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Brassite

Formula:
MgHAsO
 
4
·4H
 
2
O
System:Orthorhombic


May occur also as a dehydration product of rösslerite.

Classification of Brassite

IMA status:Approved
Strunz 8th edition ID:7/C.15-10
Nickel-Strunz 10th (pending) edition ID:8.CE.15

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
E : With only medium-sized cations, RO4:H2O about 1:2.5
Dana 8th edition ID:39.1.7.1

39 : HYDRATED ACID PHOSPHATES,ARSENATES AND VANADATES
1 : A[HXO4]·xH2O
Hey's CIM Ref.:20.2.2

20 : Arsenates (also arsenates with phosphate, but without other anions)
2 : Arsenates of Be, Mg, Ca or Ba
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Type Occurrence of Brassite

Type Locality:Jáchymov (St Joachimsthal), Ostrov, Krušné Hory Mts (Erzgebirge), Karlovy Vary Region, Bohemia (Böhmen; Boehmen), Czech Republic
Year of Discovery:1973

Crystallography of Brassite

Crystal System:Orthorhombic
Cell Parameters:a = 7.47Å, b = 10.89Å, c = 16.58Å
Ratio:a:b:c = 0.686 : 1 : 1.522
Unit Cell Volume:V 1,348.75 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
Image Loading

Radiation - Copper Kα
Data Set:
Horizontal Axis: ° to ° Vertical Axis: % Source Data: Filtered Data: Peaks:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Optical Data of Brassite

Type:Biaxial (+)
RI values: nα = 1.531 nβ = 1.546 nγ = 1.562
Maximum Birefringence:δ = 0.031

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low
Dispersion:r < v moderate

Chemical Properties of Brassite

Formula:
MgHAsO
 
4
·4H
 
2
O
Essential elements:As, H, Mg, O
All elements listed in formula:As, H, Mg, O

Relationship of Brassite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
8.CE.05Chudobaite
(Mg,Zn)
 
5
[HAsO
 
4
|AsO
 
4
]
 
2
· 10H
 
2
O
8.CE.05Geigerite
Mn
 
5
[HAsO
 
4
|AsO
 
4
]
 
2
· 10H
 
2
O
8.CE.10Newberyite
MgHPO
 
4
·3H
 
2
O
8.CE.20Phosphorrösslerite
MgHPO
 
4
·7H
 
2
O
8.CE.20Rösslerite
MgHAsO
 
4
·7H
 
2
O
8.CE.25Metaswitzerite
Mn
 
3
(PO
 
4
)
 
2
·4H
 
2
O
8.CE.25Switzerite
(Mn,Fe)
 
3
(PO
 
4
)
 
2
·7H
 
2
O
8.CE.30Lindackerite
CuCu
 
4
[HAsO
 
4
|AsO
 
4
]
 
2
· 8-9H
 
2
O
8.CE.30IMA2008-010
CaCu
 
4
(AsO
 
4
)
 
2
(AsO
 
3
OH)
 
2
·10H
 
2
O
8.CE.30Veselovskýite
ZnCu
 
4
(AsO
 
4
)
 
2
(AsO
 
3
OH)
 
2
· 9H
 
2
O
8.CE.30Pradetite
CoCu
 
4
(AsO
 
4
)
 
2
(AsO
 
3
OH)
 
2
·9H
 
2
O
8.CE.35Bobierrite
Mg
 
3
(PO
 
4
)
 
2
·8H
 
2
O
8.CE.40Annabergite
Ni
 
3
(AsO
 
4
)
 
2
·8H
 
2
O
8.CE.40Arupite
Ni
 
3
(PO
 
4
)
 
2
·8H
 
2
O
8.CE.40Barićite
(Mg,Fe)
 
3
(PO
 
4
)
 
2
·8H
 
2
O
8.CE.40Erythrite
Co
 
3
(AsO
 
4
)
 
2
·8H
 
2
O
8.CE.40Ferrisymplesite
Fe
3+
3
[(OH)
 
3
|(AsO
 
4
)
 
2
] · 5H
 
2
O
8.CE.40Hörnesite
Mg
 
3
(AsO
 
4
)
 
2
·8H
 
2
O
8.CE.40Köttigite
Zn
 
3
(AsO
 
4
)
 
2
·8H
 
2
O
8.CE.40Manganohörnesite
(Mn,Mg)
 
3
(AsO
 
4
)
 
2
·8H
 
2
O
8.CE.40Parasymplesite
Fe
2+
3
(AsO
 
4
)
 
2
·8H
 
2
O
8.CE.40Vivianite
Fe
2+
3
(PO
 
4
)
 
2
·8H
 
2
O
8.CE.40Pakhomovskyite
Co
 
3
[PO
 
4
]
 
2
· 8H
 
2
O
8.CE.45Symplesite
Fe
2+
3
(AsO
 
4
)
 
2
·8H
 
2
O
8.CE.50Cattiite
Mg
 
3
(PO
 
4
)
 
2
·22H
 
2
O
8.CE.55Koninckite
Fe
3+
 
[PO
 
4
] · 3H
 
2
O
8.CE.60Kaňkite
FeAsO
 
4
·3.5H
 
2
O
8.CE.65Steigerite
AlVO
 
4
·3H
 
2
O
8.CE.70Metaschoderite
Al
 
2
(PO
 
4
)(VO
 
4
)·6H
 
2
O
8.CE.70Schoderite
Al
 
2
(PO
 
4
)(VO
 
4
)·8H
 
2
O
8.CE.75Malhmoodite
FeZr(PO
 
4
)
 
2
·4H
 
2
O
8.CE.75Zigrasite
MgZr(PO
 
4
)
 
2
·4H
 
2
O
8.CE.75Unnamed (Ca-analogue of Zigrasite)
CaZr[PO
 
4
]
 
2
·4H
 
2
O
8.CE.80Santabarbaraite
Fe
3+
3
[(OH)
 
3
|(PO
 
4
)
 
2
] · 5H
 
2
O
8.CE.85Metaköttigite
(Zn,Fe,Fe)
 
3
(AsO
 
4
)
 
2
·8(H
 
2
O,OH)
8.CE.85Metavivianite
Fe
2+
3-x
Fe
3+
x
(PO
 
4
)
 
2
(OH)x·(8-x)H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
20.2.1Bearsite
Be
 
2
[OH|AsO
 
4
] · 4H
 
2
O
20.2.3Rösslerite
MgHAsO
 
4
·7H
 
2
O
20.2.4Hörnesite
Mg
 
3
(AsO
 
4
)
 
2
·8H
 
2
O
20.2.5Weilite
CaHAsO
 
4
20.2.6Johnbaumite
Ca
 
5
[OH|(AsO
 
4
)
 
3
]
20.2.7Haidingerite
Ca[HAsO
 
4
] · H
 
2
O
20.2.8Pharmacolite
CaHAsO
 
4
·2H
 
2
O
20.2.9Sainfeldite
CaCa
 
2
Ca
 
2
(AsO
 
3
OH)
 
2
(AsO
 
4
)
 
2
·4H
 
2
O
20.2.10Vladimirite
Ca
 
5
[(HAsO
 
4
)
 
2
|(AsO
 
4
)
 
2
] · 5H
 
2
O
20.2.11Guérinite
Ca
 
5
[(HAsO
 
4
)
 
2
|(AsO
 
4
)
 
2
] · 9H
 
2
O
20.2.12Ferrarisite
Ca
 
5
[(HAsO
 
4
)
 
2
|(AsO
 
4
)
 
2
] · 9H
 
2
O
20.2.13Rauenthalite
Ca
 
3
[AsO
 
4
]
 
2
· 10H
 
2
O
20.2.14Phaunouxite
Ca
 
3
[AsO
 
4
]
 
2
· 11H
 
2
O
20.2.15Mcnearite
NaCa
 
5
[(HAsO
 
4
)
 
4
|AsO
 
4
] · 4H
 
2
O
20.2.16Bergslagite
CaBe[OH|AsO
 
4
]
20.2.17Adelite
CaMg[AsO
 
4
](OH)
20.2.18Talmessite
Ca
 
2
Mg[AsO
 
4
]
 
2
· 2H
 
2
O
20.2.19Irhtemite
Ca
 
4
Mg[(HAsO
 
4
)
 
2
|(AsO
 
4
)
 
2
] · 4H
 
2
O
20.2.20Camgasite
CaMg[OH|AsO
 
4
] · 5H
 
2
O
20.2.21Picropharmacolite
Ca
 
4
Mg[(HAsO
 
4
)
 
2
|(AsO
 
4
)
 
2
] · 11H
 
2
O
20.2.22Bariopharmacosiderite
BaFe
3+
4
[(OH)
 
5
|(AsO
 
4
)
 
3
] · 5H
 
2
O

Other Names for Brassite

Synonyms:
IMA1973-047
Other Languages:
German:Brassit
Russian:Брассит
Spanish:Brassita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Brassite

Reference List:American Mineralogist: 60: 945.

Acta Crystallographica: B32: 1460-1466.

Internet Links for Brassite

Search Engines:
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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Brassite in the Natural History Museum (London) online catalogue
  • Brassite details from Handbook of Mineralogy (PDF)
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    Localities for Brassite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Karlovy Vary Region
        • Krušné Hory Mts (Erzgebirge)
          • Ostrov
    Bull.Soc.fr.Min.Crist.(1974) 96, 365-370
    France
     
    • Languedoc-Roussillon
      • Aude
        • Carcassonne
          • Mas-Cabardès
            • Salsigne
    Le Règne Minéral, Hors série (3), 36-54
    G. Favreau : "La mine d'or de Salsigne : Les minéraux des scories de Villagnère", Le Règne Minéral, hors série, 3, 55-60, 1997
    Germany
     
    • Hesse
      • North Hesse
        • Richelsdorf District
          • Bauhaus
    Weiss: "Mineralfundstellen, Deutschland West", Weise (Munich), 1990
          • Süss
            • Richelsdorf Smelter
    S. Weiß: "Mineralfundstellen, Deutschland West", Weise (Munich), 1992
    Mineral and/or Locality
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