Paulkerrite
A valid IMA mineral species
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About Paulkerrite
Formula:
K(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2O
Colour:
Colorless to very light yellow-brown
Lustre:
Vitreous, Sub-Vitreous
Hardness:
3
Specific Gravity:
2.36
Crystal System:
Monoclinic
Member of:
Name:
Named by Donald Peacor, Pete Dunn, and William Simmons in honor of Paul Francis Kerr [January 12, 1897 Helmet, California, USA - February 27, 1981 Chicago, Illinois, USA], professor of mineralogy, Columbia University, New York, New York, USA.
Unique Identifiers
Mindat ID:
3134
Long-form identifier:
mindat:1:1:3134:5
GUID
(UUID V4):
(UUID V4):
36dcab80-6c92-4253-9744-451e75348d86
IMA Classification of Paulkerrite
Approved
IMA Formula:
KMg2TiFe3+2(PO4)4(OH)3 · 15H2O
Approval year:
1984
Classification of Paulkerrite
8.DH.35
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
42.11.21.1
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
19.8.24
19 : Phosphates
8 : Phosphates of Al and other metals
19 : Phosphates
8 : Phosphates of Al and other metals
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Pke | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Paulkerrite
Vitreous, Sub-Vitreous
Transparency:
Transparent
Colour:
Colorless to very light yellow-brown
Streak:
White
Hardness:
3 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
{100} perfect
{100} perfect
Fracture:
Sub-Conchoidal
Density:
2.36 g/cm3 (Measured) 2.36 g/cm3 (Calculated)
Optical Data of Paulkerrite
Type:
Biaxial (-)
RI values:
nα = 1.591 - 1.598 nβ = 1.615 - 1.624 nγ = 1.639 - 1.643
2V:
Measured: 80° , Calculated: 78° to 88°
Birefringence:
0.045
Max Birefringence:
δ = 0.048
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r > v strong
Optical Extinction:
Parallel, XYZ = cba
Pleochroism:
Non-pleochroic
Chemistry of Paulkerrite
Mindat Formula:
K(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2O
Crystallography of Paulkerrite
Crystal System:
Monoclinic
Class (H-M):
m - Domatic
Cell Parameters:
a = 10.569(2) Å, b = 20.590(4) Å, c = 12.413(2) Å
β = 90.33(3)°
β = 90.33(3)°
Ratio:
a:b:c = 0.513 : 1 : 0.603
Unit Cell V:
2,701.22 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Nearly colorless equant to nearly equant flattened crystals with simple forms: {010}, {100}, and {111}.
Comment:
p21/c
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
10.3 Å | (90) |
7.46 Å | (80) |
6.20 Å | (100) |
3.75 Å | (40) |
3.13 Å | (70) |
2.872 Å | (40) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 4b: Highly evolved igneous rocks | >3.0 |
34 : Complex granite pegmatites | |
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47c : [Carbonates, phosphates, borates, nitrates] | |
47e : [Vanadates, chromates, manganates] |
Geological Setting:
Granite pegmatite
Type Occurrence of Paulkerrite
General Appearance of Type Material:
Flattened to equant transparent nearly colorless to very light yellowish brown 0.2 mm crystals.
Place of Conservation of Type Material:
National Museum of Natural History (Smithsonian), Washington, D.C., USA, R7778, 120405, 163777.
Geological Setting of Type Material:
Secondary phosphate mineralization in a granite pegmatite.
Associated Minerals at Type Locality:
Reference:
Peacor, D.R., Dunn, P.J., Simmons, W.B. (1984) Paulkerrite a new titanium phosphate from Arizona. The Mineralogical Record: 15: 303-306.
Synonyms of Paulkerrite
Other Language Names for Paulkerrite
Relationship of Paulkerrite to other Species
Member of:
Other Members of this group:
Benyacarite | (H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2O | Orth. mmm (2/m 2/m 2/m) : Pbca |
Hochleitnerite | Mn2Ti3(PO4)4O2(H2O)2 · 14H2O | Orth. mmm (2/m 2/m 2/m) : Pbca |
Hydroxylbenyacarite | (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10 · 4H2O | Orth. mmm (2/m 2/m 2/m) : Pbca |
Macraeite | K(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 · 4H2O | Mon. 2/m : P21/b |
Mantienneite | KMg2Al2Ti(PO4)4(OH)3 · 15H2O | Orth. mmm (2/m 2/m 2/m) : Pbca |
Pleysteinite | [(H2O)0.5K0.5]2Mn2Al3(PO4)4F2 · 14H2O | Orth. mmm (2/m 2/m 2/m) : Pbca |
Rewitzerite | [K(H2O)]Mn2Al3(PO4)4(OH)2 · 14H2O | Mon. 2/m : P21/b |
Sperlingite | (H2O)K(Mn2+Fe3+)(Al2Ti)(PO4)4[O(OH)] [(H2O)9(OH)] · 4H2O | Mon. 2/m : P21/b |
Common Associates
Associated Minerals Based on Photo Data:
6 photos of Paulkerrite associated with Phosphosiderite | FePO4 · 2H2O |
2 photos of Paulkerrite associated with Leucophosphite | KFe3+2(PO4)2(OH) · 2H2O |
2 photos of Paulkerrite associated with Benyacarite | (H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2O |
2 photos of Paulkerrite associated with Nsutite | (Mn4+,Mn2+)(O,OH)2 |
2 photos of Paulkerrite associated with Strengite | FePO4 · 2H2O |
2 photos of Paulkerrite associated with Rockbridgeite | Fe2+Fe3+4(PO4)3(OH)5 |
Related Minerals - Strunz-mindat Grouping
8.DH. | Ferroberaunite | Fe2+Fe3+5(PO4)4(OH)5 · 6H2O |
8.DH. | Rowleyite | [Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl] |
8.DH. | Ammoniotinsleyite | (NH4)Al2(PO4)2(OH) · 2H2O |
8.DH. | Thebaite-(NH4) | (NH4)3Al(C2O4)(PO3OH)2(H2O) |
8.DH. | Dendoraite-(NH4) | (NH4)2NaAl(C2O4)(PO3OH)2(H2O)2 |
8.DH. | Whiteite-(MnMnMn) | Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 · 8H2O |
8.DH. | Whiteite-(CaMnFe) | CaMnFe2Al2(PO4)4(OH)2 · 8H2O |
8.DH. | Hochleitnerite | Mn2Ti3(PO4)4O2(H2O)2 · 14H2O |
8.DH. | Regerite | KFe6(PO4)4(OH)7(H2O)6 · 4H2O |
8.DH.05 | Minyulite | KAl2(PO4)2F · 4H2O |
8.DH.10 | Leucophosphite | KFe3+2(PO4)2(OH) · 2H2O |
8.DH.10 | Spheniscidite | (NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2O |
8.DH.10 | Tinsleyite | KAl2(PO4)2(OH) · 2H2O |
8.DH.15 | Jahnsite-(CaMnFe) | {Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaMnMg) | {Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaMnMn) | {Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Keckite | CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2O |
8.DH.15 | Rittmannite | {(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(CaFeMg) | {Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(CaMnMg) | {Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(MnFeMg) | {(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(MnMnMn) | {Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Kaluginite | (Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2O |
8.DH.15 | Jahnsite-(CaFeFe) | {Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(NaFeMg) | NaFe3+Mg2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(NaMnMg) | {(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaMgMg) | {Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(CaMnMn) | {Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(MnMnMg) | MnMnMg2Al2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(MnMnMg) | Mn2+Mn2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaFeMg) | CaFe2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(MnMnFe) | Mn2+Mn2+Fe2+2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(CaMgMg) | CaMg3Al2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(MnMnZn) | Mn2+Mn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(NaMnMn) | NaMn2+(Mn2+Fe3+)Σ2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaMnZn) | CaMn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.20 | Lun'okite | (Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2O |
8.DH.20 | Manganosegelerite | (Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2O |
8.DH.20 | Overite | CaMgAl(PO4)2(OH) · 4H2O |
8.DH.20 | Segelerite | Ca2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.20 | Wilhelmvierlingite | CaMnFe3+(PO4)2(OH) · 2H2O |
8.DH.20 | Juonniite | CaMgSc(PO4)2(OH) · 4H2O |
8.DH.25 | Calcioferrite | Ca2Fe3+2(PO4)3(OH) · 7H2O |
8.DH.25 | Kingsmountite | Ca3MnFeAl4(PO4)6(OH)4 · 12H2O |
8.DH.25 | Montgomeryite | Ca4MgAl4(PO4)6(OH)4 · 12H2O |
8.DH.25 | Zodacite | Ca4Mn2+Fe3+4(PO4)6(OH)4 · 12H2O |
8.DH.25 | Fanfaniite | Ca4MnAl4(PO4)6(OH)4 · 12H2O |
8.DH.30 | Arseniosiderite | Ca2Fe3+3(AsO4)3O2 · 3H2O |
8.DH.30 | Kolfanite | Ca2Fe3+3O2(AsO4)3 · 2H2O |
8.DH.30 | Mitridatite | Ca2Fe3+3(PO4)3O2 · 3H2O |
8.DH.30 | Pararobertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
8.DH.30 | Robertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
8.DH.30 | Sailaufite | (Ca,Na,◻)2Mn3+3(AsO4)2(CO3)O2 · 3H2O |
8.DH.35 | Mantienneite | KMg2Al2Ti(PO4)4(OH)3 · 15H2O |
8.DH.35 | Benyacarite | (H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2O |
8.DH.35 | Hydroxylbenyacarite | (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10 · 4H2O |
8.DH.35 | Macraeite | K(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 · 4H2O |
8.DH.40 | Xanthoxenite | Ca4Fe3+2(PO4)4(OH)2 · 3H2O |
8.DH.45 | Mahnertite | NaCu3(AsO4)2Cl · 5H2O |
8.DH.50 | Andyrobertsite | KCdCu5(AsO4)4(H2AsO4) · 2H2O |
8.DH.50 | Calcioandyrobertsite | KCaCu5(AsO4)4(H2AsO4) · 2H2O |
8.DH.55 | Englishite | K3Na2Ca10Al15(PO4)21(OH)7 · 26H2O |
8.DH.60 | Bouazzerite | Bi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2O |
8.DH.65 | Galliskiite | Ca4Al2(PO4)2F8 · 5H2O |
8.DH.70 | Joteite | Ca2CuAl(AsO4)[AsO3(OH)]2(OH)2 · 5H2O |
8.DH.75 | Kampelite | Ba6Mg3Sc8(PO4)12(OH)6 · 7H2O |
8.DH.80 | Kapundaite | NaCaFe4(PO4)4(OH)3 · 5H2O |
8.DH.85 | Vaniniite | Ca2Mn2+3Mn3+2O2(AsO4)4 · 2H2O |
Fluorescence of Paulkerrite
Not fluorescent
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Paulkerrite
mindat.org URL:
https://www.mindat.org/min-3134.html
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References for Paulkerrite
Reference List:
Dunn, Pete J., Simmons, William B., Peacor, Donald R. (1984) Paulkerrite, a new titanium phosphate from Arizona. The Mineralogical Record, 15 (5) 303-306
Dunn, Pete J., Fleischer, Michael, Langley, Richard H., Shigley, James E., Zilczer, Janet A. (1985) New mineral names. American Mineralogist, 70 (7-8) 871-881 p.875
Localities for Paulkerrite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Czech Republic | |
| Staně +4 other references |
Staněk | |
Germany | |
| Dill et al. (2011) |
| DILL et al. (2009) |
Morocco | |
| Favreau (2012) |
Portugal | |
| Schnorrer et al. (2005) |
Lapis 15 (7/8) | |
| Schnorrer-Köhler (1991) |
USA (TL) | |
| Dunn et al. (1984) +1 other reference |
Quick NavTopAbout PaulkerriteUnique IdentifiersIMA Classification Classification Mineral SymbolsPhysical Properties Optical Data Chemistry Crystallography X-Ray Powder DiffractionGeological EnvironmentType Occurrence SynonymsOther LanguagesRelationshipsCommon AssociatesStrunz-MindatFluorescence Other InformationInternet Links References Localities Locality List
7U7 Ranch, Bagdad Mine area, Hillside, Eureka Mining District, Yavapai County, Arizona, USA