Mindat Logo
Home Page Log In Message Board The Mindat Directory
Register Search Pages Chat Now! (2 online) Mindat Auctions

Cuprotungstite

Big Photo

Clara Mine, Rankach valley, Oberwolfach, Wolfach, Black Forest, Baden-Württemberg, Germany
© Stephan Wolfsried

Show Cuprotungstite Photos (16)
Formula:
Cu
 
2
[(OH)
 
2
|WO
 
4
]
System:TetragonalColour:Emerald green, brown, ...
Hardness:4 - 5
Name:In allusion to the composition, containing copper (Latin = CUPRum) and TUNGSTen.


A rare secondary mineral commonly occurring as the result of scheelite altering in a copper-rich environment.

Classification of Cuprotungstite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Explanation of status:Valid, but formula still somewhat uncertain (crystal structure not solved yet); alternate formula: Cu3(WO4)2(OH)2.
Strunz 8th edition ID:6/G.02-20
Nickel-Strunz 10th (pending) edition ID:7.GB.15

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
G : Molybdates, Wolframates and Niobates
B : With additional anions and/or H2O
Dana 8th edition ID:48.3.2.1

48 : ANHYDROUS MOLYBDATES AND TUNGSTATES
3 : Basic Anhydrous Molybdates and Tungstates
Hey's CIM Ref.:27.4.1

27 : Sulphites, Chromates, Molybdates and Tungstates
4 : Tungstates
mindat.org URL:http://www.mindat.org/min-1194.html
Please feel free to link to this page.

Type Occurrence of Cuprotungstite

Type Locality:La Paz, Mun. de La Paz, Baja California Sur, Mexico
Place of Conservation of Type Material:Natural History Museum, Paris, France: #69.47.
Year of Discovery:1869

Physical Properties of Cuprotungstite

Lustre:Vitreous, Waxy, Earthy
Diaphaneity (Transparency):Translucent
Colour:Emerald green, brown, olive-green, pistachio-green
Streak:Greenish gray to greenish yellow
Hardness (Mohs):4 - 5
Density (measured):5.4 - 6.98 g/cm3
Density (calculated):7.06 g/cm3

Crystallography of Cuprotungstite

Crystal System:Tetragonal
Class (H-M):4 2 2 - Trapezohedral
Space Group:P41 21 2
Cell Parameters:a = 8.93Å, c = 14.48Å
Ratio:a:c = 1 : 1.622
Unit Cell Volume:V 1,154.71 ų (Calculated from Unit Cell)
Z:12
Morphology:Crystals minute, dipyramidal; forms microcrystalline aggregates of botryoidal globules, incrustations, and veinlets; also compact to friable massive.

Optical Data of Cuprotungstite

Type:Uniaxial (-)
RI values: nω = 2.180 nε = 2.100
Maximum Birefringence:δ = 0.080

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High

Chemical Properties of Cuprotungstite

Formula:
Cu
 
2
[(OH)
 
2
|WO
 
4
]
Essential elements:Cu, H, O, W
All elements listed in formula:Cu, H, O, W

Relationship of Cuprotungstite to other Species

Common Associates:
StolziteScheeliteRaspite
Related Minerals - Nickel-Strunz Grouping):

- +
7.GB.05Lindgrenite
Cu
 
3
[OH|MoO
 
4
]
 
2
7.GB.10Szenicsite
Cu
 
3
(MoO
 
4
)(OH)
 
4
7.GB.15UM1999-38-WO:CrV
V, Cr, W, O, H [V:Cr:W ratio about· 2:1:3]
7.GB.20Phyllotungstite
Ca
 
x
[(W,Fe)(O,OH)
 
3
]·yH
 
2
O
7.GB.25Rankachite
(V
4+
 
,V
5+
 
)(W
6+
 
,Fe
3+
 
)
 
2
O
 
8
(OH)•(Ca
 
x
H
 
2
O
 
y
) with x ~ 0.5, y ~ 2.
7.GB.30Ferrimolybdite
Fe
 
2
[MoO
 
4
]
 
3
 · nH
 
2
O
7.GB.35Anthoinite
WAlO
 
3
(OH)
 
3
 (?)
7.GB.35Mpororoite
AlWO
 
3
(OH)
 
3
·2H
 
2
O
7.GB.40Obradovicite
H
 
4
(K,Na)CuFe
 
2
AsO
 
4
(MoO
 
4
)
 
5
·12H
 
2
O
7.GB.45Mendozavilite
Na(Ca,Mg)
 
2
[Fe
 
6
(PO
 
4
)
 
2
(PMo
 
11
O
 
39
)(OH,Cl)
 
10
]·33H
 
2
O
7.GB.45Paramendozavilite
NaAl
 
4
[Fe
 
7
(PO
 
4
)
 
5
(PMo
 
12
O
 
40
)(OH)
 
16
]·56H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
27.4.2Scheelite
Ca[WO
 
4
]
27.4.4Anthoinite
WAlO
 
3
(OH)
 
3
 (?)
27.4.5Mpororoite
AlWO
 
3
(OH)
 
3
·2H
 
2
O
27.4.6Yttrotungstite-(Y)
YW
 
2
O
 
6
(OH)
 
3
27.4.7Yttrotungstite-(Ce)
(Ce,Nd,Y)W
 
2
O
 
6
(OH)
 
3
27.4.8Stolzite
Pb[WO
 
4
]
27.4.9Raspite
PbWO
 
4
27.4.10Russellite
(BiO)
 
2
[WO
 
4
]
27.4.11Pinalite
Pb
 
3
WO
 
5
Cl
 
2
27.4.12Uranotungstite
(Fe
2+
 
,Ba,Pb)(UO
 
2
)
 
2
[(OH)
 
4
|WO
 
4
] · 12H
 
2
O
27.4.13Hübnerite
MnWO
 
4
27.4.14Ferberite
FeWO
 
4
27.4.15Wolframite
(Fe
2+
 
)WO
 
4
 
 
to (Mn
2+
 
)WO
 
4
27.4.16Ferritungstite
(W,Fe
3+
 
)(O,OH)
 
3
27.4.17Phyllotungstite
Ca
 
x
[(W,Fe)(O,OH)
 
3
]·yH
 
2
O
27.4.18Qitianlingite
(Fe,Mn)
 
2
(Nb,Ta)
 
2
WO
 
10

Other Names for Cuprotungstite

Synonyms:
Cuproscheelite
Other Languages:
French:Tungstate de cuivre
German:Cupritungstit

Other Information

Other Information:Readily soluble in acids.

Forms more or less complete pseudomorphs after Scheelite.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Cuprotungstite

Reference List:Whitney (1866) Proceedings of the California Academy of Science: 3: 287 (as Cuproscheelite).

Adam, M. (1869) Tableau minéralogique, Paris: 32.

Domeyko (1869) Annales des mines: 16: 537 (as Tungstate de cuivre).

Dana, E.S. (1892) System of Mineralogy, 6th. Edition, New York: 988.

Hess (1917) U.S. Geological Survey Bulletin 652: 32.

Larsen, E.S. (1921) The Microscopic Determination of the Nonopaque Minerals, First edition, USGS Bulletin 679: 64.

Hintze, Carl (1929) Handbuch der Mineralogie. Berlin and Leipzig. 6 volumes: 1 [3B]: 4087.

Schaller, W. T. (1932): Chemical composition of cuprotungstite. American Mineralogist: 17: 234-237.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 1091-1092.

Doucet, S., Pierrot, R. & Pillard, F. (1969): Synthesis and new data on cuprotungstite. Bull. Soc. Fr. Mineral. Cristallogr.: 92, 497-499. (in French).

Walenta, K. (1979): New data for cuprotungstite. Mineralogical Magazine: 43: 448-450.

Duggan, M.B. (1988) Cuprotungstite from the Cordillera mine, Crookwell, New South Wales. Australian Mineralogist, 3, 61–64.

American Mineralogist (1990): 75: 713.

Internet Links for Cuprotungstite

Search Engines:
  • Look for Cuprotungstite on Google
  • Look for Cuprotungstite images on Google
    • External Links:
  • Look for Cuprotungstite on Webmineral
  • Look for Cuprotungstite on Athena Mineralogy
  • Look for Cuprotungstite on Wikipedia
  • Look for Cuprotungstite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Cuprotungstite in the Natural History Museum (London) online catalogue
  • Cuprotungstite details from Handbook of Mineralogy (PDF)
    • Mineral Dealers:
  • Search for - Cuprotungstite - on e-Rocks Mineral Sales & Auctions
  • DAKOTA MATRIX offers Cabinet and Rare Species from Worldwide Localities.
  • Buy Minerals and Crystals from Crystalarium.com
  • Buy from David K Joyce minerals
  • Fabre Minerals - search for Cuprotungstite specimens
  • rare and unusual minerals mainly crystallized
  • Wilensky Fine Minerals
  • Mineral Classics - Worldwide Collector Quality Minerals and Gems
  • Top quality minerals from Kristalle of California
  • Buy fine minerals and gemstones from Pala International
  • Lapis Mineral Magazin
  • Buy Fine Minerals from mineralsweb.com
    • Jobs:
  • Mining & Geology Jobs

    • Page Sponsor

    Sponsorship:This page is currently not sponsored. Click here to sponsor this page.

    Localities for Cuprotungstite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • New South Wales
      • Georgiana Co.
        • Tuena
          • Kangaloolah
    		M. B. Duggan (1988): Cuprotungstite from the Cordillera mine, Crookwell, New South Wales. Australian Mineralogist 3 (2), 61-64.
      • Yancowinna Co.
    		No reference listed
    • Tasmania
      • Rossarden district
    		Bottrill RS & Baker, WE (in prep) Catalogue of Minerals of Tasmania. Mineral Resources Tasmania
    Chile
     
    • Atacama Region
      • Copiapó Province
        • Cerro Blanco district
    		R.H.Sillitoe/A.H.Clark/A.E.S.Mayer: \"Cuproscheelite from the Copiapó Mining district, Northern Chile\": AM, Vol 55 july-august 1970
      • Huasco Province
        • Vallenar
    		C. Ruiz Fuller/F. Peebles (1988): \"Yacimientos metalíferos de Chile\": Fondecyt, Stgo de Chile.
    • Coquimbo Region
      • Choapa Province
        • Salamanca
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1091.
      • Elqui Province
        • Chingoles
    		C. Ruiz Fuller/F. Peebles (1988): \"Yacimientos metalíferos de Chile\": Fondecyt, Stgo de Chile
    Germany
     
    • Baden-Württemberg
      • Black Forest
        • Wolfach
          • Oberwolfach
            • Rankach valley
    		Walenta, K. (1992): Die Mineralien des Schwarzwaldes. Chr. Weise Verlag, München, 336 pp. (in German)
    • Saxony
      • Erzgebirge
        • Clausnitz - Sayda District
          • Clausnitz
    		J. Gröbner und U. Kolitsch (2006): Neufunde aus dem Erzgebirge (II). Mineralien-Welt 17 (3), 22-27.
    Italy
     
    • Piedmont
      • Torino Province
        • Canavese District
          • Léssolo
            • Cálea
    		http://www.webmineralshop.com/articoli/brosso_eng.htm
    Japan
     
    • Honshu Island
      • Chubu region
        • Yamanashi prefecture
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1091.
      • Chugoku Region
        • Yamaguchi Prefecture
          • Mine city
    		Alfredo Petrov collection
    Alfredo Petrov collection
    Yamada (2001) Suisyou, 14, 7-11.
    Kazakhstan
     
    • Qaraghandy Oblysy (Karaganda Oblast')
      • Betpakdala Desert (Bet-Pak-Dal Desert)
    		P.M. Kartashov data
    Mexico
     
    • Baja California Sur
      • Mun. de La Paz
    		Adam (1869) Tableau minéral: 32; Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1091.
    • Chihuahua
      • Mun. de Buenaventura
        • San Lorenzo
    		Panczner (1987): 176.
    • Sonora
      • Mun. de Arizpe
        • Arizpe
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1091.
      • Mun. de Huépac
        • Huépac
    		Panczner (1987): 176.
      • Mun. de Yécora
        • San Nicolás
    		Panczner(1987):336.
    Panczner(1987):176,336.
    Namibia
     
    • Khomas Region
    		Collection of NHM, Vienna
    • Kunene Region
      • Damaraland District
    		[MinRecord 29:164]
          • Copper Valley
    		Gerhard Niedermayr: Mesopotamia 504 - die Typlokalität des Namibit
    South Africa
     
    • Mpumalanga Province
      • Marble Hall
    		Minerals of South Africa
    • Northern Cape Province
      • Upington
    		Minerals of South Africa
    UK
     
    • England
      • Cornwall
        • Callington District
          • Gunnislake Area
    		[Golley & Williams, 1995, "Cornish Mineral Reference Manual", p21]
        • Camborne - Redruth - St Day District
          • Gwennap area
            • St Day United Mines (Poldice Mines)
    		[Golley & Williams, 1995, "Cornish Mineral Reference Manual", p21]
        • St Austell District
          • Luxulyan Area (Luxulian Area)
            • Hensbarrow Downs
              • Stenalees
    		[Golley & Williams, 1995, "Cornish Mineral Reference Manual", p21]
      • Cumbria
        • North and Western Region (Cumberland)
          • Southern Fells
            • Waberthwaite
    		BMS Database
    USA
     
    • Arizona
      • Cochise Co.
        • Little Dragoon Mts
          • Cochise District
    		Keith, Stanton B. (1973), Arizona Bureau of Geology & Mineral Technology, Geol. Sur. Branch Bull. 187, Index of Mining Properties in Cochise Co., AZ: 55 (Table 4); Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 197; Dale, V.B., et al (1960), Tungsten deposits of Cochise, Pima, and Santa Cruz Cos., AZ, US Bur. of mines Rept. Inv. 5650: 50.
            • Dragoon
    		Wilson, E.D. 91941), AZ Bur. Mines Bull. 148: 44.
      • Maricopa Co.
    		Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 423; Dale, V.B. (1959), Tungsten deposits of Yuma, Maricopa, Pinal and Graham Cos., AZ, US Bur. Mines Rept. Inv. 5516; Wilson, E.D. (1941), AZ Bur. Mines Bull. 148: 26-27; Hess, F.L. (1917), Tungsten minerals and deposits, USGS Bull. 652: 33, 64..
        • Verde Mts
    		Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 278; Schaller, W.T. (1932), Chemical composition of cuprotungstite, Am.Min.: 17: 234-237; Galbraith, F.W. & D.J. Brennan (1959), Minerals of AZ: 82; Hess, Frank L. (1917), Tungsten minerals and deposits, USGS Bull. 652: 25 (Plate XVII).
    Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 363; Schaller, W.T. (1932),Chemical composition of cuprotungstite, Am.Min. 17:234-237.
      • Mohave Co.
        • Hualapai (Hualpai) Mts
          • Boriana District
            • Boriana Canyon
    		Conway, C.M., et al (1990), USGS Bull. 1737-E: E10; Wilson, E.D. (1941), AZ Bur. of Mines Bull. 148, Tungsten Deps. of AZ: 11-14.
      • Pima Co.
        • Santa Rita Mts
          • Helvetia-Rosemont District
            • Helvetia
    		Galbraith, F.W. & D.J. Brennan (1959), Minerals of AZ: 82.
              • Monument Mountain
    		Collected personally; Cuprotungstite - knowledge among local collectors
      • Yuma Co.
        • Eagle Tail Mts (Cemetary Ridge)
          • Eagle Tail District
    		Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 197; Galbraith, F.W. & D.J. Brennan (1959), Minerals of AZ: 82.
    • California
      • Kern Co.
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1091.
      • Plumas Co.
        • Last Chance District
          • Spring Creek area
    		Mineralogical Record (In press)
    Mineralogical Record (In press)
      • Sierra Co.
    		Pemberton, H. Earl (1983), Minerals of California; Van Nostrand Reinholt Press: 338.
    • Colorado
      • Chaffee Co.
        • Cleora District
    		Minerals of Colorado (1997) Eckels, E. B.
    Minerals of Colorado (1997) Eckels, E. B.
    • Idaho
      • Adams Co.
    		Rocks & Min. 70:244
          • Cuprum
    		[O'Donoghue, 1978 - "Encyclopedia of Minerals & Gemstones", p284]
    Ream, Lanny R. 2004. Idaho Minerals, 2nd edition, Revised and Updated
    • Nevada
      • Esmeralda Co.
    		NBMG Spec. Pub. 31 Minerals of Nevada
      • Mineral Co.
        • Leonard District
    		NBMG Spec. Pub. 31 Minerals of Nevada
    • New Mexico
      • Hidalgo Co.
    		DeMark, R.S. (2004): News from the Apache mine, New Mexico. Mineral News, 20, 8.
    Min News 20:10 p 8
      • Sierra Co.
    		Minerals of New Mexico 3rd ed.
      • Taos Co.
    		Northrop, Minerals of New Mexico, 3rd Rev. Ed., 1996
    A Listing of North Carolina Minerals- Leonard S. Wiener and Sigrid Ballew- 2001
      • Cabarrus Co.
    		Genth,F.A ,1891,The Minerals of North Carolina,pg 90
    • Utah
      • Tooele Co.
        • Deep Creek Mts
          • Gold Hill District (Clifton District)
    		UGMS Bull 117 Minerals and Mineral Localities of Utah
    UGMS Bull 117 Minerals and Mineral Localities of Utah
    UGMS Bull 117 Minerals and Mineral Localities of Utah
    • Virginia
      • Mecklenburg Co.
        • Hamme Tungsten
    		Minerals of Virginia, 1990 by R. V. Dietrich
    Minerals of Virginia, 1990 by R. V. Dietrich
    Minerals of Virginia, 1990 by R. V. Dietrich
    Mineral and/or Locality
    Google
     
    www.mindat.org Web
    Copyright © Jolyon Ralph and Ida Chau 1993-2009. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them.Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. If you would like to add information to improve the quality of our database, then click here to register. Current server date and time: 7th Nov 2009 11:46:33