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Merrihueite

A valid IMA mineral species
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About MerrihueiteHide

07089870015710573366528.jpg
Craig M. Merrihue
Formula:
K(◻Na)Fe2+2Fe2+3[Si12O30]
Colour:
Greenish-blue
Hardness:
5 - 6
Specific Gravity:
2.87 (Calculated)
Crystal System:
Hexagonal
Member of:
Name:
Named by R.T. Dodd Jr., W.R. van Schmus, and U.B. Marvin in 1965 in honor of Craig Morris Merrihue (8 July 1933, Schenectady, New York, USA - 14 March 1965, Mount Washington, New Hampshire, USA), physicist at the Smithsonian Astrophysics Observatory. He developed the 40Ar/39Ar argon dating technique for measuring the ages of meteorites. He died tragically in a mountain climbing accident.

Unique IdentifiersHide

Mindat ID:
2652
Long-form identifier:
mindat:1:1:2652:5
GUID
(UUID V4):
35706a51-d198-4e72-8c15-c861f5714166

IMA Classification of MerrihueiteHide

Classification of MerrihueiteHide

9.CM.05

9 : SILICATES (Germanates)
C : Cyclosilicates
M : [Si6O18]12- 6-membered double rings (sechser-Doppelringe)
63.2.1a.5

63 : CYCLOSILICATES Condensed Rings
2 : Condensed Rings (Milarite - Osumilite group)
14.24.5

14 : Silicates not Containing Aluminum
24 : Silicates of Fe, Mg and alkalis

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
MhuIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
MrhThe Canadian Mineralogist (2019)The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download

Physical Properties of MerrihueiteHide

Transparency:
Translucent
Colour:
Greenish-blue
Hardness:
5 - 6 on Mohs scale
Density:
2.87 g/cm3 (Calculated)

Optical Data of MerrihueiteHide

Type:
Uniaxial (-)
RI values:
nω = 1.570 nε = 1.559 - 1.592
2V:
Measured: 5° to 10°
Birefringence:
Low to moderate
Max Birefringence:
δ = 0.011
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low
Pleochroism:
Visible
Comments:
Colorless to greenish-blue
Comments:
Anomalously biaxial.

Chemistry of MerrihueiteHide

Mindat Formula:
K(◻Na)Fe2+2Fe2+3[Si12O30]
Common Impurities:
Al,Mn,Ca

Crystallography of MerrihueiteHide

Crystal System:
Hexagonal
Class (H-M):
6/mmm (6/m 2/m 2/m) - Dihexagonal Dipyramidal
Space Group:
P6/mcc
Setting:
P6/mcc
Cell Parameters:
a = 10.16(6) Å, c = 14.32(6) Å
Ratio:
a:c = 1 : 1.409
Unit Cell V:
1,280.15 ų (Calculated from Unit Cell)
Z:
2
Comment:
By analogy to osumilite.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0009423MerrihueiteKhan A A, Baur W H, Forbes W C (1972) Synthetic magnesian merrihueite, dipotassium pentamagnesium dodecasilicate: a tetrahedral magnesiosilicate framework crystal structure Acta Crystallographica B28 267-2721972synthetic0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.73 Å(100)
2.774 Å(100)
3.23 Å(90)
7.13 Å(80)
2.92 Å(60)
2.530 Å(50)
5.03 Å(30)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 1: Primary nebular phases4.567-4.561
4 : Primary chondrule phases4.566–4.561
Stage 2: Planetesimal differentiation and alteration4.566-4.550
5 : Primary asteroid phases4.566–4.560
6 : Secondary asteroid phases4.566-4.560

Type Occurrence of MerrihueiteHide

General Appearance of Type Material:
Aggregates, to 150 ”m, of smaller individuals.
Place of Conservation of Type Material:
n.d.
Geological Setting of Type Material:
Chondrite meteorite.
Associated Minerals at Type Locality:
Reference:
Dodd, R.T., Van Schmus, W.R., Marvin, U.B. (1965) Merrihueite, a new alkali-ferromagnesian silicate from the Mezö-Madaras chondrite. Science: 149: 972-974.

Synonyms of MerrihueiteHide

Other Language Names for MerrihueiteHide

Relationship of Merrihueite to other SpeciesHide

Member of:
Other Members of this group:
Agakhanovite-(Y)K◻2(YCa)Be3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
AlmaruditeK◻2Mn2+2(Be2Al)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
AluminosugiliteKNa2Al2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
ArmeniteBa(H2O)2Ca2Al3[Al3Si9O30]Orth. mmm (2/m 2/m 2/m) : Pnna
BerezanskiteK◻2Ti2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
BrannockiteK◻2Sn2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
ChayesiteK◻2Mg2(Mg2Fe3+)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
DarapiositeKNa2Mn2(Zn2Li)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
DusmatoviteK(K◻)Mn2+2Zn3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
EifeliteKNa2(MgNa)Mg3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
FriedrichbeckeiteK(◻Na)Mg2(Be2Mg)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
KlöchiteK◻2(Fe2+Fe3+)Zn3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
LaurentthomasiteK◻2Mg2(Be2Al)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
MilariteK(◻H2O)Ca2(Be2Al)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
OftedaliteK◻2(ScCa)Be3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
OsumiliteK◻2Fe2+2Al3[Al2Si10O30] Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Osumilite-(Mg)K◻2Mg2Al3[Al2Si10O30] Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
PoudretteiteK◻2Na2B3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
RoedderiteK(◻Na)Mg2Mg3[Si12O30]Hex. 6 m2 : P62c
ShibkoviteK(◻K)Ca2Zn3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
SogdianiteK◻2Zr2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
SugiliteKNa2Fe3+2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
Trattnerite◻(◻)2Fe3+2Mg3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
UM1990-73-SiO:KMnNaZnK(KNa0.5◻0.5)(Mn1.5Na0.5)Zn3[Si12O30]Hex.
Unnamed (Mn3+-dominant analog of Sugilite)KNa2Mn3+2Li3[Si12O30]
YagiiteNa◻2Mg2Al3[Al2Si10O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc

Common AssociatesHide

Associated Minerals Based on Photo Data:
10 photos of Merrihueite associated with ChayesiteK◻2Mg2(Mg2Fe3+)[Si12O30]

Related Minerals - Strunz-mindat GroupingHide

9.CM.Agakhanovite-(Y)K◻2(YCa)Be3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05ArmeniteBa(H2O)2Ca2Al3[Al3Si9O30]Orth. mmm (2/m 2/m 2/m) : Pnna
9.CM.05BrannockiteK◻2Sn2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05ChayesiteK◻2Mg2(Mg2Fe3+)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05DarapiositeKNa2Mn2(Zn2Li)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05EifeliteKNa2(MgNa)Mg3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05MilariteK(◻H2O)Ca2(Be2Al)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05Osumilite-(Mg)K◻2Mg2Al3[Al2Si10O30] Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05OsumiliteK◻2Fe2+2Al3[Al2Si10O30] Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05PoudretteiteK◻2Na2B3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05RoedderiteK(◻Na)Mg2Mg3[Si12O30]Hex. 6 m2 : P62c
9.CM.05SogdianiteK◻2Zr2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05SugiliteKNa2Fe3+2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05YagiiteNa◻2Mg2Al3[Al2Si10O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05BerezanskiteK◻2Ti2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05DusmatoviteK(K◻)Mn2+2Zn3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05ShibkoviteK(◻K)Ca2Zn3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05AlmaruditeK◻2Mn2+2(Be2Al)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm
9.CM.05Trattnerite◻(◻)2Fe3+2Mg3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05OftedaliteK◻2(ScCa)Be3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05KlöchiteK◻2(Fe2+Fe3+)Zn3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
9.CM.05FriedrichbeckeiteK(◻Na)Mg2(Be2Mg)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.05UM1990-73-SiO:KMnNaZnK(KNa0.5◻0.5)(Mn1.5Na0.5)Zn3[Si12O30]Hex.
9.CM.05LaurentthomasiteK◻2Mg2(Be2Al)[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.9.CM.AluminosugiliteKNa2Al2Li3[Si12O30]Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc
9.CM.10FaizieviteK2Na(Ca6Na)Ti4Li6[Si6O18]2[Si12O30]F2Tric. 1 : P1

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MerrihueiteHide

References for MerrihueiteHide

Reference List:

Localities for MerrihueiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Austria
 
  • Burgenland
    • Oberpullendorf District
      • Markt Sankt Martin
        • Pauliberg
  • Styria
    • SĂŒdoststeiermark District
      • Klöch
Germany
 
  • Rhineland-Palatinate
    • Mayen-Koblenz
      • Vordereifel
        • Ettringen
Romania (TL)
 
  • Harghita County
Russia
 
  • Saratov Oblast
 
and/or  
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