia, Sakha Republic, Siberia, Russia0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.348 Å(100)
3.134 Å(85)
12.5 Å(70)
2.79 Å(50)
2.71 Å(35)
3.90 Å(30)
2.97 Å(30)
Comments:
Murun massif, Russia. Data from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks
Geological Setting:
Potassic feldspar metasomatites

Type Occurrence of CharoiteHide

Place of Conservation of Type Material:
University of Rome, Rome, Italy, number 24352.
A.E. Fersman Mineralogical Museum, Moscow, Russia.
Geological Setting of Type Material:
K-feldspar metasomatites at the contact of nepheline- and aegirine-syenites with limestones.
Associated Minerals at Type Locality:

Synonyms of CharoiteHide

Other Language Names for CharoiteHide

Dutch:Charoiet
German:Charoit
Italian:Charoite
Lithuanian:Čaroitas
Polish:Czaroit
Russian:Чароит
Spanish:Charoita

Common AssociatesHide

Associated Minerals Based on Photo Data:
184 photos of Charoite associated with AegirineNaFe3+Si2O6
103 photos of Charoite associated with TinaksiteK2Na(Ca,Mn2+)2TiO[Si7O18(OH)]
48 photos of Charoite associated with SteacyiteK0.3(Na,Ca)2ThSi8O20
37 photos of Charoite associated with QuartzSiO2
21 photos of Charoite associated with FrankameniteK3Na3Ca5(Si12O30)(F,OH)4 · H2O
16 photos of Charoite associated with Fedorite(Na,K)2-3(Ca4Na3)Si16O38(OH,F)2 · 3.5H2O
15 photos of Charoite associated with PectoliteNaCa2Si3O8(OH)
11 photos of Charoite associated with GalenaPbS
11 photos of Charoite associated with MicroclineK(AlSi3O8)
10 photos of Charoite associated with TokkoiteK2Ca4[Si7O18(OH)](OH,F)

Related Minerals - Strunz-mindat GroupingHide

9.DG.CalcinaksiteKNaCa(Si4O10) · H2OTric. 1 : P1
9.DG.Barrydawsonite-(Y)Na1.5Y0.5CaSi3O8(OH)Mon. 2/m : P21/b
9.DG.ParatobermoriteCa4(Al0.5Si0.5)2Si4O16(OH)(H2O)2 · (Ca · 3H2O)Mon. 2/m
9.DG.AlvesiteNaKZrSi6O15 · 2H2OOrth. mmm (2/m 2/m 2/m)
9.DG.02SteedeiteNaMn2[Si3BO9](OH)2Tric. 1 : P1
9.DG.02NolzeiteNaMn2[Si3BO9](OH)2 · 2H2OTric. 1 : P1
9.DG.05BustamiteCaMn2+(Si2O6)Tric. 1 : P1
9.DG.05FerrobustamiteCaFe2+(Si2O6)Tric. 1
9.DG.05PectoliteNaCa2Si3O8(OH)Tric. 1 : P1
9.DG.05SeranditeNaMn2+2Si3O8(OH)Tric. 1 : P1
9.DG.05WollastoniteCa3(Si3O9)Tric. 1 : P1
9.DG.05Wollastonite-1ACaSiO3Tric. 1 : P1
9.DG.05TanohataiteLiMn2Si3O8(OH)Tric. 1 : P1
9.DG.05SchizoliteNaCaMnSi3O8(OH)Tric. 1 : P1
9.DG.05MurakamiiteLiCa2Si3O8(OH)Tric. 1 : P1
9.DG.05DalnegorskiteCa5Mn(Si3O9)2Tric. 1 : P1
9.DG.07CascanditeCaScSi3O8(OH)Tric. 1
9.DG.08Plombièrite[Ca4Si6O16(OH)2 · 2H2O] · (Ca · 5H2O)Orth.
9.DG.10Clinotobermorite[Ca4Si6O17 · 2H2O] · (Ca · 3H2O)Mon.
9.DG.10RiversideiteCa5(HSi3O9)2 · 2H2OOrth.
9.DG.10TobermoriteCa4Si6O17(H2O)2 · (Ca · 3H2O)Mon. 2 : P21
9.DG.12JusiteNa2Ca15Al4Si16O54 · 17H2O
9.DG.12KenotobermoriteCa4Si6O15(OH)2(H2O)2 · 3H2OMon.
9.DG.15FoshagiteCa4(Si3O9)(OH)2Tric. 1 : P1
9.DG.20JenniteCa9(Si3O9)2(OH)8 · 8H2OTric. 1 : P1
9.DG.20KameneviteK2TiSi3O9 · H2OOrth. 2 2 2 : P21 21 21
9.DG.25ParaumbiteK3Zr2H(Si3O9)2 · nH2OOrth. mm2
9.DG.25UmbiteK2(Zr,Ti)Si3O9 · H2OOrth. 2 2 2 : P21 21 21
9.DG.30SørenseniteNa4SnBe2Si6O16(OH)4Mon. 2/m : B2/b
9.DG.32Escheite Ca2NaMnTi5[Si12O34]O2(OH)3 · 12H2OOrth. mm2 : Ama2
9.DG.35XonotliteCa6(Si6O17)(OH)2Mon. 2/m : B2/m
9.DG.40HillebranditeCa2(SiO3)(OH)2Orth. mmm (2/m 2/m 2/m) : Cmcm
9.DG.45ZoriteNa8(Ti,Nb)5(Si6O17)2(OH,O)5 · 14H2OOrth.
9.DG.45ChivruaiiteCa4(Ti,Nb)5(Si6O17)2(OH,O)5 · 13-14H2OOrth. mmm (2/m 2/m 2/m) : Cmmm
9.DG.50Haineaultite(Na,Ca)5Ca(Ti,Nb)5(Si6O17)2(OH,F)8 · 5H2OOrth. 2 2 2 : C2 2 2
9.DG.55EpididymiteNa2Be2Si6O15 · H2OOrth. mmm (2/m 2/m 2/m) : Pnma
9.DG.60EudidymiteNa2Be2Si6O15 · H2OMon. 2/m : B2/b
9.DG.65ElpiditeNa2ZrSi6O15 · 3H2OOrth.
9.DG.65PatyniteNaKCa4[Si9O23]Tric. 1 : P1
9.DG.67WhelaniteCu2+2Ca6[Si6O17(OH)](CO3)(OH)3 · 2H2OOrth. mm2 : Pnn2
9.DG.70Fenaksite(K,Na)4(Fe,Mn)2(Si4O10)2(OH,F)Tric. 1 : P1
9.DG.70LitidioniteCuNaKSi4O10Tric. 1 : P1
9.DG.70ManaksiteKNaMnSi4O10Tric. 1 : P1
9.DG.70YusupoviteNa2Zr(Si6O15) · 2.5H2OMon. 2/m : B2/m
9.DG.70EnricofrancoiteKNaCaSi4O10Tric. 1 : P1
9.DG.75TinaksiteK2Na(Ca,Mn2+)2TiO[Si7O18(OH)]Tric.
9.DG.75TokkoiteK2Ca4[Si7O18(OH)](OH,F)Tric.
9.DG.75SenkevichiteCsKNaCa2TiO[Si7O18](OH)Tric. 1 : P1
9.DG.80CanasiteK3Na3Ca5Si12O30(OH)4Mon. m : Bm
9.DG.80FluorcanasiteK3Na3Ca5Si12O30F4 · H2OMon. m : Bm
9.DG.85MiseriteK1.5-x(Ca,Y,REE)5(Si6O15)(Si2O7)(OH,F)2 · yH2OTric.
9.DG.90FrankameniteK3Na3Ca5(Si12O30)(F,OH)4 · H2OTric. 1 : P1
9.DG.95YuksporiteK4(Ca,Na)14(Sr,Ba)2(◻,Mn,Fe)(Ti,Nb)4(O,OH)4(Si6O17)2(Si2O7)3(H2O,OH)3Mon. 2/m : P21/m
9.DG.97Eveslogite(Na,K,Ca,Sr,Ba)48 [(Ti,Nb,Mn,Fe2+)12Si48O144(OH)12](F,OH,Cl)14Mon. 2/m : P2/m

Other InformationHide

IR Spectrum:
The IR spectrum shows the presence of both molecular
water and hydroxyl.
Thermal Behaviour:
About 2.4% H2O is lost up to 300° and l.3% more to 600°. Small endothermic effects are noted at 440°, 760°, and 970°.
Notes:
Insoluble in acids.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Industrial Uses:
Jewelry

Charoite in petrologyHide

An essential component of rock names highlighted in red, an accessory component in rock names highlighted in green.

Internet Links for CharoiteHide

References for CharoiteHide

Reference List:

Localities for CharoiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
India
 
  • Tamil Nadu
    • Chengalpattu district
Deepthi et al. (2015)
Russia (TL)
 
  • Aldan Shield
    • Chara and Tokko Rivers Confluence
[Lapis 1993:4 p.13-20] +1 other reference
Kaneva +4 other references
Solyanik et al. (2008) +3 other references
Pavel.M. Kartashov (n.d.)
- (n.d.)
Pekov (1998)
Vorob'yov E.I. (2008)
Vorob'yov E.I. (2008)
Pavel.M. Kartashov (n.d.)
Kaneva +3 other references
  • Irkutsk Oblast
Vladykin et al. (2008)
Kaneva et al. (2020)
  • Kemerovo Oblast
    • Synzas River
doi.org (n.d.) +1 other reference
 
Mineral and/or Locality  
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