Tsepinite-Ca
A valid IMA mineral species
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About Tsepinite-Ca
Formula:
Ca(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O
Colour:
White, colourless, pale brownish
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
2.73
Crystal System:
Monoclinic
Member of:
Name:
Named for its relationship to previously described tsepinite-Na and tsepinite-K, with Ca dominant over Na or K. The root name is after Anatoliy Ivanovich Tsepin (b. 1946), physicist of the Institute of Geology of Ore Deposits, Petrography, Mineralogy and Geochemistry of the Russian Academy of Sciences (IGEM), specialist in X-ray spectroscopy and the electron-microprobe analysis of minerals, who initiated in the 1970s an electron-microprobe investigation of Labuntsovite Group minerals.
This page provides mineralogical data about Tsepinite-Ca.
Unique Identifiers
Mindat ID:
26367
Long-form identifier:
mindat:1:1:26367:8
GUID
(UUID V4):
(UUID V4):
924acc46-3734-46df-bbba-7ea486fde067
IMA Classification of Tsepinite-Ca
Approved
IMA Formula:
(Ca,K,Na)2-x(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2O
Approval year:
2002
First published:
2003
Type description reference:
Pekov, Igor V., Chukanov, Nikita V., Ferraris, Giovanni, Gula, Angela, Pushcharovsky, Dmitry Yu., Zadov, Aleksandr E. (2003) Tsepinite–Ca, (Ca,K,Na,□)2(Ti,Nb)2(Si4O12) (OH,O)2·4H2O, a new mineral of the labuntsovite group from the Khibiny alkaline
massif, Kola Peninsula – Novel disordered sites in the vuoriyarvite-type structure. Neues Jahrbuch für Mineralogie - Monatshefte, 2003 (10) 461-480 doi:10.1127/0028-3649/2003/2003-0461
Classification of Tsepinite-Ca
9.CE.30b
9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Tsp-Ca | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Tsepinite-Ca
Vitreous
Transparency:
Transparent
Colour:
White, colourless, pale brownish
Streak:
White
Hardness:
5 on Mohs scale
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven
Density:
2.73(1) g/cm3 (Measured) 2.72 g/cm3 (Calculated)
Optical Data of Tsepinite-Ca
Type:
Biaxial (+)
RI values:
nα = 1.666 nβ = 1.676 nγ = 1.780
2V:
Measured: 30° , Calculated: 36°
Max Birefringence:
δ = 0.114
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
very weak: r < n.
Pleochroism:
Non-pleochroic
Chemistry of Tsepinite-Ca
Mindat Formula:
Ca(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O
Common Impurities:
K,Na
Crystallography of Tsepinite-Ca
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Setting:
C2/m
Cell Parameters:
a = 14.484 Å, b = 14.191 Å, c = 7.907 Å
β = 117.26°
β = 117.26°
Ratio:
a:b:c = 1.021 : 1 : 0.557
Unit Cell V:
1,444.72 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Combine both in sheaf-like clusters up to 2 x 6 mm large and chaotic open-worked aggregates up to 1 cm as maximum dimension.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0014929 | Tsepinite-Ca | Pekov I V, Chukanov N V, Ferraris G, Gula A, Pushcharovsky D Y, Zadov A E (2003) Tsepinite-Ca,(Ca,K,Na,[])2(Ti,Nb)2(Si4O12)(OH,O)2*4H2O, a new mineral of the labuntsovite group from the Khibiny alkaline massif, Kola peninsula - novel disordered sites in the vuoriyarvite-type structure Kola Peninsula, Russia Neues Jahrbuch fur Mineralogie, Monatshefte 2003 461-480 | 2003 | Lovchorrite mine, Hackman Valley, Yukspor Mountian, Khibiny massif, | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
7.02 Å | (60) |
6.38 Å | (40) |
3.53 Å | (45) |
3.16 Å | (100) |
2.62 Å | (45) |
2.51 Å | (85) |
1.718 Å | (50) |
Comments:
From Type Description.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 4b: Highly evolved igneous rocks | >3.0 |
35 : Ultra-alkali and agpaitic igneous rocks |
Type Occurrence of Tsepinite-Ca
General Appearance of Type Material:
Coarse long-prismatic to needle-shaped crystals up to 0.2 x 0.6 x 5mm in size.
Place of Conservation of Type Material:
A. E. Fersman Mineralogical Museum, Moscow, Russia, 2877/1.
Geological Setting of Type Material:
In cavities of replaced rinkite.
Associated Minerals at Type Locality:
Reference:
Pekov, I.V., Chukanov, N.V., Ferraris, G., Gula, A., Pushcharovsky, D.Y., Zadov, A.E. (2003) Tsepinite–Ca,(Ca,K,Na,□)2(Ti,Nb)2(Si4O12)(OH,O)2·4H2O, a new mineral of the labuntsovite group from the Khibiny alkaline massif, Kola Peninsula–Novel disordered sites in the vuoriyarvite-type structure. Neues Jahrbuch für Mineralogie-Monatshefte: 2003(10): 461-480.
Synonyms of Tsepinite-Ca
Other Language Names for Tsepinite-Ca
Relationship of Tsepinite-Ca to other Species
Member of:
Other Members of this group:
Tsepinite-K | K2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O | Mon. m : Bm |
Tsepinite-Na | Na2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O | Mon. m : Bm |
Tsepinite-Sr | Sr(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O | Mon. m : Bm |
Vuoriyarvite-K | K2(Nb,Ti)2(Si4O12)(O,OH)2 · 4H2O | Mon. m : Bm |
Common Associates
Associated Minerals Based on Photo Data:
3 photos of Tsepinite-Ca associated with Pyatenkoite-(Y) | Na5YTi[SiO3]6 · 6H2O |
3 photos of Tsepinite-Ca associated with Kentbrooksite | (Na,REE)15(Ca,REE)6(Mn2+,Fe2+)3Zr3Nb[Si25O74]F2 · 2H2O |
1 photo of Tsepinite-Ca associated with Eudialyte | Na15Ca6Fe3Zr3Si(Si25O73)(O,OH,H2O)3(Cl,OH)2 |
1 photo of Tsepinite-Ca associated with Aegirine | NaFe3+Si2O6 |
Related Minerals - Strunz-mindat Grouping
9.CE. | Dutkevichite-(Ce) | NaZnBa2Ce2Ti2Si8O26F · H2O |
9.CE. | Niobobaotite | Ba4(Ti2.5Fe2+1.5)Nb4Si4O28Cl |
9.CE.05 | Papagoite | CaCu[H3AlSi2O9] |
9.CE.10 | Verplanckite | Ba4Mn2+2Si4O12(OH,H2O)3Cl3 |
9.CE.15 | Baotite | Ba4(Ti,Nb,W)8O16(SiO3)4Cl |
9.CE.20 | Nagashimalite | Ba4(V,Ti)4B2Si8O27(O,OH)2Cl |
9.CE.20 | Taramellite | Ba4(Fe3+,Ti,Fe2+,Mg)4(B2Si8O27)O2Clx |
9.CE.20 | Titantaramellite | Ba4(Ti,Fe3+,Fe2+,Mg)4(B2Si8O27)O2Clx |
9.CE.25 | Bario-orthojoaquinite | (Ba,Sr)4Fe2Ti2[Si4O12]2O2 · H2O |
9.CE.25 | Byelorussite-(Ce) | NaBa2Ce2MnTi2[Si4O12]2O2(F,OH) · H2O |
9.CE.25 | Joaquinite-(Ce) | NaBa2Ce2FeTi2[Si4O12]2O2(OH,F) · H2O |
9.CE.25 | Orthojoaquinite-(Ce) | NaBa2Ce2FeTi2[Si4O12]2O2(O,OH) · H2O |
9.CE.25 | Strontiojoaquinite | Sr2Ba2(Na,Fe)2Ti2[Si4O12]2O2(O,OH)2 · H2O |
9.CE.25 | Strontio-orthojoaquinite | (Na,Fe)2Sr2Ba2Ti2[Si4O12]2O2(O,OH)2 · H2O |
9.CE.25 | Orthojoaquinite-(La) | NaBa2La2Fe2+Ti2[Si4O12]2O2(O,OH) · H2O |
9.CE.30a | Unnamed (Ca-Na-ordered analogue of Korobitsynite) | (Ca,Na)2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2O |
9.CE.30e | Labuntsovite-Mn | Na4K4(Ba,K)2Mn2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10-12H2O |
9.CE.30a | Nenadkevichite | (Na,◻)8Nb4(Si4O12)2(O,OH)4 · 8H2O |
9.CE.30d | Lemmleinite-K | K2(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2O |
9.CE.30a | Korobitsynite | Na2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2O |
9.CE.30c | Kuzmenkoite-Mn | K2Mn2+(Ti,Nb)4(Si4O12)2(OH,O)4 · 5-6H2O |
9.CE.30b | Vuoriyarvite-K | K2(Nb,Ti)2(Si4O12)(O,OH)2 · 4H2O |
9.CE.30b | Tsepinite-Na | Na2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O |
9.CE.30c | Karupmøllerite-Ca | (Na,Ca,K)2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 7H2O |
9.CE.30e | Labuntsovite-Mg | Na4K4(Ba,K)2Mg(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2O |
9.CE.30e | Labuntsovite-Fe | Na4K4(Ba,K)2Fe2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2O |
9.CE.30d | Lemmleinite-Ba | Na2K2Ba(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2O |
9.CE.30c | Gjerdingenite-Fe | K2Fe2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O |
9.CE.30h | Neskevaaraite-Fe | K3Na2Fe2+(Ti,Nb)4(Si4O12)2(O,OH)4 · 5-6 H2O |
9.CE.30b | Tsepinite-K | K2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O |
9.CE.30b | Paratsepinite-Ba | Ba4(Ti,Nb)8(Si4O12)4(OH,O)8 · 8H2O |
9.CE.30h | Alsakharovite-Zn | NaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2O |
9.CE.30c | Gjerdingenite-Mn | K2Mn2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O |
9.CE.30c | Lepkhenelmite-Zn | (Ba,K)2Zn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2O |
9.CE.30b | Tsepinite-Sr | Sr(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O |
9.CE.30b | Paratsepinite-Na | (Na,Sr,K,Ca)7(Ti,Nb)8(Si4O12)4(O,OH)8 · nH2O n ~ 8 |
9.CE.30f | Paralabuntsovite-Mg | Na8K8Mg4Ti16(Si4O12)8(OH,O)16 · 20-24H2O |
9.CE.30c | Gjerdingenite-Ca | K2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O |
9.CE.30c | Gjerdingenite-Na | K2Na(Nb,Ti)4(Si4O12)2(OH,O)4 · 5H2O |
9.CE.30h | Gutkovaite-Mn | K2CaMn(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2O |
9.CE.30c | Kuzmenkoite-Zn | K2Zn(Ti,Nb)4(Si4O12)2(OH,O)4 · 6-8H2O |
9.CE.30g | Organovaite-Mn | K2Mn(Nb,Ti)4(Si4O12)2(O,OH)4 · 5-7H2O |
9.CE.30g | Organovaite-Zn | K2Zn(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O |
9.CE.30g | Parakuzmenkoite-Fe | (K,Ba)4Fe(Ti,Nb)8(Si4O12)4(O,OH)8 · 14H2O |
9.CE.30c | Burovaite-Ca | (Na,K)4Ca2(Ti,Nb)8(Si4O12)4(OH,O)8 · 12H2O |
9.CE.45 | Komarovite | (Ca,Mn)(Nb,Ti)2[Si2O7](O,F)3 · 3.5H2O |
9.CE.45 | Natrokomarovite | (Na,Ca,H)2Nb2Si2O10(OH,F)2 · H2O |
Fluorescence of Tsepinite-Ca
None
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Tsepinite-Ca
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https://www.mindat.org/min-26367.html
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References for Tsepinite-Ca
Reference List:
Pekov, Igor V., Chukanov, Nikita V., Ferraris, Giovanni, Gula, Angela, Pushcharovsky, Dmitry Yu., Zadov, Aleksandr E. (2003) Tsepinite–Ca, (Ca,K,Na,□)2(Ti,Nb)2(Si4O12) (OH,O)2·4H2O, a new mineral of the labuntsovite group from the Khibiny alkaline
massif, Kola Peninsula – Novel disordered sites in the vuoriyarvite-type structure. Neues Jahrbuch für Mineralogie - Monatshefte, 2003 (10) 461-480 doi:10.1127/0028-3649/2003/2003-0461
Localities for Tsepinite-Ca
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Russia | |
| Lykova et al. (2016) |
| Pekov et al. (2005) |
| Pekov et al. (2003) |
Quick NavTopAbout Tsepinite-CaUnique IdentifiersIMA Classification Classification Mineral SymbolsPhysical Properties Optical Data Chemistry Crystallography Crystal StructureX-Ray Powder DiffractionGeological EnvironmentType Occurrence SynonymsOther LanguagesRelationshipsCommon AssociatesStrunz-MindatFluorescence Other InformationInternet Links References Localities Locality List
Hackman Valley, Yukspor Mt, Khibiny Massif, Murmansk Oblast, Russia