Ziminaite
A valid IMA mineral species
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Formula:
Fe3+ 6 (VO4)6
Colour:
Yellowish-brown
Lustre:
Adamantine
Hardness:
4½
Specific Gravity:
3.448 (Calculated)
Crystal System:
Triclinic
Member of:
Name:
Named after the Zimina volcano situated near the discovery locality.
This page provides mineralogical data about Ziminaite.
Unique Identifiers
Mindat ID:
46494
Long-form identifier:
mindat:1:1:46494:9
GUID
(UUID V4):
(UUID V4):
2ca3ab04-05e4-46df-a34e-bfa79f6edafc
Classification of Ziminaite
Approved
Approval year:
2014
First published:
2018
Type description reference:
8.AC.02
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Zim | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Ziminaite
Adamantine
Transparency:
Translucent
Colour:
Yellowish-brown
Streak:
Yellow
Hardness:
4½ on Mohs scale
Hardness:
VHN20=426(50) kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
None Observed
Fracture:
Irregular/Uneven
Density:
3.448 g/cm3 (Calculated)
Optical Data of Ziminaite
Anisotropism:
weak
Bireflectance:
Weak
Reflectivity:
Wavelength | R1 | R2 |
---|---|---|
400nm | 19.4% | 20.8% |
440nm | 17.6% | 19.0% |
470nm | 16.3% | 17.7% |
480nm | 15.8% | 17.2% |
520nm | 14.6% | 16.1% |
546nm | 14.1% | 15.7% |
560nm | 14.0% | 15.5% |
589nm | 13.8% | 15.1% |
620nm | 13.7% | 14.9% |
650nm | 13.6% | 14.7% |
680nm | 13.5% | 14.6% |
700nm | 13.5% | 14.6% |
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 20.8%.
R1 shown in black, R2 shown in red
Colour in reflected light:
Light grey
Internal Reflections:
Deep yellow
Chemical Properties of Ziminaite
Formula:
Fe3+ 6 (VO4)6
IMA Formula:
Fe3+(VO4)
Elements listed:
Crystallography of Ziminaite
Crystal System:
Triclinic
Class (H-M):
1 - Pinacoidal
Space Group:
P1
Cell Parameters:
a = 8.012(4) Å, b = 9.345(5) Å, c = 6.678(3) Å
α = 106.992(10)°, β = 101.547(8)°, γ = 96.594(11)°
α = 106.992(10)°, β = 101.547(8)°, γ = 96.594(11)°
Ratio:
a:b:c = 0.857 : 1 : 0.715
Unit Cell V:
460.4 ų
Z:
1
Morphology:
Lamellar, tabular or flattened prismatic crystals, as aggregates.
Epitaxially overgrows crystals of koksharovite
Epitaxially overgrows crystals of koksharovite
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0020265 | Ziminaite | Robertson B, Kostiner E (1972) Crystal structure and Moessbauer effect investigation of FeVO4 Journal of Solid State Chemistry 4 29-37 | 1972 | Synthetic | 0 | 293 |
CIF Raw Data - click here to close
Epitaxial Relationships of Ziminaite
Epitaxial Minerals:
Koksharovite | CaMg2Fe3+4(VO4)6 |
Epitaxy Comments:
Epitaxially overgrowing koksharovite
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.751 Å | (17) |
3.539 Å | (86) |
3.270 Å | (67) |
3.209 Å | (100) |
3.090 Å | (20) |
3.041 Å | (18) |
2.934 Å | (14) |
1.665 Å | (24) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
45b : [Other oxidized fumarolic minerals] |
Type Occurrence of Ziminaite
General Appearance of Type Material:
Lamellar, tabular or flattened prismatic crystals up to 10 × 30 × 50 μm typically epitaxially overgrowing koksharovite, and as aggregates (up to 0.15 mm) associated with bannermanite.
Place of Conservation of Type Material:
In the collections of the Fersman Mineralogical Museum of the Russian Academy of Sciences, Moscow, Russia, registration number 4603/1.
Empirical Formula of Type Material:
(Fe3+3.29Al1.48Ti0.54Mg0.53) Σ5.84(V6.05Si0.04P0.01) Σ6.10O24
Chemical Analysis of Type Material:
MgO | 2.20 % |
---|---|
CaO | 0.01 % |
Al2O3 | 7.81 % |
TiO2 | 4.50 % |
SiO2 | 0.26 % |
P2O5 | 0.09 % |
V2O5 | 57.01 % |
Fe2O3 | 27.18 % |
Total: | 99.06 % |
Geological Setting of Type Material:
Fumarole
Associated Minerals at Type Locality:
Reference:
Pekov, I.V., Siidra, O.I., Yapaskurt, V.O., Polekhovsky, Yu.S., Kartashov, P.M. (2018) Ziminaite, Fe3+VO4, a new howardevansite-group mineral from the Bezymyannyi volcano, Kamchatka, Russia. Mineralogy and Petrology: 112: 371–379.
Synonyms of Ziminaite
Relationship of Ziminaite to other Species
Member of:
Other Members of this group:
Grigorievite | Cu3Fe3+2Al2(VO4)6 | Tric. 1 : P1 |
Howardevansite | NaCuFe2(VO4)3 | Tric. 1 : P1 |
Kabalovite | Fe2+3Fe3+4(PO4)6 | Tric. 1 : P1 |
Koksharovite | CaMg2Fe3+4(VO4)6 | Tric. 1 : P1 |
Related Minerals - Strunz-mindat Grouping
8.AC. | Angarfite | NaFe3+5(PO4)4(OH)4 · 4H2O | Orth. 2 2 2 : C2 2 21 |
8.AC. | Wopmayite | Ca6Na3◻Mn(PO4)3(PO3OH)4 | Trig. 3m : R3c |
8.AC.X | Dyrnaesite-(La) | Na8Ce4+(La,REE)2(PO4)6 | Orth. mmm (2/m 2/m 2/m) : Pnma |
8.AC. | Edtollite | K2NaCu5Fe3+O2(AsO4)4 | Tric. 1 : P1 |
8.AC. | Alumoedtollite | K2NaCu5AlO2(AsO4)4 | Tric. 1 : P1 |
8.AC. | Crocobelonite | CaFe3+2O(PO4)2 | Orth. mmm (2/m 2/m 2/m) : Pnma |
8.AC. | Manganobadalovite | NaNaMn(MgFe3+)(AsO4)3 | Mon. 2/m : B2/b |
8.AC. | Beershevaite | CaFe3+3(PO4)3O | Mon. 2/m : P21/m |
8.AC. | Calciohatertite | NaNaCa(CaFe3+)(AsO4)3 | Mon. 2/m : B2/b |
8.AC. | Kabalovite | Fe2+3Fe3+4(PO4)6 | Tric. 1 : P1 |
8.AC. | Nazarchukite | Ca2NiFe3+2(PO4)4 | Orth. mmm (2/m 2/m 2/m) : Pbca |
8.AC. | Changesite–(Y) | (Ca8Y)◻Fe2+(PO4)7 | Trig. 3m : R3c |
8.AC. | Crocobelonite-1M | CaFe3+2O(PO4)2 | Mon. 2/m : P21/m |
8.AC. | Ebnerite | (NH4)Zn(PO4) | Hex. 6 : P63 |
8.AC.02 | Grigorievite | Cu3Fe3+2Al2(VO4)6 | Tric. 1 : P1 |
8.AC.02 | Koksharovite | CaMg2Fe3+4(VO4)6 | Tric. 1 : P1 |
8.AC.05 | Calciojohillerite | NaCaMg3(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Howardevansite | NaCuFe2(VO4)3 | Tric. 1 : P1 |
8.AC.05 | O'Danielite | Na(Zn,Mg)3(AsO4)(AsO3OH)2 | Mon. 2/m : B2/b |
8.AC.05 va | Alluaudite-Na□ | ◻4Na4Mn2+4Fe3+8(PO4)12 | Mon. 2/m : B2/b |
8.AC.05 va | Alluaudite-Ca□ | ◻4Ca4Mn2+4Fe3+8(PO4)12 | Mon. 2/m : B2/b |
8.AC.05 va | Ferroalluaudite-NaNa | Na4Na4Fe2+4Fe3+8(PO4)12 | Mon. 2/m : B2/m |
8.AC.05 | Hagendorfite-NaNa | NaNaFe2+(Mn2+,Mn3+)(PO4)3 (?) | Mon. 2/m : B2/b |
8.AC.05 | Erikapohlite | Cu3(Zn,Cu,Mg)4Ca2(AsO4)6 · 2H2O | Mon. 2/m : B2/m |
8.AC.05 | Hatertite | Na2(Ca,Na)(Fe3+,Cu)2(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Unnamed (Na-Mg Arsenate Hydroxyarsenate) | NaMg3(AsO4)(AsO3OH)2 | Mon. 2/m : B2/b |
8.AC.05 | Unnamed (Na-Zn-H Arsenate Hydrxyarsenate) | Na(Na0.6Zn0.4)Zn2(H0.6AsO4)(AsO3OH)2 | Mon. 2/m : B2/b |
8.AC.05 | Zincobradaczekite | NaZn2Cu2(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Badalovite | Na2Mg2Fe(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Magnesiocanutite | NaMnMg2[AsO4]2[AsO2(OH)2] | Mon. 2/m : B2/b |
8.AC.05 | Magnesiohatertite | (Na,Ca)2Ca(Mg,Fe3+)2(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Khrenovite | Na3Fe3+2(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Paraberzeliite | NaCa2Mg2(AsO4)3 | Mon. 2/m : B2/b |
8.AC.05 | Camanchacaite | NaCaMg2[AsO4][AsO3(OH)]2 | Mon. 2/m : B2/b |
8.AC.07 | Zhanghuifenite | Na3Mn4Mg2Al(PO4)6 | Mon. 2/m |
8.AC.07 | Ferrobobfergusonite | Na2Fe2+5Fe3+Al(PO4)6 | Mon. |
8.AC.10 | Alluaudite | (Na,Ca)Mn2+(Fe3+,Mn2+,Fe2+,Mg)2(PO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Arseniopleite | NaCaMnMn2(AsO4)3 | Mon. 2/m |
8.AC.10 | Caryinite | (Na,Pb)(Ca,Na)CaMn2+2(AsO4)3 | Mon. 2/m |
8.AC.10 | Ferroalluaudite | (Na,Ca)Fe2+(Fe3+,Mn2+,Fe2+)2(PO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Hagendorfite | NaCaMn2+Fe2+2(PO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Johillerite | Na(Mg,Zn)3Cu(AsO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Maghagendorfite | (Na,◻)MgMn2+(Fe2+,Fe3+)2(PO4)3 | Mon. 2/m |
8.AC.10 | Nickenichite | Na0.8Ca0.4Cu0.4(Mg,Fe)3(AsO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Varulite | NaCaMn2+Mn2+2(PO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Ferrohagendorfite | NaCaFe2+Fe2+2(PO4)3 | Mon. |
8.AC.10 | Bradaczekite | NaCu4(AsO4)3 | Mon. 2/m : B2/b |
8.AC.10 | Groatite | NaCaMn2(PO4)[PO3(OH)]2 | Mon. 2/m : B2/b |
8.AC.15 | Bobfergusonite | Na2Mn5FeAl(PO4)6 | Mon. 2/m : P2/b |
8.AC.15 | Ferrowyllieite | (Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO4)3 | Mon. 2/m : P21/b |
8.AC.15 | Qingheiite | NaNaMn2+(MgAl)(PO4)3 | Mon. 2/m : P21/b |
8.AC.15 | Rosemaryite | (Na,Ca,Mn)(Mn,Fe2+)(Fe3+,Mg)Al(PO4)3 | Mon. 2/m : P21/b |
8.AC.15 | Wyllieite | (Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO4)3 | Mon. 2/m |
8.AC.15 | Ferrorosemaryite | ◻NaFe2+Fe3+Al(PO4)3 | Mon. 2/m |
8.AC.15 | Ferroqingheiite | NaNaFe2+(MgAl)(PO4)3 | Mon. 2/m : P21/m |
8.AC.17 | Czochralskiite | Na4Ca3Mg(PO4)4 | Orth. mmm (2/m 2/m 2/m) : Pnma |
8.AC.18 | Manitobaite | Na16Mn2+ 25Al8(PO4)30 | Mon. m : Pb |
8.AC.20 | Marićite | NaFe2+(PO4) | Orth. mmm (2/m 2/m 2/m) : Pmna |
8.AC.25 | Berzeliite | (NaCa2)Mg2(AsO4)3 | Iso. m3m (4/m 3 2/m) : Ia3d |
8.AC.25 | Manganberzeliite | (NaCa2)Mn2+2(AsO4)3 | Iso. m3m (4/m 3 2/m) : Ia3d |
8.AC.25 | Palenzonaite | (NaCa2)Mn2+2(VO4)3 | Iso. m3m (4/m 3 2/m) : Ia3d |
8.AC.25 | Schäferite | (NaCa2)Mg2(VO4)3 | Iso. m3m (4/m 3 2/m) : Ia3d |
8.AC.25 | Hedegaardite | (Ca,Na)9(Ca,Na)Mg(PO4)6(PO3OH) | Trig. 3m : R3c |
8.AC.25 | Matyhite | Ca18(Ca,◻)2Fe2+2(PO4)14 | Trig. 3m : R3c |
8.AC.30 | Brianite | Na2CaMg(PO4)2 | Mon. 2/m : P21/b |
8.AC.35 | Vitusite-(Ce) | Na3(Ce,La,Nd)(PO4)2 | Orth. mm2 : Pca21 |
8.AC.40 | Olgite | (Sr,Ba)(Na,Sr,REE)2Na(PO4)2 | Trig. 3m (3 2/m) : P3m1 |
8.AC.40 | Bario-olgite | (Ba,Sr)(Na,Sr,REE)2Na(PO4)2 · | Trig. 3 : P3 |
8.AC.45 | Strontiowhitlockite | Sr9Mg(PO4)6(PO3OH) | Trig. 3m : R3c |
8.AC.45 | Whitlockite | Ca9Mg(PO4)6(PO3OH) | Trig. 3m : R3c |
8.AC.45 | Merrillite | Ca9NaMg(PO4)7 | Trig. 3m : R3m |
8.AC.45 | Tuite | Ca3(PO4)2 | Trig. 3m (3 2/m) : R3m |
8.AC.45 | Ferromerrillite | Ca9NaFe2+(PO4)7 | Trig. 3m : R3c |
8.AC.47 | Iwateite | Na2BaMn(PO4)2 | Trig. 3 : P3 |
8.AC.47 | Yurmarinite | Na7(Fe3+,Mg,Cu)4(AsO4)6 | Trig. 3m (3 2/m) : R3c |
8.AC.47 | Ozerovaite | Na2KAl3(AsO4)4 | Orth. mmm (2/m 2/m 2/m) : Cmca |
8.AC.47 | Anatolyite | Na6(Ca,Na)(Mg,Fe3+)3Al(AsO4)6 | Trig. 3m (3 2/m) : R3c |
8.AC.47 | Pansnerite | K3Na3(Fe3+,Al)6(AsO4)8 | Orth. mmm (2/m 2/m 2/m) |
8.AC.50 | Chladniite | Na3CaMg11(PO4)9 | Trig. 3 : R3 |
8.AC.50 | Fillowite | Na3CaMn2+11(PO4)9 | Trig. 3 : R3 |
8.AC.50 | Johnsomervilleite | Na3CaFe11(PO4)9 | Trig. 3 : R3 |
8.AC.50 | Galileiite | Na3Fe2+Fe2+11(PO4)9 | Trig. 3 : R3 |
8.AC.50 | Xenophyllite | Na4Fe2+7(PO4)6 | Tric. 1 : P1 |
8.AC.50 | Udinaite | NaMg4(VO4)3 | Tet. 4 2m : I4 2d |
8.AC.50 | Arsenudinaite | NaMg4(AsO4)3 | Tet. 4 2m : I4 2d |
8.AC.52 | Lasnierite | (Ca,Sr)(Mg,Fe2+)2Al(P[O,F]4)3 | Orth. mmm (2/m 2/m 2/m) : Pbcn |
8.AC.55 | Pharmazincite | KZnAsO4 | Hex. 6 : P63 |
8.AC.57 | Zubkovaite | Ca3Cu3(AsO4)4 | Mon. 2 : B2 |
8.AC.60 | Kosnarite | KZr2(PO4)3 | Trig. 3m (3 2/m) : R3c |
8.AC.65 | Panethite | (Na,Ca)2(Mg,Fe2+)2(PO4)2 | Mon. 2/m : P21/b |
8.AC.70 | Stanfieldite | Ca4Mg5(PO4)6 | Mon. |
8.AC.75 | Ronneburgite | K2MnV4O12 | Mon. 2/m |
8.AC.80 | Tillmannsite | Ag3Hg[(V,As)O4] | Tet. 4 : I4 |
8.AC.85 | Filatovite | K(Al,Zn)2(As,Si)2O8 | Mon. 2/m |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Ziminaite
mindat.org URL:
https://www.mindat.org/min-46494.html
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References for Ziminaite
Reference List:
Localities for Ziminaite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Russia (TL) | |
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