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Vestaite

A valid IMA mineral species
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Formula:
(Ti4+Fe2+)Ti4+3O9
Crystal System:
Monoclinic
Name:
Named after asteroid 4 Vesta. Vestaite was found in a meteorite of the howardite-eucrite-diogenite (HED) clan, all thought to have originated from the crust of the asteroid Vesta.
The Ti4+-Fe2+ analogue of schreyerite. A shock-generated mineral first found in a meteorite.


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Unique IdentifiersHide

Mindat ID:
52576
Long-form identifier:
mindat:1:1:52576:3
GUID
(UUID V4):
6400e948-3d3f-4a6d-b575-a0c75b69276c

IMA Classification of VestaiteHide

Classification of VestaiteHide

4.CB.35

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
B : With medium-sized cations

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
VstIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Chemistry of VestaiteHide

Mindat Formula:
(Ti4+Fe2+)Ti4+3O9

Crystallography of VestaiteHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Setting:
C2/c
Cell Parameters:
a = 17.03(2) Å, b = 4.98(1) Å, c = 7.08(1) Å
β = 106.3(2)°
Ratio:
a:b:c = 3.42 : 1 : 1.422
Unit Cell V:
576.32 ų (Calculated from Unit Cell)

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
4.084 Ã…(44)
3.398 Ã…(60)
2.880 Ã…(77)
2.732 Ã…(100)
2.425 Ã…(42)
1.705 Ã…(38)
1.694 Ã…(50)
1.643 Ã…(48)
Comments:
From Type Description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 2: Planetesimal differentiation and alteration4.566-4.550
6 : Secondary asteroid phases4.566-4.560

Type Occurrence of VestaiteHide

General Appearance of Type Material:
Euhedral to subhedral crystals, ~0.2–0.5 µm in width and up to ~2.5 µm in length with normally columnar to platy habit.
Place of Conservation of Type Material:
Type material is deposited in the mineralogical collections of the Friedrich Schiller University Jena, Sellierstrasse 6, 07745 Jena, Germany, catalogue numbers 42073 and 42074.
Empirical Formula of Type Material:
(Ti4+0.73Fe2+0.63Al0.60Mn0.03Mg0.02Cr0.01)Ti4+3O9
Geological Setting of Type Material:
In shock melt pockets of eucrite meteorite
Associated Minerals at Type Locality:
Reference:
Pang, R.-L., Harries, D., Pollok, K., Zhang, Ai-C., Langenhorst, F. (2018) Vestaite, (Ti4+Fe2+)Ti34+O9, a new mineral in the shocked eucrite Northwest Africa 8003. American Mineralogist: 103: 1502–1511.

Synonyms of VestaiteHide

Related Minerals - Strunz-mindat GroupingHide

4.CB.Ferrohögbomite-2N2S[(Fe2+,Mg,Zn,Al)3(Al,Ti,Fe3+)8O15(OH)]2Hex. 6mm : P63mc
4.CB.Magnesiohögbomite-6N12SMg5Al11TiO23(OH)Trig. 3m (3 2/m) : R3m
4.CB.Zhenruite(MoO3)2 · H2OMon. 2/m : P21/m
4.CB.Pengite(Pb8Sb3+3)Σ11Sb5+9O35Trig. 3m (3 2/m) : R3m
4.CB.VirgilluethiteMoO3 · H2OMon. 2/m : P21/b
4.CB.05BrizziiteNaSb5+O3Trig. 3 : R3
4.CB.05CorundumAl2O3Trig. 3m (3 2/m) : R3c
4.CB.05Ecandrewsite(Zn,Fe2+,Mn2+)TiO3Trig. 3 : R3
4.CB.05EskolaiteCr2O3Trig. 3m (3 2/m) : R3c
4.CB.05GeikieliteMgTiO3Trig. 3 : R3
4.CB.05HematiteFe2O3Trig. 3m (3 2/m) : R3c
4.CB.05IlmeniteFe2+TiO3Trig. 3 : R3
4.CB.05KarelianiteV3+2O3Trig. 3m (3 2/m) : R3c
4.CB.05MelanostibiteMn2+2Fe3+Sb5+O6Trig. 3 : R3
4.CB.05PyrophaniteMn2+TiO3Trig. 3 : R3
4.CB.05Akimotoite(Mg,Fe2+)SiO3Trig. 3 : R3
4.CB.05AuroantimonateAuSbO3
4.CB.05UM1998-11-O-AuHSbAu+2Sb3+O2(OH)
4.CB.05TistariteTi3+2O3Trig. 3m (3 2/m) : R3c
4.CB.05Unnamed (Fe-Cr Oxide)FeCrO3Trig. 3 : R3
4.CB.05Hemleyite(Fe2+0.48Mg0.37Ca0.04Na0.04Mn2+0.03Al0.03Cr3+0.01)sum=1.00Si1.00O3Trig. 3 : R3
4.CB.10AvicenniteTl2O3Iso. m3 (2/m 3) : Ia3
4.CB.10Bixbyite-(Mn)Mn3+2O3Iso. m3 (2/m 3) : Ia3
4.CB.10Bixbyite-(Fe)(Fe,Mn)2O3Iso.
4.CB.15Armalcolite(Mg,Fe2+)Ti2O5Orth. mmm (2/m 2/m 2/m)
4.CB.15SassiteTi3+2Ti4+O5Orth. mmm (2/m 2/m 2/m) : Cmcm
4.CB.15PseudobrookiteFe2TiO5Orth. mmm (2/m 2/m 2/m)
4.CB.15FerropseudobrookiteFe2+Ti2O5Orth. mmm (2/m 2/m 2/m) : Cmcm
4.CB.15GriffiniteAl2TiO5Orth. mmm (2/m 2/m 2/m) : Cmcm
4.CB.15Pseudobrookite Group
4.CB.20Zincohögbomite-2N2S[(Zn,Al,Fe2+)3(Al,Fe3+,Ti)8O15(OH)]2Hex. 6mm : P63mc
4.CB.20Zincohögbomite-2N6S[(Zn,Mg)7(Al,Fe3+,Ti)16O31(OH)]2Hex. 6mm : P63mc
4.CB.20Magnesiohögbomite-6N6S[(Mg,Fe2+)3(Al,Ti,Fe3+)8O15(OH)]6Trig. 3m (3 2/m) : R3m
4.CB.20Magnesiohögbomite-2N3S[(Mg,Fe2+,Zn)4(Al,Ti,Fe3+)10O19(OH)]2Trig. 3m (3 2/m) : P3 1m
4.CB.20Magnesiohögbomite-2N2S[(Mg,Fe2+)3[Al7(Ti,Fe3+)]O15(OH)]2Hex. 6mm : P63mc
4.CB.20Ferrohögbomite-6N12S[(Fe2+,Mg,Zn)5(Al,Ti,Fe3+)12O23(OH)]6Trig. 3m (3 2/m) : R3m
4.CB.20Magnesiohögbomite-2N4S(Mg8.43Fe2+1.57)sum=10Al22Ti4+2O46(OH)2Hex. 6mm : P63mc
4.CB.20Magnesiobeltrandoite-2N3S(Mg6Al2)(Al18Fe3+2)O38(OH)2 Trig. 3m : P3m1
4.CB.20Zincovelesite-6N6SZn3(Fe3+,Mn3+,Al,Ti)8O15(OH)Trig. 3m (3 2/m) : P3m1
4.CB.25PseudorutileFe2Ti3O9Hex. 6 2 2 : P63 2 2
4.CB.25KleberiteFeTi6O11(OH)5Mon. 2/m : P21/b
4.CB.30BerdesinskiiteV3+2TiO5Mon.
4.CB.30OxyvaniteV3+2V4+O5Mon. 2/m : B2/b
4.CB.30KaitianiteTi3+2Ti4+O5Mon. 2/m : B2/b
4.CB.35Olkhonskite(Cr,V)2Ti3O9Mon.
4.CB.35SchreyeriteV3+2Ti3O9Mon. 2/m : B2/b
4.CB.35MachiiteAl2Ti3O9Mon. 2/m : B2/b
4.CB.40KamiokiteFe2Mo3O8Hex. 6mm : P63mc
4.CB.40NolaniteV3+8Fe3+2O14(OH)2Hex. 6mm : P63mc
4.CB.40RinmaniteZn2Sb2Mg2Fe4O14(OH)2Hex. 6 : P63
4.CB.40IseiteMn2Mo3O8Hex. 6mm : P63mc
4.CB.40MajindeiteMg2Mo3O8Hex. 6mm : P63mc
4.CB.45ClaudetiteAs2O3Mon. 2/m
4.CB.45StibioclaudetiteAsSbO3Mon. 2/m : P21/m
4.CB.50ArsenoliteAs2O3Iso. m3m (4/m 3 2/m) : Fd3m
4.CB.50SenarmontiteSb2O3Iso. m3m (4/m 3 2/m) : Fd3m
4.CB.55ValentiniteSb2O3Orth. mmm (2/m 2/m 2/m) : Pccn
4.CB.60BismiteBi2O3Mon. 2/m : P21/b
4.CB.65SphaerobismoiteBi2O3Tet.
4.CB.70SilléniteBi12SiO20Iso. 2 3 : I2 3
4.CB.75KyzylkumiteV3+Ti2O5(OH)Mon. 2/m : P21/b
4.CB.80TietaiyangiteFe3+4Fe2+TiO9Hex.
4.CB.85LiuiteFeTiO3Orth. mmm (2/m 2/m 2/m) : Pnma
4.CB.90LuogufengiteFe2O3Orth. mm2 : Pna21
4.CB.95WangdaodeiteFeTiO3Trig. 3m : R3c

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for VestaiteHide

References for VestaiteHide

Localities for VestaiteHide

ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Morocco (TL)
 
Mineralogical Magazine: 81: 1577–1581 +3 other references
 
Mineral and/or Locality  
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