Bannisterite
A valid IMA mineral species
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About Bannisterite
Formula:
(Ca,K,Na)(Mn2+,Fe2+)10(Si,Al)16O38(OH)8 · nH2O
n ~ 5.5
Colour:
Dark brown
Lustre:
Sub-Vitreous, Resinous, Greasy
Hardness:
4
Specific Gravity:
2.83 - 2.84
Crystal System:
Monoclinic
Name:
Named by Marie Louise Lindberg Smith and Clifford Frondel in 1968 in honor of Dr. Frederick Allan Bannister (14th May 1901, St Marys, Peckham, Borough of Camberwell, London, England - 4th October 1971, Surrey Mid-Eastern Registration District), mineralogist and x-ray crystallographer, formerly Keeper of Minerals, British Museum (Natural History), London, England, UK 1952 - 1953.
(Originally identified as ganophyllite in 1936 by William Frederic).
(Originally identified as ganophyllite in 1936 by William Frederic).
Dark brown flat platy aggregates.
A Ba analogue is known: UM1989-30-SiO:AlBaCaFeHKMgMn.
Chemically similar to tamaite (Ca-dominant member of the ganophyllite group).
Structurally related to the Stilpnomelane Group.
A Ba analogue is known: UM1989-30-SiO:AlBaCaFeHKMgMn.
Chemically similar to tamaite (Ca-dominant member of the ganophyllite group).
Structurally related to the Stilpnomelane Group.
Unique Identifiers
Mindat ID:
509
Long-form identifier:
mindat:1:1:509:2
GUID
(UUID V4):
(UUID V4):
db6ecd16-f338-4b65-8b92-549b25bfe02c
IMA Classification of Bannisterite
Approved
Approval year:
1967
Classification of Bannisterite
9.EG.75
9 : SILICATES (Germanates)
E : Phyllosilicates
G : Double nets with 6-membered and larger rings
9 : SILICATES (Germanates)
E : Phyllosilicates
G : Double nets with 6-membered and larger rings
74.1.1.4
74 : PHYLLOSILICATES Modulated Layers
1 : Modulated Layers with joined islands
74 : PHYLLOSILICATES Modulated Layers
1 : Modulated Layers with joined islands
16.16.15
16 : Silicates Containing Aluminum and other Metals
16 : Aluminosilicates of Mn
16 : Silicates Containing Aluminum and other Metals
16 : Aluminosilicates of Mn
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Ban | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Ban | Warr (2020) | Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30 |
Physical Properties of Bannisterite
Sub-Vitreous, Resinous, Greasy
Transparency:
Translucent
Colour:
Dark brown
Streak:
Creamy white
Hardness:
4 on Mohs scale
Cleavage:
Perfect
{001}
{001}
Fracture:
Micaceous
Comment:
Cleavages are smooth without ruling, A-structure, or imperfections typical of True Micas.
Density:
2.83 - 2.84 g/cm3 (Measured) 2.84 g/cm3 (Calculated)
Optical Data of Bannisterite
Type:
Biaxial
RI values:
nα = 1.544 - 1.574 nβ = 1.586 - 1.611 nγ = 1.589 - 1.612
2V:
Calculated: 18° to 28°
Birefringence:
0.045
Max Birefringence:
δ = 0.045
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
r < v weak to moderate
Pleochroism:
Visible
Comments:
X colorless to pale yellow
Chemistry of Bannisterite
Mindat Formula:
(Ca,K,Na)(Mn2+,Fe2+)10(Si,Al)16O38(OH)8 · nH2O
n ~ 5.5
n ~ 5.5
Common Impurities:
Zn,Na
Crystallography of Bannisterite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Cell Parameters:
a = 22.26 Å, b = 16.36 Å, c = 24.66 Å
β = 94.28°
β = 94.28°
Ratio:
a:b:c = 1.361 : 1 : 1.507
Unit Cell V:
8,955.48 ų (Calculated from Unit Cell)
Z:
4
Morphology:
Platy aggregates
Comment:
A2/a
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0012233 | Bannisterite | Heaney P J, Post J E, Evans H T (1992) The crystal structure of bannisterite Clays and Clay Minerals 40 129-144 | 1992 | Broken Hill, Australia | 0 | 293 | |
0012234 | Bannisterite | Heaney P J, Post J E, Evans H T (1992) The crystal structure of bannisterite Clays and Clay Minerals 40 129-144 | 1992 | Franklin Furnace, New Jersey, USA | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
12.33 Å | (100) |
11.5 Å | (2) |
8.78 Å | (2) |
8.43 Å | (2) |
7.95 Å | (2) |
7.11 Å | (4) |
6.82 Å | (4) |
6.61 Å | (2) |
6.38 Å | (2) |
6.16 Å | (2) |
5.93 Å | (2) |
5.56 Å | (6) |
5.20 Å | (6) |
4.91 Å | (2) |
4.71 Å | (2) |
4.593 Å | (10) |
4.28 Å | (6) |
4.21 Å | (2) |
4.09 Å | (16b) |
3.79 Å | (8) |
3.69 Å | (2) |
3.57 Å | (6) |
3.44 Å | (20) |
3.40 Å | (2) |
3.36 Å | (10) |
3.31 Å | (2) |
3.24 Å | (2) |
3.21 Å | (2) |
3.13 Å | (2) |
3.08 Å | (12) |
3.02 Å | (2) |
2.97 Å | (4) |
2.91 Å | (2) |
2.84 Å | (2) |
2.79 Å | (8) |
2.75 Å | (8) |
2.71 Å | (2) |
2.64 Å | (16) |
2.61 Å | (12) |
2.48 Å | (2) |
2.46 Å | (2) |
2.41 Å | (10) |
2.38 Å | (10) |
2.33 Å | (2) |
2.30 Å | (2) |
2.25 Å | (4) |
2.22 Å | (4) |
2.20 Å | (2) |
2.16 Å | (6) |
2.11 Å | (2) |
1.998 Å | (2b) |
1.930 Å | (4) |
1.916 Å | (2) |
1.885 Å | (2) |
1.860 Å | (2) |
1.831 Å | (2) |
1.796 Å | (2) |
1.754 Å | (2) |
1.720 Å | (2) |
1.708 Å | (4) |
1.668 Å | (2) |
1.657 Å | (2) |
1.633 Å | (4) |
1.614 Å | (8) |
1.599 Å | (8) |
1.573 Å | (2) |
1.561 Å | (4) |
1.546 Å | (2) |
1.537 Å | (2) |
1.516 Å | (2) |
1.505 Å | (2) |
1.451 Å | (2) |
1.442 Å | (2) |
1.430 Å | (2) |
1.407 Å | (2) |
1.386 Å | (2) |
1.367 Å | (2) |
1.349 Å | (2) |
1.343 Å | (2) |
1.332 Å | (2) |
1.320 Å | (2) |
1.311 Å | (2) |
1.300 Å | (2) |
1.287 Å | (2) |
1.278 Å | (2) |
1.269 Å | (2) |
Comments:
ICDD 21-57; Structurally similar to ganophyllite and the stilpnomelane group
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
High-𝑇 alteration and/or metamorphism | |
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits |
Geological Setting:
Sulfide-bearing zinc deposits
Type Occurrence of Bannisterite
Co-Type Localities:
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, numbers 145728-145730.
Natural History Museum, London, United Kingdom, number BM 1967,321.
Harvard University, Cambridge, Massachusetts, USA, numbers 91862, 91863, 108571, 128253.
Natural History Museum, London, United Kingdom, number BM 1967,321.
Harvard University, Cambridge, Massachusetts, USA, numbers 91862, 91863, 108571, 128253.
Geological Setting of Type Material:
Silicate-carbonate hosted zinc deposit.
Associated Minerals at Type Locality:
Synonyms of Bannisterite
Other Language Names for Bannisterite
Relationship of Bannisterite to other Species
Structurally related to group(s):
Common Associates
Associated Minerals Based on Photo Data:
24 photos of Bannisterite associated with Rhodonite | CaMn3Mn[Si5O15] |
7 photos of Bannisterite associated with Calcite | CaCO3 |
4 photos of Bannisterite associated with Rhodochrosite | MnCO3 |
2 photos of Bannisterite associated with Richterite | Na(NaCa)Mg5(Si8O22)(OH)2 |
1 photo of Bannisterite associated with Galena | PbS |
1 photo of Bannisterite associated with Pyroxmangite | Mn2+SiO3 |
Related Minerals - Strunz-mindat Grouping
9.EG.05 | Cymrite | BaAl2Si2(O,OH)8 · H2O |
9.EG.10 | Naujakasite | (Na,K)6(Fe2+,Mn2+,Ca)(Al,Fe)4Si8O26 |
9.EG.10 | Manganonaujakasite | Na6(Mn2+,Fe2+)Al4Si8O26 |
9.EG.15 | Dmisteinbergite | Ca(Al2Si2O8) |
9.EG.20 | Kampfite | Ba12(Si11Al5)O31(CO3)8Cl5 |
9.EG.25 | Strätlingite | Ca2Al2SiO7 · 8H2O |
9.EG.25 | Vertumnite | Ca4Al4Si4O6(OH)24 · 3H2O |
9.EG.30 | Eggletonite | (Na,K,Ca)2(Mn,Fe)8(Si,Al)12O29(OH)7 · 11H2O |
9.EG.30 | Ganophyllite | (K,Na,Ca)2Mn8(Si,Al)12(O,OH)32 · 8H2O |
9.EG.30 | Tamaite | (Ca,K,Ba,Na)3-4Mn24(Si,Al)40(O,OH)112 · 21H2O |
9.EG.35 | Coombsite | KMn2+13(Si,Al)18O42(OH)14 |
9.EG.35 | Zussmanite | K(Fe,Mg,Mn)13(Si,Al)18O42(OH)14 |
9.EG.40 | Franklinphilite | (K,Na)4(Mn2+,Mg,Zn)48(Si,Al)72(O,OH)216 · 6H2O |
9.EG.40 | Lennilenapeite | K6-7(Mg,Mn,Fe,Zn)48(Si,Al)72(O,OH)216 · 16H2O |
9.EG.40 | Parsettensite | (K,Na,Ca)7.5(Mn,Mg)49Si72O168(OH)50 · nH2O |
9.EG.40 | Stilpnomelane | (K,Ca,Na)(Fe,Mg,Al)8(Si,Al)12(O,OH)36 · nH2O |
9.EG.40 | Chalcodite | K(Fe3+,Mg,Fe2+)8(Si,Al)12(O,OH)27 |
9.EG.45 | Latiumite | (Ca,K)4(Si,Al)5O11(SO4,CO3) |
9.EG.45 | Tuscanite | KCa6(Si,Al)10O22(SO4,CO3)2(OH) · H2O |
9.EG.45 | Levantite | KCa3Al2(SiO4)(Si2O7)(PO4) |
9.EG.50 | Jagoite | Pb18Fe3+4[Si4(Si,Fe3+)6][Pb4Si16(Si,Fe)4]O82Cl6 |
9.EG.55 | Wickenburgite | CaPb3Al2Si10O24(OH)6 |
9.EG.60 | Hyttsjöite | Pb18Ba2Ca5Mn2+2Fe3+2Si30O90Cl · 6H2O |
9.EG.65 | Armbrusterite | K5Na7Mn15[(Si9O22)4](OH)10 · 4H2O |
9.EG.70 | Britvinite | [Pb7(OH)3F(BO3)2(CO3)][Mg4.5(OH)3(Si5O14)] |
9.EG.70 | Roymillerite | Pb24Mg9(Si10O28)(CO3)10(BO3)(SiO4)(OH)13O5 |
9.EG.75 | UM1989-30-SiO:AlBaCaFeHKMgMn | (Ba,Ca)(Mn,Fe,Mg)22(Si,Al)32O76(OH)16 · 12H2O |
9.EG.75 | Kayupovaite | Na2Mn10[(Si14Al2)O38(OH)8] · 7H2O |
Fluorescence of Bannisterite
Not fluorescent in UV
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Bannisterite
mindat.org URL:
https://www.mindat.org/min-509.html
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References for Bannisterite
Reference List:
Smith, Marie Lindberg, Frondel, Clifford (1968) The related layered minerals ganophyllite, bannisterite, and stilpnomelane. Mineralogical Magazine and Journal of the Mineralogical Society, 36 (283) 893-913 doi:10.1180/minmag.1968.283.036.01
Localities for Bannisterite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Australia | |
| Birch (1999) |
Birch (1999) | |
| Keith Compton collection |
Canada | |
| Canadian Museum of Nature collection |
Italy | |
| //doi.org/10.57635/MICRO.2023.21.7 |
| Analyses of Anthony Kampf of Natural ... |
Japan | |
| Dr. Matsuo Nambu ore collection (curated at Geological Survey of Japan) |
| Masutomi Museum specimen +1 other reference |
| Yamada (2004) |
| Satoshi Matsubara (1981) |
Yamada (2004) | |
| Sameshima +1 other reference |
Norway | |
| Larsen (1988) +2 other references |
Romania | |
Hîrtopanu et al. (2003) +1 other reference | |
| minerals-of-the-carpathians.eu (2008) |
| Hîrtopanu (1997) +1 other reference |
Russia | |
| Brusnitsyn et al. (2009) |
| Semkova +3 other references |
| Kassandrov et al. (2009) |
Kassandrov et al. (2009) | |
| Brusnitsyn A.I. (2000) |
Slovakia | |
| Koděra (1986) |
| republika +2 other references |
| Pauliš P. |
Sweden | |
| |
Gatedal (n.d.) | |
UK (TL) | |
| Smith et al. (1968) +2 other references |
USA (TL) | |
| Smith et al. (1968) +1 other reference |
|
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Broken Hill, Broken Hill district, Yancowinna Co., New South Wales, Australia