| Reference Type | Journal (article/letter/editorial) |
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| Title | Tolstykhite, Au3S4Te6, a new mineral from Maletoyvayam deposit, Kamchatka peninsula, Russia |
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| Journal | Mineralogical Magazine |
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| Authors | Kasatkin, Anatoly V. | Author |
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| Nestola, Fabrizio | Author |
| Plášil, Jakub | Author |
| Sejkora, Jiří | Author |
| Vymazalová, Anna | Author |
| Škoda, Radek | Author |
| Year | 2023 (February) | Volume | 87 |
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| Page(s) | 34-39 | Issue | 1 |
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| Publisher | Mineralogical Society |
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| DOI | doi:10.1180/mgm.2022.109Search in ResearchGate |
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| Classification | Not set | LoC | Not set |
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| Mindat Ref. ID | 15718296 | Long-form Identifier | mindat:1:5:15718296:7 |
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| GUID | c88bdb5e-a60d-4ab3-92a3-20ffba516b6b |
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| Full Reference | Kasatkin, Anatoly V., Nestola, Fabrizio, Plášil, Jakub, Sejkora, Jiří, Vymazalová, Anna, Škoda, Radek (2023) Tolstykhite, Au3S4Te6, a new mineral from Maletoyvayam deposit, Kamchatka peninsula, Russia. Mineralogical Magazine, 87 (1) 34-39 doi:10.1180/mgm.2022.109 |
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| Plain Text | Kasatkin, Anatoly V., Nestola, Fabrizio, Plášil, Jakub, Sejkora, Jiří, Vymazalová, Anna, Škoda, Radek (2023) Tolstykhite, Au3S4Te6, a new mineral from Maletoyvayam deposit, Kamchatka peninsula, Russia. Mineralogical Magazine, 87 (1) 34-39 doi:10.1180/mgm.2022.109 |
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| In | (2023, February) Mineralogical Magazine Vol. 87 (1) Mineralogical Society |
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| Abstract/Notes | Tolstykhite, ideally Au3S4Te6, is a new mineral from the Gaching ore occurrence of the Maletoyvayam deposit, Kamchatka peninsula, Russia. It occurs as individual anhedral grains up to 0.05 mm or as intergrowths with native Se, native Te and tripuhyite. Other associated minerals include calaverite, fischesserite, Cu–Te-rich ‘fahlores' [stibiogoldfieldite, ‘arsenogoldfieldite', tennantite-(Cu), tetrahedrite-(Zn)], galena, gold, maletoyvayamite, minerals of famatinite–luzonite series, pyrite, baryte, ilmenite, magnetite, quartz and V-bearing rutile. Tolstykhite is bluish-grey, opaque with metallic lustre and grey streak. It is brittle and has an uneven fracture. Cleavage is good on {010} and {001}. Dcalc = 7.347 g/cm3. In reflected light, tolstykhite is grey with a bluish shade. No bireflectance, pleochroism and internal reflections are observed. In crossed polars, it is weakly anisotropic with bluish to brownish rotation tints. The reflectance values for wavelengths recommended by the Commission on Ore Mineralogy of the International Mineralogical Association are (Rmin/Rmax, %): 32.6/34.3 (470 nm), 32.4/34.1 (546 nm), 32.6/34.5 (589 nm) and 33.0/35.0 (650 nm). The Raman spectrum of tolstykhite contains the main bands at 297, 203, 181, 151 and 127 cm–1. The empirical formula calculated on the basis of 13 atoms per formula unit is (Au2.98Ag0.01)Σ2.99(S3.59Se0.41)Σ4.00Te6.01. Tolstykhite is triclinic, space group P$\bar{1}$, a = 8.977(5), b = 9.023(2), c = 9.342(6) Å, α = 94.03(3), β = 110.03(3), γ = 104.27(4)°, V = 679.0(3) Å3 and Z = 2. The strongest lines of the powder X-ray diffraction (XRD) pattern [d, Å (I, %) (hkl)] are: 8.59 (18) (010); 2.90 (100) (0$\bar{1}$3); 2.23 (13) (13$\bar{3}$); 1.89 (21) (13$\bar{4}$). Tolstykhite is the S-analogue of maletoyvayamite, Au3Se4Te6. The structural identity between them is confirmed by powder XRD and Raman spectroscopy. The mineral honours Russian mineralogist Dr. Nadezhda Dmitrievna Tolstykh for her contributions to the mineralogy of gold and platinum-group elements and the study of ore deposits. |
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These are the references the publisher has listed as being connected to the article. Please check the article itself for the full list of references which may differ. Not all references are currently linkable within the Digital Library.
 | Tolstykh, Nadezhda, Vymazalová, Anna, Tuhý, Marek, Shapovalova, Mariya (2018) Conditions of formation of Au–Se–Te mineralization in the Gaching ore occurrence (Maletoyvayam ore field), Kamchatka, Russia. Mineralogical Magazine, 82 (3) 649-674 doi:10.1180/mgm.2018.84 |
 | Tolstykh, Nadhezda D., Tuhý, Marek, Vymazalová, Anna, Laufek, František, Plášil, Jakub, Košek, Filip (2022) Gachingite, Au(Te1–xSex) 0.2 ≈ x ≤ 0.5, a new mineral from Maletoyvayam deposit, Kamchatka peninsula, Russia. Mineralogical Magazine, 86 (2) 205-213 doi:10.1180/mgm.2022.9 |
 | Sidorov, Evgeny G., Borovikov, Andrey A., Tolstykh, Nadezhda D., Bukhanova, Daria S., Palyanova, Galina A., Chubarov, Valery M. (2020) Gold Mineralization at the Maletoyvayam Deposit (Koryak Highland, Russia) and Physicochemical Conditions of Its Formation. Minerals, 10 (12) 1093 doi:10.3390/min10121093 |
| Wang (2000) Neues Jahrbuch für Mineralogie New synthetic ternary chalcogenides 8, 348 |
| Kalinin (2012) Materials XI Regional youth scientific conference “The Natural Environment of Kamchatka” , 39 |
| Pouchou (1985) Microbeam Analysis (J.T. Armstrong , 104 |
 | Tolstykh, , Palyanova, , Bobrova, , Sidorov, (2019) Mustard Gold of the Gaching Ore Deposit (Maletoyvayam Ore Field, Kamchatka, Russia) Minerals, 9 (8) 489 doi:10.3390/min9080489 |
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 | Tolstykh, Nadezhda, Bukhanova, Daria, Shapovalova, Maria, Borovikov, Andrey, Podlipsky, Maksim (2021) The Gold Mineralization of the Baranyevskoe Au-Ag Epithermal Deposit in Central Kamchatka. Minerals, 11 (11) 1225 doi:10.3390/min11111225 |
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| Not Yet Imported: Solid State Communications - journal-article : 10.1016/0038-1098(94)90343-3
If you would like this item imported into the Digital Library, please contact us quoting Journal ID 74926 |
| Nakamoto (1986) Infrared and Raman Spectra of Inorganic and Coordination Compounds |
| Kasatkin (2022) Mineralogical Magazine Tolstykhite, IMA 2022-007, in: CNMNC Newsletter 67 86, 849 |
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 | Škácha, Pavel, Buixaderas, Elena, Plášil, Jakub, Sejkora, Jiří, Goliáš, Viktor, Vlček, Vojtěch (2014) Permingeatite, Cu3SbSe4, from Příbram (Czech republic): Description and Raman spectroscopy investigations of the luzonite-subgroup of minerals. The Canadian Mineralogist, 52 (3) 501-511 doi:10.3749/canmin.52.3.501 |
| Shapovalova (2019) IOP Conf. Series: Earth and Environmental Science Chemical composition and varieties of sulfosalts from gold mineralization in the Gaching ore occurrence (Maletoyvayam ore field) 319, 012019 |
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 | Tolstykh, Nadhezda D., Tuhý, Marek, Vymazalová, Anna, Plášil, Jakub, Laufek, František, Kasatkin, Anatoly V., Nestola, Fabrizio, Bobrova, Olga V. (2020) Maletoyvayamite, Au3Se4Te6, a new mineral from Maletoyvayam deposit, Kamchatka peninsula, Russia. Mineralogical Magazine, 84 (1) 117-123 doi:10.1180/mgm.2019.81 |
 | Palyanova, G. A., Tolstykh, N. D., Zinina, V. Yu., Kokh, K. A., Seryotkin, Yu. V., Bortnikov, N. S. (2019) Synthetic Gold Chalcogenides in the Au–Te–Se–S System and Their Natural Analogs. Doklady Earth Sciences, 487 (2) 929-934 doi:10.1134/s1028334x19080099 |
| Tolstykh (2008) Noble Metal Mineralization in Layered Ultramafic-basic Massifs in the South of the Siberian Platform |
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| Palyanova, Galina, Beliaeva, Tatiana, Kokh, Konstantin, Seryotkin, Yurii, Moroz, Tatyana, Tolstykh, Nadezda (2022) Characterization of synthetic and natural gold chalcogenides by electron microprobe analysis, X‐ray powder diffraction, and Raman spectroscopic methods. Journal of Raman Spectroscopy, 53 (5) 1012-1022 doi:10.1002/jrs.6327 |
| Palyanova, Galina, Mikhlin, Yuri, Zinina, Veronika, Kokh, Konstantin, Seryotkin, Yurii, Zhuravkova, Tatyana (2020) New gold chalcogenides in the Au–Te–Se–S system. Journal of Physics and Chemistry of Solids, 138. 109276pp. doi:10.1016/j.jpcs.2019.109276 |
| Not Yet Imported: Beilstein Journal of Nanotechnology - journal-article : 10.3762/bjnano.10.22
If you would like this item imported into the Digital Library, please contact us quoting Journal ID 8807 |
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