Metaköttigite
A valid IMA mineral species
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About Metaköttigite
Formula:
(Zn,Fe,Fe)3(AsO4)2 · 8(H2O,OH)
Colour:
Bluish-gray
Crystal System:
Triclinic
Member of:
Name:
For the relation to köttigite.
Type Locality:
Dimorph of:
Formed by both oxidation and dehydrogenization of ferroan kottigite.
Unique Identifiers
Mindat ID:
2678
Long-form identifier:
mindat:1:1:2678:5
GUID
(UUID V4):
(UUID V4):
30837e0a-9b01-4535-868a-e01fa2b0f548
IMA Classification of Metaköttigite
Approved
IMA Formula:
(Zn,Fe3+)3(AsO4)2 · 8(H2O,OH)
First published:
1982
Classification of Metaköttigite
8.CE.85
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
E : With only medium-sized cations, RO4:H2O about 1:2.5
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
E : With only medium-sized cations, RO4:H2O about 1:2.5
40.3.8.2
40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
3 : A3(XO4)2·xH2O
40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
3 : A3(XO4)2·xH2O
20.3.19
20 : Arsenates (also arsenates with phosphate, but without other anions)
3 : Arsenates of Zn, Cd or Hg
20 : Arsenates (also arsenates with phosphate, but without other anions)
3 : Arsenates of Zn, Cd or Hg
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference |
|---|---|---|
| Mköt | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Metaköttigite
Transparency:
Translucent
Colour:
Bluish-gray
Cleavage:
Perfect
{110}
{110}
Optical Data of Metaköttigite
Type:
Biaxial (+)
RI values:
nα = 1.648(3) nβ = 1.680(1) nγ = 1.716(2)
2V:
Measured: 93° , Calculated: 90°
Max Birefringence:
δ = 0.068
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
r > v
Pleochroism:
Strong
Comments:
X = dark blue, Y = yellow, Z = pale yellow.
Chemistry of Metaköttigite
Mindat Formula:
(Zn,Fe,Fe)3(AsO4)2 · 8(H2O,OH)
Crystallography of Metaköttigite
Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 7.96(2) Å, b = 9.44(2) Å, c = 4.72(1) Å
α = 95.6(2)°, β = 97.0(2)°, γ = 107.8(2)°
α = 95.6(2)°, β = 97.0(2)°, γ = 107.8(2)°
Ratio:
a:b:c = 0.843 : 1 : 0.5
Unit Cell V:
331.75 ų (Calculated from Unit Cell)
Z:
1
Twinning:
Universal on {110}.
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 8.90 Å | (40) |
| 6.91 Å | (100) |
| 4.99 Å | (20) |
| 3.93 Å | (30) |
| 3.11 Å | (25) |
| 3.00 Å | (30) |
| 2.83 Å | (25) |
Comments:
Very similar to the data of symplesite.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47d : [Arsenates, antimonates, selenates, bismuthinates] |
Type Occurrence of Metaköttigite
General Appearance of Type Material:
Minute, bluish-gray crystals in oriented intergrowth with kottigite.
Place of Conservation of Type Material:
National Museum of Natural History, Washington, D.C., USA, 160541.
Geological Setting of Type Material:
Oxide zone of an arsenic-rich polymetallic mineral deposit.
Associated Minerals at Type Locality:
Reference:
Schmetzer, K., Amthauer, G., Stähle, V., Medenbach, O. (1982) Metaköttigit, (Zn,Fe3+)(Zn,Fe3+,Fe2+)2(AsO4)2·8(H2O,OH), ein neues mineral aus Mapimi, Mexiko. Neues Jahrbuch für Mineralogie, Monatshefte: 1982: 506-518.
Synonyms of Metaköttigite
Other Language Names for Metaköttigite
German:Metakoettigit
Metaköttigit
Metaköttigit
Spanish:Metakoettigita
Metaköttigita
Metaköttigita
Relationship of Metaköttigite to other Species
Member of:
Other Members of this group:
| Ferrisymplesite | Fe3+3(AsO4)2(OH)3 · 5H2O | Mon. |
| Symplesite | Fe2+3(AsO4)2 · 8H2O | Tric. 1 : P1 |
Common Associates
Associated Minerals Based on Photo Data:
Related Minerals - Strunz-mindat Grouping
| 8.CE.X | Babánekite | Cu3(AsO4)2 · 8H2O |
| 8.CE. | Monteneroite | Cu2+Mn2+2(AsO4)2 · 8H2O |
| 8.CE.05 | Chudobaite | (Mg,Zn)5(AsO4)2(HAsO4)2 · 10H2O |
| 8.CE.05 | Geigerite | Mn2+5(AsO4)2(HAsO4)2 · 10H2O |
| 8.CE.10 | Newberyite | Mg(PO3OH) · 3H2O |
| 8.CE.15 | Brassite | Mg(HAsO4) · 4H2O |
| 8.CE.20 | Phosphorrösslerite | Mg(PO3OH) · 7H2O |
| 8.CE.20 | Rösslerite | Mg(HAsO4) · 7H2O |
| 8.CE.25 | Metaswitzerite | Mn2+3(PO4)2 · 4H2O |
| 8.CE.25 | Switzerite | Mn2+3(PO4)2 · 7H2O |
| 8.CE.30 | Lindackerite | CuCu4(AsO4)2(HAsO4)2 · 9H2O |
| 8.CE.30 | Ondrušite | CaCu4(AsO4)2(HAsO4)2 · 10H2O |
| 8.CE.30 | Veselovskýite | ZnCu4(AsO4)2(HAsO4)2 · 9H2O |
| 8.CE.30 | Pradetite | CoCu4(AsO4)2(HAsO4)2 · 9H2O |
| 8.CE.30 | Klajite | MnCu4(AsO4)2(HAsO4)2 · 9-10H2O |
| 8.CE.30 | Hloušekite | (Ni,Co)Cu4(AsO4)2(AsO3OH)2 · 9H2O |
| 8.CE.35 | Bobierrite | Mg3(PO4)2 · 8H2O |
| 8.CE.40 | Annabergite | Ni3(AsO4)2 · 8H2O |
| 8.CE.40 | Arupite | Ni3(PO4)2 · 8H2O |
| 8.CE.40 | Barićite | (Mg,Fe)3(PO4)2 · 8H2O |
| 8.CE.40 | Erythrite | Co3(AsO4)2 · 8H2O |
| 8.CE.40 | Ferrisymplesite | Fe3+3(AsO4)2(OH)3 · 5H2O |
| 8.CE.40 | Hörnesite | Mg3(AsO4)2 · 8H2O |
| 8.CE.40 | Köttigite | Zn3(AsO4)2 · 8H2O |
| 8.CE.40 | Manganohörnesite | Mn2+3(AsO4)2 · 8H2O |
| 8.CE.40 | Parasymplesite | Fe2+3(AsO4)2 · 8H2O |
| 8.CE.40 | Vivianite | Fe2+Fe2+2(PO4)2 · 8H2O |
| 8.CE.40 | Pakhomovskyite | Co3(PO4)2 · 8H2O |
| 8.CE.45 | Symplesite | Fe2+3(AsO4)2 · 8H2O |
| 8.CE.50 | Cattiite | Mg3(PO4)2 · 22H2O |
| 8.CE.55 | Koninckite | Fe3+PO4 · 3H2O |
| 8.CE.60 | Kaňkite | FeAsO4 · 3.5H2O |
| 8.CE.60 | Hilarionite | Fe3+2(SO4)(AsO4)(OH) · 6H2O |
| 8.CE.65 | Steigerite | Al(VO4) · 3H2O |
| 8.CE.70 | Metaschoderite | Al2(PO4)(VO4) · 6H2O |
| 8.CE.70 | Schoderite | Al2(PO4)(VO4) · 8H2O |
| 8.CE.75 | Malhmoodite | FeZr(PO4)2 · 4H2O |
| 8.CE.75 | Zigrasite | MgZr(PO4)2 · 4H2O |
| 8.CE.75 | UM2009-11-PO:CaHZr | CaZr[PO4]2 · 4H2O |
| 8.CE.80 | Santabarbaraite | Fe3+3(PO4)2(OH)3 · 5H2O |
| 8.CE.90 | Slavkovite | Cu13(AsO4)6(AsO3OH)4 · 23H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Metaköttigite
mindat.org URL:
https://www.mindat.org/min-2678.html
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References for Metaköttigite
Reference List:
Localities for Metaköttigite
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Mexico (TL) | |
| Schmetzer et al. (1982) +1 other reference |
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Ojuela Mine, Mapimí, Mapimí Municipality, Durango, Mexico