Leucophosphite
A valid IMA mineral species - grandfathered
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About Leucophosphite
Formula:
KFe3+2(PO4)2(OH) · 2H2O
Colour:
White to greenish, buff, yellow-brown, orange-brown, pink, greenish brown, brownish purple
Lustre:
Sub-Vitreous, Resinous, Earthy
Hardness:
3½
Specific Gravity:
2.948
Crystal System:
Monoclinic
Member of:
Name:
Named in 1932 by Edward Sydney Simpson from the Greek word "LEUCO" meaning "white" and the prefix PHOSPHate, in allusion to its colour and composition as a phosphate.
Type Locality:
Isostructural with:
Leucophosphite Group.
The Fe3+ analogue of tinsleyite.
Originally phosphate formed by the action of solutions derived from bird or bat guano upon serpentine (TL), or earlier iron-bearing minerals, also formed from the hydrothermal alteration of earlier iron-bearing phosphates in granite pegmatites.
The Fe3+ analogue of tinsleyite.
Originally phosphate formed by the action of solutions derived from bird or bat guano upon serpentine (TL), or earlier iron-bearing minerals, also formed from the hydrothermal alteration of earlier iron-bearing phosphates in granite pegmatites.
Unique Identifiers
Mindat ID:
2385
Long-form identifier:
mindat:1:1:2385:2
GUID
(UUID V4):
(UUID V4):
15c14003-70ff-45d9-87b8-e2e02435bb6f
IMA Classification of Leucophosphite
Approved, 'Grandfathered' (first described prior to 1959)
First published:
1932
Classification of Leucophosphite
8.DH.10
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
42.11.6.1
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
19.14.7
19 : Phosphates
14 : Phosphates of Fe and other metals
19 : Phosphates
14 : Phosphates of Fe and other metals
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Lpp | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Leucophosphite
Sub-Vitreous, Resinous, Earthy
Transparency:
Transparent, Translucent
Comment:
Chalky from guano deposits.
Colour:
White to greenish, buff, yellow-brown, orange-brown, pink, greenish brown, brownish purple
Streak:
White
Hardness:
3½ on Mohs scale
Tenacity:
Fragile
Cleavage:
Perfect
On {100}, perfect.
On {100}, perfect.
Density:
2.948 g/cm3 (Measured) 2.911 g/cm3 (Calculated)
Comment:
Type locality density values = 2.30 to 2.65 (porous and chalk-like).
Optical Data of Leucophosphite
Type:
Biaxial (+)
RI values:
nα = 1.707 nβ = 1.721 nγ = 1.739
2V:
Calculated: 84°
Birefringence:
0.032
Max Birefringence:
δ = 0.032
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
High
Dispersion:
r > v
Optical Extinction:
X = b, Z ∧ c = 26°
Pleochroism:
Non-pleochroic
Chemistry of Leucophosphite
Mindat Formula:
KFe3+2(PO4)2(OH) · 2H2O
Crystallography of Leucophosphite
Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P21/b
Cell Parameters:
a = 9.76 Å, b = 9.65 Å, c = 9.74 Å
β = 102.44°
β = 102.44°
Ratio:
a:b:c = 1.011 : 1 : 1.009
Unit Cell V:
895.81 ų (Calculated from Unit Cell)
Morphology:
Pseudo-orthorhombic. Crystals rhombic-shaped, exhibiting {100}, {210}, {111}, and {111}. Fine-grained, chalk-like masses. Amorphous in part.
Comment:
P21/n
Crystal Structure
Load
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
Unit Cell | Unit Cell Packed
2x2x2 | 3x3x3 | 4x4x4
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0000274 | Leucophosphite | Moore P B (1972) Octahedral tetramer in the crystal structure of leucophosphite, K2[Fe4(OH)2(H2O)2(PO4)4].2H2O American Mineralogist 57 397-410 | 1972 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
7.60 Å | (70) |
6.79 Å | (100) |
5.99 Å | (70) |
4.76 Å | (30) |
3.06 Å | (70) |
2.916 Å | (40) |
2.829 Å | (40) |
Comments:
Material from Sapucaia pegmatite, Brazil. See also ICDD 9-446, 37-466.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Near-surface Processes | |
21 : Chemically precipitated carbonate, phosphate, iron formations | |
High-𝑇 alteration and/or metamorphism | |
31 : Thermally altered carbonate, phosphate, and iron formations |
Geological Setting:
Cave deposits resulting from bird or bat guano reactions with earlier iron-bearing minerals; hydrothermally altered iron-rich phosphates in pegmatites; phosphate rock deposits; crosscutting fluorapatite nodules.
Type Occurrence of Leucophosphite
General Appearance of Type Material:
Chalk like mass.
Place of Conservation of Type Material:
Western Australian Museum, Perth, Australia: M.69.1991, MDC6129.
Geological Setting of Type Material:
Guano deposits forming veins in serpentinite.
Associated Minerals at Type Locality:
Reference:
Simpson, E.S. (1932) Contributions to the mineralogy of Western Australia, (7) Variscite (redondite) and leucophosphite (Sp. nov.), Ninghanboun Hills, S.W.. Journal of the Royal Society of Western Australia: 18: 69-74.
Other Language Names for Leucophosphite
Relationship of Leucophosphite to other Species
Member of:
Other Members of this group:
Ammoniotinsleyite | (NH4)Al2(PO4)2(OH) · 2H2O | Mon. 2/m : P21/m |
Spheniscidite | (NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2O | Mon. 2/m |
Tinsleyite | KAl2(PO4)2(OH) · 2H2O | Mon. |
Common Associates
Associated Minerals Based on Photo Data:
79 photos of Leucophosphite associated with Dufrénite | Ca0.5Fe2+Fe3+5(PO4)4(OH)6 · 2H2O |
41 photos of Leucophosphite associated with Hureaulite | Mn2+5(PO3OH)2(PO4)2 · 4H2O |
39 photos of Leucophosphite associated with Cyrilovite | NaFe3+3(PO4)2(OH)4 · 2H2O |
28 photos of Leucophosphite associated with Strengite | FePO4 · 2H2O |
20 photos of Leucophosphite associated with Kidwellite | NaFe3+9+x(PO4)6(OH)11 · 3H2O, x = 0.33 |
18 photos of Leucophosphite associated with Bariopharmacosiderite | Ba0.5Fe3+4(AsO4)3(OH)4 · 5H2O |
17 photos of Leucophosphite associated with Jahnsite Group | XM1M22M32(H2O)8(OH)2(PO4)4 |
16 photos of Leucophosphite associated with Rockbridgeite | Fe2+Fe3+4(PO4)3(OH)5 |
16 photos of Leucophosphite associated with Cacoxenite | Fe3+24AlO6(PO4)17(OH)12 · 75H2O |
15 photos of Leucophosphite associated with Meurigite-K | KFe3+8(PO4)6(OH)7 · 6.5H2O |
Related Minerals - Strunz-mindat Grouping
8.DH. | Ferroberaunite | Fe2+Fe3+5(PO4)4(OH)5 · 6H2O |
8.DH. | Rowleyite | [Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl] |
8.DH. | Ammoniotinsleyite | (NH4)Al2(PO4)2(OH) · 2H2O |
8.DH. | Thebaite-(NH4) | (NH4)3Al(C2O4)(PO3OH)2(H2O) |
8.DH. | Dendoraite-(NH4) | (NH4)2NaAl(C2O4)(PO3OH)2(H2O)2 |
8.DH. | Whiteite-(MnMnMn) | Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 · 8H2O |
8.DH. | Whiteite-(CaMnFe) | CaMnFe2Al2(PO4)4(OH)2 · 8H2O |
8.DH. | Hochleitnerite | Mn2Ti3(PO4)4O2(H2O)2 · 14H2O |
8.DH. | Regerite | KFe6(PO4)4(OH)7(H2O)6 · 4H2O |
8.DH. | Hydroxylbenyacarite | (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10 · 4H2O |
8.DH. | Macraeite | K(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 · 4H2O |
8.DH.05 | Minyulite | KAl2(PO4)2F · 4H2O |
8.DH.10 | Spheniscidite | (NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2O |
8.DH.10 | Tinsleyite | KAl2(PO4)2(OH) · 2H2O |
8.DH.15 | Jahnsite-(CaMnFe) | {Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaMnMg) | {Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaMnMn) | {Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Keckite | CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2O |
8.DH.15 | Rittmannite | {(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(CaFeMg) | {Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(CaMnMg) | {Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(MnFeMg) | {(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(MnMnMn) | {Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Kaluginite | (Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2O |
8.DH.15 | Jahnsite-(CaFeFe) | {Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(NaFeMg) | NaFe3+Mg2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(NaMnMg) | {(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaMgMg) | {Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(CaMnMn) | {Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(MnMnMg) | MnMnMg2Al2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(MnMnMg) | Mn2+Mn2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaFeMg) | CaFe2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(MnMnFe) | Mn2+Mn2+Fe2+2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(CaMgMg) | CaMg3Al2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(MnMnZn) | Mn2+Mn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(NaMnMn) | NaMn2+(Mn2+Fe3+)Σ2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaMnZn) | CaMn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.20 | Lun'okite | (Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2O |
8.DH.20 | Manganosegelerite | (Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2O |
8.DH.20 | Overite | CaMgAl(PO4)2(OH) · 4H2O |
8.DH.20 | Segelerite | Ca2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.20 | Wilhelmvierlingite | CaMnFe3+(PO4)2(OH) · 2H2O |
8.DH.20 | Juonniite | CaMgSc(PO4)2(OH) · 4H2O |
8.DH.25 | Calcioferrite | Ca2Fe3+2(PO4)3(OH) · 7H2O |
8.DH.25 | Kingsmountite | Ca3MnFeAl4(PO4)6(OH)4 · 12H2O |
8.DH.25 | Montgomeryite | Ca4MgAl4(PO4)6(OH)4 · 12H2O |
8.DH.25 | Zodacite | Ca4Mn2+Fe3+4(PO4)6(OH)4 · 12H2O |
8.DH.25 | Fanfaniite | Ca4MnAl4(PO4)6(OH)4 · 12H2O |
8.DH.30 | Arseniosiderite | Ca2Fe3+3(AsO4)3O2 · 3H2O |
8.DH.30 | Kolfanite | Ca2Fe3+3O2(AsO4)3 · 2H2O |
8.DH.30 | Mitridatite | Ca2Fe3+3(PO4)3O2 · 3H2O |
8.DH.30 | Pararobertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
8.DH.30 | Robertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
8.DH.30 | Sailaufite | (Ca,Na,◻)2Mn3+3(AsO4)2(CO3)O2 · 3H2O |
8.DH.35 | Mantienneite | KMg2Al2Ti(PO4)4(OH)3 · 15H2O |
8.DH.35 | Paulkerrite | K(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2O |
8.DH.35 | Benyacarite | (H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2O |
8.DH.40 | Xanthoxenite | Ca4Fe3+2(PO4)4(OH)2 · 3H2O |
8.DH.45 | Mahnertite | NaCu3(AsO4)2Cl · 5H2O |
8.DH.50 | Andyrobertsite | KCdCu5(AsO4)4(H2AsO4) · 2H2O |
8.DH.50 | Calcioandyrobertsite | KCaCu5(AsO4)4(H2AsO4) · 2H2O |
8.DH.55 | Englishite | K3Na2Ca10Al15(PO4)21(OH)7 · 26H2O |
8.DH.60 | Bouazzerite | Bi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2O |
8.DH.65 | Galliskiite | Ca4Al2(PO4)2F8 · 5H2O |
8.DH.70 | Joteite | Ca2CuAl(AsO4)[AsO3(OH)]2(OH)2 · 5H2O |
8.DH.75 | Kampelite | Ba6Mg3Sc8(PO4)12(OH)6 · 7H2O |
8.DH.80 | Kapundaite | NaCaFe4(PO4)4(OH)3 · 5H2O |
8.DH.85 | Vaniniite | Ca2Mn2+3Mn3+2O2(AsO4)4 · 2H2O |
Fluorescence of Leucophosphite
Not fluorescent in UV
Other Information
Notes:
Insoluble in water. Completely soluble in hot strong HCl.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Leucophosphite
mindat.org URL:
https://www.mindat.org/min-2385.html
Please feel free to link to this page.
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External Links:
Mineral Dealers:
References for Leucophosphite
Reference List:
Lindberg, Marie Louise (1957) Leucophosphite from the Sapucaia pegmatite mine, Minas Gerais, Brazil. American Mineralogist, 42 (3-4) 214-221
Localities for Leucophosphite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Antarctica | |
| Barczuk A. & Tatur A. 2003: BIOGENIC ... |
| Tatjir et al. (1984) |
Tatur et al. (1985) | |
Argentina | |
| Galliski (1983) +1 other reference |
| Roda-Robles et al. (2012) |
Australia | |
| McQueen et al. (1988) |
| McQueen +3 other references |
| R Bottrill |
| A.L. McLean et al. (2004) |
| Podgson RE |
| Birch et al. (1997) |
| Day et al. (1996) |
| Sorrell (n.d.) |
| Harrowfield et al. (1981) +1 other reference |
| |
Pilkington et al. (1982) +1 other reference | |
| Norrish et al. (1957) +1 other reference |
| Elliott (2022) |
| Bottrill et al. (2008) |
| W.D.Birch. Phosphate Minerals of ... |
| Birch et al. (1993) |
| Mineralogical Magazine 39 (1974) +1 other reference |
| Simpson (1932) +1 other reference |
| Pegmatites of Western Australia +3 other references |
Brazil | |
| various photographs |
sergio varvello | |
Natural History Museum Collections (London 2008) +2 other references | |
luigi chiappino specimen +1 other reference | |
| Sergio Varvello photo |
| Atencio et al. (2005) |
| Cassedanne et al. (1999) |
| Piló et al. (2023) |
| Piló et al. (2023) |
Figueira et al. (2019) | |
Canada | |
| TRAILL (1983) |
| Peatfield (n.d.) |
Chile | |
| EDS analisis +1 other reference |
EDS-SEM analisis +1 other reference | |
| Sulphides analysed by geology dep. of ... +1 other reference |
Czech Republic | |
| Sejkora +1 other reference |
| Jirásek J. et al. (2016) |
Sejkora +1 other reference | |
| Janouš +4 other references |
| Vrtiška L et al. (2017) |
| Škoda +3 other references |
France | |
| Chollet Pascal Collection |
| Cuchet et al. (2000) |
| Pierre Le Roc'h & Jean-Marc Johannet ... |
| Lièvre et al. (2002) |
| Karkanas et al. (2002) |
| Natural History Museum Paris analysis |
| Boisson (1988) |
| Gayraud et al. (2011) |
Germany | |
| Lapis (4) |
| Dill et al. (2009) |
| www.berthold-weber.de (2001) +1 other reference |
Wittern (2001) +1 other reference | |
| Pöllmann et al. (2005) |
Iran | |
| Amin et al. (2022) |
Israel | |
| Weiner et al. (1993) |
Italy | |
| Raudsepp M. and Pani E. (1994) |
| Sauro et al. (2014) +1 other reference |
| D'Angeli et al. (2018) |
Liberia | |
| Axelrod et al. (1952) |
Madagascar | |
| Behier (1960) |
Malaysia | |
| Bridge et al. (1983) |
| Wurster et al. (2015) |
Mexico | |
| Sergio Varvello collection |
Morocco | |
| Favreau (2012) |
Namibia | |
| von Bezing (2007) |
Keller (1974) | |
| P. Keller and O. von Knorring |
Netherlands | |
| Stienstra (1985) |
New Zealand | |
| Landis et al. (2003) |
Philippines | |
| Wurster et al. (2015) |
Wurster et al. (2015) | |
Choa et al. (2014) | |
Portugal | |
| Pedro Alves collection and analytical ... |
| Pavel M. Kartashov analytical data |
| Schnorrer-Köhler (1991) |
| Rewitzer et al. (1984) +1 other reference |
Mineralien Atlas | |
| Pedro Alves collection and analytical ... |
| Pedro Alves collection and analytical ... |
Romania | |
| Eur.Journ.Min. 14:157-164 |
Russia | |
| Sokol et al. (2022) |
Rwanda | |
| Daltry et al. (1998) |
South Africa | |
| Martini (1978) |
Martini (1978) | |
| Martini (1978) |
| Martini (1978) |
Martini (1978) | |
Martini (1978) | |
| Martini (1978) |
| Martini (1997) |
| Martini (1978) |
Spain | |
| Roda et al. (2001) |
| Encarnación Roda-Robles (2007) |
| Roda-Robles et al. (1998) |
| Calvo Rebollar et al. (2022) |
Thailand | |
| Lenoble et al. (2006, September) |
UK | |
| Golley et al. (1995) |
| Mineralogical Magazine 1996 60 : ... +1 other reference |
| Judd +9 other references |
Young et al. (1978) | |
USA | |
| Min.Rec.:20 (5) |
| Rocks & Minerals: 70 (5) |
| Leavens (1967) +1 other reference |
| Van Nostrand Reinholt Press: 310 +3 other references |
| King (n.d.) |
| Eckel et al. (1997) |
| Coveney et al. (1984) |
| Falster et al. (2019) |
| Castor et al. (2004) |
| Jensen et al. (1995) |
| [Anthony (1997) +1 other reference |
| Mineralogical Record 26:467 |
Nevada Bureau of Mines and Geology ... | |
| Rocks & Minerals |
| Dr. William S. Wise presentation to ... |
| Rocks & Min. 80:251 |
Smith (2005) | |
Moore (1973) | |
| Thompson et al. (2022) |
| Northrop et al. (1996) |
Northrop et al. (1996) | |
| Northrop et al. (1996) |
Northrop et al. (1996) | |
| Mineralogical Magazine 60:787-793. |
| JBS collection |
| Campbell et al. (1985) |
| Rocks & Minerals: 60: 117. +1 other reference |
| Smith et al. (2000) |
| Smith et al. (2000) |
| Campbell et al. (1985) |
| Smith et al. (2000) |
| King (n.d.) |
| Dietrich (1990) |
| Jones +1 other reference |
Venezuela | |
Franco Urbani (2009) |
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Sítio do Castelo Mine, Folgosinho, Gouveia, Guarda, Portugal