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Clino-ferro-ferri-holmquistite

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Formula:
◻{Li2}{Fe32+Fe23+}(Si8O22)(OH)2
The clino-holmquistite group minerals are monoclinic lithium amphiboles defined with:
A(Na+K+2Ca)< 0.5 apfu,
CLi < 0,5 apfu

Clino-ferro-ferri-holmquistite is defined with
C2+ position: Fe dominant
C3+ position: Fe dominant
W position: (OH) dominant
System:
Monoclinic
Colour:
Black
Hardness:
6
This page provides mineralogical data about Clino-ferro-ferri-holmquistite.

Classification of Clino-ferro-ferri-holmquistite

Approved 2001
Explanation of status:
IMA 2001-066
9.DE.25

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles
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First Recorded Occurrence of Clino-ferro-ferri-holmquistite

General Appearance of First Recorded Material:
Intergranular aggregates of subhedral to euhedral habit (size not stated,
but extremely small).
Geological Setting of First Recorded Material:
The episyenites from the Sierra de Guadarrama (Spanish Central System) were formed by the hydrothermal alteration (dequartzification and alkalinization) of granitoids

Physical Properties of Clino-ferro-ferri-holmquistite

Vitreous
Colour:
Black
Streak:
Grey
Hardness (Mohs):
6
Tenacity:
Brittle
Fracture:
Irregular/Uneven
Density:
3.24 g/cm3 (Calculated)
Comment:
Could not be measured

Crystallography of Clino-ferro-ferri-holmquistite

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/m
Space Group Setting:
C2/m
Cell Parameters:
a = 9.462Å, b = 17.898Å, c = 5.302Å
β = 101.88°°
Ratio:
a:b:c = 0.529 : 1 : 0.296
Unit Cell Volume:
V 878.6 ų
Z:
2
X-Ray Powder Diffraction Data:
d-spacingIntensity
X-ray powder-diffraction(
data: 8.224(100)
4.474(31)
3.420(30)
3.042(54)
(
2.717(70)
2.492(32)
2.165(22)

Chemical Properties of Clino-ferro-ferri-holmquistite

Formula:
◻{Li2}{Fe32+Fe23+}(Si8O22)(OH)2

The clino-holmquistite group minerals are monoclinic lithium amphiboles defined with:
A(Na+K+2Ca)< 0.5 apfu,
CLi < 0,5 apfu

Clino-ferro-ferri-holmquistite is defined with
C2+ position: Fe dominant
C3+ position: Fe dominant
W position: (OH) dominant
Essential elements:
All elements listed in formula:
Analytical Data:
Electron-microprobe data (Li2O, H2O and
F by SIMS): Li2O 3.80, Na2O 1.29, K2O 0.01, MgO 5.04, CaO 0.13, MnO 1.14, FeO
12.98, ZnO 0.21, Al2O3 1.51, Fe2O3 15.63, SiO2 56.11, TiO2 0.07, H2O 1.88, F 0.54,
sum 100.34, less O = F 0.23, Total 100.11 wt.%.
Empirical Formula:
Na0.28(Li1.90Na0.08 Ca0.02)2.00(Fe3+ 1.68Fe2+ 1.55Mg1.07Li0.28Al0.25Mn0.14Zn0.02Ti0.01)5.00Si8.00O21.97 [(OH)1.79F0.24]2.03

Relationship of Clino-ferro-ferri-holmquistite to other Species

Other Members of Group:
Clino-ferri-fluoro-holmquistite☐{Li2}{Mg3Fe23+}(Si8O22)F2
Clino-ferri-holmquistite◻{Li2}{Mg3Fe23+}(Si8O22)(OH)2
Clino-ferro-ferri-fluoro-holmquistite☐{Li2}{Fe32+Fe23+}(Si8O22)F2
Clino-ferro-fluoro-holmquistite☐{Li2}{Fe32+Al2}(Si8O22)F2
Clino-fluoro-holmquistite◻{Li2}{Mg3Al2}(Si8O22)F2
Clino-holmquistite☐{Li2}{Mg3Al2}(Si8O22)(OH)2
9.DE.05Anthophyllite☐{Mg2}{Mg5}(Si8O22)(OH)2
9.DE.05Cummingtonite☐{Mg2}{Mg5}(Si8O22)(OH)2
9.DE.05Clino-holmquistite Root Name☐{Li2}{Z32+Z23+}(Si8O22)(OH,F,Cl)2
9.DE.05Grunerite☐{Fe22+}{Fe52+}(Si8O22)(OH)2
9.DE.05Manganocummingtonite☐{Mn22+}{Mg5}(Si8O22)(OH)2
9.DE.05Manganogrunerite☐{Mn22+}{Fe52+}(Si8O22)(OH)2
9.DE.05Permanganogrunerite☐{Mn22+}{Mn52+}(Si8O22)(OH)2
9.DE.05Ferro-fluoro-pedrizite{Na}{Li2}{Fe2Al2Li}(Al2Si6O22)F2
9.DE.05Ferri-fluoro-leakeite{Na}{Na2}{Mg2Fe23+Li}(Si8O22)F2
9.DE.10Actinolite☐{Ca2}{Mg4.5-2.5Fe0.5-2.5}(Si8O22)(OH)2
9.DE.10Ferri-tschermakite☐{Ca2}{Mg3Fe23+}(Al2Si6O22)(OH)2
9.DE.10Ferro-actinolite☐{Ca2}{Fe52+}(Si8O22)(OH)2
9.DE.10Ferro-hornblende☐{Ca2}{Fe42+Al}(AlSi7O22)(OH)2
9.DE.10Ferro-tschermakite☐{Ca2}{Fe32+Al2}(Al2Si6O22)(OH)2
9.DE.10Joesmithite{Pb}{Ca2}{Mg3Fe23+}(Be2Si6O22)(OH)2
9.DE.10Magnesio-hornblende☐{Ca2}{Mg4Al}(AlSi7O22)(OH)2
9.DE.10Tremolite☐{Ca2}{Mg5}(Si8O22)(OH)2
9.DE.10Tschermakite☐(Ca2)(Mg3Al2)(Al2Si6O22)(OH)2
9.DE.10CannilloiteCa(Ca2)(Mg4Al)(Al3Si5O22)(OH)2
9.DE.10Fluoro-cannilloite{Ca}{Ca2}{Mg4Al}(Al3Si5O22)(F,OH)2
9.DE.10Parvo-manganotremolite☐{CaMn2+}{Mg5}(Si8O22)(OH)2
9.DE.10Fluoro-tremolite☐{Ca2}{Mg5}(Si8O22)F2
9.DE.10Potassic-fluoro-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)F2
9.DE.15Edenite{Na}{Ca2}{Mg5}(AlSi7O22)(OH)2
9.DE.15Ferro-edenite{Na}{Ca2}{Fe52+}(AlSi7O22)(OH)2
9.DE.15Ferro-kaersutite{Na}{Ca2}{Fe32+AlTi}(Al2Si6O22)O2
9.DE.15Ferro-pargasite{Na}{Ca2}{Fe42+Al}(Al2Si6O22)(OH)2
9.DE.15Hastingsite{Na}{Ca2}{Fe42+Fe3+}(Al2Si6O22)(OH)2
9.DE.15Kaersutite{Na}{Ca2}{Mg3AlTi}(Al2Si6O22)O2
9.DE.15Magnesio-hastingsite{Na}{Ca2}{Mg4Fe3+}(Al2Si6O22)(OH)2
9.DE.15Pargasite{Na}{Ca2}{Mg4Al}(Al2Si6O22)(OH)2
9.DE.15Sadanagaite{Na}{Ca2}{Mg3Al2}(Al3Si5O22)(OH)2
9.DE.15Fluoro-edenite{Na}{Ca2}{Mg5}(AlSi7O22)(F,OH)2
9.DE.15Potassic-ferro-ferri-sadanagaite{K}{Ca2}{Fe32+Fe23+}(Al3Si5O22)(OH)2
9.DE.15Potassic-sadanagaite{K}{Ca2}{Mg3Al2}(Al3Si5O22)(OH)2
9.DE.15Potassic-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)(OH)2
9.DE.15Potassic-ferro-sadanagaite{K}{Ca2}{Fe32+Al2}(Al3Si5O22)(OH)2
9.DE.15Magnesio-fluoro-hastingsite{Na}{Ca2}{Mg4Fe3+}(Al2Si6O22)F2
9.DE.15Potassic-fluoro-hastingsite{K}{Ca2}{Fe42+Fe3+}(Al2Si6O22)(F,OH)2
9.DE.15Potassic-chloro-hastingsite{K}{Ca2}{Fe42+Fe3+}(Al2Si6O22)(Cl,OH)2
9.DE.15Fluoro-pargasite{Na}{Ca2}{Mg4Al}(Al2Si6O22)(F,OH)2
9.DE.15Parvo-mangano-edenite{Na}{CaMn2+}{Mg5}(AlSi7O22)(OH)2
9.DE.15Potassic-chloro-pargasite{K}{Ca2}{Mg4Al}(Al2Si6O22)(Cl,OH)2
9.DE.15Potassic-ferro-chloro-edenite{K}{Ca2}{Fe52+}(AlSi7O22)(Cl,OH)2
9.DE.15Potassic-magnesio-hastingsite{K}{Ca2}{Mg4Fe3+}(Al2Si6O22)(OH)2
9.DE.15Potassic-ferro-pargasite{K}{Ca2}{Fe42+Al}(Al2Si6O22)(OH)2
9.DE.15Chromio-pargasite{Na}{Ca2}{Mg4Cr3+}(Al2Si6O22)(OH)2
9.DE.20Ferro-taramiteNa(CaNa)(Fe32+Al2)(Al2Si6O22)(OH)2
9.DE.20Barroisite☐{CaNa}{Mg3Al2}(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-barroisite☐(CaNa)(Fe32+Fe23+)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-winchite☐[CaNa][Fe42+(Fe3+,Al)]Si8O22(OH)2
9.DE.20Ferri-barroisite☐(CaNa)(Mg3Fe23+)(AlSi7O22)(OH)2
9.DE.20Ferro-ferri-taramiteNa(CaNa)(Fe32+Fe23+)(Al2Si6O22)(OH)2
9.DE.20Ferro-ferri-katophoriteNaCaNaFe42+(Fe3+)[(AlSi7)O22](OH)2
9.DE.20Ferro-barroisite☐{CaNa}{Fe32+Al2}(AlSi7O22)(OH)2
9.DE.20Ferro-richterite{Na}{CaNa}{Fe52+}(Si8O22)(OH)2
9.DE.20Ferro-winchite ☐{CaNa}{Fe42+Al}(Si8O22)(OH)2
9.DE.20Ferro-katophorite{Na}{CaNa}{Fe42+Al}[(AlSi7)O22](OH)2
9.DE.20Ferri-taramiteNa(CaNa)(Mg3Fe23+)(Al2Si6O22)(OH)2
9.DE.20Magnesiotaramite{Na}{CaNa}{Mg3AlFe3+}(Al2Si6O22)(OH)2
9.DE.20Richterite{Na}{CaNa}{Mg5}(Si8O22)(OH)2
9.DE.20Winchite☐{CaNa}{Mg4Al}(Si8O22)(OH)2
9.DE.20Taramite{Na}{CaNa}{Mg3Al2}(Al2Si6O22)(OH)2
9.DE.20Fluoro-richterite{Na}{CaNa}{Mg5}(Si8O22)(F,OH)2
9.DE.20Katophorite{Na}{CaNa}{Mg4Al}[(AlSi7)O22](OH)2
9.DE.20Potassic-fluoro-richterite{K}{CaNa}{Mg5}(Si8O22)(F,OH)2
9.DE.20Potassic-richteriteK[CaNa][Mg5]Si8O22(OH)2
9.DE.20Ferri-ghoseite☐[Mn2+Na][Mg4Fe3+]Si8O22(OH)2
9.DE.20Ferri-winchite☐[CaNa][Mg4(Fe3+,Al)]Si8O22(OH)2
9.DE.20Fluoro-taramite{Na}{CaNa}{Mg3Al2}(Al2Si6O22)F2
9.DE.25Arfvedsonite[Na][Na2][Fe42+Fe3+]Si8O22(OH)2
9.DE.25EckermanniteNaNa2(Mg4Al}Si8O22(OH)2
9.DE.25Ferro-eckermanniteNaNa2(Fe2+,4Al)Si8O22(OH)2
9.DE.25Ferro-glaucophane◻[Na2][Fe32+Al2]Si8O22(OH)2
9.DE.25Glaucophane◻[Na2][Mg3Al2]Si8O22(OH)2
9.DE.25Potassic-mangani-leakeite[(Na,K)][Na2][Mg2Mn23+Li]Si8O22(OH)2
9.DE.25Mangano-ferri-eckermannite[Na][Na2][Mn42+(Fe3+)]Si8O22(OH)2
9.DE.25Ferri-leakeite[Na][Na2][Mg2Fe23+Li]Si8O22(OH)2
9.DE.25Magnesio-riebeckite◻{Na2}{Mg3Fe23+}(Si8O22)(OH)2
9.DE.25Magnesio-arfvedsonite{Na}{Na2}{Mg4Fe3+}(Si8O22)(OH)2
9.DE.25NybøiteNaNa2(Mg3Al2)(AlSi7O22)(OH)2
9.DE.25Riebeckite◻[Na2][Fe32+Fe23+]Si8O22(OH)2
9.DE.25Mangano-mangani-ungarettiiteNaNa2(Mn22+Mn33+)(Si8O22)O2
9.DE.25Ferro-ferri-nybøiteNaNa2[(Fe32+,Mg)Fe23+](AlSi7O22)(OH)2
9.DE.25Ferri-nybøiteNaNa2(Mg3Fe23+](AlSi7O22)(OH)2
9.DE.25Ferro-ferri-leakeite[Na][Na2][Fe22+Fe23+Li]Si8O22(OH)2
9.DE.25Ferro-ferri-fluoro-leakeiteNa(Na2)(Fe22+Fe23+Li)(Si8O22)(F)2
9.DE.25Sodic-ferri-clinoferroholmquistiteNa0.5{Li2}{Fe32+Fe23+}(Si8O22)(OH)2
9.DE.25Magnesio-fluoro-arfvedsonite[Na][Na2][Mg4Fe3+][Si8O22](F,OH)2
9.DE.25Ferri-pedrizite[Na][Li2][Mg2Fe23+Li]Si8O22(OH)2
9.DE.25Potassic-ferri-leakeite[K][Na2][Mg2Fe23+Li]Si8O22(OH)2
9.DE.25Fluoro-nybøiteNaNa2(Mg3Al2)(AlSi7O22)(F,OH)2
9.DE.25Mangani-dellaventuraite{Na}{Na2}{MgMn23+LiTi4+}Si8O22O2
9.DE.25Fluoro-pedriziteNaLi2(Mg2Al2Li)(Si8O22)F2
9.DE.25Potassic-arfvedsonite[(K,Na)][Na2][Fe42+Fe3+]Si8O22(OH)2
9.DE.25Mangani-obertiiteNa(Na2)(Mg3Mn3+Ti)(Si8O22)O2
9.DE.25Potassic-magnesio-fluoro-arfvedsonite[(K,Na)][Na2][Mg4Fe3+][Si8O22][(F,OH)2]
9.DE.25Ferro-ferri-pedrizite[Na][Li2][Fe22+Fe23+Li]Si8O22(OH)2
9.DE.25Potassic-magnesio-arfvedsonite[K][Na2][Mg4Fe3+]Si8O22(OH)2
9.DE.25PedriziteNaLi2(LiMg2Al2)(Si8O22)(OH)2
9.DE.25Ferro-pedriziteNaLi2(Fe22+Al2Li)Si8O22(OH)2
9.DE.25Fluoro-leakeiteNaNa2(Mg2Al2Li)(Si8O22)F2
9.DE.25Ferro-ferri-obertiiteNaNa2(Fe32+Fe3+Ti)Si8O22O2

Other Names for Clino-ferro-ferri-holmquistite

Name in Other Languages:
Simplified Chinese:单斜二铁锂闪石
Traditional Chinese:單斜二鐵鋰閃石

Other Information

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Clino-ferro-ferri-holmquistite

Reference List:
OBERTI, R., CÁMARA, F., CABALLERO, J.M. & OTTOLINI, L. (2003): Sodic-ferri-ferropedrizite and ferri-clinoferroholmquistite: mineral data and degree of order of the A-site cations in Li-rich amphiboles. Canadian Mineralogist 41, 1345-1354.


Hawthorne, Frank C., and Roberta Oberti (2006), On the classification of amphiboles: Canadian Mineralogist: 44(1): 1-21.

Frank C. Hawthorne, Roberta Oberti, George E. Harlow, Walter V. Maresch, Robert F. Martin, John C. Schumacer, Mark D. Welch (2012): Nomenclature of the amphibole supergroup, American Mineralogist, Volume 97, pages 2031–2048

Internet Links for Clino-ferro-ferri-holmquistite

Localities for Clino-ferro-ferri-holmquistite

(TL) indicates type locality for a valid mineral species. (FRL) indicates first recorded locality for everything else. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
Spain
 
  • Madrid
    • Manzanares el Real
Oberti, R., et al. (2003) Canadian Mineralogist, 41, 1345-1354
Mineral and/or Locality  
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