Djerfisherite
A valid IMA mineral species
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About Djerfisherite
D. Jerome Fisher
Formula:
K6(Fe,Cu,Ni)25S26Cl
May contain minor Na substituting K.
Originally assumed to be K6Na(Fe2+)24S26Cl
Originally assumed to be K6Na(Fe2+)24S26Cl
Colour:
Greenish yellow, khaki, to olive drab
Lustre:
Sub-Metallic
Hardness:
3½
Crystal System:
Isometric
Member of:
Name:
Named by L.H. Fuchs in 1966 in honor of Daniel Jerome (Jerry) Fisher (14 June 1896, Canton, New York, USA – 18 January 1988, Phoenix, Arizona, USA), mineralogist and professor at the University of Chicago, Chicago, Illinois, USA.
A possible Cu analogue is known (Cu-djerfisherite). Compare a possibly related phase 'UM1977-11-S:CuFeKNi', UM1997-41-S:CuFeKNiPbTl (its Cl-free or S-substituted analogue), chemically very similar chlorbartonite, and somewhat similar UM1990-101-S:CuFeK.
May occur as fluid inclusions in chromite (Potapov et al., 2022).
May occur as fluid inclusions in chromite (Potapov et al., 2022).
Unique Identifiers
Mindat ID:
1299
Long-form identifier:
mindat:1:1:1299:3
GUID
(UUID V4):
(UUID V4):
3599673a-8bcd-4514-a255-1b50012a825f
IMA Classification of Djerfisherite
Approved
Approval year:
1965
First published:
1966
Classification of Djerfisherite
2.FC.05
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
F : Sulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2O
C : With Cl, Br, I (halide-sulfides)
2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
F : Sulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2O
C : With Cl, Br, I (halide-sulfides)
2.15.2.1
2 : SULFIDES
15 : Chlor-sulfides
2 : SULFIDES
15 : Chlor-sulfides
6.5.11
6 : Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and Sulphohalides
5 : Sulphohalides
6 : Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and Sulphohalides
5 : Sulphohalides
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
| Symbol | Source | Reference |
|---|---|---|
| Djr | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
| Djr | The Canadian Mineralogist (2019) | The Canadian Mineralogist (2019) The Canadian Mineralogist list of symbols for rock- and ore-forming minerals (December 30, 2019). download |
Physical Properties of Djerfisherite
Sub-Metallic
Transparency:
Opaque
Colour:
Greenish yellow, khaki, to olive drab
Hardness:
3½ on Mohs scale
Hardness:
VHN100=172 - Vickers
Chemistry of Djerfisherite
Mindat Formula:
K6(Fe,Cu,Ni)25S26Cl
May contain minor Na substituting K.
Originally assumed to be K6Na(Fe2+)24S26Cl
May contain minor Na substituting K.
Originally assumed to be K6Na(Fe2+)24S26Cl
Common Impurities:
Na,Mg
Crystallography of Djerfisherite
Crystal System:
Isometric
Class (H-M):
m3m (4/m 3 2/m) - Hexoctahedral
Space Group:
Pm3m
Setting:
Pm3m
Cell Parameters:
a = 10.465 Å
Unit Cell V:
1,146.09 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Rounded grains to 0.4 mm.
Crystal Structure
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Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
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2x2x2 | 3x3x3 | 4x4x4
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0006153 | Djerfisherite | Zaccarini F, Thalhammer O A R, Princivalle F, Lenaz D, Stanley C J, Garuti G (2007) Djerfisherite in the Guli dunite complex, Polar Siberia: a primary or metasomatic phase? The Canadian Mineralogist 45 1201-1211 |  | 2007 | Guli dunite complex, Polar Siberia, Russia | 0 | 293 |
| 0015579 | Djerfisherite | Dmitrieva M T, Ilyukhin V V, Bokii G B (1979) Close packing and cation arrangement in the djerfisherite structure Soviet Physics Crystallography 24 683-685 | 1979 | Khibiny massif, Kola peninsula, Russia | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 1.828 Å | (100) |
| 2.985 Å | (70) |
| 2.372 Å | (60) |
| 10.34 Å | (50) |
| 5.97 Å | (50) |
| 3.118 Å | (50) |
| 3.269 Å | (40) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 2: Planetesimal differentiation and alteration | 4.566-4.550 |
| 5 : Primary asteroid phases | 4.566–4.560 |
| 6 : Secondary asteroid phases | 4.566-4.560 |
| Stage 3a: Earth’s earliest Hadean crust | >4.50 |
| 7 : Ultramafic igneous rocks | |
| Stage 3b: Earth’s earliest hydrosphere | >4.45 |
| 12 : Hadean hydrothermal subsurface sulfide deposits (see also #33) | |
| High-𝑇 alteration and/or metamorphism | |
| 33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12]) | |
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 35 : Ultra-alkali and agpaitic igneous rocks | |
| Stage 10a: Neoproterozoic oxygenation/terrestrial biosphere | <0.6 |
| 51 : Pyrometamorphic minerals (see also #54 and #56) | <0.36 |
Geological Setting:
Meteorites, hydrothermal Ni-Cu ores, pegmatites, kimberlites, mafic alkalic diatreme.
Type Occurrence of Djerfisherite
Co-Type Localities:
General Appearance of Type Material:
Grains, 0.02-0.4 mm in diameter.
Place of Conservation of Type Material:
No defined type material.
Geological Setting of Type Material:
Enstatite chondrite meteorites.
Associated Minerals at Type Locality:
Reference:
Fuchs, L.H. (1966) Djerfisherite, alkali copper–iron sulfide: a new mineral from enstatite chondrites. Science: 153: 166–167.
Synonyms of Djerfisherite
Other Language Names for Djerfisherite
Relationship of Djerfisherite to other Species
Member of:
Other Members of this group:
| Cu-djerfisherite | K6(Cu,Fe)25S26Cl | |
| Gmalimite | K6◻Fe2+24S27 | Iso. m3m (4/m 3 2/m) : Pm3m |
| Owensite | (Ba,Pb)6(Cu,Fe,Ni)25S27 | Iso. m3m (4/m 3 2/m) : Pm3m |
| Thalfenisite | Tl6(Fe,Ni,Cu)25S26Cl | Iso. |
| Zoharite | (Ba,K)6(Fe,Cu,Ni)25S27 | Iso. m3m (4/m 3 2/m) : Pm3m |
Common Associates
Associated Minerals Based on Photo Data:
| 6 photos of Djerfisherite associated with Microcline | K(AlSi3O8) |
| 4 photos of Djerfisherite associated with Nepheline | Na3K(Al4Si4O16) |
| 4 photos of Djerfisherite associated with Eudialyte | Na15Ca6Fe3Zr3Si(Si25O73)(O,OH,H2O)3(Cl,OH)2 |
| 3 photos of Djerfisherite associated with Aegirine | NaFe3+Si2O6 |
| 3 photos of Djerfisherite associated with Villiaumite | NaF |
| 3 photos of Djerfisherite associated with Titanite | CaTi(SiO4)O |
| 2 photos of Djerfisherite associated with Ilmenite | Fe2+TiO3 |
| 2 photos of Djerfisherite associated with Aenigmatite | Na4[Fe2+10Ti2]O4[Si12O36] |
| 2 photos of Djerfisherite associated with Pyrrhotite | Fe1-xS |
| 1 photo of Djerfisherite associated with Umbite | K2(Zr,Ti)Si3O9 · H2O |
Related Minerals - Strunz-mindat Grouping
| 2.FC. | Demicheleite-(I) | BiSI |
| 2.FC.05 | Thalfenisite | Tl6(Fe,Ni,Cu)25S26Cl |
| 2.FC.05 | Owensite | (Ba,Pb)6(Cu,Fe,Ni)25S27 |
| 2.FC.05 | Cu-djerfisherite | K6(Cu,Fe)25S26Cl |
| 2.FC.05 | Zoharite | (Ba,K)6(Fe,Cu,Ni)25S27 |
| 2.FC.05 | Gmalimite | K6◻Fe2+24S27 |
| 2.FC.10 | Bartonite | K6Fe20S26S |
| 2.FC.10 | Chlorbartonite | K6Fe24S26(Cl,S) |
| 2.FC.15a | Arzakite | Hg2+3S2(Br,Cl)2 |
| 2.FC.15a | Corderoite | Hg2+3S2Cl2 |
| 2.FC.15c | Grechishchevite | Hg2+3S2(Br,Cl,I)2 |
| 2.FC.15a | Lavrentievite | Hg2+3S2(Cl,Br)2 |
| 2.FC.15d | Radtkeite | Hg2+3S2ICl |
| 2.FC.15b | Kenhsuite | Hg2+3S2Cl2 |
| 2.FC.20a | Capgaronnite | AgHgClS |
| 2.FC.20c | Perroudite | Hg5Ag4S5(I,Br)2Cl2 |
| 2.FC.20b | Iltisite | HgAgSCl |
| 2.FC.20d | Hanauerite | AgHgSI |
| 2.FC.25 | Demicheleite-(Br) | BiSBr |
| 2.FC.25 | Demicheleite-(Cl) | BiSCl |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Djerfisherite
mindat.org URL:
https://www.mindat.org/min-1299.html
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Please feel free to link to this page.
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References for Djerfisherite
Reference List:
Fuchs, L. H. (1966) Djerfisherite, Alkali Copper-Iron Sulfide: A New Mineral from Enstatite Chondrites. Science, 153 (3732). 166-167 doi:10.1126/science.153.3732.166
Fuchs, L. H. (1966) Djerfisherite, Alkali Copper-Iron Sulfide: A New Mineral from Enstatite Chondrites. Science, 153 (3732). 166-167 doi:10.1126/science.153.3732.166
Czamanske, Gerald K., Erd, Richard C., Sokolova, Maja N., Dobrovol'skaya, Maja G., Dmitrieva, Margret T. (1979) New data on rasvumite and djerfisherite. American Mineralogist, 64 (7-8) 776-778
Evans, Howard T., Clark, Joan R (1981) The crystal structure of bartonite, a potassium iron sulfide, and its relationship to pentlandite and djerfisherite. American Mineralogist, 66 (3-4) 376-384
Sharygin, V. V., Kamenetsky, V. S., Kamenetsky, M. B. (2008) Potassium sulfides in kimberlite-hosted chloride-"neyerereite" and chloride clasts of Udachnaya-East Pipe, Yakutia, Russia. The Canadian Mineralogist, 46 (4) 1079-1095 doi:10.3749/canmin.46.4.1079
Localities for Djerfisherite
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Antarctica | |
| Lin et al. (1991) +1 other reference |
| El Gorsey et al. (1988) |
| Lin et al. (1998) | |
| Rosenshein et al. (2006) |
Australia | |
| Riley (1978) |
Azerbaijan | |
| American Mineralogist |
Canada | |
| Anton R. Chakhmouradian and Roger H. Mitchell (2001) |
| Hogarth (1997) |
| December 1994 +3 other references |
| Henderson et al. (1999) |
China | |
| Qijia Zang and Keqiao Chen (1985) |
| Daode Wang and Rambaldi (1988) |
Finland | |
| o´Brien |
Germany | |
| - (n.d.) |
Greenland | |
| Kracher et al. (1977) |
| [Mineralogical Record - Vol 24 No 2] |
Iraq | |
| Al-Hermezi et al. (1986) |
Italy | |
| Stoppa et al. (1997) |
Japan | |
| Takechi et al (1999) |
Kazakhstan | |
| Sharygin (2019) |
Malawi (TL) | |
| Fuchs (1966) +1 other reference |
North Africa | |
| Gannoun et al. (2011) |
Norway | |
| Jamtveit et al. (1997) |
Romania | |
| www.researchgate.net (n.d.) |
| Pascal et al. (2001) |
Russia | |
| [Lapis 1993:4 p.13-20] +1 other reference |
| Kislov +1 other reference |
| Konev A.A. (1974) +1 other reference |
| Sokol et al. (2019) +1 other reference |
| Henderson et al. (1999) +2 other references |
| Henderson et al. (1999) | |
| Zaitsev et al. (2022) |
| Pekov (1998) |
| Pekov (1998) | |
| Am Min 66:638-639 +1 other reference | |
| Spiridonov et al. (2016) | |
| Thomas R. Watters & Martin Prinz (1979) |
| American Mineralogist |
| Pekov (1998) |
| Pekov (1998) | |
| Pekov (1998) +1 other reference | |
| Pekov (1998) |
| Sokolova et al (2005) +1 other reference | |
| Pavel.M. Kartashov (n.d.) |
| Henderson et al. (1999) +3 other references |
| [World of Stones 95:5-6 | |
| ... +1 other reference | |
| Pakhomovsky et al. (2018) |
| Pakhomovsky et al. (2014) | |
| Zaitsev et al. (2004) |
| A. N. Korobeinikov et al. (1998) | |
| ... +2 other references |
| Patchen et al. (1997) |
| Rezvukhin +15 other references | |
| Anthony et al. (1990) |
| Anthony et al. (1990) +1 other reference |
| Sharygin et al. (2011, February) | |
| Potapov et al. (2022) +1 other reference |
South Africa (TL) | |
| Fuchs (1966) +2 other references |
| H.F.J. Theart and C.D. de Nooy (2001) |
| Henderson et al. (1999) |
Sudan | |
| Theo Ntaflos (1988) |
Switzerland | |
| Stalder et al. (1998) |
Tajikistan | |
| Solovova et al. (2006, October) |
Tanzania | |
| Victoria Sekisova et al. (2015) |
Uganda | |
| Kracher +4 other references |
UK | |
| Beard et al. (2007) |
USA | |
| Van Nostrand Reinholt Press: 67 +5 other references |
| Li +3 other references |
| El Goresy +2 other references |
| Watters et al. (1979) |
Yemen | |
| Zolensky et al. (2003) |
Quick NavTopAbout DjerfisheriteUnique IdentifiersIMA Classification Classification Mineral SymbolsPhysical Properties Chemistry Crystallography Crystal StructureX-Ray Powder DiffractionGeological EnvironmentType Occurrence SynonymsOther LanguagesRelationshipsCommon AssociatesStrunz-MindatOther InformationInternet Links References Localities Locality List
Gulinskii massif, Maimecha and Kotui Rivers Basin, Krasnoyarsk Krai, Russia