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Kerimasite

A valid IMA mineral species

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Photos of Kerimasite (2)

Search Photos of Kerimasite

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Kerimasite, etc.

Magnet Cove, Hot Spring County, Arkansas, USA

Kerimasite

Magnet Cove, Hot Spring County, Arkansas, USA

Kerimasite, etc.

Magnet Cove, Hot Spring County, Arkansas, USA

Kerimasite

Magnet Cove, Hot Spring County, Arkansas, USA

Kerimasite, etc.

Magnet Cove, Hot Spring County, Arkansas, USA

Kerimasite

Magnet Cove, Hot Spring County, Arkansas, USA

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About KerimasiteHide

Kerimasi volcano, Tanzania

Formula:

Ca₃Zr₂(SiO₄)(Fe³⁺O₄)₂

Colour:

light to dark brown

Lustre:

Vitreous

Hardness:

Specific Gravity:

4.105 (Calculated)

Crystal System:

Isometric

Member of:

Schorlomite Group > Garnet Supergroup

Name:

Named for the Kerimasi volcano, Tanzania, the type locality.

Type Locality:

ⓘ Kerimasi volcano, Monduli District, Arusha Region, Tanzania

Ferric iron analogue of kimzeyite and Zr-analogue of toturite.

Unique IdentifiersHide

Mindat ID:

39563

Long-form identifier:

mindat:1:1:39563:0

GUID
(UUID V4):

85aeb65d-fb01-4c77-9e5e-1131e0636f96

IMA Classification of KerimasiteHide

IMA status:

Approved

IMA Formula:

Ca₃Zr₂(SiFe³⁺₂)O₁₂

Approval year:

2009

First published:

2010

Type description reference:

Zaitsev, A. N., Williams, C. T., Britvin, S. N., Kuznetsova, I. V., Spratt, J., Petrov, S. V., Keller, J. (2010) Kerimasite, Ca₃Zr₂(Fe₂³⁺Si)O₁₂, a new garnet from carbonatites of Kerimasi volcano and surrounding explosion craters, northern Tanzania. Mineralogical Magazine, 74 (5) 803-820 doi:10.1180/minmag.2010.074.5.803

Classification of KerimasiteHide

Strunz-mindat (2024):

9.AD.25

9 : SILICATES (Germanates)
A : Nesosilicates
D : Nesosilicates without additional anions; cations in [6] and/or greater coordination

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference
Kms	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of KerimasiteHide

Lustre:

Vitreous

Transparency:

Transparent

Colour:

light to dark brown

Hardness:

7 on Mohs scale

Hardness:

VHN₂₅=1168 - 1288 kg/mm² - Vickers

Tenacity:

Brittle

Cleavage:

None Observed

Parting:

Not observed.

Density:

4.105(1) g/cm³ (Calculated)

Optical Data of KerimasiteHide

Type:

Isotropic

RI values:

n = 1.945(5)

Birefringence:

Isotropic minerals have no birefringence

Surface Relief:

Very High

Comments:

Yellowish-greenish colour
Optically heterogeneous, isotropic to anisotropic

Chemistry of KerimasiteHide

Mindat Formula:

Ca₃Zr₂(SiO₄)(Fe³⁺O₄)₂

Elements listed:

Ca, Fe, O, Si, Zr - search for minerals with similar chemistry

Crystallography of KerimasiteHide

Crystal System:

Isometric

Class (H-M):

m3m (4/m 3 2/m) - Hexoctahedral

Space Group:

Ia3d

Setting:

Ia3d

Cell Parameters:

a = 12.549(1) Å

Unit Cell V:

1976.2 Å³

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Year	Locality	Temp (K)
0014052	Kerimasite	Whittle K R, Lumpkin G R, Berry F J, Oates G, Smith K L, Yudintsev S, Zaluzec N J (2007) The structure and ordering of zirconium and hafnium containing garnets studied by electron channelling, neutron diffraction and Mossbauer spectroscopy Journal of Solid State Chemistry 180 785-791	2007	synthetic	293
0014052	Kerimasite	Whittle K R, Lumpkin G R, Berry F J, Oates G, Smith K L, Yudintsev S, Zaluzec N J (2007) The structure and ordering of zirconium and hafnium containing garnets studied by electron channelling, neutron diffraction and Mossbauer spectroscopy Journal of Solid State Chemistry 180 785-791	2007	synthetic	293
0018324	Kerimasite	Zaitsev A N, Williams C T, Britvin S N, Kuznetsova I V, Spratt J, Petrov S V, Keller J (2010) Kerimasite, Ca3Zr2(Fe3+2Si)O12, a new garnet from carbonatites of Kerimasi volcano and surrounding explosion craters, northern Tanzania Mineralogical Magazine 74 803-820	2010	Kerimasi volcano, Tanzania	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Kerimasite'
loop_
_publ_author_name
'Whittle K R'
'Lumpkin G R'
'Berry F J'
'Oates G'
'Smith K L'
'Yudintsev S'
'Zaluzec N J'
_journal_name_full 'Journal of Solid State Chemistry'
_journal_volume 180 
_journal_year 2007
_journal_page_first 785
_journal_page_last 791
_publ_section_title
;
 The structure and ordering of zirconium and hafnium containing garnets studied
 by electron channelling, neutron diffraction and Mossbauer spectroscopy
;
_database_code_amcsd 0014052
_chemical_compound_source 'Synthetic'
_chemical_formula_sum 'Ca3 Zr2 Fe1.95 Si.93 O12'
_cell_length_a 12.6164
_cell_length_b 12.6164
_cell_length_c 12.6164
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 2008.197
_exptl_crystal_density_diffrn      4.165
_symmetry_space_group_name_H-M 'I a 3 d'
loop_
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  '3/4-x,1/4+z,3/4+y'
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  '1/4+z,3/4-y,1/4-x'
  '3/4-y,1/4+x,3/4+z'
  '1/4-y,3/4+x,1/4+z'
  '1/4+x,1/4+z,1/4+y'
  '3/4+x,3/4+z,3/4+y'
  '1/4-z,1/4-y,1/4-x'
  '3/4-z,3/4-y,3/4-x'
  '1/4+y,1/4+x,1/4+z'
  '3/4+y,3/4+x,3/4+z'
  '1/4-x,1/4-z,1/4-y'
  '3/4-x,3/4-z,3/4-y'
  '1/4+z,1/4+y,1/4+x'
  '3/4+z,3/4+y,3/4+x'
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  '+z,-x,1/2-y'
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  '+x,-y,1/2-z'
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  '1/4-x,1/4+z,3/4-y'
  '3/4+z,3/4-y,1/4+x'
  '1/4+z,1/4-y,3/4+x'
  '3/4-y,3/4+x,1/4-z'
  '1/4-y,1/4+x,3/4-z'
  '3/4+x,3/4-z,1/4+y'
  '1/4+x,1/4-z,3/4+y'
  '3/4-z,3/4+y,1/4-x'
  '1/4-z,1/4+y,3/4-x'
  '3/4+y,3/4-x,1/4+z'
  '1/4+y,1/4-x,3/4+z'
  '1/4-x,3/4-z,3/4+y'
  '3/4-x,1/4-z,1/4+y'
  '1/4+z,3/4+y,3/4-x'
  '3/4+z,1/4+y,1/4-x'
  '1/4-y,3/4-x,3/4+z'
  '3/4-y,1/4-x,1/4+z'
  '1/4+x,3/4+z,3/4-y'
  '3/4+x,1/4+z,1/4-y'
  '1/4-z,3/4-y,3/4+x'
  '3/4-z,1/4-y,1/4+x'
  '1/4+y,3/4+x,3/4-z'
  '3/4+y,1/4+x,1/4-z'
  '-z,-x,-y'
  '1/2-z,1/2-x,1/2-y'
  'y,z,x'
  '1/2+y,1/2+z,1/2+x'
  '-x,-y,-z'
  '1/2-x,1/2-y,1/2-z'
  'z,x,y'
  '1/2+z,1/2+x,1/2+y'
  '-y,-z,-x'
  '1/2-y,1/2-z,1/2-x'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
Ca   0.12500   0.00000   0.25000   1.00000   0.00830
Zr   0.00000   0.00000   0.00000   1.00000   0.00630
Fe   0.37500   0.00000   0.25000   0.65000   0.00570
Si   0.37500   0.00000   0.25000   0.31000   0.00570
O  -0.03318   0.05152   0.15365   1.00000   0.01270

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
4.441 Å	(41)
3.140 Å	(91)
2.808 Å	(70)
2.564 Å	(93)
1.985 Å	(21)
1.741 Å	(26)
1.677 Å	(100)
1.403 Å	(17)

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 4b: Highly evolved igneous rocks	>3.0
36 : Carbonatites, kimberlites, and related igneous rocks

Type Occurrence of KerimasiteHide

Type Locality:

ⓘ Kerimasi volcano, Monduli District, Arusha Region, Tanzania

General Appearance of Type Material:

subhedral crystals up to 100 µm in calcite carbonatites; euhedral to subhedral crystals up to 180 µm in carbonatite eluvium.

Place of Conservation of Type Material:

1) Natural History Museum, London, UK (catalogue BM.1995,P6(47) and BM.1995,P6(22))
2) Mineralogical Museum, Department of Mineralogy, Faculty of Geology, St. Petersburg State University, St. Petersburg, Russia (catalogue number 1/19363)

Geological Setting of Type Material:

Calcite carbonatites; carbonatite eluvium.

Associated Minerals at Type Locality:

Pyrochlore Group	Magnesioferrite	Forsterite	Fluorapatite	Calcite
Baddeleyite

Reference:

Zaitsev, A.N., Williams, C.T., Britvin, S.N., Kuznetsova, I.V., Spratt, J., Petrov, S.V., and Keller, J. (2010) Kerimasite, Ca3Zr2(Fe3+2Si)O12, a new garnet from carbonatites of Kerimasi volcano and surrounding explosion craters, northern Tanzania. Mineralogical Magazine: 74(5): 803-820.

Download:

https://rruff.info/rruff_1.0/uploads/MM74_803.pdf

Synonyms of KerimasiteHide

IMA2009-029

Other Language Names for KerimasiteHide

German:Kerimasit

Japanese:ケリマシ石

Spanish:Kerimasita

Relationship of Kerimasite to other SpeciesHide

Member of:

Schorlomite Group > Garnet Supergroup

Other Members of this group:

Hutcheonite	Ca₃Ti₂(SiO₄)(AlO₄)₂	Iso. m3m (4/m 3 2/m) : Ia3d
Irinarassite	Ca₃Sn₂(SiO₄)(AlO₄)₂	Iso. m3m (4/m 3 2/m) : Ia3d
Kimzeyite	Ca₃Zr₂(SiO₄)(AlO₄)₂	Iso. m3m (4/m 3 2/m) : Ia3d
Schorlomite	Ca₃Ti₂(SiO₄)(Fe³⁺O₄)₂	Iso. m3m (4/m 3 2/m) : Ia3d
Toturite	Ca₃Sn₂(SiO₄)(Fe³⁺O₄)₂	Iso. m3m (4/m 3 2/m) : Ia3d

Common AssociatesHide

Associated Minerals Based on Photo Data:

1 photo of Kerimasite associated with Perovskite

CaTiO₃

Related Minerals - Strunz-mindat Grouping Hide

9.AD.	Adrianite	Ca₁₂(Al₄Mg₃Si₇)O₃₂Cl₆	Iso. 4 3m : I4 3d
9.AD.05	Larnite	Ca₂SiO₄	Mon. 2/m
9.AD.10	Calcio-olivine	Ca₂SiO₄	Orth. mmm (2/m 2/m 2/m)
9.AD.15	Merwinite	Ca₃Mg(SiO₄)₂	Mon. 2/m : P2₁/b
9.AD.20	Bredigite	Ca₇Mg(SiO₄)₄	Orth. mm2 : Pnn2
9.AD.25	Andradite	Ca₃Fe³⁺₂(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Almandine	Fe²⁺₃Al₂(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Calderite	Mn²⁺₃Fe³⁺₂(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Goldmanite	Ca₃V³⁺₂(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Grossular	Ca₃Al₂(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Henritermierite	Ca₃Mn³⁺₂(SiO₄)₂[◻(OH)₄]	Tet. 4/mmm (4/m 2/m 2/m) : I4₁/acd
9.AD.25	Kimzeyite	Ca₃Zr₂(SiO₄)(AlO₄)₂	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Knorringite	Mg₃Cr₂(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Majorite	Mg₃(MgSi)(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Morimotoite	Ca₃(TiFe²⁺)(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Pyrope	Mg₃Al₂(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Schorlomite	Ca₃Ti₂(SiO₄)(Fe³⁺O₄)₂	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Spessartine	Mn²⁺₃Al₂(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Uvarovite	Ca₃Cr₂(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Wadalite	(Ca,Mg)₆(Al,Fe³⁺)₄((Si,Al)O₄)₃O₄Cl₃	Iso. 4 3m : I4 3d
9.AD.25 va	Hydrougrandite	(Ca,Mg,Fe²⁺)₃(Fe³⁺,Al)₂[(OH)₄(SiO₄)₂]	Iso.
9.AD.25 va	Yamatoite	(Mn²⁺,Ca)₃(V³⁺,Al)₂(SiO₄)₃	Iso.
9.AD.25	Holtstamite	Ca₃Al₂(SiO₄)₂[◻(OH)₄]	Tet. 4/mmm (4/m 2/m 2/m) : I4₁/acd
9.AD.25	Khoharite	Mg₃Fe³⁺₂(SiO₄)₃
9.AD.25	Toturite	Ca₃Sn₂(SiO₄)(Fe³⁺O₄)₂	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Momoiite	Mn²⁺₃V³⁺₂(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Eringaite	Ca₃Sc₂(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Irinarassite	Ca₃Sn₂(SiO₄)(AlO₄)₂	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Menzerite-(Y)	(Y₂Ca)Mg₂(SiO₄)₃	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	Eltyubyuite	Ca₁₂Fe³⁺₁₀Si₄O₃₂Cl₆	Iso. 4 3m : I4 3d
9.AD.25	Blythite	Mn²⁺₃Mn³⁺₂[SiO₄]₃
9.AD.25	Skiagite	Fe²⁺₃Fe³⁺₂[SiO₄]₃
9.AD.25	Hutcheonite	Ca₃Ti₂(SiO₄)(AlO₄)₂	Iso. m3m (4/m 3 2/m) : Ia3d
9.AD.25	UM1984-37-SiO:CrMn	Mn²⁺₃Cr³⁺₂(SiO₄)₃
9.AD.25	Rubinite	Ca₃Ti³⁺₂Si₃O₁₂	Iso.
9.AD.25	Nikmelnikovite	Ca₁₂(Fe²⁺Fe³⁺₃Al₃◻)[SiO₄]₆[◻(OH)₄]₅◻₄	Trig. 3 : R3
9.AD.30 va	Auerlite	near Th(Si,P)O₄
9.AD.30	Coffinite	U(SiO₄) · nH₂O	Tet. 4/mmm (4/m 2/m 2/m) : I4₁/amd
9.AD.30	Hafnon	HfSiO₄	Tet. 4/mmm (4/m 2/m 2/m) : I4₁/amd
9.AD.30	Thorite	Th(SiO₄)	Tet. 4/mmm (4/m 2/m 2/m) : I4₁/amd
9.AD.30	Zircon	Zr(SiO₄)	Tet. 4/mmm (4/m 2/m 2/m) : I4₁/amd
9.AD.30	Stetindite-(Ce)	Ce(SiO₄)	Tet. 4/mmm (4/m 2/m 2/m) : I4₁/amd
9.AD.35	Huttonite	ThSiO₄	Mon. 2/m
9.AD.35	Tombarthite-(Y)	Y₄(Si,H₄)₄O_12-x(OH)_4+2x	Mon.
9.AD.40	Eulytine	Bi₄(SiO₄)₃	Iso. 4 3m : I4 3d
9.AD.45	Reidite	ZrSiO₄	Tet. 4/m : I4₁/a
9.AD.55	Jeffbenite	Mg₃Al₂Si₃O₁₂	Tet. 4 2m : I4 2d

Other InformationHide

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for KerimasiteHide

mindat.org URL:

https://www.mindat.org/min-39563.html
Please feel free to link to this page.

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External Links:

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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References for KerimasiteHide

Reference List:

Uher, Pavel, Milovská, Stanislava, Milovský, Rastislav, Koděra, Peter, Bačík, Peter, Bilohuščin, Vladimír (2015) Kerimasite, {Ca₃}[Zr₂](SiFe³⁺₂)O₁₂ garnet from the Vysoká-Zlatno skarn, Štiavnica stratovolcano, Slovakia. Mineralogical Magazine, 79 (3) 715-733 doi:10.1180/minmag.2015.079.3.15

(2023) Kerimasite. Handbook of Mineralogy. Mineralogical Society of America

Localities for KerimasiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Germany
Rhineland-Palatinate Mayen-Koblenz Vordereifel Ettringen ⓘ Caspar quarry	EMPA data
ⓘ Wernerkrauseite-bearing xenolith	Galuskin et al. (2016)
ⓘ Xenolith CS-029	in the collection of Christof Schäfer
ⓘ Xenolith CS-034 (Alfredcasparite bearing xenolith)	in the collection of Christof Schäfer
ⓘ Xenolith CS-036 (Vondechenite-bearing xenolith)	in the collection of Christof Schäfer
Vulkaneifel Daun Üdersdorf ⓘ Emmelberg	Blaß et al. (2014)

Israel
Southern District (HaDarom District) Tamar Regional Council Hatrurim Basin ⓘ Aravaite type locality	doi:10.3390/min8030109. +1 other reference

Russia
Irkutsk Oblast Narin-Kunta ⓘ Birkhin gabbro massif (Ozernovskii)	Lazic et al. (2011)
Kabardino-Balkaria Baksan Valley ⓘ Upper Chegem volcanic caldera (Verkhnechegemskaya caldera)	Bailau +1 other reference
Lakargi Mountain ⓘ Xenolith no. 1	Galuskina et al. (2015)
ⓘ Xenolith no. 3	Galuskin et al. (2011)
ⓘ Xenolith no. 7	Galuskina et al. (2013)

Slovakia
Banská Bystrica Region Banská Štiavnica District Vysoká ⓘ Zlatno	Uher P. et al. (2012) +1 other reference

Tanzania (TL)
Arusha Region Monduli District ⓘ Kerimasi volcano (TL)	Zaitsev et al. (2010)
ⓘ Kisete crater	Zaitsev et al. (2010)
ⓘ Loolmurwak crater	Zaitsev et al. (2010)

USA
Arkansas Hot Spring County ⓘ Magnet Cove	Mikail Murashko

Kerimasite

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