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Livingstonite

A valid IMA mineral species - grandfathered
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About LivingstoniteHide

00858580014964461604564.jpg
David Livingstone
Formula:
HgSb4S6(S2)
Colour:
Blackish-gray
Lustre:
Adamantine, Metallic
Hardness:
2
Specific Gravity:
4.88
Crystal System:
Monoclinic
Name:
Named by Mariano Barcena in 1874 in honor of David Livingstone (19 March 1813, Blantyre, South Lanarkshire, Scotland - 1 May 1873, Chief Chitambo's Village, Zambia), the African explorer and missionary. Livingstone had died the year before the mineral was described and Barcena noted that 'the benefactors of humanity belong to all nations, and that all humanity must honor their memory.'
This page provides mineralogical data about Livingstonite.


Unique IdentifiersHide

Mindat ID:
2424
Long-form identifier:
mindat:1:1:2424:8
GUID
(UUID V4):
41d7fa5e-5513-432c-b2f4-0b87d15201b1

IMA Classification of LivingstoniteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
HgSb4S6(S)2
First published:
1874

Classification of LivingstoniteHide

2.JA.05i

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
J : Sulfosalts of PbS archetype
A : Galena derivatives with little or no Pb
3.7.11.1

3 : SULFOSALTS
7 : ø = 2
5.4.6

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
4 : Sulpharsenites etc. of Zn and Hg

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
LstIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of LivingstoniteHide

Adamantine, Metallic
Transparency:
Translucent, Opaque
Colour:
Blackish-gray
Streak:
Red
Hardness:
Hardness:
VHN100=96 - 125 kg/mm2 - Vickers
Tenacity:
Elastic
Cleavage:
Perfect
{001} perfect, {010}, and {100} poor.
Density:
4.88(2) g/cm3 (Measured)    5.013 g/cm3 (Calculated)

Optical Data of LivingstoniteHide

Type:
Biaxial (-)
Anisotropism:
Strong
Dispersion:
relatively strong
Reflectivity:
WavelengthR1R2
400nm35.0%44.3%
420nm34.2%44.3%
440nm33.2%44.4%
460nm32.8%44.9%
480nm32.6%44.9%
500nm32.3%43.8%
520nm31.8%42.3%
540nm31.2%41.0%
560nm30.7%40.0%
580nm30.4%39.2%
600nm29.9%38.1%
620nm29.1%36.8%
640nm28.4%35.7%
660nm27.8%34.9%
680nm27.4%34.2%
700nm26.9%33.6%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 44.9%.
R1 shown in black, R2 shown in red
Colour in reflected light:
White
Internal Reflections:
Deep red
Pleochroism:
Weak

Chemistry of LivingstoniteHide

Mindat Formula:
HgSb4S6(S2)

Crystallography of LivingstoniteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Cell Parameters:
a = 30.1543(10) Å, b = 3.9953(2) Å, c = 21.4262(13) Å
β = 104.265(1)°
Ratio:
a:b:c = 7.547 : 1 : 5.363
Unit Cell V:
2501.7 ų
Z:
8
Morphology:
Minute needles elongated [010]. Columnar to fibrous massive; in globular masses of interlaced needles. Forms include c{001}, a{100}, d{101}, e{101}, p{111}, q{122}.
Comment:
A2/a

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0010580LivingstoniteNiizeki N, Buerger M J (1957) The crystal structure of livingstonite, HgSb4S8 Zeitschrift fur Kristallographie 109 129-1571957Guerrido, Mexico0293
0010773LivingstoniteSrikrishnan T, Nowacki W (1975) A redetermination of the crystal structure of livingstonite, HgSb4S8 Zeitschrift fur Kristallographie 141 174-1921975Huitzuco, Guerrero, Mexico0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

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Radiation - Copper Kα
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.
Powder Diffraction Data:
d-spacingIntensity
3.00 Å(100)
3.74 Å(70)
3.48 Å(70)
2.28 Å(60)
1.734 Å(50)
5.16 Å(40)
2.67 Å(30)
Comments:
Huitzuco, Mexico. May show preferred orientation.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])
Geological Setting:
Low temperature hydrothermal veins

Type Occurrence of LivingstoniteHide

General Appearance of Type Material:
Prisms in columnar groups.
Place of Conservation of Type Material:
No designated type specimen.

Other Language Names for LivingstoniteHide

Simplified Chinese:硫锑汞矿

Common AssociatesHide

Associated Minerals Based on Photo Data:
17 photos of Livingstonite associated with CalciteCaCO3
16 photos of Livingstonite associated with StibniteSb2S3
14 photos of Livingstonite associated with CinnabarHgS
8 photos of Livingstonite associated with ArsenopyriteFeAsS
7 photos of Livingstonite associated with FluoriteCaF2
2 photos of Livingstonite associated with SulphurS8
1 photo of Livingstonite associated with MercuryHg

Related Minerals - Strunz-mindat GroupingHide

2.JA.FerdowsiiteAg8(Sb5As3)S16Mon. 2/m : P21/b
2.JA.SangenaroiteAg8(Sb8-xAsx)SΣ16 Mon. 2/m
2.JA.LuboržákiteMn2AsSbS5Mon. 2/m : B2/m
2.JA.05eBenjaminiteAg3Bi7S12Mon. 2/m : B2/m
2.JA.05gBorodaeviteAg5(Bi,Pb,Fe)8(Sb,Bi)2S17Mon.
2.JA.05aCupropavoniteCu0.9Ag0.5Pb0.6Bi2.5S5 Mon. 2/m : B2/m
2.JA.05dMakovickyiteCu1.12Ag0.81Pb0.27Bi5.35S9Mon. 2/m
2.JA.05fMummeiteCu0.58Ag3.11Pb1.10Bi6.65S13Mon.
2.JA.05aPavoniteAgBi3S5Mon. 2/m : B2/m
2.JA.05bGrumipluciteHgBi2S4Mon. 2/m : B2/m
2.JA.05hMozgovaitePbBi4S7Orth. mmm (2/m 2/m 2/m)
2.JA.05dCupromakovickyiteCu4AgPb2Bi9S18Mon. 2/m : B2/m
2.JA.05cKudriavite(Cd,Pb)Bi2S4Mon. 2/m : B2/m
2.JA.05aCupromakopavoniteAg3Cu8Pb4Bi19S38Mon. 2/m : B2/m
2.JA.05DantopaiteAg5Bi13S22Mon. 2/m : B2/m
2.JA.05SelenodantopaiteAg5Bi13Se22Mon. 2/m : B2/m
2.JA.10aCuprobismutiteCu8AgBi13S24Mon. 2/m : B2/m
2.JA.10cHodrušiteCu8Bi12S22Mon. 2/m
2.JA.10ePadĕraiteCu7[(Cu,Ag)0.33Pb1.33Bi11.33]S22Mon. 2/m : P21/m
2.JA.10dPizgrischite(Cu,Fe)Cu14PbBi17S35Mon. 2/m : B2/m
2.JA.10bKupčíkiteCu3.4Fe0.6Bi5S10Mon. 2/m : B2/m
2.JA.15SchapbachiteAg0.4Pb0.2Bi0.4SIso. m3m (4/m 3 2/m) : Fm3m
2.JA.15CuboargyriteAgSbS2Iso. m3m (4/m 3 2/m)
2.JA.20BohdanowicziteAgBiSe2Trig. 3m (3 2/m) : P3m1
2.JA.20MatilditeAgBiS2Trig. 3 2 : P31 2 1
2.JA.20VolynskiteAgBiTe2Trig. 3m (3 2/m) : P3m1

Other InformationHide

Thermal Behaviour:
Fuses at the first touch of the blowpipe flame, and produces abundant white fumes.
Notes:
Not attacked by cold nitric acid but warm nitric acid decomposes it, giving a white residue. Easily dissolved in aqua regia, producing a solution with a white color.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for LivingstoniteHide

References for LivingstoniteHide

Reference List:

Localities for LivingstoniteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • New South Wales
    • Yancowinna Co.
      • Broken Hill district
G. Nottes & U. Heidtke (1986)
China
 
  • Qinghai
    • Hainan
      • Xinghai County
Zhengjiang Ding et al. (2010)
Germany
 
  • Baden-Württemberg
    • Karlsruhe Region
      • Rhein-Neckar-Kreis
        • Wiesloch
undefined +2 other references
Weiß (1990)
  • Rhineland-Palatinate
    • Donnersbergkreis
      • Nordpfälzer Land
        • Obermoschel
Lapis 2001 (6)
Italy
 
  • Tuscany
    • Massa-Carrara Province
Pellecchia et al. (2018)
        • Miseglia quarrying basin (Miseglia-Fantiscritti quarrying basin; Fantiscritti quarrying basin)
          • Fantiscritti
Pellecchia et al. (2018) +1 other reference
Japan
 
  • Iwate Prefecture
    • Hachimantai City
Mineralogical Journal et al. (1971)
Kyrgyzstan
 
  • Batken Region
    • Kadamjay District
Kolesar et al. (1993)
Kolesar et al. (1993) +1 other reference
Mexico (TL)
 
  • Guerrero
    • Huitzuco de los Figueroa Municipality
Barcena (1874) +1 other reference
Panczner (1987)
Panczner (1987)
Panczner (1987)
Panczner (1987)
New Zealand
 
  • Northland Region
    • Whangarei District
Mineralogical Magazine +4 other references
Hampton et al. (2004)
Russia
 
  • Chelyabinsk Oblast
    • Plastovsky District
      • Plast
        • Kochkar' District
Vikent'eva et al. (2016, April) +1 other reference
  • Sverdlovsk Oblast
    • Beryozovsky
Vikent'eva et al. (2016, April)
Spain
 
  • Castile and Leon
    • León
      • Crémenes
Crespo et al. (2000)
      • Maraña
        • Boicibacar
Luque et al. (1989)
Anthony et al. (1990)
USA
 
  • Arkansas
Howard (1987) +1 other reference
    • Howard County
- (2005)
    • Pike County
Roberts et al. (2003)
- (2005)
  • Nevada
    • Nye County
      • Hot Creek Range
        • Tybo Mining District
NBMG Bull 99B Geology and Mineral ...
    • Pershing County
      • Antelope Springs Mining District
Castor et al. (2004)
 
and/or  
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