Mahnertite
A valid IMA mineral species
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About Mahnertite
Formula:
NaCu3(AsO4)2Cl ¡ 5H2O
Colour:
Blue to emerald green.
Lustre:
Vitreous
Hardness:
2 - 3
Specific Gravity:
3.33
Crystal System:
Tetragonal
Name:
Named after Volker Mahnert (3 December 1943, Innsbruck, Austria - 23 November 2018, Geneva, Switzerland), zoologist, Director of the MusĂŠum dâHistoire Naturelle, Geneva, Switzerland.
Unique Identifiers
Mindat ID:
7165
Long-form identifier:
mindat:1:1:7165:5
GUID
(UUID V4):
(UUID V4):
2f6cac79-8407-4c9a-b9fe-e67b987bb8c8
IMA Classification of Mahnertite
Approved
IMA Formula:
(Na,Ca,K)Cu3(AsO4)2Cl ¡ 5H2O
Approval year:
1994
First published:
1996
Classification of Mahnertite
8.DH.45
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
Mineral Symbols
As of 2021 there are now IMAâCNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Mah | IMAâCNMNC | Warr, L.N. (2021). IMAâCNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Mahnertite
Vitreous
Transparency:
Translucent
Colour:
Blue to emerald green.
Streak:
Pale blue
Hardness:
2 - 3 on Mohs scale
Cleavage:
Perfect
{001}
{001}
Fracture:
Irregular/Uneven
Density:
3.33(2) g/cm3 (Measured) 3.36(1) g/cm3 (Calculated)
Optical Data of Mahnertite
Type:
Uniaxial (-)
RI values:
nω = 1.686(2) nε = 1.635(2)
Max Birefringence:
δ = 0.051
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Pleochroism:
Strong
Comments:
O = blue to intense green-blue, E = clear blue to clear green.
Chemistry of Mahnertite
Mindat Formula:
NaCu3(AsO4)2Cl ¡ 5H2O
Crystallography of Mahnertite
Crystal System:
Tetragonal
Class (H-M):
4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal
Space Group:
I4/mmm
Cell Parameters:
a = 10.037 Å, c = 23.739 Å
Ratio:
a:c = 1 : 2.365
Unit Cell V:
2391.5 Ă
Âł
Z:
8
Morphology:
Thin tetragonal plates. Tabular on {001}, also showing {100}.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0007079 | Mahnertite | Pushcharovsky D Y, Zubkova N V, Teat S J, Maclean E J, Sarp H (2004) Crystal structure of mahnertite European Journal of Mineralogy 16 687-692 | 2004 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
11.90 Ă | (100) |
9.29 Ă | (60) |
7.131 Ă | (50) |
5.043 Ă | (60) |
4.641 Ă | (40) |
3.098 Ă | (80) |
3.061 Ă | (70) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47d : [Arsenates, antimonates, selenates, bismuthinates] | |
47g : [Halogen-bearing surface weathering minerals] |
Type Occurrence of Mahnertite
General Appearance of Type Material:
Blue to emerald green aggregates of thin (0.1 mm) square crystals, and as spherules to 0.2 mm in diameter.
Place of Conservation of Type Material:
Natural History Museum, Geneva, Switzerland.
Geological Setting of Type Material:
Oxidation product in a sedimentary-hosted copper deposit.
Associated Minerals at Type Locality:
Reference:
Sarp, H. (1996) Mahnertite, (Na,Ca)Cu(AsO4)4Cl.5H2O, a new mineral from the Cap Garonne Mine, Var France. Archs. Sci. Genève: 49(2): 119-124
Synonyms of Mahnertite
Other Language Names for Mahnertite
Relationship of Mahnertite to other Species
Structurally related to group(s):
Lavendulan Group | Mahnertite, richelsdorfite, andyrobertsite and calcioandyrobertsite are structurally ... |
Common Associates
Associated Minerals Based on Photo Data:
2 photos of Mahnertite associated with ZdenÄkite | NaPbCu5(AsO4)4Cl ¡ 5H2O |
2 photos of Mahnertite associated with Caracolite | Na3Pb2(SO4)3Cl |
1 photo of Mahnertite associated with Scorodite | Fe3+AsO4 ¡ 2H2O |
1 photo of Mahnertite associated with Carminite | PbFe3+2(AsO4)2(OH)2 |
1 photo of Mahnertite associated with Beudantite | PbFe3(AsO4)(SO4)(OH)6 |
1 photo of Mahnertite associated with Juansilvaite | Na5Al3[AsO3(OH)]4[AsO2(OH)2]2(SO4)2 ¡ 4H2O |
Related Minerals - Strunz-mindat Grouping
8.DH. | Ferroberaunite | Fe2+Fe3+5(PO4)4(OH)5 ¡ 6H2O |
8.DH. | Rowleyite | [Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 ¡ n[H2O,Na,NH4,K,Cl] |
8.DH. | Ammoniotinsleyite | (NH4)Al2(PO4)2(OH) ¡ 2H2O |
8.DH. | Thebaite-(NH4) | (NH4)3Al(C2O4)(PO3OH)2(H2O) |
8.DH. | Dendoraite-(NH4) | (NH4)2NaAl(C2O4)(PO3OH)2(H2O)2 |
8.DH. | Whiteite-(MnMnMn) | Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 ¡ 8H2O |
8.DH. | Whiteite-(CaMnFe) | CaMnFe2Al2(PO4)4(OH)2 ¡ 8H2O |
8.DH. | Hochleitnerite | Mn2Ti3(PO4)4O2(H2O)2 ¡ 14H2O |
8.DH. | Regerite | KFe6(PO4)4(OH)7(H2O)6 ¡ 4H2O |
8.DH.05 | Minyulite | KAl2(PO4)2F ¡ 4H2O |
8.DH.10 | Leucophosphite | KFe3+2(PO4)2(OH) ¡ 2H2O |
8.DH.10 | Spheniscidite | (NH4,K)(Fe3+,Al)2(PO4)2(OH) ¡ 2H2O |
8.DH.10 | Tinsleyite | KAl2(PO4)2(OH) ¡ 2H2O |
8.DH.15 | Jahnsite-(CaMnFe) | {Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Jahnsite-(CaMnMg) | {Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Jahnsite-(CaMnMn) | {Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Keckite | CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 ¡ 7H2O |
8.DH.15 | Rittmannite | {(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Whiteite-(CaFeMg) | {Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Whiteite-(CaMnMg) | {Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Whiteite-(MnFeMg) | {(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Jahnsite-(MnMnMn) | {Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Kaluginite | (Mn2+,Ca)MgFe3+(PO4)2(OH) ¡ 4H2O |
8.DH.15 | Jahnsite-(CaFeFe) | {Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Jahnsite-(NaFeMg) | NaFe3+Mg2Fe3+2(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Jahnsite-(NaMnMg) | {(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Jahnsite-(CaMgMg) | {Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Whiteite-(CaMnMn) | {Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Whiteite-(MnMnMg) | MnMnMg2Al2(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Jahnsite-(MnMnMg) | Mn2+Mn2+Mg2Fe3+2(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Jahnsite-(CaFeMg) | CaFe2+Mg2Fe3+2(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Jahnsite-(MnMnFe) | Mn2+Mn2+Fe2+2Fe3+2(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Whiteite-(CaMgMg) | CaMg3Al2(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Jahnsite-(MnMnZn) | Mn2+Mn2+Zn2Fe3+2(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Jahnsite-(NaMnMn) | NaMn2+(Mn2+Fe3+)Σ2Fe3+2(PO4)4(OH)2 ¡ 8H2O |
8.DH.15 | Jahnsite-(CaMnZn) | CaMn2+Zn2Fe3+2(PO4)4(OH)2 ¡ 8H2O |
8.DH.20 | Lun'okite | (Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH ¡ 4H2O |
8.DH.20 | Manganosegelerite | (Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) ¡ 4H2O |
8.DH.20 | Overite | CaMgAl(PO4)2(OH) ¡ 4H2O |
8.DH.20 | Segelerite | Ca2 Mg2 Fe3+2(PO4)4(OH)2 ¡ 8H2O |
8.DH.20 | Wilhelmvierlingite | CaMnFe3+(PO4)2(OH) ¡ 2H2O |
8.DH.20 | Juonniite | CaMgSc(PO4)2(OH) ¡ 4H2O |
8.DH.25 | Calcioferrite | Ca2Fe3+2(PO4)3(OH) ¡ 7H2O |
8.DH.25 | Kingsmountite | Ca3MnFeAl4(PO4)6(OH)4 ¡ 12H2O |
8.DH.25 | Montgomeryite | Ca4MgAl4(PO4)6(OH)4 ¡ 12H2O |
8.DH.25 | Zodacite | Ca4Mn2+Fe3+4(PO4)6(OH)4 ¡ 12H2O |
8.DH.25 | Fanfaniite | Ca4MnAl4(PO4)6(OH)4 ¡ 12H2O |
8.DH.30 | Arseniosiderite | Ca2Fe3+3(AsO4)3O2 ¡ 3H2O |
8.DH.30 | Kolfanite | Ca2Fe3+3O2(AsO4)3 ¡ 2H2O |
8.DH.30 | Mitridatite | Ca2Fe3+3(PO4)3O2 ¡ 3H2O |
8.DH.30 | Pararobertsite | Ca2Mn3+3(PO4)3O2 ¡ 3H2O |
8.DH.30 | Robertsite | Ca2Mn3+3(PO4)3O2 ¡ 3H2O |
8.DH.30 | Sailaufite | (Ca,Na,âť)2Mn3+3(AsO4)2(CO3)O2 ¡ 3H2O |
8.DH.35 | Mantienneite | KMg2Al2Ti(PO4)4(OH)3 ¡ 15H2O |
8.DH.35 | Paulkerrite | K(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 ¡ 15H2O |
8.DH.35 | Benyacarite | (H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 ¡ 4H2O |
8.DH.35 | Hydroxylbenyacarite | (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10 ¡ 4H2O |
8.DH.35 | Macraeite | K(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 ¡ 4H2O |
8.DH.40 | Xanthoxenite | Ca4Fe3+2(PO4)4(OH)2 ¡ 3H2O |
8.DH.50 | Andyrobertsite | KCdCu5(AsO4)4(H2AsO4) ¡ 2H2O |
8.DH.50 | Calcioandyrobertsite | KCaCu5(AsO4)4(H2AsO4) ¡ 2H2O |
8.DH.55 | Englishite | K3Na2Ca10Al15(PO4)21(OH)7 ¡ 26H2O |
8.DH.60 | Bouazzerite | Bi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 ¡ 86H2O |
8.DH.65 | Galliskiite | Ca4Al2(PO4)2F8 ¡ 5H2O |
8.DH.70 | Joteite | Ca2CuAl(AsO4)[AsO3(OH)]2(OH)2 ¡ 5H2O |
8.DH.75 | Kampelite | Ba6Mg3Sc8(PO4)12(OH)6 ¡ 7H2O |
8.DH.80 | Kapundaite | NaCaFe4(PO4)4(OH)3 ¡ 5H2O |
8.DH.85 | Vaniniite | Ca2Mn2+3Mn3+2O2(AsO4)4 ¡ 2H2O |
Fluorescence of Mahnertite
Not fluorescent
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Mahnertite
mindat.org URL:
https://www.mindat.org/min-7165.html
Please feel free to link to this page.
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External Links:
References for Mahnertite
Reference List:
Sarp, H. (1996) La mahnertite, (Na,Ca)Cu3(AsO4)2Cl¡5H2O, un nouveau minÊral de la mine de Cap Garonne, Var, France. Archives des Sciences, Genève, 49 (2) 119-124
Localities for Mahnertite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
â - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Chile | |
| SEM-EDS by Joy Desor |
France (TL) | |
| Jean-Marie Claude collection +1 other reference |
Germany | |
| Joy Desor (SEM-EDS and Raman analyses) |
Greece | |
| Lapis (7) +1 other reference |
Rieck (1999) | |
Italy | |
| Desor (2017) |
Caboni et al. (2018) | |
Spain | |
| Calvo Rebollar et al. (2022) |
USA | |
| Kampf et al. (2018) |
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Cap Garonne Mine, Le Pradet, Toulon, Var, Provence-Alpes-CĂ´te d'Azur, France