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Seidozerite Supergroup

A group of related mineral species
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About Seidozerite SupergroupHide

Formula:
AP2DP2MH2MO4(Si2O7)2X4+n
The Seidozerite supergroup is divided into four groups: rinkite group, bafertisite group, lamprophyllite group and murmanite group.
The four groups are characterized by having a Ti (+ Nb + Zr + Fe3+ + Mg + Mn) sum of 1, 2, 3 and 4 atoms per formula unit, respectively.

The minerals consist of titanosilicate (TS) and intermediate (I) blocks.
The general formula of the TS block is as follows: AP2DP2MP2MH4(Si2O7)2X4+n, where MH2 and MO4 are cations of the H and O sheets; MH is Ti, Nb, Zr, Y, Mn, Ca + REE, Ca; MO is Ti, Zr, Nb, Fe3+, Fe2+, Mg, Mn, Zn, Ca, Na; AP and DP are cations at the peripheral (P) sites: Na, Ca + REE, Ca, Zn, Ba, Sr, K; X are anions: O, OH, F, H2O; X4+n = XO4 + XPn, where n = 0, 1, 1.5, 2, 4; XP = XPM and XPA: apical anions of MH and AP cations located at the periphery of TS.

There are currently 45 members of the supergroup.


Unique IdentifiersHide

Mindat ID:
50368
Long-form identifier:
mindat:1:1:50368:2
GUID
(UUID V4):
5b52e5d0-2547-43f8-a29b-ac016735aa06

IMA Classification of Seidozerite SupergroupHide

IMA status notes:
IMA Approved Group Name
Approval year:
2016
Approval history:
Established by IMA in aug. 2016.

Chemistry of Seidozerite SupergroupHide

Mindat Formula:
AP2DP2MH2MO4(Si2O7)2X4+n

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0006183BarytolamprophylliteSokolova E, Camara F (2008) From structure topology to chemical composition. III. Titanium silicates: The crystal chemistry of barytolamprophyllite The Canadian Mineralogist 46 403-4122008Mt. Yuksporr, Khibina alkaline massif, Kola Peninsula, Russia0293
0012348BarytolamprophylliteRastsvetaeva R K, Dorfman M D (1995) Crystal structure of Ba-lamprophyllite in the isomorphous lamprophyllite- baritolamprophyllite series Crystallography Reports 40 951-9541995Khibiny Massif0293
0012443BafertisiteGuan Y S, Simonov V I, Belov N V (1963) The crystal structure of bafertisite BaFe2TiO[Si2O7](OH)2 Doklady Akademii Nauk SSSR 149 1416-141919630293
0015566ParalomonosoviteRastsvetaeva R K, Sirota M I, Belov N V (1975) Crystal structure of betalomonosovite Soviet Physics Crystallography 20 158-16019750293
0005756BornemaniteFerraris G, Belluso E, Gula A, Soboleva S V, Ageeva O A, Borutskii B E (2001) A structure model of the layer titanosilicate bornemanite based on seidozerite and lomonosovite modules The Canadian Mineralogist 39 1665-167320010293
0005741DelindeiteFerraris G, Ivaldi G, Pushcharovsky D Y, Zubkova N V, Pekov I V (2001) The crystal structure of delindeite, Ba2{(Na,K,_)3(Ti,Fe)[Ti2(O,OH)4Si4O14](H2O,OH)2}, a member of the mero-plesiotype bafertisite series The Canadian Mineralogist 39 1307-131620010293
0006156DelindeiteSokolova E, Camara F (2007) From structure topology to chemical composition. II. Titanium silicates: revision of the crystal structure and chemical formula of delindeite The Canadian Mineralogist 45 1247-12612007Mt. Yuksporr, Khibina alkaline massif, Kola Peninsula, Russia0293
0005940EpistoliteSokolova E V, Hawthorne F C (2004) The crystal chemistry of epistolite The Canadian Mineralogist 42 797-80620040293
0020128HejtmaniteRastsvetaeva R K, Tamazyan R A, Sokolova E V, Belakovskii D I (1991) Crystal structures of two modifications of natural Ba, Mn-titanosilicate Soviet Physics Crystallography 36 186-1891991Inyl'chek ridge, southeast Kirgiziya0293
0020129HejtmaniteRastsvetaeva R K, Tamazyan R A, Sokolova E V, Belakovskii D I (1991) Crystal structures of two modifications of natural Ba, Mn-titanosilicate Soviet Physics Crystallography 36 186-1891991Inyl'chek ridge, southeast Kirgiziya0293
0018495InneliteSokolova E, Camara F, Hawthorne F C (2011) From structure topology to chemical composition. XI. Titanium silicates: crystal structures of innelite-1T and innelite-2M from the Inagli massif, Yakutia, Russia, and the crystal chemistry of innelite Mineralogical Magazine 75 2495-25182011Inagli massif, Yakutia, Russia0293
0018496InneliteSokolova E, Camara F, Hawthorne F C (2011) From structure topology to chemical composition. XI. Titanium silicates: crystal structures of innelite-1T and innelite-2M from the Inagli massif, Yakutia, Russia, and the crystal chemistry of innelite Mineralogical Magazine 75 2495-25182011Inagli massif, Yakutia, Russia0293
0015554InneliteChernov A N, Ilyukhin V V, Maksimov B A, Belov N V (1971) Crystal structure of innelite - Na2Ba3(Ba,K,Mn)(Ca,Na)Ti(TiO2)2[Si2O7]2(SO4)2 Soviet Physics Crystallography 16 65-691971Inaglinskii Massif, Southern Yakusk, Russia0293
0007327JinshajiangiteSokolova E, Camara F, Hawthorne F C, Abdu Y (2009) From structure topology to chemical composition. VII. Titanium silicates: the crystal structure and crystal chemistry of jinshajiangite European Journal of Mineralogy 21 871-8832009Norra Karr, Tonkoping province, Sweden0293
0012410JinshajiangiteRastsvetaeva R K, Chukanov N V, Rozenberg K (2008) A crystal structure of jinshajiangite from the Norra Karr complex (Sweden) Crystallography Reports 53 553-5562008Norra Karr alkaline complex, Sweden0293
0007012LamprophylliteKrivovichev S V, Armbruster T, Yakovenchuk V N, Pakhomovsky Y A, Men'shikov Y P (2003) Crystal structures of lamprophyllite-2M and lamprophyllite-2O from the Lovozero alkaline massif, Kola peninsula, Russia European Journal of Mineralogy 15 711-7182003Lovozero alkaline massif, Kola peninsula, Russia0293
0007013LamprophylliteKrivovichev S V, Armbruster T, Yakovenchuk V N, Pakhomovsky Y A, Men'shikov Y P (2003) Crystal structures of lamprophyllite-2M and lamprophyllite-2O from the Lovozero alkaline massif, Kola peninsula, Russia European Journal of Mineralogy 15 711-7182003Lovozero alkaline massif, Kola peninsula, Russia0293
0015612LamprophylliteSaf'yanov Y N, Vasil'eva N O, Golovachev V P, Kuz'min E A, Belov N V (1983) The crystal structure of lamprophyllite Soviet Physics Doklady 28 207-2091983Kola Peninsula, Russia0293
0018518LomonosoviteCamara F, Sokolova E, Hawthorne F C, Abdu Y (2008) From structure topology to chemical composition. IX. Titanium silicates: revision of the crystal chemistry of lomonosovite and murmanite, Group-IV minerals Mineralogical Magazine 72 1207-12282008Lovozero alkaline massif, Russia0293
0015603LomonosoviteBelov N V, Gavrilova G S, Solov'eva L P, Khalilov A D (1977) The refined structure of lomonosovite Soviet Physics Doklady 22 422-42419770293
0012444MurmaniteKhalilov A D, Mamedov K S, Makarov E S, Pyanzina L A (1965) Crystal structure of murmanite Doklady Akademii Nauk SSSR 161 1409-141119650293
0018519MurmaniteCamara F, Sokolova E, Hawthorne F C, Abdu Y (2008) From structure topology to chemical composition. IX. Titanium silicates: revision of the crystal chemistry of lomonosovite and murmanite, Group-IV minerals Mineralogical Magazine 72 1207-12282008Yubileynaya pegmatite vein, Karnasut Mountain, Lovozero alkaline massif0293
0018521MurmaniteKhalilov A D (1989) Refinement of the crystal structure of murmanite and new data on its crystal-chemical characteristics Mineralogiceskij Zhurnal 11 19-2719890293
0015586MurmaniteRastsvetaeva R K, Andrianov V I (1986) New data on the crystal structure of murmanite Soviet Physics Crystallography 31 44-4819860293
0019480Nacareniobsite-(Ce)Sokolova E, Hawthorne F C (2008) From structure topology to chemical composition. V. Titanium silicates: The crystal chemistry of nacareniobsite-(Ce) The Canadian Mineralogist 46 1333-13422008Kvanefjeld, Ilimaussaq alkaline complex, South Greenland0293
0012356PerraultiteYamnova N A, Egorov-Tismenko Y K, Pekov I V (1998) Crystal structure of perraultite from the coastal region of the Sea of Azov Crystallography Reports 43 401-4101998Sea of Azov, Mariupol massif, Ukraine0293
0006065PolyphiteSokolova E, Hawthorne F C, Khomyakov A P (2005) Polyphite and sobolevite: Revision of their crystal structures The Canadian Mineralogist 43 1527-15442005Khibina-Lovozero alkaline complex, Kola peninsula, Russia0293
0005739QuadruphiteSokolova E V, Hawthorne F C (2001) The crystal chemistry of the [M3_11-14] trimeric structures: From hyperagpaitic complexes to saline lakes The Canadian Mineralogist 39 1275-129420010293
0005887RosenbuschiteChristiansen C C, Johnsen O, Makovicky E (2003) Crystal chemistry of the rosenbuschite group The Canadian Mineralogist 41 1203-12242003Langesund Fjord, Norway0293
0015546RosenbuschiteShibaeva R P, Simonov V I, Belov N V (1963) Crystal structure of the Ca,Na,Zr,Ti silicate rosenbuschite, Ca3.5Na2.5Zr(Ti,Mn,Nb)[Si2O7]2F2O(F,O) Soviet Physics Crystallography 8 406-4131963Kol'skii Peninsula, Russia0293
0005888SeidozeriteChristiansen C C, Johnsen O, Makovicky E (2003) Crystal chemistry of the rosenbuschite group The Canadian Mineralogist 41 1203-12242003Lovozero Complex, Kola Peninsula, Russia0293
0015540SeidozeriteSimonov V I, Belov N V (1960) The determination of the structure of seidozerite Soviet Physics Crystallography 4 146-15719600293
0015550SeidozeriteSkszat S M, Simonov V I (1966) The structure of calcium seidozerite Soviet Physics Crystallography 10 505-5081966Baikal area, Russia0293
0006066SoboleviteSokolova E, Hawthorne F C, Khomyakov A P (2005) Polyphite and sobolevite: Revision of their crystal structures The Canadian Mineralogist 43 1527-15442005Khibina-Lovozero alkaline complex, Kola peninsula, Russia0293
0005581VuonnemiteErcit T S, Cooper M A, Hawthorne F C (1998) The crystal structure of vuonnemite, Na11TiNb2(Si2O7)2(PO4)2O3(F,OH), a phosphate-bearing sorosilicate of the lomonosovite group The Canadian Mineralogist 36 1311-13201998Ilimaussaq, Greenland0293
0005582VuonnemiteErcit T S, Cooper M A, Hawthorne F C (1998) The crystal structure of vuonnemite, Na11TiNb2(Si2O7)2(PO4)2O3(F,OH), a phosphate-bearing sorosilicate of the lomonosovite group The Canadian Mineralogist 36 1311-13201998Lovozero, Kola Peninsula, Russia0293
0005651YoshimuraiteMcDonald A M, Grice J D, Chao G Y (2000) The crystal structure of yoshimuraite, a layered Ba-Mn-Ti silicophosphate, with comments on five-coordinated Ti The Canadian Mineralogist 38 649-65620000293
0012376BusseniteZhou H, Rastsvetaeva R K, Khomyakov A P, Ma Z, Shi N (2002) Crystal structure of new micalike titanosilicate - bussenite, Na2Ba2Fe2+[TiSi2O7][CO3]O(OH)(H2O)F Crystallography Reports 47 43-462002Khibiny alkaline massif, Kola Peninsula, Russia0293
0006999KochiteChristiansen C C, Gault R A, Grice J D, Johnsen O (2003) Kochite, a new member of the rosenbuschite group from the Werner Bjerge alkaline complex, East Greenland European Journal of Mineralogy 15 551-5542003Werner Bjerge alkaline complex, East Greenland0293
0019470NabalamprophylliteSokolova E, Hawthorne F C (2008) From structure topology to chemical composition. IV. Titanium silicates: The orthorhombic polytype of nabalamprophyllite from Lovozero Massif, Kola Peninsula, Russia The Canadian Mineralogist 46 1323-13312008Lovozero Massif, Kola Peninsula, Russia0293
0007085GrenmariteBellezza M, Franzini M, Larsen A O , Merlino S, Perchiazzi N (2004) Grenmarite, a new member of the gotzenite-seidozerite-rosenbuschite group from the Langesundsfjord district, Norway: definition and crystal structure European Journal of Mineralogy 16 971-9782004Langesundsfjord district, Norway0293
0014594NechelyustoviteCamara F, Sokolova E (2009) From structure topology to chemical composition. X. Titanium silicates: the crystal structure and crystal chemistry of nechelyustovite, a group III Ti-disilicate mineral Khibina alkaline massif, Kola peninsula, Russia Mineralogical Magazine 73 753-7752009hydrothermally altered pegmatite, Kirovskii mine, Mt Kukisvumchorr,0293
0018995KazanskyiteCamara F, Sokolova E, Hawthorne F C (2012) Kazanskyite, BaTiNbNa3Ti(Si2O7)2O2(OH)2(H2O)4, a Group-III Ti-disilicate mineral from the Khibiny alkaline massif, Kola Peninsula, Russia: description and crystal structure Mineralogical Magazine 76 473-4922012Khibiny alkaline massif, Kola Peninsula, Russia0293
0020036KolskyiteCamara F, Sokolova E, Abdu Y, Hawthorne F C, Khomyakov A P (2013) Kolskyite, (Ca[_])Na2Ti4(Si2O7)2O4(H2O)7, a group-IV Ti-disilicate mineral from the Khibiny alkaline massif, Kola Peninsula, Russia: Description and crystal structure The Canadian Mineralogist 51 921-9362013Khibiny alkaline massif, Kola Peninsula, Russia0293
0020471SaamiteCamara F, Sokolova E, Abdu Y A, Hawthorne F C (2014) Saamite, Ba[]TiNbNa3Ti(Si2O7)2O2(OH)2(H2O)2, a group-III Ti-disilicate mineral from the Khibiny alkaline massif, Kola Peninsula, Russia: description and crystal structure The Canadian Mineralogist 52 745-7612014Kirovskii mine, Khibiny alkaline massif, Kola Peninsula, Russia0293
CIF Raw Data - click here to close

Relationship of Seidozerite Supergroup to other SpeciesHide

Group Members:
Bafertisite Group APDPMO4MH2(Si2O7)2(XOM)2(XOA)2XPM
  Bafertisite Ba2Fe2+4Ti2(Si2O7)2O2(OH)2F2Tric.
  Bobshannonite Na2KBa(Mn,Na)8(Nb,Ti)4(Si2O7)4O4(OH)4(O,F)2Tric.
  Bussenite Na2Ba2Fe2+Ti(Si2O7)(CO3)(OH)3FTric. 1 : P1
  Cámaraite Ba3Na(Fe2+,Mn)8Ti4(Si2O7)4O4(OH,F)7Tric. 1
  Hejtmanite Ba2Mn2+4Ti2(Si2O7)2O2(OH)2F2Tric. 1
  Jinshajiangite BaNaFe2+4Ti2(Si2O7)2O2(OH)2FTric. 1 : P1
  Perraultite BaNaMn2+4Ti2(Si2O7)2O2(OH)2FTric. 1
  Yoshimuraite Ba2Mn2Ti(Si2O7)(PO4)O(OH)Tric. 1 : P1
Bortolanite Ca2(Ca1.5Zr0.5)Na(NaCa)Ti(Si2O7)2(OF)F2Tric. 1 : P1
Lamprophyllite Group AP2MH2MO4(Si2O7)2(XOM)2(XOA)2
  Barytolamprophyllite (Ba,Na)2(Na,Ti,Fe3+)4Ti2(Si2O7)2O(OH,F)Mon.
  Bornemanite Na6BaTi2Nb(Si2O7)2(PO4)O2(OH)F Tric. 1 : P1
  Delindeite (Na,K)2(Ba,Ca)2(Ti,Fe,Al)3(Si2O7)2O2(OH)2 · 2H2OMon. 2/m : B2/m
  Emmerichite Ba2Na(Na,Fe2+)2(Fe3+,Mg)Ti2(Si2O7)2O2F2Mon. 2/m : B2/m
  Epistolite (Naâ—»)Nb2Na3Ti(Si2O7)2O2(OH)2(H2O)4Tric. 1 : P1
  Fluorbarytolamprophyllite (Ba,Sr)2[(Na,Fe2+)3(Ti,Mg)F2][Ti2(Si2O7)2O2]Mon. 2/m : B2/m
  Fluorlamprophyllite Na3(SrNa)Ti3(Si2O7)2O2F2Mon. 2/m : B2/m
  Innelite  Ba4Ti2Na(NaMn2+)Ti(Si2O7)2[(SO4)(PO4)]O2[O(OH)]Tric. 1 : P1
  Kazanskyite BaNa3Ti2Nb(Si2O7)2O2(OH)2(H2O)4Tric. 1 : P1
  Lamprophyllite (Na,Mn2+)3(Sr,Na)2(Ti,Fe3+)3(Si2O7)2O2(OH,O,F)2Mon. 2/m
  Lileyite Ba2(Na,Fe,Ca)3MgTi2(Si2O7)2O2F2Mon. 2/m : B2/m
  Nabalamprophyllite (BaNa)Ti2Na3Ti(Si2O7)2O2(OH)2Mon. 2/m : P2/m
  Nechelyustovite (Ba,Sr,K)2(Na,Ti,Mn)4(Ti,Nb)2(Si2O7)2O2(O,H2O,F)2 · 4.5H2OMon. 2/m : B2/m
  Phosphoinnelite Na3Ba4Ti3(Si2O7)2(PO4,SO4)2O2FTric.
  Polyphite Na5(Na4Ca2)Ti2(Si2O7)(PO4)3O2F2Tric. 1 : P1
  Saamite Baâ—»Na3Ti2Nb(Si2O7)2O2(OH)F(H2O)2Tric. 1 : P1
  Shkatulkalite  Na2Nb2Na3Ti(Si2O7)2O2(FO)(H2O)4(H2O)3Tric. 1 : P1
  Vuonnemite Na11Ti4+Nb2(Si2O7)2(PO4)2O3(F,OH)Tric.
  Zvyaginite NaZnNb2Ti[Si2O7]20(OH,F)3(H2O)4 + (x < 1)Tric. 1 : P1
Murmanite Group AP2MH2MO4(Si2O7)2(XOM,A)4 (XPM,A)4
  Calciomurmanite (Na,â—»)2Ca(Ti,Mg,Nb)4[Si2O7]2O2(OH,O)2(H2O)4Tric. 1 : P1
  Kolskyite CaNa2Ti4(Si2O7)2O4(H2O)7Tric. 1 : P1
  Lomonosovite Na5Ti2(Si2O7)(PO4)O2Tric. 1 : P1
  Murmanite Na2Ti2(Si2O7)O2 · 2H2OTric. 1 : P1
  Paralomonosovite Na6â—»4Ti4(Si2O7)2[PO3OH][PO2(OH)2]O2(OF)Tric. 1 : P1
  Quadruphite Na6Na2(CaNa)2Na2Ti2Na2Ti2(Si2O7)2(PO4)4O4F2Tric. 1 : P1
  Schüllerite Ba2Na(Mn,Ca)(Fe3+,Mg,Fe2+)2Ti2(Si2O7)2(O,F)4Tric. 1 : P1
  Selivanovaite NaFe3+Ti4(Si2O7)2O4(H2O)4Tric. 1 : P1
  Sobolevite Na13Ca2Mn2Ti3(Si2O7)2(PO4)4O3F3Mon. m : Pb
  Vigrishinite NaZnTi4(Si2O7)2O3(OH)(H2O)4Tric. 1 : P1
Rinkite Group AP2MH2MO4(Si2O7)2(XOM)2(XOA)2
  Batievaite-(Y) Y2Ca2Ti(Si2O7)2(OH)2(H2O)4Tric. 1 : P1
  Fogoite-(Y) Na3Ca2Y2Ti(Si2O7)2OF3Tric. 1 : P1
  Götzenite NaCa6Ti(Si2O7)2OF3Tric. 1 : P1
  Grenmarite Na4MnZr3(Si2O7)2O2F2Mon. 2/m : P2/b
  Hainite-(Y) Na2Ca4(Y,REE)Ti(Si2O7)2OF3Tric. 1 : P1
  Kochite Na3Ca2MnZrTi(Si2O7)2OF3Tric. 1 : P1
  Mosandrite-(Ce) (Ca3REE)[(H2O)2Ca0.5â—»0.5]Ti(Si2O7)2(OH)2(H2O)2Mon. 2/m : P21/b
  Nacareniobsite-(Ce) Na3Ca3(Ce,REE)Nb(Si2O7)2OF3Mon. 2/m : P21/b
  Nacareniobsite-(Y) Na3Ca3YNb(Si2O7)2OF3Mon. 2/m : P21/b
  Rinkite-(Ce) (Ca3Ce)Na(NaCa)Ti(Si2O7)2(OF)F2Mon. 2/m : P21/b
  Rinkite-(Y) Na2Ca4YTi(Si2O7)2OF3Mon. 2/m : P21/b
  Rosenbuschite Na6Ca6Zr3Ti(Si2O7)4O2F6Tric. 1 : P1
  Roumaite (Ca,Na,REE,â—»)7(Nb,Ti)[Si2O7]2OF3Mon. m : Bb
  Seidozerite Na4MnZr2Ti(Si2O7)2O2F2Mon. 2/m : P2/b
  Unnamed (Ca-deficient Mosandrite) (Ca1.2REE0.9Th0.1Zn0.1Al0.1Na0.2K0.1)((H2O)2â—»)(Ti,Nb)(Si2O7)2(OH,F,Cl)2(H2O)2

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Seidozerite SupergroupHide

References for Seidozerite SupergroupHide

 
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