Merrihueite
A valid IMA mineral species
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About Merrihueite
Formula:
K(â»Na)Fe2+2Fe2+3[Si12O30]
Colour:
Greenish-blue
Hardness:
5 - 6
Specific Gravity:
2.87 (Calculated)
Crystal System:
Hexagonal
Member of:
Name:
Named by R.T. Dodd Jr., W.R. van Schmus, and U.B. Marvin in 1965 in honor of Craig Morris Merrihue (8 July 1933, Schenectady, New York, USA - 14 March 1965, Mount Washington, New Hampshire, USA), physicist at the Smithsonian Astrophysics Observatory. He developed the 40Ar/39Ar argon dating technique for measuring the ages of meteorites. He died tragically in a mountain climbing accident.
Unique Identifiers
Mindat ID:
2652
Long-form identifier:
mindat:1:1:2652:5
GUID
(UUID V4):
(UUID V4):
35706a51-d198-4e72-8c15-c861f5714166
IMA Classification of Merrihueite
Approved
IMA Formula:
(K,Na)2(Fe2+,Mg)5Si12O30
First published:
1965
Classification of Merrihueite
9.CM.05
9 : SILICATES (Germanates)
C : Cyclosilicates
M : [Si6O18]12- 6-membered double rings (sechser-Doppelringe)
9 : SILICATES (Germanates)
C : Cyclosilicates
M : [Si6O18]12- 6-membered double rings (sechser-Doppelringe)
63.2.1a.5
63 : CYCLOSILICATES Condensed Rings
2 : Condensed Rings (Milarite - Osumilite group)
63 : CYCLOSILICATES Condensed Rings
2 : Condensed Rings (Milarite - Osumilite group)
14.24.5
14 : Silicates not Containing Aluminum
24 : Silicates of Fe, Mg and alkalis
14 : Silicates not Containing Aluminum
24 : Silicates of Fe, Mg and alkalis
Mineral Symbols
As of 2021 there are now IMAâCNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMAâCNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMAâCNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Mhu | IMAâCNMNC | Warr, L.N. (2021). IMAâCNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Mrh | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Merrihueite
Transparency:
Translucent
Colour:
Greenish-blue
Hardness:
5 - 6 on Mohs scale
Density:
2.87 g/cm3 (Calculated)
Optical Data of Merrihueite
Type:
Uniaxial (-)
RI values:
nω = 1.570 nε = 1.559 - 1.592
2V:
Measured: 5° to 10°
Birefringence:
Low to moderate
Max Birefringence:
δ = 0.011
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Low
Pleochroism:
Visible
Comments:
Colorless to greenish-blue
Comments:
Anomalously biaxial.
Chemistry of Merrihueite
Mindat Formula:
K(â»Na)Fe2+2Fe2+3[Si12O30]
Common Impurities:
Al,Mn,Ca
Crystallography of Merrihueite
Crystal System:
Hexagonal
Class (H-M):
6/mmm (6/m 2/m 2/m) - Dihexagonal Dipyramidal
Space Group:
P6/mcc
Setting:
P6/mcc
Cell Parameters:
a = 10.16(6) Å, c = 14.32(6) Å
Ratio:
a:c = 1 : 1.409
Unit Cell V:
1,280.15 Ă
Âł (Calculated from Unit Cell)
Z:
2
Comment:
By analogy to osumilite.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0009423 | Merrihueite | Khan A A, Baur W H, Forbes W C (1972) Synthetic magnesian merrihueite, dipotassium pentamagnesium dodecasilicate: a tetrahedral magnesiosilicate framework crystal structure Acta Crystallographica B28 267-272 | 1972 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.73 Ă | (100) |
2.774 Ă | (100) |
3.23 Ă | (90) |
7.13 Ă | (80) |
2.92 Ă | (60) |
2.530 Ă | (50) |
5.03 Ă | (30) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 1: Primary nebular phases | 4.567-4.561 |
4 : Primary chondrule phases | 4.566â4.561 |
Stage 2: Planetesimal differentiation and alteration | 4.566-4.550 |
5 : Primary asteroid phases | 4.566â4.560 |
6 : Secondary asteroid phases | 4.566-4.560 |
Type Occurrence of Merrihueite
General Appearance of Type Material:
Aggregates, to 150 ”m, of smaller individuals.
Place of Conservation of Type Material:
n.d.
Geological Setting of Type Material:
Chondrite meteorite.
Associated Minerals at Type Locality:
Reference:
Dodd, R.T., Van Schmus, W.R., Marvin, U.B. (1965) Merrihueite, a new alkali-ferromagnesian silicate from the Mezö-Madaras chondrite. Science: 149: 972-974.
Synonyms of Merrihueite
Other Language Names for Merrihueite
Relationship of Merrihueite to other Species
Member of:
Other Members of this group:
Agakhanovite-(Y) | Kâ»2(YCa)Be3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Almarudite | Kâ»2Mn2+2(Be2Al)[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mmm |
Aluminosugilite | KNa2Al2Li3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Armenite | Ba(H2O)2Ca2Al3[Al3Si9O30] | Orth. mmm (2/m 2/m 2/m) : Pnna |
Berezanskite | Kâ»2Ti2Li3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Brannockite | Kâ»2Sn2Li3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Chayesite | Kâ»2Mg2(Mg2Fe3+)[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Darapiosite | KNa2Mn2(Zn2Li)[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Dusmatovite | K(Kâ»)Mn2+2Zn3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Eifelite | KNa2(MgNa)Mg3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Friedrichbeckeite | K(â»Na)Mg2(Be2Mg)[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Klöchite | Kâ»2(Fe2+Fe3+)Zn3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc |
Laurentthomasite | Kâ»2Mg2(Be2Al)[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Milarite | K(â»H2O)Ca2(Be2Al)[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Oftedalite | Kâ»2(ScCa)Be3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Osumilite | Kâ»2Fe2+2Al3[Al2Si10O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Osumilite-(Mg) | Kâ»2Mg2Al3[Al2Si10O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Poudretteite | Kâ»2Na2B3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Roedderite | K(â»Na)Mg2Mg3[Si12O30] | Hex. 6 m2 : P62c |
Shibkovite | K(â»K)Ca2Zn3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Sogdianite | Kâ»2Zr2Li3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Sugilite | KNa2Fe3+2Li3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Trattnerite | â»(â»)2Fe3+2Mg3[Si12O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
UM1990-73-SiO:KMnNaZn | K(KNa0.5â»0.5)(Mn1.5Na0.5)Zn3[Si12O30] | Hex. |
Unnamed (Mn3+-dominant analog of Sugilite) | KNa2Mn3+2Li3[Si12O30] | |
Yagiite | Naâ»2Mg2Al3[Al2Si10O30] | Hex. 6/mmm (6/m 2/m 2/m) : P6/mcc |
Common Associates
Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
9.CM. | Agakhanovite-(Y) | Kâ»2(YCa)Be3[Si12O30] |
9.CM.05 | Armenite | Ba(H2O)2Ca2Al3[Al3Si9O30] |
9.CM.05 | Brannockite | Kâ»2Sn2Li3[Si12O30] |
9.CM.05 | Chayesite | Kâ»2Mg2(Mg2Fe3+)[Si12O30] |
9.CM.05 | Darapiosite | KNa2Mn2(Zn2Li)[Si12O30] |
9.CM.05 | Eifelite | KNa2(MgNa)Mg3[Si12O30] |
9.CM.05 | Milarite | K(â»H2O)Ca2(Be2Al)[Si12O30] |
9.CM.05 | Osumilite-(Mg) | Kâ»2Mg2Al3[Al2Si10O30] |
9.CM.05 | Osumilite | Kâ»2Fe2+2Al3[Al2Si10O30] |
9.CM.05 | Poudretteite | Kâ»2Na2B3[Si12O30] |
9.CM.05 | Roedderite | K(â»Na)Mg2Mg3[Si12O30] |
9.CM.05 | Sogdianite | Kâ»2Zr2Li3[Si12O30] |
9.CM.05 | Sugilite | KNa2Fe3+2Li3[Si12O30] |
9.CM.05 | Yagiite | Naâ»2Mg2Al3[Al2Si10O30] |
9.CM.05 | Berezanskite | Kâ»2Ti2Li3[Si12O30] |
9.CM.05 | Dusmatovite | K(Kâ»)Mn2+2Zn3[Si12O30] |
9.CM.05 | Shibkovite | K(â»K)Ca2Zn3[Si12O30] |
9.CM.05 | Almarudite | Kâ»2Mn2+2(Be2Al)[Si12O30] |
9.CM.05 | Trattnerite | â»(â»)2Fe3+2Mg3[Si12O30] |
9.CM.05 | Oftedalite | Kâ»2(ScCa)Be3[Si12O30] |
9.CM.05 | Klöchite | Kâ»2(Fe2+Fe3+)Zn3[Si12O30] |
9.CM.05 | Friedrichbeckeite | K(â»Na)Mg2(Be2Mg)[Si12O30] |
9.CM.05 | UM1990-73-SiO:KMnNaZn | K(KNa0.5â»0.5)(Mn1.5Na0.5)Zn3[Si12O30] |
9.CM.05 | Laurentthomasite | Kâ»2Mg2(Be2Al)[Si12O30] |
9.CM.9.CM. | Aluminosugilite | KNa2Al2Li3[Si12O30] |
9.CM.10 | Faizievite | K2Na(Ca6Na)Ti4Li6[Si6O18]2[Si12O30]F2 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Merrihueite
mindat.org URL:
https://www.mindat.org/min-2652.html
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References for Merrihueite
Reference List:
Localities for Merrihueite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
â - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
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Romania (TL) | |
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Caspar quarry, Ettringen, Vordereifel, Mayen-Koblenz, Rhineland-Palatinate, Germany