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Vanadoandrosite-(Ce)

A valid IMA mineral species
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Formula:
(Mn2+Ce)(V3+AlMn2+)O[Si2O7][SiO4](OH)
Colour:
Very dark brown to black
Lustre:
Adamantine, Vitreous
Specific Gravity:
4.27 (Calculated)
Crystal System:
Monoclinic
Name:
Named according to the IMA nomenclature scheme for the epidote group, for its relationship to other 'androsite' species, the first one being manganiandrosite-(La). The root name is for Andros Island, Greece, where manganiandrosite-(La) was discovered. The prefix indicates a predominance of V3+ at the M1 site. The suffix/modifier indicates the dominant cation at the A2 site, which for the allanite subgroup is always a REE.
A member of the Allanite Subgroupof the Epidote Group. Unique combination of elements (at the upload time).

The Fe3+ analogue of androsite-(Ce), ferriandrosite-(Ce), and manganiandrosite-(Ce).


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Unique IdentifiersHide

Mindat ID:
27466
Long-form identifier:
mindat:1:1:27466:5
GUID
(UUID V4):
81da72b5-def8-4f97-a901-9a65726e6a5c

IMA Classification of Vanadoandrosite-(Ce)Hide

Approved
IMA Formula:
MnCe(V3+AlMn2+)[Si2O7][SiO4]O(OH)
Approval year:
2004
First published:
2006

Classification of Vanadoandrosite-(Ce)Hide

9.BG.05

9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
Vda-CeIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of Vanadoandrosite-(Ce)Hide

Adamantine, Vitreous
Transparency:
Transparent
Colour:
Very dark brown to black
Comment:
Transparent in thin section only.
Tenacity:
Brittle
Cleavage:
None Observed
Density:
4.27 g/cm3 (Calculated)
Comment:
Calculated value based on the empirical formula.

Optical Data of Vanadoandrosite-(Ce)Hide

Type:
Biaxial
RI values:
n = 1.82
Max Birefringence:
δ = 0.000
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Very High
Pleochroism:
Strong
Comments:
yellow-brown < red-brown < dark greenish brown // b
Comments:
α > l .74 (589 nm); the mean calculated refractive index is l.82 for the holotype composition.

Chemistry of Vanadoandrosite-(Ce)Hide

Mindat Formula:
(Mn2+Ce)(V3+AlMn2+)O[Si2O7][SiO4](OH)
Common Impurities:
Ca,REE

Crystallography of Vanadoandrosite-(Ce)Hide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/m
Cell Parameters:
a = 8.856 Å, b = 5.729 Å, c = 10.038 Å
β = 113.088°
Ratio:
a:b:c = 1.546 : 1 : 1.752
Unit Cell V:
468.5 ų
Z:
2

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0007164Vanadoandrosite-(Ce)Cenki-Tok B, Ragu A, Armbruster T, Chopin C, Medenbach O (2006) New Mn- and rare-earth-rich epidote-group minerals in metacherts: manganiandrosite-(Ce) and vanadoandrosite-(Ce) European Journal of Mineralogy 18 569-5822006Vielle Aure mining district, central Pyrenees, France0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
9.2340 Å(25)
8.1467 Å(24)
3.5004 Å(43)
2.8872 Å(21)
2.8890 Å(100)
2.8645 Å(41)
2.7114 Å(31)
2.7023 Å(34)
2.6124 Å(54)
2.5916 Å(26)
2.1765 Å(21)
1.6142 Å(21)
Comments:
Coustou Mine, France. Data from type description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
High-𝑇 alteration and/or metamorphism
32 : Ba/Mn/Pb/Zn deposits, including metamorphic deposits

Type Occurrence of Vanadoandrosite-(Ce)Hide

General Appearance of Type Material:
Blackish, isolated stout prismatic grains, typically a few tens of μm in length, or radiating aggregates of the same size.
Place of Conservation of Type Material:
Mineral Museum, School of Mines, Paris, France, number 73952.
Geological Setting of Type Material:
Quartz-rhodochrosite-sulphide veinlets cross-cutting the rhodochrosite ore in greenschist-facies lower carboniferous radiolarite
Associated Minerals at Type Locality:

Synonyms of Vanadoandrosite-(Ce)Hide

Other Language Names for Vanadoandrosite-(Ce)Hide

Simplified Chinese:铈钒锰绿泥石
Traditional Chinese:鈰釩錳綠泥石

Relationship of Vanadoandrosite-(Ce) to other SpeciesHide

Other Members of this group:
Allanite-(Ce)(CaCe)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Allanite-(La)(CaLa)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Allanite-(Nd)(CaNd)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Allanite-(Sm)(CaSm)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Allanite-(Y)(CaY)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon.
Androsite-(Ce)(Mn2+Ce)(AlAlMn2+)O[Si2O7][SiO4](OH)
Dissakisite-(Ce)(CaCe)(AlAlMg)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Dissakisite-(La)(CaLa)(AlAlMg)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Ferriakasakaite-(Ce)(CaCe)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Ferriakasakaite-(La)(CaLa)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Ferriallanite-(Ce)(CaCe)(Fe3+AlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Ferriallanite-(La)(CaLa)(Fe3+AlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Ferriandrosite-(Ce)(Mn2+Ce)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Ferriandrosite-(La)(Mn2+La)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Manganiakasakaite-(La)(CaLa)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Manganiandrosite-(Ce)(Mn2+Ce)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Manganiandrosite-(La)(Mn2+La)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
Uedaite-(Ce)(Mn2+Ce)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
UM1989-32-SiO:AlCaFeHREE(Ca0.50.5REE)(AlAlFe3+)O[Si2O7][SiO4](OH)
UM1994-25-SiO:AlCaFeHREEV(CaREE)(V3+AlFe2+)O[Si2O7][SiO4](OH)
UM2006-14-SiO:AlCaHMnREE(CaCe)(AlAlMn2+)O[Si2O7][SiO4](OH)
Unnamed (Mg-analogue of Ferriallanite-(Ce))(CaCe)(Fe3+AlMg)O[Si2O7][SiO4](OH)
Unnamed (Mn3+-analogue of Ferriakasakaite-(Ce))(CaCe)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)
Vanadoallanite-(La)(CaLa)(V3+AlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m

Related Minerals - Strunz-mindat GroupingHide

9.BG.Shuiskite-(Cr)Ca2Cr3+Cr3+2[Si2O6OH][SiO4](OH)2OMon. 2/m : B2/m
9.BG.Alnaperbøeite-(Ce)Ca(Ce2.5Na0.5)(AlAl2Al)[Si2O7][SiO4]3O(OH)2Mon. 2/m : P21/m
9.BG.MagnesiovesuvianiteCa19MgAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9Tet. 4/m : P4/n
9.BG.AlumovesuvianiteCa19AlAl4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9Tet. 4/m : P4/n
9.BG.Zoisite-(Pb)(CaPb)(AlAlAl)O[Si2O7][SiO4](OH)Orth. mmm (2/m 2/m 2/m) : Pnma
9.BG.Vielleaureite-(Ce)(Mn2+Ce)(MgAlMn2+)F[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.Heflikite(CaCa)(AlAlSc)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.Zilbermintsite-(La)(CaLa5)(Fe3+Al3Fe2+)[Si2O7][SiO4]5O(OH)3Mon. 2/m : P21/m
9.BG.05bAllanite-(Ce)(CaCe)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(La)(CaLa)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(Y)(CaY)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon.
9.BG.05aClinozoisite(CaCa)(AlAlAl)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bDissakisite-(Ce)(CaCe)(AlAlMg)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Dollaseite-(Ce)(CaCe)(MgAlMg)F[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aEpidote(CaCa)(AlAlFe3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aHancockite(CaPb)(AlAlFe3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Khristovite-(Ce)(CaCe)(MgAlMn2+)F[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aMukhinite(CaCa)(AlAlV3+)O[Si2O7][SiO4](OH)Mon.
9.BG.05aPiemontite(CaCa)(AlAlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Piemontite-(Sr)(CaSr)(AlAlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bManganiandrosite-(La)(Mn2+La)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Tweddillite(CaSr)(Mn3+AlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bFerriallanite-(Ce)(CaCe)(Fe3+AlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Niigataite(CaSr)(AlAlAl)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Manganiandrosite-(Ce)(Mn2+Ce)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Dissakisite-(La)(CaLa)(AlAlMg)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Uedaite-(Ce)(Mn2+Ce)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05aEpidote-(Sr)(CaSr)(AlAlFe3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(Nd)(CaNd)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bUnnamed (Mg-analogue of Ferriallanite-(Ce))(CaCe)(Fe3+AlMg)O[Si2O7][SiO4](OH)
9.BG.05bUnnamed (Mn3+-analogue of Ferriakasakaite-(Ce))(CaCe)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)
9.BG.05bFerriallanite-(La)(CaLa)(Fe3+AlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bÅskagenite-(Nd)(Mn2+Nd)(AlAlFe3+)O[Si2O7][SiO4]OMon. 2/m : P21/m
9.BG.05Piemontite-(Pb)(CaPb)(AlAlMn3+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bVanadoallanite-(La)(CaLa)(V3+AlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bFerriakasakaite-(La)(CaLa)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Ferriandrosite-(La)(Mn2+La)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05Androsite-(Ce)(Mn2+Ce)(AlAlMn2+)O[Si2O7][SiO4](OH)
9.BG.05Ferriandrosite-(Ce)(Mn2+Ce)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05a vUnnamed (Ga-analogue of Epidote)(CaCa)(AlAlGa3+)O[Si2O7][SiO4](OH)
9.BG.05bUM1989-32-SiO:AlCaFeHREE(Ca0.50.5REE)(AlAlFe3+)O[Si2O7][SiO4](OH)
9.BG.05bManganiakasakaite-(La)(CaLa)(Mn3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bFerriakasakaite-(Ce)(CaCe)(Fe3+AlMn2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.05bAllanite-(Sm)(CaSm)(AlAlFe2+)O[Si2O7][SiO4](OH)Mon. 2/m : P21/m
9.BG.10Zoisite(CaCa)(AlAlAl)O[Si2O7][SiO4](OH)Orth. mmm (2/m 2/m 2/m) : Pnma
9.BG.15MacfalliteCa2Mn3+3(SiO4)(Si2O7)(OH)3Mon. 2/m : P21/m
9.BG.15SursassiteMn2+2Al3(SiO4)(Si2O7)(OH)3Mon. 2/m : P21/m
9.BG.20Julgoldite-(Fe2+)Ca2Fe2+Fe3+2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.20OkhotskiteCa2Mn2+Mn3+2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.20Pumpellyite-(Fe2+)Ca2Fe2+Al2(Si2O7)(SiO4)(OH,O)2 · H2OMon. 2/m
9.BG.20Pumpellyite-(Fe3+)Ca2Fe3+Al2(Si2O7)(SiO4)(OH,O)2 · H2OMon. 2/m
9.BG.20Pumpellyite-(Mg)Ca2MgAl2(Si2O7)(SiO4)(OH)2 · H2OMon. 2/m
9.BG.20Pumpellyite-(Mn2+)Ca2Mn2+Al2(Si2O7)(SiO4)(OH)2 · H2OMon. 2/m
9.BG.20Shuiskite-(Mg)Ca2MgCr3+2[Si2O6OH][SiO4](OH)2(OH)Mon. 2/m
9.BG.20Julgoldite-(Fe3+)Ca2Fe3+Fe3+2[Si2O6OH][SiO4](OH)2OMon.
9.BG.20Pumpellyite-(Al)Ca2Al3(Si2O7)(SiO4)(OH,O)2 · H2OMon. 2/m
9.BG.20PoppiiteCa2V3+V3+2[Si2O6OH][SiO4](OH)2OMon. 2/m : B2/m
9.BG.20Julgoldite-(Mg)Ca2MgFe3+2[Si2O6OH][SiO4](OH)2(OH)Mon.
9.BG.25GanomalitePb9Ca5Mn(Si2O7)4(SiO4)OHex. 6 : P6
9.BG.25WayneburnhamitePb9Ca6(Si2O7)3(SiO4)3Hex. 6 : P6
9.BG.30RustumiteCa10(Si2O7)2(SiO4)(OH)2Cl2Mon. 2/m : B2/b
9.BG.35VesuvianiteCa19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.35WiluiteCa19MgAl4(Al,Mg)8(B,◻)4◻[Si2O7]4[(SiO4)10]O(O,OH)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.35ManganvesuvianiteCa19Mn3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(OH)9Tet. 4/m : P4/n
9.BG.35FluorvesuvianiteCa19Fe3+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10]O(F,OH)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.35CyprineCa19Cu2+Al4(Al6Mg2)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9Tet. 4/m : P4/n
9.BG.35HongheiteCa19Fe2+Al4(Fe3+,Mg)8(◻4)B[Si2O7]4[(SiO4)10]O(OH,O)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.35Milanriederite(Ca18[REE])Fe3+Al4(Mg4Al4)(◻4)◻[Si2O7]4[(SiO4)10](OH)(OH)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.35Manaevite-(Ce)(Ca13Ce4[H2O]2)Mg(Al3Mg)(Mg3Ti3Fe3+2)(◻4)◻[Si2O7]4[(SiO4)8(H4O4)2]O(OH)9Tet. 4/mmm (4/m 2/m 2/m) : P4/nnc
9.BG.40Vyuntspakhkite-(Y)(Y,Yb)4Al2.5-1.5(Si,Al)1.5-2.5(SiO4)4O(OH)7Mon.
9.BG.45DellaiteCa6Si3O11(OH)2Tric.
9.BG.50Gatelite-(Ce)CaCe3(AlAl2Mg)[Si2O7][SiO4]3O(OH)2Mon. 2/m : P21/b
9.BG.50Perbøeite-(Ce)CaCe3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 Mon. 2/m : P21/m
9.BG.50Ferriperbøeite-(Ce)CaCe3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2Mon. 2/m : P21/m
9.BG.50Ferriperbøeite-(La) CaLa3(Fe3+Al2Fe2+)[Si2O7][SiO4]3O(OH)2Mon. 2/m : P21/m
9.BG.50Perbøeite-(La)CaLa3(AlAl2Fe2+)[Si2O7][SiO4]3O(OH)2 Mon. 2/m : P21/m
9.BG.55Västmanlandite-(Ce)CaCe3(MgAl2Mg)[Si2O7][SiO4]3F(OH)2Mon. 2/m : P21/m
9.BG.60Radekškodaite-(La) (CaLa5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3Mon. 2/m : P21/m
9.BG.60Radekškodaite-(Ce)(CaCe5)(Al4Fe2+)[Si2O7][SiO4]5O(OH)3Mon. 2/m : P21/m
9.BG.60Radekškodaite Group(CaM5)([Fe3+Al3]Fe2+)[Si2O7][SiO4]5O(OH)3

Other InformationHide

Notes:
Non-fluorescent under the electron beam.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for Vanadoandrosite-(Ce)Hide

References for Vanadoandrosite-(Ce)Hide

Localities for Vanadoandrosite-(Ce)Hide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
France (TL)
 
  • Occitanie
    • Hautes-Pyrénées
      • Bagnères-de-Bigorre
        • Vielle-Aure
Cenki-Tok et al. (2006) +1 other reference
 
and/or  
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