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Clino-ferro-ferri-holmquistite

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Formula:
◻{Li
 
2
}{Fe
2+
3
Fe
3+
2
}(Si
 
8
O
 
22
)(OH)
 
2
The clino-holmquistite group minerals are monoclinic lithium amphiboles defined with:
A(Na+K+2Ca)< 0.5 apfu,
CLi < 0,5 apfu

Clino-ferro-ferri-holmquistite is defined with
C2+ position: Fe dominant
C3+ position: Fe dominant
W position: (OH) dominant
System:MonoclinicColour:Black
Hardness:6
Member of:Clino-holmquistite Root Name Group > Lithium Amphibole Subgroup > w(OH, F, Cl)-dominant Amphibole Group > Amphibole Supergroup
This page provides mineralogical data about Clino-ferro-ferri-holmquistite.

Classification of Clino-ferro-ferri-holmquistite

IMA status:Approved 2001
Explanation of status:IMA 2001-066
Strunz 8th edition ID:8/F.07-85
Nickel-Strunz 10th (pending) edition ID:9.DE.25

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles
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Type Occurrence of Clino-ferro-ferri-holmquistite

Type Locality:Arroyo de la Yedra, Manzanares el Real, Madrid, Spain
General Appearance of Type Material:Intergranular aggregates of subhedral to euhedral habit (size not stated,
but extremely small).
Geological Setting of type material:The episyenites from the Sierra de Guadarrama (Spanish Central System) were formed by the hydrothermal alteration (dequartzification and alkalinization) of granitoids

Physical Properties of Clino-ferro-ferri-holmquistite

Lustre:Vitreous
Colour:Black
Streak:Grey
Hardness (Mohs):6
Tenacity:Brittle
Fracture:Irregular/Uneven
Density (calculated):3.24 g/cm3
Comment:Could not be measured

Crystallography of Clino-ferro-ferri-holmquistite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/m
Space Group Setting:C2/m
Cell Parameters:a = 9.462Å, b = 17.898Å, c = 5.302Å
β = 101.88°°
Ratio:a:b:c = 0.529 : 1 : 0.296
Unit Cell Volume:V 878.6 ų
Z:2
X-Ray Powder Diffraction:
d-spacingIntensity
X-ray powder-diffraction(
data: 8.224(100)
4.474(31)
3.420(30)
3.042(54)
(
2.717(70)
2.492(32)
2.165(22)

Chemical Properties of Clino-ferro-ferri-holmquistite

Formula:
◻{Li
 
2
}{Fe
2+
3
Fe
3+
2
}(Si
 
8
O
 
22
)(OH)
 
2


The clino-holmquistite group minerals are monoclinic lithium amphiboles defined with:
A(Na+K+2Ca)< 0.5 apfu,
CLi < 0,5 apfu

Clino-ferro-ferri-holmquistite is defined with
C2+ position: Fe dominant
C3+ position: Fe dominant
W position: (OH) dominant
Simplified for copy/paste:◻{Li2}{Fe2+3Fe3+2}(Si8O22)(
Essential elements:Fe, H, Li, O, Si
All elements listed in formula:Fe, H, Li, O, Si
Analytical Data:
Electron-microprobe data (Li2O, H2O and
F by SIMS): Li2O 3.80, Na2O 1.29, K2O 0.01, MgO 5.04, CaO 0.13, MnO 1.14, FeO
12.98, ZnO 0.21, Al2O3 1.51, Fe2O3 15.63, SiO2 56.11, TiO2 0.07, H2O 1.88, F 0.54,
sum 100.34, less O = F 0.23, Total 100.11 wt.%.
Empirical Formula:
Na
 
0.28
(Li
 
1.90
Na
 
0.08
Ca
 
0.02
)
 
2.00
(Fe
3+
 
 
1.68
Fe
2+
 
 
1.55
Mg
 
1.07
Li
 
0.28
Al
 
0.25
Mn
 
0.14
Zn
 
0.02
Ti
 
0.01
)
 
5.00
Si
 
8.00
O
 
21.97
[(OH)
 
1.79
F
 
0.24
]
 
2.03

Relationship of Clino-ferro-ferri-holmquistite to other Species

Member of:Clino-holmquistite Root Name Group > Lithium Amphibole Subgroup > w(OH, F, Cl)-dominant Amphibole Group > Amphibole Supergroup
Other Members of Group:

- +
Clino-ferri-fluoro-holmquistite
☐{Li
 
2
}{Mg
 
3
Fe
3+
2
}(Si
 
8
O
 
22
)F
 
2
Clino-ferri-holmquistite
◻{Li
 
2
}{Mg
 
3
Fe
3+
2
}(Si
 
8
O
 
22
)(OH)
 
2
Clino-ferro-ferri-fluoro-holmquistite
☐{Li
 
2
}{Fe
2+
3
Fe
3+
2
}(Si
 
8
O
 
22
)F
 
2
Clino-ferro-fluoro-holmquistite
☐{Li
 
2
}{Fe
2+
3
Al
 
2
}(Si
 
8
O
 
22
)F
 
2
Clino-fluoro-holmquistite
◻{Li
 
2
}{Mg
 
3
Al
 
2
}(Si
 
8
O
 
22
)F
 
2
Clino-holmquistite
☐{Li
 
2
}{Mg
 
3
Al
 
2
}(Si
 
8
O
 
22
)(OH)
 
2
Related Minerals - Nickel-Strunz Grouping):

- +
9.DE.05Anthophyllite
☐{Mg
 
2
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Cummingtonite
☐{Mg
 
2
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Clino-holmquistite Root Name
☐{Li
 
2
}{Z
2+
3
Z
3+
2
}(Si
 
8
O
 
22
)(OH,F,Cl)
 
2
9.DE.05Grunerite
☐{Fe
2+
2
}{Fe
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Manganocummingtonite
☐{Mn
2+
2
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Manganogrunerite
☐{Mn
2+
2
}{Fe
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Permanganogrunerite
☐{Mn
2+
2
}{Mn
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Ferro-fluoro-pedrizite
{Na}{Li
 
2
}{Fe
 
2
Al
 
2
Li}(Al
 
2
Si
 
6
O
 
22
)F
 
2
9.DE.05Ferri-fluoro-leakeite
{Na}{Na
 
2
}{Mg
 
2
Fe
3+
2
Li}(Si
 
8
O
 
22
)F
 
2
9.DE.10Actinolite
☐{Ca
 
2
}{(Mg,Fe
2+
 
)
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Ferri-tschermakite
☐{Ca
 
2
}{Mg
 
3
Fe
3+
2
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.10Ferro-actinolite
☐{Ca
 
2
}{Fe
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Ferro-hornblende
☐{Ca
 
2
}{Fe
2+
4
Al}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.10Ferro-tschermakite
☐{Ca
 
2
}{Fe
2+
3
Al
 
2
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.10Joesmithite
{Pb}{Ca
 
2
}{Mg
 
3
Fe
3+
2
}(Be
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.10Magnesio-hornblende
☐{Ca
 
2
}{Mg
 
4
Al}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.10Tremolite
☐{Ca
 
2
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Tschermakite
☐(Ca
 
2
)(Mg
 
3
Al
 
2
)(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.10Cannilloite
Ca(Ca
 
2
)(Mg
 
4
Al)(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.10Fluoro-cannilloite
{Ca}{Ca
 
2
}{Mg
 
4
Al}(Al
 
3
Si
 
5
O
 
22
)(F,OH)
 
2
9.DE.10Parvo-manganotremolite
☐{CaMn
2+
 
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Fluoro-tremolite
☐{Ca
 
2
}{Mg
 
5
}(Si
 
8
O
 
22
)F
 
2
9.DE.10Potassic-fluoro-pargasite
{K}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)F
 
2
9.DE.15Edenite
{Na}{Ca
 
2
}{Mg
 
5
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.15Ferro-edenite
{Na}{Ca
 
2
}{Fe
2+
5
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.15Ferro-kaersutite
{Na}{Ca
 
2
}{Fe
2+
3
AlTi}(Al
 
2
Si
 
6
O
 
22
)O
 
2
9.DE.15Ferro-pargasite
{Na}{Ca
 
2
}{Fe
2+
4
Al}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Hastingsite
{Na}{Ca
 
2
}{Fe
2+
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Kaersutite
{Na}{Ca
 
2
}{Mg
 
3
AlTi}(Al
 
2
Si
 
6
O
 
22
)O
 
2
9.DE.15Magnesio-hastingsite
{Na}{Ca
 
2
}{Mg
 
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Pargasite
{Na}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Sadanagaite
{Na}{Ca
 
2
}{Mg
 
3
Al
 
2
}(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.15Fluoro-edenite
{Na}{Ca
 
2
}{Mg
 
5
}(AlSi
 
7
O
 
22
)(F,OH)
 
2
9.DE.15Potassic-ferro-ferri-sadanagaite
{K}{Ca
 
2
}{Fe
2+
3
Fe
3+
2
}(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.15Potassic-sadanagaite
{K}{Ca
 
2
}{Mg
 
3
Al
 
2
}(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.15Potassic-pargasite
{K}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Potassic-ferro-sadanagaite
{K}{Ca
 
2
}{Fe
2+
3
Al
 
2
}(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.15Magnesio-fluoro-hastingsite
{Na}{Ca
 
2
}{Mg
 
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)F
 
2
9.DE.15Potassic-fluoro-hastingsite
{K}{Ca
 
2
}{Fe
2+
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(F,OH)
 
2
9.DE.15Potassic-chloro-hastingsite
{K}{Ca
 
2
}{Fe
2+
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(Cl,OH)
 
2
9.DE.15Fluoro-pargasite
{Na}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)(F,OH)
 
2
9.DE.15Parvo-mangano-edenite
{Na}{CaMn
2+
 
}{Mg
 
5
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.15Potassic-chloro-pargasite
{K}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)(Cl,OH)
 
2
9.DE.15Potassic-ferro-chloro-edenite
{K}{Ca
 
2
}{Fe
2+
5
}(AlSi
 
7
O
 
22
)(Cl,OH)
 
2
9.DE.15Potassic-magnesio-hastingsite
{K}{Ca
 
2
}{Mg
 
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Potassic-ferro-pargasite
{K}{Ca
 
2
}{Fe
2+
4
Al}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Chromio-pargasite
{Na}{Ca
 
2
}{Mg
 
4
Cr
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Ferro-taramite
Na(CaNa)(Fe
2+
3
Al
 
2
)(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Barroisite
☐{CaNa}{Mg
 
3
Al
 
2
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.20Ferro-ferri-barroisite
☐(CaNa)(Fe
2+
3
Fe
3+
2
)(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.20Ferro-ferri-winchite
☐[CaNa][Fe
2+
4
(Fe
3+
 
,Al)]Si
 
8
O
 
22
(OH)
 
2
9.DE.20Ferri-barroisite
☐(CaNa)(Mg
 
3
Fe
3+
2
)(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.20Ferro-ferri-taramite
Na(CaNa)(Fe
2+
3
Fe
3+
2
)(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Ferro-ferri-katophorite
NaCaNaFe
2+
4
(Fe
3+
 
)[(AlSi
 
7
)O
 
22
](OH)
 
2
9.DE.20Ferro-barroisite
☐{CaNa}{Fe
2+
3
Al
 
2
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.20Ferro-richterite
{Na}{CaNa}{Fe
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.20Ferro-winchite
☐{CaNa}{Fe
2+
4
Al}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.20Ferro-katophorite
{Na}{CaNa}{Fe
2+
4
Al}[(AlSi
 
7
)O
 
22
](OH)
 
2
9.DE.20Ferri-taramite
Na(CaNa)(Mg
 
3
Fe
3+
2
)(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Magnesiotaramite
{Na}{CaNa}{Mg
 
3
AlFe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Richterite
{Na}{CaNa}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.20Winchite
☐{CaNa}{Mg
 
4
Al}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.20Taramite
{Na}{CaNa}{Mg
 
3
Al
 
2
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Fluoro-richterite
{Na}{CaNa}{Mg
 
5
}(Si
 
8
O
 
22
)(F,OH)
 
2
9.DE.20Katophorite
{Na}{CaNa}{Mg
 
4
Al}[(AlSi
 
7
)O
 
22
](OH)
 
2
9.DE.20Potassic-fluoro-richterite
{K}{CaNa}{Mg
 
5
}(Si
 
8
O
 
22
)(F,OH)
 
2
9.DE.20Potassic-richterite
K[CaNa][Mg
 
5
]Si
 
8
O
 
22
(OH)
 
2
9.DE.20Ferri-ghoseite
☐[Mn
2+
 
Na][Mg
 
4
Fe
3+
 
]Si
 
8
O
 
22
(OH)
 
2
9.DE.20Ferri-winchite
☐[CaNa][Mg
 
4
(Fe
3+
 
,Al)]Si
 
8
O
 
22
(OH)
 
2
9.DE.20Fluoro-taramite
{Na}{CaNa}{Mg
 
3
Al
 
2
}(Al
 
2
Si
 
6
O
 
22
)F
 
2
9.DE.25Arfvedsonite
[Na][Na
 
2
][Fe
2+
4
Fe
3+
 
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Eckermannite
NaNa
 
2
(Mg
 
4
Al}Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferro-eckermannite
NaNa
 
2
(Fe
2+
 
,
 
4
Al)Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferro-glaucophane
◻[Na
 
2
][Fe
2+
3
Al
 
2
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Glaucophane
◻[Na
 
2
][Mg
 
3
Al
 
2
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Potassic-mangani-leakeite
[(Na,K)][Na
 
2
][Mg
 
2
Mn
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Mangano-ferri-eckermannite
[Na][Na
 
2
][Mn
2+
4
(Fe
3+
 
)]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferri-leakeite
[Na][Na
 
2
][Mg
 
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Magnesio-riebeckite
◻{Na
 
2
}{Mg
 
3
Fe
3+
2
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Magnesio-arfvedsonite
{Na}{Na
 
2
}{Mg
 
4
Fe
3+
 
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Nybøite
NaNa
 
2
(Mg
 
3
Al
 
2
)(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.25Riebeckite
◻[Na
 
2
][Fe
2+
3
Fe
3+
2
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Mangano-mangani-ungarettiite
NaNa
 
2
(Mn
2+
2
Mn
3+
3
)(Si
 
8
O
 
22
)O
 
2
9.DE.25Ferro-ferri-nybøite
NaNa
 
2
[(Fe
2+
3
,Mg)Fe
3+
2
](AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.25Ferri-nybøite
NaNa
 
2
(Mg
 
3
Fe
3+
2
](AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.25Ferro-ferri-leakeite
[Na][Na
 
2
][Fe
2+
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferro-ferri-fluoro-leakeite
Na(Na
 
2
)(Fe
2+
2
Fe
3+
2
Li)(Si
 
8
O
 
22
)(F)
 
2
9.DE.25Sodic-ferri-clinoferroholmquistite
Na
 
0.5
{Li
 
2
}{Fe
2+
3
Fe
3+
2
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Magnesio-fluoro-arfvedsonite
[Na][Na
 
2
][Mg
 
4
Fe
3+
 
][Si
 
8
O
 
22
](F,OH)
 
2
9.DE.25Ferri-pedrizite
[Na][Li
 
2
][Mg
 
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Potassic-ferri-leakeite
[K][Na
 
2
][Mg
 
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Fluoro-nybøite
NaNa
 
2
(Mg
 
3
Al
 
2
)(AlSi
 
7
O
 
22
)(F,OH)
 
2
9.DE.25Mangani-dellaventuraite
{Na}{Na
 
2
}{MgMn
3+
2
LiTi
4+
 
}Si
 
8
O
 
22
O
 
2
9.DE.25Fluoro-pedrizite
NaLi
 
2
(Mg
 
2
Al
 
2
Li)(Si
 
8
O
 
22
)F
 
2
9.DE.25Potassic-arfvedsonite
[(K,Na)][Na
 
2
][Fe
2+
4
Fe
3+
 
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferri-obertiite
Na(Na
 
2
)(Mg
 
3
Fe
3+
 
Ti)(Si
 
8
O
 
22
)O
 
2
9.DE.25Potassic-magnesio-fluoro-arfvedsonite
[(K,Na)][Na
 
2
][Mg
 
4
Fe
3+
 
][Si
 
8
O
 
22
][(F,OH)
 
2
]
9.DE.25Ferro-ferri-pedrizite
[Na][Li
 
2
][Fe
2+
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Potassic-magnesio-arfvedsonite
[K][Na
 
2
][Mg
 
4
Fe
3+
 
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Pedrizite
NaLi
 
2
(LiMg
 
2
Al
 
2
)(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Ferro-pedrizite
NaLi
 
2
(Fe
2+
2
Al
 
2
Li)Si
 
8
O
 
22
(OH)
 
2
9.DE.25Fluoro-leakeite
NaNa
 
2
(Mg
 
2
Al
 
2
Li)(Si
 
8
O
 
22
)F
 
2
9.DE.25Ferro-ferri-obertiite
NaNa
 
2
(Fe
2+
3
Fe
3+
 
Ti)Si
 
8
O
 
22
O
 
2

Other Names for Clino-ferro-ferri-holmquistite

Other Languages:
Simplified Chinese:单斜二铁锂闪石
Traditional Chinese:單斜二鐵鋰閃石

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Clino-ferro-ferri-holmquistite

Reference List:

- +
OBERTI, R., CÁMARA, F., CABALLERO, J.M. & OTTOLINI, L. (2003): Sodic-ferri-ferropedrizite and ferri-clinoferroholmquistite: mineral data and degree of order of the A-site cations in Li-rich amphiboles. Canadian Mineralogist 41, 1345-1354.


Hawthorne, Frank C., and Roberta Oberti (2006), On the classification of amphiboles: Canadian Mineralogist: 44(1): 1-21.

Frank C. Hawthorne, Roberta Oberti, George E. Harlow, Walter V. Maresch, Robert F. Martin, John C. Schumacer, Mark D. Welch (2012): Nomenclature of the amphibole supergroup, American Mineralogist, Volume 97, pages 2031–2048

Internet Links for Clino-ferro-ferri-holmquistite

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  • Localities for Clino-ferro-ferri-holmquistite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Spain
     
    • Madrid
      • Manzanares el Real
    Oberti, R., et al. (2003) Canadian Mineralogist, 41, 1345-1354
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