Named in 2012 by Dan Topa, Emil Makoviky, Gheorghe Ilinca and Herbert Dittrich as a portmanteau of "cupromakovickyite" and "cupropavonite", chemically and structurally related minerals of which it is ideally a 1:1 interstratification. Pavonite is named for Martin Alfred Peacock; pavo = peacock in Latin.

Type Locality:

ⓘ Western ore field, Mittersill Scheelite deposit, Mittersill, Zell am See District, Salzburg, Austria

This page provides mineralogical data about Cupromakopavonite.

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Unique IdentifiersHide

Mindat ID:

28892

Long-form identifier:

mindat:1:1:28892:3

GUID
(UUID V4):

ceb5c1e4-a2ef-4ac1-a82a-058e901acc4f

IMA Classification of CupromakopavoniteHide

IMA status:

Approved

IMA Formula:

Cu₈Pb₄Ag₃Bi₁₉S₃₈

Approval year:

2005

First published:

2012

Type description reference:

Topa, D., Makovicky, E., Ilinca, G., Dittrich, H. (2012) Cupromakopavonite, Cu₈Ag₃Pb₄Bi₁₉S₃₈, a new mineral species, its crystal structure and the cupropavonite homologous series. The Canadian Mineralogist, 50 (2) 295-312 doi:10.3749/canmin.50.2.295

Classification of CupromakopavoniteHide

Strunz-mindat (2024):

2.JA.05a

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
A : Galena derivatives with little or no Pb

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference
Cmpav	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of CupromakopavoniteHide

Lustre:

Metallic

Transparency:

Opaque

Colour:

Gray

Streak:

Gray

Comment:

Could not be measured

Tenacity:

Brittle

Cleavage:

None Observed

Density:

6.78 g/cm³ (Calculated)

Comment:

Could not be measured. Calculated is based on ideal formula.

Optical Data of CupromakopavoniteHide

Anisotropism:

Moderate in air and strong in oil. Dark bluish grey to yellowish brown.

Bireflectance:

Perceptible in air and moderate in oil

Reflectivity:

Wavelength	R₁	R₂
400nm	43.45%	45.82%
440nm	43.22%	45.29%
470nm	42.91%	46.56%
500nm	42.74%	46.94%
520nm	42.58%	46.64%
546nm	42.1%	46.46%
560nm	42.22%	46.06%
589nm	41.34%	45.78%
620nm	41.01%	45.25%
650nm	40.24%	45.13%
680nm	40.64%	44.43%
700nm	39.72%	44.61%

Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 46.94%.
R₁ shown in black, R₂ shown in red

Colour in reflected light:

Greyish white

Internal Reflections:

None

Pleochroism:

Not Visible

Chemistry of CupromakopavoniteHide

Mindat Formula:

Ag₃Cu₈Pb₄Bi₁₉S₃₈

Elements listed:

Ag, Bi, Cu, Pb, S - search for minerals with similar chemistry

Crystallography of CupromakopavoniteHide

Crystal System:

Monoclinic

Class (H-M):

2/m - Prismatic

Space Group:

B2/m

Setting:

C2/m

Cell Parameters:

a = 13.380(2) Å, b = 4.0007(6) Å, c = 31.083(4) Å
β = 93.064(2)°

Ratio:

a:b:c = 3.344 : 1 : 7.769

Unit Cell V:

1,661.47 Å³ (Calculated from Unit Cell)

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0019215	Cupromakopavonite	Topa D, Makovicky E, Ilinca G, Dittrich H (2012) Cupromakopavonite, Cu8Ag3Pb4Bi19S38, a new mineral species, its crystal structure and the cupropavonite homologous series The Canadian Mineralogist 50 295-312		2012	the scheelite deposit Felbertal, Salzburg Province, Austria	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Cupromakopavonite'
loop_
_publ_author_name
'Topa D'
'Makovicky E'
'Ilinca G'
'Dittrich H'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 50 
_journal_year 2012
_journal_page_first 295
_journal_page_last 312
_publ_section_title
;
 Cupromakopavonite, Cu8Ag3Pb4Bi19S38, a new mineral species, its crystal
 structure and the cupropavonite homologous series
;
_database_code_amcsd 0019215
_chemical_compound_source 'the scheelite deposit Felbertal, Salzburg Province, Austria'
_chemical_formula_sum 'Cu4 Ag1.621 Pb2 Bi9.379 S19'
_cell_length_a 13.3801
_cell_length_b 4.0007
_cell_length_c 31.083
_cell_angle_alpha 90
_cell_angle_beta 93.064
_cell_angle_gamma 90
_cell_volume 1661.487
_exptl_crystal_density_diffrn      6.822
_symmetry_space_group_name_H-M 'C 1 2/m 1'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,z'
  'x,-y,z'
  '1/2+x,1/2-y,z'
  '-x,y,-z'
  '1/2-x,1/2+y,-z'
  '-x,-y,-z'
  '1/2-x,1/2-y,-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Cu1   0.05660   0.00000   0.22570   1.00000   0.02950
Cu2   0.48850   0.00000   0.71340   1.00000   0.02940
Ag   0.00000   0.00000   0.00000   0.93700   0.03400
Pb   0.28681   0.00000   0.33522   1.00000   0.02990
Bi   0.00000   0.00000   0.00000   0.06300   0.03400
Bi1   0.27808   0.00000   0.05767   1.00000   0.01380
Bi2   0.44173   0.00000   0.88385   1.00000   0.01330
Bi3   0.18026   0.00000   0.78873   1.00000   0.01810
Bi4   0.42586   0.00000   0.58778   0.80300   0.02070
Ag4   0.42586   0.00000   0.58778   0.19700   0.02070
Bi5   0.14238   0.00000   0.53161   0.85500   0.02020
Ag5   0.14238   0.00000   0.53161   0.14500   0.02020
S1   0.35370   0.00000   0.97120   1.00000   0.01600
S2   0.07420   0.00000   0.92150   1.00000   0.02300
S3   0.19770   0.00000   0.13650   1.00000   0.01220
S4   0.49060   0.00000   0.19400   1.00000   0.01420
S5   0.21940   0.00000   0.24820   1.00000   0.01370
S6   0.07450   0.00000   0.71700   1.00000   0.01220
S7   0.35530   0.00000   0.66530   1.00000   0.01660
S8   0.06110   0.00000   0.60650   1.00000   0.01700
S9   0.22450   0.00000   0.44030   1.00000   0.02300
S10   0.50000   0.00000   0.50000   1.00000   0.02000
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
Cu1 0.02300 0.02900 0.03500 0.00000 -0.00900 0.00000
Cu2 0.03000 0.01600 0.04100 0.00000 -0.01000 0.00000
Ag 0.03000 0.04100 0.03100 0.00000 -0.00200 0.00000
Pb 0.03490 0.01790 0.03760 0.00000 0.00800 0.00000
Bi 0.03000 0.04100 0.03100 0.00000 -0.00200 0.00000
Bi1 0.01590 0.01180 0.01370 0.00000 0.00130 0.00000
Bi2 0.01580 0.01170 0.01260 0.00000 0.00220 0.00000
Bi3 0.01950 0.02100 0.01330 0.00000 -0.00310 0.00000
Bi4 0.02460 0.02040 0.01700 0.00000 0.00190 0.00000
Ag4 0.02460 0.02040 0.01700 0.00000 0.00190 0.00000
Bi5 0.02080 0.01790 0.02180 0.00000 -0.00030 0.00000
Ag5 0.02080 0.01790 0.02180 0.00000 -0.00030 0.00000
S1 0.01700 0.01700 0.01500 0.00000 0.00400 0.00000
S2 0.01900 0.01400 0.03400 0.00000 -0.00400 0.00000
S3 0.01500 0.01500 0.00700 0.00000 0.00000 0.00000
S4 0.01900 0.01500 0.01000 0.00000 0.00400 0.00000
S5 0.01200 0.01400 0.01500 0.00000 -0.00100 0.00000
S6 0.01400 0.01100 0.01200 0.00000 -0.00100 0.00000
S7 0.01700 0.01300 0.02000 0.00000 0.00200 0.00000
S8 0.01800 0.01600 0.01600 0.00000 -0.00100 0.00000
S9 0.01900 0.01500 0.03600 0.00000 -0.00400 0.00000
S10 0.02200 0.01900 0.02000 0.00000 0.00000 0.00000

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
3.607 Å	(54)
3.457 Å	(99)
3.436 Å	(27)
3.340 Å	(34)
2.9526 Å	(28)
2.8742 Å	(33)
2.8335 Å	(100)
2.2558 Å	(29)

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])

Type Occurrence of CupromakopavoniteHide

Type Locality:

ⓘ Western ore field, Mittersill Scheelite deposit, Mittersill, Zell am See District, Salzburg, Austria

General Appearance of Type Material:

Inclusions in oversubstituded krupkaite. Homogeneous grains or as a component in lamellar intergrowths with Cu-bearing makovickyite.

Place of Conservation of Type Material:

Reference collection (museum) of the Division of Mineralogy, University of Salzburg, Austria, catalog no. 14955.

Geological Setting of Type Material:

Recrystallization of sulfide and sulfosalt material in quartz veins hosted within felsic gneisses and amphibolites. Retrograde Alpine metamorphism.

Associated Minerals at Type Locality:

Wittichenite	Quartz	Pyrrhotite	Makovickyite	Kupčíkite
Hodrušite	Cuprobismutite	Chalcopyrite	Bismuth	Aikinite-Bismuthinite Series

Reference:

Topa, D., Makovicky, E., Ilinca, G., Dittrich, H. (2012) Cupromakopavonite, Cu8Ag3Pb4Bi19S38, a new mineral species, its crystal structure and the cupropavonite homologous series. The Canadian Mineralogist: 50: 295-312.

Synonyms of CupromakopavoniteHide

IMA2005-036

Relationship of Cupromakopavonite to other SpeciesHide

Member of:

Pavonite Homologous Series Group

Other Members of this group:

Benjaminite	Ag₃Bi₇S₁₂	Mon. 2/m : B2/m
Cupromakovickyite	Cu₄AgPb₂Bi₉S₁₈	Mon. 2/m : B2/m
Cupropavonite	Cu_0.9Ag_0.5Pb_0.6Bi_2.5S₅	Mon. 2/m : B2/m
Dantopaite	Ag₅Bi₁₃S₂₂	Mon. 2/m : B2/m
Luboržákite	Mn₂AsSbS₅	Mon. 2/m : B2/m
Makovickyite	Cu_1.12Ag_0.81Pb_0.27Bi_5.35S₉	Mon. 2/m
Mummeite	Cu_0.58Ag_3.11Pb_1.10Bi_6.65S₁₃	Mon.
Pavonite	AgBi₃S₅	Mon. 2/m : B2/m

Related Minerals - Strunz-mindat Grouping Hide

2.JA.	Ferdowsiite	Ag₈(Sb₅As₃)S₁₆	Mon. 2/m : P2₁/b
2.JA.	Sangenaroite	Ag₈(Sb_8-xAs_x)S_Σ16	Mon. 2/m
2.JA.	Luboržákite	Mn₂AsSbS₅	Mon. 2/m : B2/m
2.JA.05e	Benjaminite	Ag₃Bi₇S₁₂	Mon. 2/m : B2/m
2.JA.05g	Borodaevite	Ag₅(Bi,Pb,Fe)₈(Sb,Bi)₂S₁₇	Mon.
2.JA.05a	Cupropavonite	Cu_0.9Ag_0.5Pb_0.6Bi_2.5S₅	Mon. 2/m : B2/m
2.JA.05i	Livingstonite	HgSb₄S₆(S₂)	Mon. 2/m : B2/b
2.JA.05d	Makovickyite	Cu_1.12Ag_0.81Pb_0.27Bi_5.35S₉	Mon. 2/m
2.JA.05f	Mummeite	Cu_0.58Ag_3.11Pb_1.10Bi_6.65S₁₃	Mon.
2.JA.05a	Pavonite	AgBi₃S₅	Mon. 2/m : B2/m
2.JA.05b	Grumiplucite	HgBi₂S₄	Mon. 2/m : B2/m
2.JA.05h	Mozgovaite	PbBi₄S₇	Orth. mmm (2/m 2/m 2/m)
2.JA.05d	Cupromakovickyite	Cu₄AgPb₂Bi₉S₁₈	Mon. 2/m : B2/m
2.JA.05c	Kudriavite	(Cd,Pb)Bi₂S₄	Mon. 2/m : B2/m
2.JA.05	Dantopaite	Ag₅Bi₁₃S₂₂	Mon. 2/m : B2/m
2.JA.05	Selenodantopaite	Ag₅Bi₁₃Se₂₂	Mon. 2/m : B2/m
2.JA.10a	Cuprobismutite	Cu₈AgBi₁₃S₂₄	Mon. 2/m : B2/m
2.JA.10c	Hodrušite	Cu₈Bi₁₂S₂₂	Mon. 2/m
2.JA.10e	Padĕraite	Cu₇[(Cu,Ag)_0.33Pb_1.33Bi_11.33]S₂₂	Mon. 2/m : P2₁/m
2.JA.10d	Pizgrischite	(Cu,Fe)Cu₁₄PbBi₁₇S₃₅	Mon. 2/m : B2/m
2.JA.10b	Kupčíkite	Cu_3.4Fe_0.6Bi₅S₁₀	Mon. 2/m : B2/m
2.JA.15	Schapbachite	Ag_0.4Pb_0.2Bi_0.4S	Iso. m3m (4/m 3 2/m) : Fm3m
2.JA.15	Cuboargyrite	AgSbS₂	Iso. m3m (4/m 3 2/m)
2.JA.20	Bohdanowiczite	AgBiSe₂	Trig. 3m (3 2/m) : P3m1
2.JA.20	Matildite	AgBiS₂	Trig. 3 2 : P3₁ 2 1
2.JA.20	Volynskite	AgBiTe₂	Trig. 3m (3 2/m) : P3m1

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for CupromakopavoniteHide

mindat.org URL:

https://www.mindat.org/min-28892.html
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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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References for CupromakopavoniteHide

Reference List:

Topa, D., Makovicky, E., Ilinca, G., Dittrich, H. (2012) Cupromakopavonite, Cu₈Ag₃Pb₄Bi₁₉S₃₈, a new mineral species, its crystal structure and the cupropavonite homologous series: Erratum. The Canadian Mineralogist, 50 (3) 773 doi:10.3749/canmin.50.3.773

(2023) Cupromakopavonite. Handbook of Mineralogy. Mineralogical Society of America

Localities for CupromakopavoniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Austria (TL)
Salzburg Zell am See District Mittersill Mittersill Scheelite deposit ⓘ Western ore field (TL)	Topa et al. (2012)

Russia
Chelyabinsk Oblast Kaslinsky District ⓘ Porokhovskoe W deposit	Rogov et al. (2023)
ⓘ Yugo-Konevo W deposit	Rogov et al. (2023)

Cupromakopavonite