Saléeite
A valid IMA mineral species - grandfathered
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About Saléeite
Formula:
Mg(UO2)2(PO4)2 · 10H2O
Colour:
Lemon-yellow, straw-yellow, greenish yellow
Lustre:
Sub-Adamantine, Sub-Vitreous, Resinous, Waxy
Hardness:
2 - 3
Specific Gravity:
3.27
Crystal System:
Monoclinic
Member of:
Name:
Named in 1932 by Jacques Thoreau and Johannes F. Vaes in honor of canon Achille Léon Salée [September 6, 1883 Spa, Belgium - March 13, 1932 Isavi, Ruanda (not, as some sources say, in Astrida, Belgium)], Professor at Universitè Catholique de Louvain, Louvain, Belgium. Salée was a geologist and systematic paleontologist. He authored a geologic map of Rwanda. A river in the Democratic Republic of the Congo is named for him as is a street in his home town of Spa.
Isostructural with:
Autunite Group. The phosphate analogue of nováčekite-II. Chemically similar to metasaléeite (the lower hydrate), and the two minerals are the only ones with the Mg-U-P combination.
A secondary mineral occurring in the oxidized zones of uranium-bearing polymetallic hydrothermal, and sedimentary, mineral deposits.
A secondary mineral occurring in the oxidized zones of uranium-bearing polymetallic hydrothermal, and sedimentary, mineral deposits.
Unique Identifiers
Mindat ID:
3508
Long-form identifier:
mindat:1:1:3508:4
GUID
(UUID V4):
(UUID V4):
f799bb26-5a34-49fc-9b67-58d6363dc929
IMA Classification of Saléeite
Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
Mg(UO2)2(PO4)2(H2O)10
Classification of Saléeite
8.EB.05
8 : PHOSPHATES, ARSENATES, VANADATES
E : Uranyl phosphates and arsenates
B : UO2:RO4 = 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
E : Uranyl phosphates and arsenates
B : UO2:RO4 = 1:1
40.2a.11.1
40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
2a : AB2(XO4)2·xH2O, containing (UO2)2+
40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
2a : AB2(XO4)2·xH2O, containing (UO2)2+
19.11.12
19 : Phosphates
11 : Phosphates of U
19 : Phosphates
11 : Phosphates of U
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Slé | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Saléeite
Sub-Adamantine, Sub-Vitreous, Resinous, Waxy
Transparency:
Transparent, Translucent, Opaque
Colour:
Lemon-yellow, straw-yellow, greenish yellow
Streak:
Yellow-white
Hardness:
2 - 3 on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
[001] Perfect, [010] Indistinct, [110] Indistinct
[001] Perfect, [010] Indistinct, [110] Indistinct
Fracture:
Micaceous
Density:
3.27 g/cm3 (Measured) 3.21 g/cm3 (Calculated)
Optical Data of Saléeite
Type:
Biaxial (-)
RI values:
nα = 1.554 - 1.559 nβ = 1.570 - 1.582 nγ = 1.571 - 1.585 nω = 1.571 - 1.585 nε = 1.544 - 1.565
Birefringence:
0.017
Max Birefringence:
δ = 0.027
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Low
Pleochroism:
Visible
Comments:
X = Colourless
Z = Pale greenish yellow
Z = Pale greenish yellow
Comments:
Typically nearly uniaxial -, sectored.
Chemistry of Saléeite
Mindat Formula:
Mg(UO2)2(PO4)2 · 10H2O
Crystallography of Saléeite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 6.951(1) Å, b = 19.942(1) Å, c = 6.967(1) Å
β = 90.58(1)°
β = 90.58(1)°
Ratio:
a:b:c = 0.349 : 1 : 0.349
Unit Cell V:
965.69 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Saleeite is pseudotetragonal, the last few water molecules distort the structure. Forms square plates, composite, flattened on {001}, and exhibiting {001}, {100}, {120}, and {012}. Subparallel lamellar aggregates common.
Comment:
P21/n; originally given cell: a = 6.951, b = 19.947, c = 9.896 Å, β = 135.17°. The structure consists of UO2PO4 sheets between which are located Mg2+ ions and water molecules. The Mg2+ ions are octahedrally coordinated to 6 of the 10 interlayer waters, but the last 4 water molecules are not bound to Mg.
Epitaxial Relationships of Saléeite
Epitaxial Minerals:
Torbernite | Cu(UO2)2(PO4)2 · 12H2O |
Epitaxy Comments:
Oriented growths on Torbernite with parallel axes.
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
9.85 Å | (100) |
4.95 Å | (80) |
4.51 Å | (40) |
3.49 Å | (90) |
3.23 Å | (50) |
2.95 Å | (50) |
2.45 Å | (60) |
2.19 Å | (70) |
Comments:
ICDD 8-313. See also 29-874 (synthetic)
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 7: Great Oxidation Event | <2.4 |
47a : [Near-surface hydration of prior minerals] | |
47c : [Carbonates, phosphates, borates, nitrates] | |
47f : [Uranyl (U⁶⁺) minerals] |
Geological Setting:
Oxidation zone of polymetallic uranium-bearing hydrothermal deposits and sedimentary uranium deposits.
Type Occurrence of Saléeite
Place of Conservation of Type Material:
Catholic University of Louvain, Louvain-la-Neuve, Belgium: #HT:K 1.812.
Associated Minerals at Type Locality:
Synonyms of Saléeite
Other Language Names for Saléeite
Relationship of Saléeite to other Species
Member of:
Other Members of this group:
Autunite | Ca(UO2)2(PO4)2 · 10-12H2O | Orth. mmm (2/m 2/m 2/m) : Pnma |
Bassetite | Fe2+(UO2)2(PO4)2 · 10H2O | Mon. 2/m |
Heinrichite | Ba(UO2)2(AsO4)2 · 10H2O | Mon. 2/m : P2/b |
Hydronováčekite | Mg(UO2)2(AsO4)2 · 12H2O | Tric. 1 : P1 |
Kahlerite | Fe(UO2)2(AsO4)2 · 12H2O | Tet. 4/m : P42/n |
Nováčekite | Mg(UO2)2(AsO4)2 · 10H2O | Mon. 2/m |
Rauchite | Ni(UO2)2(AsO4)2 · 10H2O | Tric. 1 : P1 |
Sabugalite | HAl(UO2)4(PO4)4 · 16H2O | Mon. 2/m : B2/m |
Torbernite | Cu(UO2)2(PO4)2 · 12H2O | Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm |
Uranocircite | Ba(UO2)2(PO4)2 · 10H2O | Tet. |
Uranospinite | Ca(UO2)2(AsO4)2 · 10H2O | Tet. 4/mmm (4/m 2/m 2/m) : P4/nmm |
Zeunerite | Cu(UO2)2(AsO4)2 · 12H2O | Tet. 4/mmm (4/m 2/m 2/m) : I4/mmm |
Common Associates
Associated Minerals Based on Photo Data:
20 photos of Saléeite associated with Torbernite | Cu(UO2)2(PO4)2 · 12H2O |
13 photos of Saléeite associated with Leucophosphite | KFe3+2(PO4)2(OH) · 2H2O |
11 photos of Saléeite associated with Cyrilovite | NaFe3+3(PO4)2(OH)4 · 2H2O |
8 photos of Saléeite associated with Metatorbernite | Cu(UO2)2(PO4)2 · 8H2O |
6 photos of Saléeite associated with Wulfenite | Pb(MoO4) |
6 photos of Saléeite associated with Variscite | AlPO4 · 2H2O |
6 photos of Saléeite associated with Quartz | SiO2 |
5 photos of Saléeite associated with Autunite | Ca(UO2)2(PO4)2 · 10-12H2O |
4 photos of Saléeite associated with Orthoclase | K(AlSi3O8) |
4 photos of Saléeite associated with Phosphosiderite | FePO4 · 2H2O |
Related Minerals - Strunz-mindat Grouping
8.EB. | Meta-autunite Group | A1-2(UO2)2(TO4)2 · 5-10H2O |
8.EB.05 | Autunite | Ca(UO2)2(PO4)2 · 10-12H2O |
8.EB.05 | Heinrichite | Ba(UO2)2(AsO4)2 · 10H2O |
8.EB.05 | Kahlerite | Fe(UO2)2(AsO4)2 · 12H2O |
8.EB.05 | Hydronováčekite | Mg(UO2)2(AsO4)2 · 12H2O |
8.EB.05 | Torbernite | Cu(UO2)2(PO4)2 · 12H2O |
8.EB.05 | Uranocircite | Ba(UO2)2(PO4)2 · 10H2O |
8.EB.05 | Uranospinite | Ca(UO2)2(AsO4)2 · 10H2O |
8.EB.05 | Xiangjiangite | (Fe3+,Al)(UO2)4(PO4)2(SO4)2(OH) · 22H2O |
8.EB.05 | Zeunerite | Cu(UO2)2(AsO4)2 · 12H2O |
8.EB.05 | Metarauchite | Ni(UO2)2(AsO4)2 · 8H2O |
8.EB.05 | Nováčekite | Mg(UO2)2(AsO4)2 · 10H2O |
8.EB.05 | Rauchite | Ni(UO2)2(AsO4)2 · 10H2O |
8.EB.10 | Bassetite | Fe2+(UO2)2(PO4)2 · 10H2O |
8.EB.10 | Lehnerite | Mn2+(UO2)2(PO4)2 · 8H2O |
8.EB.10 | Meta-autunite | Ca(UO2)2(PO4)2 · 6H2O |
8.EB.10 | Metasaléeite | Mg(UO2)2(PO4)2 · 8H2O |
8.EB.10 | Metauranocircite | Ba(UO2)2(PO4)2 · 7H2O |
8.EB.10 | Metauranospinite | Ca(UO2)2(AsO4)2 · 8H2O |
8.EB.10 | Metaheinrichite | Ba(UO2)2(AsO4)2 · 8H2O |
8.EB.10 | Metakahlerite | Fe2+(UO2)2(AsO4)2 · 8H2O |
8.EB.10 | Metakirchheimerite | Co(UO2)2(AsO4)2 · 8H2O |
8.EB.10 | Metanováčekite | Mg(UO2)2(AsO4)2 · 8H2O |
8.EB.10 | Metatorbernite | Cu(UO2)2(PO4)2 · 8H2O |
8.EB.10 | Metazeunerite | Cu(UO2)2(AsO4)2 · 8H2O |
8.EB.10 | Przhevalskite | Pb2(UO2)3(PO4)2(OH)4 · 3H2O |
8.EB.10 | Pseudo-autunite | (H3O)4Ca2(UO2)2(PO4)4 · 5H2O |
8.EB.10 | Metanatroautunite | Na(UO2)(PO4)(H2O)3 |
8.EB.15 | Abernathyite | K(UO2)(AsO4) · 3H2O |
8.EB.15 | Chernikovite | (H3O)2(UO2)2(PO4)2 · 6H2O |
8.EB.15 | Meta-ankoleite | K2(UO2)2(PO4)2 · 6H2O |
8.EB.15 | Natrouranospinite | Na2(UO2)2(AsO4)2 · 5H2O |
8.EB.15 | Trögerite | (H3O)(UO2)(AsO4) · 3H2O |
8.EB.15 | Uramphite | (NH4)2(UO2)2(PO4)2 · 6H2O |
8.EB.15 | Uramarsite | (NH4)(UO2)(AsO4) · 3H2O |
8.EB.20 | Threadgoldite | Al(UO2)2(PO4)2(OH) · 8H2O |
8.EB.20 | Chistyakovaite | Al(UO2)2(AsO4)2(F,OH) · 6.5H2O |
8.EB.25 | Arsenuranospathite | Al(UO2)2(AsO4)2F · 20H2O |
8.EB.25 | Uranospathite | (Al,◻)(UO2)2(PO4)2F · 20(H2O,F) |
8.EB.30 | Vochtenite | (Fe2+,Mg)Fe3+(UO2)4(PO4)4(OH) · 12-13H2O |
8.EB.35 | Coconinoite | Fe3+2Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2O |
8.EB.40 | Ranunculite | HAl(UO2)(PO4)(OH)3 · 4H2O |
8.EB.45 | Triangulite | Al3(UO2)4(PO4)4(OH)5 · 5H2O |
8.EB.50 | Furongite | Al13(UO2)7(PO4)13(OH)14 · 58H2O |
8.EB.55 | Sabugalite | HAl(UO2)4(PO4)4 · 16H2O |
8.EB.60 | Horákite | (Bi7O7OH)[(UO2)4(PO4)2(AsO4)2(OH)2] · 3.5H2O |
Fluorescence of Saléeite
Bright lemon-yellow (LW UV); pale yellow (SW UV).
Other Information
Notes:
Radioactive.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Saléeite
mindat.org URL:
https://www.mindat.org/min-3508.html
Please feel free to link to this page.
Please feel free to link to this page.
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External Links:
Mineral Dealers:
References for Saléeite
Reference List:
Mrose, Mary E. (1950) Studies on uranium minerals (III): Saléeite from Schneeberg, Saxon. American Mineralogist, 35 (7-8) 525-530
(1958) Systematic mineralogy of uranium and thorium. Bulletin Vol. 1064. US Geological Survey doi:10.3133/b1064 pp.177-183
Piret, Paul, Deliens, Michel (1980) Nouvelles données sur la saléeite holotype de Shinkolobwe. Bulletin de Minéralogie, 103 (6) 630-632 doi:10.3406/bulmi.1980.7430
Miller, S. A., Taylor, J. C. (1986) The crystal structure of saleeite, Mg[UO2PO4]2· 10H2O. Zeitschrift für Kristallographie - Crystalline Materials, 177 (3) 247-253 doi:10.1524/zkri.1986.177.3-4.247
Burns, Peter C. (2005) U6+ minerals and inorganic compounds: insights into an expanded structural hierarchy of crystal structures. The Canadian Mineralogist, 43 (6) 1839-1894 doi:10.2113/gscanmin.43.6.1839
Localities for Saléeite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Argentina | |
| O. Morello y C. N. Reyes Encinas (1990) |
O. Morello y C. N. Reyes Encinas (1990) | |
M. E. Saulnier y F. Greco (1988) | |
Australia | |
| |
Geosciences +1 other reference | |
D A Berkman (1968) | |
D.A.Berkman (1968) | |
| Economic Geology of Australia and papua ... |
Waite & Payne (1993) +2 other references | |
Henry et al (1999) +2 other references | |
Henry et al. (1999) | |
| P Haas collection |
Henry et al. (2005) | |
| Uwe Kolitsch (powder X-ray diffraction & SEM-EDS) |
| W.D.Birch. Phosphate Minerals of ... |
| Henry et al. (1988) +3 other references |
| Judy Rowe collection |
Austria | |
| F. Brandstätter (1998) |
Brazil | |
| Cassedanne et al. (1982) |
Baijot et al. (2014) | |
Sergio Varvello collection +1 other reference | |
Atencio et al. (2004) | |
| Tony Nikischer |
| Cassedanne et al. (1981) |
| Sergio Varvello collection |
Cassedanne et al. (1999) | |
| Chukanov et al. (2007) |
Luis Menezes +1 other reference | |
Sergio Varvello collection | |
| Sergio Varvello collection |
Canada | |
| BOYLE et al. (1981) |
| Carruzzo (2003) |
Czech Republic | |
| Pauliš P. et al. (Kutna Hora, issue 1) |
| Plášil J. et al. (Giant) +2 other references |
| Pauliš (1999) |
Sejkora et al. (2012) | |
| M.E. Ciriotti |
| Sejkora |
| Jakub Kristek Collection |
Jakub Kristek Collection | |
DR Congo (TL) | |
| Thoreau et al. (1932) +4 other references |
| In the collection of Chuck Adan. EDS by ... |
| Wilson (2018) |
| |
France | |
| - (1998) |
R. Pierrot | |
R. Pierrot +1 other reference | |
| AFM 1-2002 |
| AFM 1-2002 p.17 |
| Jean-Marc Johannet collection |
| Collection Laurent GAYRAUD |
| - (1998) |
| Caubel (1997) |
| [Le Cahier des Micromonteurs |
| - (1998) |
Germany | |
| Walenta (1998) |
| Walenta (1992) |
| DILL et al. (1986) +2 other references |
| Dill et al. (2010) |
| Schnorrer (1995) +1 other reference |
| Mrose (1950) |
Massanek et al. (2005) | |
| T. Witzke & F. Rüger: Lapis 1998 (7/8) |
Hungary | |
| Szakáll Sándor et al. (2016) +1 other reference |
| Koch: Minerals of Hungary |
| Szakáll:Minerals of Hungary |
Italy | |
| Vignola P. et al. (2011) |
| Guastoni A. et al. (2016) |
| Garavelli et al. (1959) +2 other references |
| Ref: Daniele Ravagnani - I giacimenti ... +1 other reference |
| EDS G. Blass (M.E. Ciriotti, 2007) |
| Ravagnani (1974) |
New Zealand | |
| Christie et al. (2000) |
Poland | |
| Siuda R. (Rudawy Janowickie Mts., Poland) |
| Syczewski et al. (2023) |
Syczewski et al. (2023) +1 other reference | |
Domańska-Siuda J. 2010: New data on secondary uranium minerals from the Western Sudetes (Poland) +1 other reference | |
Portugal | |
| International Geological Congress (2008) |
| Cabral Pinto (2008) |
| |
| LNEG - Laboratório Nacional de Energia ... |
| LNEG Siorminp database |
| LNEG / Siorminp database +1 other reference |
| |
| Pavel M. Kartashov analytical data |
Romania | |
| Hîrtopanu P. et al. (2004) |
Slovakia | |
| Ferenc Š. et al. (2019) |
Slovenia | |
| Dolenec (1985) |
Spain | |
| Arribas (1962) |
| Carles Curto Mila collection |
| Grupo Mineralogista de Madrid (1994) |
| Pierre Cléroux Collection |
www.foro-minerales.com (n.d.) | |
| www.foro-minerales.com (n.d.) |
| Calvo Rebollar (2015) |
UK | |
| Golley et al. (1995) |
| Golley et al. (1995) |
| Golley et al. (1995) |
| Golley et al. (1995) |
| Alysson Rowan collection |
USA | |
| Granger (1969) +1 other reference |
| Granger (1969) +1 other reference |
| Eckel et al. (1997) |
| Eckel et al. (1997) |
| Castor et al. (2004) |
Castor et al. (2004) | |
| Northrop et al. (1996) |
| Northrop et al. (1996) |
| Nevada Bureau of Mines and Geology NBMG ... |
| Roberts et al. (1965) |
| Roberts et al. (1965) |
Roberts et al. (1965) | |
| Rocks & Minerals: 68 (6) |
| Bullock (1981) |
Uzbekistan | |
| Pavel.M. Kartashov (n.d.) |
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La Commanderie mine, Le Temple, Mauléon, Bressuire, Deux-Sèvres, Nouvelle-Aquitaine, France