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Tsepinite-Ca

A valid IMA mineral species
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About Tsepinite-CaHide

Formula:
Ca(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O
Colour:
White, colourless, pale brownish
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
2.73
Crystal System:
Monoclinic
Name:
Named for its relationship to previously described tsepinite-Na and tsepinite-K, with Ca dominant over Na or K. The root name is after Anatoliy Ivanovich Tsepin (b. 1946), physicist of the Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences (IGEM), specialist in X-ray spectroscopy and the electron-microprobe analysis of minerals, who initiated in the 1970s an electron-microprobe investigation of Labuntsovite Group minerals.
This page provides mineralogical data about Tsepinite-Ca.


Unique IdentifiersHide

Mindat ID:
26367
Long-form identifier:
mindat:1:1:26367:8
GUID
(UUID V4):
924acc46-3734-46df-bbba-7ea486fde067

IMA Classification of Tsepinite-CaHide

Classification of Tsepinite-CaHide

9.CE.30b

9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
Tsp-CaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Tsepinite-CaHide

Vitreous
Transparency:
Transparent
Colour:
White, colourless, pale brownish
Streak:
White
Hardness:
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven
Density:
2.73(1) g/cm3 (Measured)    2.72 g/cm3 (Calculated)

Optical Data of Tsepinite-CaHide

Type:
Biaxial (+)
RI values:
nα = 1.666 nβ = 1.676 nγ = 1.780
2V:
Measured: 30° , Calculated: 36°
Max Birefringence:
δ = 0.114
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
very weak: r < n.
Pleochroism:
Non-pleochroic

Chemistry of Tsepinite-CaHide

Mindat Formula:
Ca(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O
Common Impurities:
K,Na

Crystallography of Tsepinite-CaHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 14.484 Å, b = 14.191 Å, c = 7.907 Å
β = 117.26°
Ratio:
a:b:c = 1.021 : 1 : 0.557
Unit Cell V:
1,444.72 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Combine both in sheaf-like clusters up to 2 x 6 mm large and chaotic open-worked aggregates up to 1 cm as maximum dimension.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014929Tsepinite-CaPekov I V, Chukanov N V, Ferraris G, Gula A, Pushcharovsky D Y, Zadov A E (2003) Tsepinite-Ca,(Ca,K,Na,[])2(Ti,Nb)2(Si4O12)(OH,O)2*4H2O, a new mineral of the labuntsovite group from the Khibiny alkaline massif, Kola peninsula - novel disordered sites in the vuoriyarvite-type structure Kola Peninsula, Russia Neues Jahrbuch fur Mineralogie, Monatshefte 2003 461-4802003Lovchorrite mine, Hackman Valley, Yukspor Mountian, Khibiny massif,0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
7.02 Å(60)
6.38 Å(40)
3.53 Å(45)
3.16 Å(100)
2.62 Å(45)
2.51 Å(85)
1.718 Å(50)
Comments:
From Type Description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 4b: Highly evolved igneous rocks>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of Tsepinite-CaHide

General Appearance of Type Material:
Coarse long-prismatic to needle-shaped crystals up to 0.2 x 0.6 x 5mm in size.
Place of Conservation of Type Material:
A. E. Fersman Mineralogical Museum, Moscow, Russia, 2877/1.
Geological Setting of Type Material:
In cavities of replaced rinkite.
Associated Minerals at Type Locality:
Reference:
Pekov, I.V., Chukanov, N.V., Ferraris, G., Gula, A., Pushcharovsky, D.Y., Zadov, A.E. (2003) Tsepinite–Ca,(Ca,K,Na,□)2(Ti,Nb)2(Si4O12)(OH,O)2·4H2O, a new mineral of the labuntsovite group from the Khibiny alkaline massif, Kola Peninsula–Novel disordered sites in the vuoriyarvite-type structure. Neues Jahrbuch für Mineralogie-Monatshefte: 2003(10): 461-480.

Synonyms of Tsepinite-CaHide

Other Language Names for Tsepinite-CaHide

Simplified Chinese:水硅铌钛钙石
Traditional Chinese:水矽鈮鈦鈣石

Relationship of Tsepinite-Ca to other SpeciesHide

Other Members of this group:
Tsepinite-KK2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
Tsepinite-NaNa2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
Tsepinite-SrSr(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
Vuoriyarvite-KK2(Nb,Ti)2(Si4O12)(O,OH)2 · 4H2OMon. m : Bm

Common AssociatesHide

Associated Minerals Based on Photo Data:
3 photos of Tsepinite-Ca associated with Pyatenkoite-(Y)Na5YTi[SiO3]6 · 6H2O
3 photos of Tsepinite-Ca associated with Kentbrooksite(Na,REE)15(Ca,REE)6(Mn2+,Fe2+)3Zr3Nb[Si25O74]F2 · 2H2O
1 photo of Tsepinite-Ca associated with EudialyteNa15Ca6Fe3Zr3Si(Si25O73)(O,OH,H2O)3(Cl,OH)2
1 photo of Tsepinite-Ca associated with AegirineNaFe3+Si2O6

Related Minerals - Strunz-mindat GroupingHide

9.CE.Dutkevichite-(Ce)NaZnBa2Ce2Ti2Si8O26F · H2OOrth. mm2 : Ama2
9.CE.NiobobaotiteBa4(Ti2.5Fe2+1.5)Nb4Si4O28ClTet. 4/m : I41/a
9.CE.05PapagoiteCaCu[H3AlSi2O9]Mon. 2/m : B2/m
9.CE.10VerplanckiteBa4Mn2+2Si4O12(OH,H2O)3Cl3Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
9.CE.15BaotiteBa4(Ti,Nb,W)8O16(SiO3)4ClTet. 4/m : I41/a
9.CE.20NagashimaliteBa4(V,Ti)4B2Si8O27(O,OH)2ClOrth. mmm (2/m 2/m 2/m) : Pmmn
9.CE.20TaramelliteBa4(Fe3+,Ti,Fe2+,Mg)4(B2Si8O27)O2ClxOrth. mmm (2/m 2/m 2/m) : Pmmn
9.CE.20TitantaramelliteBa4(Ti,Fe3+,Fe2+,Mg)4(B2Si8O27)O2ClxOrth. mmm (2/m 2/m 2/m)
9.CE.25Bario-orthojoaquinite(Ba,Sr)4Fe2Ti2[Si4O12]2O2 · H2OOrth.
9.CE.25Byelorussite-(Ce)NaBa2Ce2MnTi2[Si4O12]2O2(F,OH) · H2OOrth. mm2 : Ama2
9.CE.25Joaquinite-(Ce)NaBa2Ce2FeTi2[Si4O12]2O2(OH,F) · H2OMon. 2 : B2
9.CE.25Orthojoaquinite-(Ce)NaBa2Ce2FeTi2[Si4O12]2O2(O,OH) · H2OOrth.
9.CE.25StrontiojoaquiniteSr2Ba2(Na,Fe)2Ti2[Si4O12]2O2(O,OH)2 · H2OMon.
9.CE.25Strontio-orthojoaquinite(Na,Fe)2Sr2Ba2Ti2[Si4O12]2O2(O,OH)2 · H2OOrth.
9.CE.25Orthojoaquinite-(La)NaBa2La2Fe2+Ti2[Si4O12]2O2(O,OH) · H2OOrth. mmm (2/m 2/m 2/m)
9.CE.30aUnnamed (Ca-Na-ordered analogue of Korobitsynite)(Ca,Na)2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2OOrth. 2 2 2 : P21 21 2
9.CE.30eLabuntsovite-MnNa4K4(Ba,K)2Mn2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10-12H2OMon. 2/m : B2/m
9.CE.30aNenadkevichite(Na,◻)8Nb4(Si4O12)2(O,OH)4 · 8H2OOrth. mmm (2/m 2/m 2/m) : Pbam
9.CE.30dLemmleinite-KK2(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2OOrth.
9.CE.30aKorobitsyniteNa2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2OOrth. mmm (2/m 2/m 2/m) : Pbam
9.CE.30cKuzmenkoite-MnK2Mn2+(Ti,Nb)4(Si4O12)2(OH,O)4 · 5-6H2OMon. 2/m : B2/m
9.CE.30bVuoriyarvite-KK2(Nb,Ti)2(Si4O12)(O,OH)2 · 4H2OMon. m : Bm
9.CE.30bTsepinite-NaNa2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
9.CE.30cKarupmøllerite-Ca(Na,Ca,K)2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 7H2OMon. 2/m : B2/m
9.CE.30eLabuntsovite-MgNa4K4(Ba,K)2Mg(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2OMon. 2/m : B2/m
9.CE.30eLabuntsovite-FeNa4K4(Ba,K)2Fe2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2OMon. 2/m : B2/m
9.CE.30dLemmleinite-BaNa2K2Ba(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2OMon. 2/m : B2/m
9.CE.30cGjerdingenite-FeK2Fe2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30hNeskevaaraite-FeK3Na2Fe2+(Ti,Nb)4(Si4O12)2(O,OH)4 · 5-6 H2OMon. m : Bm
9.CE.30bTsepinite-KK2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
9.CE.30bParatsepinite-BaBa4(Ti,Nb)8(Si4O12)4(OH,O)8 · 8H2OMon. 2/m : B2/m
9.CE.30hAlsakharovite-ZnNaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2OMon. m : Bm
9.CE.30cGjerdingenite-MnK2Mn2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30cLepkhenelmite-Zn(Ba,K)2Zn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2OMon. m : Bm
9.CE.30bTsepinite-SrSr(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2OMon. m : Bm
9.CE.30bParatsepinite-Na(Na,Sr,K,Ca)7(Ti,Nb)8(Si4O12)4(O,OH)8 · nH2O n ~ 8Mon. 2/m : B2/m
9.CE.30fParalabuntsovite-MgNa8K8Mg4Ti16(Si4O12)8(OH,O)16 · 20-24H2OMon. 2/m : B2/m
9.CE.30cGjerdingenite-CaK2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30cGjerdingenite-NaK2Na(Nb,Ti)4(Si4O12)2(OH,O)4 · 5H2OMon. 2/m : B2/m
9.CE.30hGutkovaite-MnK2CaMn(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2OMon. m : Bm
9.CE.30cKuzmenkoite-ZnK2Zn(Ti,Nb)4(Si4O12)2(OH,O)4 · 6-8H2OMon. m : Bm
9.CE.30gOrganovaite-MnK2Mn(Nb,Ti)4(Si4O12)2(O,OH)4 · 5-7H2OMon. 2/m : B2/m
9.CE.30gOrganovaite-ZnK2Zn(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2OMon. 2/m : B2/m
9.CE.30gParakuzmenkoite-Fe(K,Ba)4Fe(Ti,Nb)8(Si4O12)4(O,OH)8 · 14H2OMon. 2/m : B2/m
9.CE.30cBurovaite-Ca(Na,K)4Ca2(Ti,Nb)8(Si4O12)4(OH,O)8 · 12H2OMon. 2/m : B2/m
9.CE.45Komarovite(Ca,Mn)(Nb,Ti)2[Si2O7](O,F)3 · 3.5H2OOrth. mmm (2/m 2/m 2/m) : Cmmm
9.CE.45Natrokomarovite(Na,Ca,H)2Nb2Si2O10(OH,F)2 · H2OOrth.

Fluorescence of Tsepinite-CaHide

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Tsepinite-CaHide

References for Tsepinite-CaHide

Localities for Tsepinite-CaHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Russia
 
  • Murmansk Oblast
    • Khibiny Massif
Lykova et al. (2016)
        • Astrophyllite Stream
Pekov et al. (2005)
      • Yukspor Mt
        • Hackman Valley
Pekov et al. (2003)
 
Mineral and/or Locality  
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