Bettertonite
A valid IMA mineral species
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About Bettertonite
John Betterton
Formula:
[Al6(AsO4)3(OH)9(H2O)5] · 11H2O
Colour:
White
Lustre:
Vitreous, Silky, Pearly
Specific Gravity:
2.02 (Calculated)
Crystal System:
Monoclinic
Name:
Honors John Betterton (b. 1959, London), a museum geologist/mineralogist at Haslemere Educational Museum, Surrey, England, for his extensive contributions to the characterisation of minerals from the Penberthy Croft mine for more than 30 years. Also is an advanced mineral collector and micromounter.
Type Locality:
New structure type, closely related to that of penberthycroftite; both structures are flexible layered type, comprising corner-linked columns of heteropolyhedra.
Chemically similar to liskeardite.
Transforms to penberthycroftyite at relatively low temperatures (see Thermal Behaviour section).
Chemically similar to liskeardite.
Transforms to penberthycroftyite at relatively low temperatures (see Thermal Behaviour section).
Unique Identifiers
Mindat ID:
46516
Long-form identifier:
mindat:1:1:46516:0
GUID
(UUID V4):
(UUID V4):
3b48aa0b-bf00-4f63-a2ba-d52abc19d162
IMA Classification of Bettertonite
Approved
IMA Formula:
Al6(AsO4)3(OH)9(H2O)5 · 11H2O
Approval year:
2014
First published:
2015
Type description reference:
Classification of Bettertonite
8.DD.
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
D : With only medium-sized cations, (OH, etc.):RO4= 2:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
D : With only medium-sized cations, (OH, etc.):RO4= 2:1
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference |
|---|---|---|
| Bet | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Pronunciation of Bettertonite
Pronunciation:
| Play | Recorded by | Country |
|---|---|---|
| Jolyon Ralph | United Kingdom |
Physical Properties of Bettertonite
Vitreous, Silky, Pearly
Transparency:
Translucent
Comment:
Vitreous to pearly, somewhat silky lustre
Colour:
White
Streak:
White
Tenacity:
Flexible
Fracture:
Irregular/Uneven
Density:
2.02 g/cm3 (Calculated)
Optical Data of Bettertonite
Type:
Biaxial (+)
RI values:
nα = 1.511(1) nβ = 1.517(1) nγ = 1.523(1)
Max Birefringence:
δ = 0.012
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Low
Optical Extinction:
X = c; Y = b; Z = a.
Pleochroism:
Non-pleochroic
Chemistry of Bettertonite
Mindat Formula:
[Al6(AsO4)3(OH)9(H2O)5] · 11H2O
Elements listed:
Crystallography of Bettertonite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Setting:
P21/c
Cell Parameters:
a = 7.773(2) Å, b = 26.991(5) Å, c = 15.867(3) Å
β = 94.22(3)°
β = 94.22(3)°
Ratio:
a:b:c = 0.288 : 1 : 0.588
Unit Cell V:
3,319.89 ų (Calculated from Unit Cell)
Morphology:
Ultrathin rectangular laths, with lateral dimensions generally <20 μm. The laths are flattened on {010} and exhibit the forms {010}, {100} and {001}.
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 13.648 Å | (100) |
| 13.505 Å | (50) |
| 7.805 Å | (50) |
| 7.461 Å | (30) |
| 5.880 Å | (20) |
| 5.622 Å | (12) |
| 3.589 Å | (20) |
| 2.857 Å | (14) |
Comments:
From Type Description.
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47d : [Arsenates, antimonates, selenates, bismuthinates] |
Type Occurrence of Bettertonite
General Appearance of Type Material:
As tufts of white, ultrathin (sub-micrometre) rectangular laths, with lateral dimensions generally <20 μm.
Place of Conservation of Type Material:
Cotype material is deposited in the mineralogical collections of Museum Victoria, Melbourne, Victoria, Australia, registration number M53274, and the Natural History Museum, London, UK, registration number BM2014,100
Associated Minerals at Type Locality:
Reference:
Grey, I.E., Kampf, A.R., Price, J.R. and Macrae, C.M. (2015) Bettertonite, [Al6(AsO4)3(OH)9(H2O)5]·11H2O, a new mineral from the Penberthy Croft mine, St. Hilary, Cornwall, UK, with a structure based on polyoxometalate clusters. Mineralogical Magazine: 49: 1849-1858.
Synonyms of Bettertonite
Related Minerals - Strunz-mindat Grouping
| 8.DD. | Penberthycroftite | [Al6(AsO4)3(OH)9(H2O)5] · 8H2O |
| 8.DD. | Vargite | Cu2Mn3(AsO4)2(OH)4(H2O)4 |
| 8.DD. | Galeaclolusite | Al6(AsO4)3(OH)9(H2O)4 · 8H2O |
| 8.DD.05 | Chenevixite | Cu2Fe3+2(AsO4)2(OH)4 |
| 8.DD.05 | Luetheite | Cu2Al2(AsO4)2(OH)4 |
| 8.DD.10 | Akrochordite | (Mn2+,Mg)5(AsO4)2(OH)4 · 4H2O |
| 8.DD.10 | Guanacoite | Cu2Mg3(AsO4)2(OH)4 · 4H2O |
| 8.DD.15 | Aheylite | (Fe2+,Zn)Al6(PO4)4(OH)8 · 4H2O |
| 8.DD.15 | Chalcosiderite | CuFe3+6(PO4)4(OH)8 · 4H2O |
| 8.DD.15 | Coeruleolactite | |
| 8.DD.15 | Faustite | ZnAl6(PO4)4(OH)8 · 4H2O |
| 8.DD.15 | Planerite | Al6(PO4)2(PO3OH)2(OH)8 · 4H2O |
| 8.DD.15 | Turquoise | CuAl6(PO4)4(OH)8 · 4H2O |
| 8.DD.15 | Afmite | Al3(OH)4(H2O)3(PO4)(PO3OH) · H2O |
| 8.DD.15 | UM1981-32-PO:FeH | Fe2+Fe3+6(PO4)4-x[PO3(OH)]x(OH)8 · 4H2O |
| 8.DD.20 | Childrenite | Fe2+Al(PO4)(OH)2 · H2O |
| 8.DD.20 | Eosphorite | Mn2+Al(PO4)(OH)2 · H2O |
| 8.DD.20 | Ernstite | (Mn2+,Fe3+)Al(PO4)(OH,O)2 · H2O |
| 8.DD.20 | Lefontite | Fe2Al2Be(PO4)2(OH)6 |
| 8.DD.25 | Kobokoboite | Al6(PO4)4(OH)6 · 11H2O |
| 8.DD.30 | Smamite | Ca2Sb(OH)4[H(AsO4)2] · 6H2O |
| 8.DD.35 | Gutsevichite | Al3(PO4)2(OH)3 · 8H2O |
| 8.DD.40 | Laubmannite (of Moore) | (Fe3+,Fe2+,M)8+x(OH,H2O)9(H2O)2(PO4)5, M = Fe3+, Cu2+ or other metal cation, x ~ 0.1. |
Other Information
Thermal Behaviour:
Transformation to penberthycroftyite: 67-97°C, associated with 8% contraction of layer separation and 6Å relative sliding of the adjacent layers; T>100°C: formation of a "displaced-layer" phase, associated with further 8% layer contraction.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Bettertonite
mindat.org URL:
https://www.mindat.org/min-46516.html
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References for Bettertonite
Reference List:
Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2015) New minerals and nomenclature modifications approved in 2014 and 2015. Newsletter No 23. Mineralogical Magazine, 79 (1) 51-58 doi:10.1180/minmag.2015.079.1.05
Grey, I.E., Kampf, A.R., Price, J.R., Macrae, C.M. (2015) Bettertonite, [Al6(AsO4)3(OH)9(H2O)5]·11H2O, a new mineral from the Penberthy Croft mine, St. Hilary, Cornwall, UK, with a structure based on polyoxometalate clusters. Mineralogical Magazine, 79 (7) 1849-1858 doi:10.1180/minmag.2015.079.7.16
Grey, I.E., Kampf, A.R., Price, J.R., Macrae, C.M. (2015) Bettertonite, [Al6(AsO4)3(OH)9(H2O)5]·11H2O, a new mineral from the Penberthy Croft mine, St. Hilary, Cornwall, UK, with a structure based on polyoxometalate clusters. Mineralogical Magazine, 79 (7) 1849-1858 doi:10.1180/minmag.2015.079.7.16
Localities for Bettertonite
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
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Penberthy Croft Mine, St Hilary, Cornwall, England, UK