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Shcherbakovite

A valid IMA mineral species - grandfathered

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Photos of Shcherbakovite (10)

Shcherbakovite Gallery Search Photos of Shcherbakovite

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Shcherbakovite

Rasvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia

Shcherbakovite

Rasvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia

Shcherbakovite

Rasvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia

Shcherbakovite

Rasvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia

Shcherbakovite

Rasvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia

Shcherbakovite

Rasvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia

Shcherbakovite

Rasvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia

Shcherbakovite

Rasvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia

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About ShcherbakoviteHide

Dmitri Ivanovich Shcherbakov (1893-1966)

Formula:

(K,Ba)KNa(Ti,Nb)₂(Si₄O₁₂)O₂

Colour:

Dark brown

Lustre:

Vitreous, Greasy

Hardness:

6½

Specific Gravity:

2.968

Crystal System:

Orthorhombic

Member of:

Batisite Group

Name:

Named by E.M. Es'kova and M.E. Kazakova in 1954 in honor of Dmitri Ivanovich Shcherbakov (13 January 1893 - 25 May 1966, Moscow, Russia) geochemist and mineralogist.

Type Locality:

ⓘ Apatitovyi Tsirk, Rasvumchorr Mine, Rasvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia

Batisite Group.
Easily confused with batisite.

Note: the "shcherbakovite" described by Mitchell (1990) is in fact noonkanbahite.

Unique IdentifiersHide

Mindat ID:

3635

Long-form identifier:

mindat:1:1:3635:7

GUID
(UUID V4):

3d957aea-3053-406e-a8a5-34e20e170291

IMA Classification of ShcherbakoviteHide

IMA status:

Approved, 'Grandfathered' (first described prior to 1959)

IMA Formula:

K₂NaTi₂O(OH)Si₄O₁₂

First published:

1954

Type description reference:

Es'kova, E.M., Kazakova, M.E. (1954) Shcherbakovite - a new mineral. Doklady Akademii Nauk SSSR: 99: 837-840.

Classification of ShcherbakoviteHide

Strunz-mindat (2024):

9.DH.20

9 : SILICATES (Germanates)
D : Inosilicates
H : Inosilicates with 4-periodic single chains, Si₄O₁₂

Dana 8th ed.:

65.3.4.2

65 : INOSILICATES Single-Width,Unbranched Chains,(W=1)
3 : Single-Width Unbranched Chains, W=1 with chains P=4

Hey's CIM Ref.:

17.8.13

17 : Silicates Containing other Anions
8 : Silicates with niobate or tantalate

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Symbol	Source	Reference
Sbk	IMA–CNMNC	Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of ShcherbakoviteHide

Lustre:

Vitreous, Greasy

Transparency:

Opaque

Colour:

Dark brown

Hardness:

6½ on Mohs scale

Hardness:

VHN₁₀₀=731 - 845 - Vickers

Tenacity:

Brittle

Cleavage:

Poor/Indistinct
Two directions, observed microscopically, may be parting.

Fracture:

Irregular/Uneven

Density:

2.968 g/cm³ (Measured) 3.194 g/cm³ (Calculated)

Optical Data of ShcherbakoviteHide

Type:

Biaxial (-)

RI values:

n_α = 1.707 n_β = 1.745 n_γ = 1.776

2V:

Measured: 82° , Calculated: 82°

Max Birefringence:

δ = 0.069

Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.

Surface Relief:

High

Dispersion:

r > v

Pleochroism:

Visible

Comments:

X = pale yellow; Y = yellow; Z = brownish yellow.

Chemistry of ShcherbakoviteHide

Mindat Formula:

(K,Ba)KNa(Ti,Nb)₂(Si₄O₁₂)O₂

Elements listed:

Ba, K, Na, Nb, O, Si, Ti - search for minerals with similar chemistry

Common Impurities:

Zr,Al,Fe,Ta,Mn,Mg,Ca,Cl,H₂O

Crystallography of ShcherbakoviteHide

Crystal System:

Orthorhombic

Class (H-M):

mmm (2/m 2/m 2/m) - Dipyramidal

Space Group:

Imma

Setting:

Imma

Cell Parameters:

a = 10.55 Å, b = 13.92 Å, c = 8.1 Å

Ratio:

a:b:c = 0.758 : 1 : 0.582

Unit Cell V:

1,189.53 Å³ (Calculated from Unit Cell)

Crystal StructureHide

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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure

ID	Species	Reference	Link	Year	Locality	Pressure (GPa)	Temp (K)
0005885	Shcherbakovite	Uvarova Y A, Sokolova E V, Hawthorne F C, Liferovich R P, Mitchell R H (2003) The crystal chemistry of shcherbakovite from the Khibina Massif, Kola Peninsula, Russia The Canadian Mineralogist 41 1193-1201		2003	Khibina Massif, Kola Peninsula, Russia	0	293

CIF Raw Data - click here to close

data_global
_chemical_name_mineral 'Shcherbakovite'
loop_
_publ_author_name
'Uvarova Y A'
'Sokolova E V'
'Hawthorne F C'
'Liferovich R P'
'Mitchell R H'
_journal_name_full 'The Canadian Mineralogist'
_journal_volume 41 
_journal_year 2003
_journal_page_first 1193
_journal_page_last 1201
_publ_section_title
;
 The crystal chemistry of shcherbakovite from the Khibina Massif, Kola Peninsula, Russia
;
_database_code_amcsd 0005885
_chemical_compound_source 'Khibina Massif, Kola Peninsula, Russia'
_chemical_formula_sum 'K1.66 Ba.23 Na1.07 Ca.02 Ti1.4 Nb.48 Fe.08 Zr.04 Si4 O14 H.48'
_cell_length_a 8.1538
_cell_length_b 10.5569
_cell_length_c 13.9882
_cell_angle_alpha 90
_cell_angle_beta 90
_cell_angle_gamma 90
_cell_volume 1204.088
_exptl_crystal_density_diffrn      3.191
_symmetry_space_group_name_H-M 'I m m a'
loop_
_space_group_symop_operation_xyz
  'x,y,z'
  '1/2+x,1/2+y,1/2+z'
  'x,1/2-y,z'
  '1/2+x,-y,1/2+z'
  '-x,1/2+y,-z'
  '1/2-x,+y,1/2-z'
  '-x,y,z'
  '1/2-x,1/2+y,1/2+z'
  'x,-y,-z'
  '1/2+x,1/2-y,1/2-z'
  'x,1/2+y,-z'
  '1/2+x,+y,1/2-z'
  '-x,1/2-y,z'
  '1/2-x,-y,1/2+z'
  '-x,-y,-z'
  '1/2-x,1/2-y,1/2-z'
loop_
_atom_site_label
_atom_site_fract_x
_atom_site_fract_y
_atom_site_fract_z
_atom_site_occupancy
_atom_site_U_iso_or_equiv
KA1   0.00000   0.25000   0.74564   0.66000   0.01890
BaA1   0.00000   0.25000   0.74564   0.23000   0.01890
NaA1   0.00000   0.25000   0.74564   0.07000   0.01890
CaA1   0.00000   0.25000   0.74564   0.02000   0.01890
KA2   0.00000   0.75000   0.68880   1.00000   0.02270
NaA3   0.00000   0.50000   0.50000   1.00000   0.02960
TiM1   0.27800   0.75000   0.47210   0.34000   0.01000
NbM1   0.27800   0.75000   0.47210   0.16000   0.01000
TiM2   0.22000   0.75000   0.46920   0.36000   0.01520
NbM2   0.22000   0.75000   0.46920   0.08000   0.01520
FeM2   0.22000   0.75000   0.46920   0.04000   0.01520
ZrM2   0.22000   0.75000   0.46920   0.02000   0.01520
SiT  -0.30493   0.97562   0.64432   1.00000   0.01060
O1  -0.22130   0.88260   0.56850   1.00000   0.01610
O2  -0.25110   0.12040   0.63170   1.00000   0.02000
O3  -0.25000   0.92534   0.75000   1.00000   0.02880
O4  -0.50000   0.96220   0.64390   1.00000   0.05250
O5   0.00000   0.75000   0.46000   1.00000   0.01890
O6   0.50000   0.75000   0.47850   0.52000   0.02290
O-H6   0.50000   0.75000   0.47850   0.48000   0.02290
loop_
_atom_site_aniso_label
_atom_site_aniso_U_11
_atom_site_aniso_U_22
_atom_site_aniso_U_33
_atom_site_aniso_U_12
_atom_site_aniso_U_13
_atom_site_aniso_U_23
KA1 0.02180 0.01680 0.01800 0.00000 0.00000 0.00000
BaA1 0.02180 0.01680 0.01800 0.00000 0.00000 0.00000
NaA1 0.02180 0.01680 0.01800 0.00000 0.00000 0.00000
CaA1 0.02180 0.01680 0.01800 0.00000 0.00000 0.00000
KA2 0.01950 0.01840 0.03030 0.00000 0.00000 0.00000
NaA3 0.01790 0.03600 0.03500 0.00000 0.00000 -0.02200
TiM1 0.01550 0.00720 0.00740 0.00000 0.00050 0.00000
NbM1 0.01550 0.00720 0.00740 0.00000 0.00050 0.00000
TiM2 0.02880 0.00890 0.00800 0.00000 0.00080 0.00000
NbM2 0.02880 0.00890 0.00800 0.00000 0.00080 0.00000
FeM2 0.02880 0.00890 0.00800 0.00000 0.00080 0.00000
ZrM2 0.02880 0.00890 0.00800 0.00000 0.00080 0.00000
SiT 0.01250 0.00940 0.00990 -0.00002 0.00030 -0.00030
O1 0.02450 0.01180 0.01180 0.00120 0.00240 -0.00270
O2 0.03670 0.01040 0.01280 -0.00320 0.00110 0.00050
O3 0.06350 0.01270 0.01020 0.00000 -0.00510 0.00000
O4 0.01140 0.04680 0.09930 0.00000 0.00000 -0.01610
O5 0.02350 0.01760 0.01570 0.00000 0.00000 0.00000
O6 0.02270 0.01880 0.02730 0.00000 0.00000 0.00000
O-H6 0.02270 0.01880 0.02730 0.00000 0.00000 0.00000

X-Ray Powder DiffractionHide

Powder Diffraction Data:

d-spacing	Intensity
2.90 Å	(100)
1.081 Å	(100)
2.64 Å	(70)
1.688 Å	(70)
1.576 Å	(60)
3.39 Å	(50)
2.04 Å	(50)
1.538 Å	(50)

Comments:

Apatitovyi Tsirk, Rasvumchorr Mine, Khibiny Massif, Russia. The data are from the type description.

Geological EnvironmentHide

Paragenetic Mode(s):

Paragenetic Mode	Earliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust	>4.50
7 : Ultramafic igneous rocks
Stage 4b: Highly evolved igneous rocks	>3.0
35 : Ultra-alkali and agpaitic igneous rocks

Type Occurrence of ShcherbakoviteHide

Type Locality:

ⓘ Apatitovyi Tsirk, Rasvumchorr Mine, Rasvumchorr Mt, Khibiny Massif, Murmansk Oblast, Russia

General Appearance of Type Material:

Crystals are long prismatic, to 6 cm; terminated crystals are uncommon.

Place of Conservation of Type Material:

A.E. Fersman Mineralogical Museum, Russian Academy of Sciences, Moscow, Russia; 57256.

Geological Setting of Type Material:

In a pegmatite in alkalic rocks.

Associated Minerals at Type Locality:

Titanite	Natrolite	Natrolite	K Feldspar	Astrophyllite
Astrophyllite	Albite

Reference:

Es'kova, E.M., Kazakova, M.E. (1954) Shcherbakovite - a new mineral. Doklady Akademii Nauk SSSR: 99: 837-840.

Synonyms of ShcherbakoviteHide

Scherbakovite

Other Language Names for ShcherbakoviteHide

German:Scherbakovit
Shcherbakovit

Russian:Щербаковит

Simplified Chinese:硅铌钡钠石

Spanish:Scherbakovita
Shcherbakovita

Traditional Chinese:矽鈮鋇鈉石

Relationship of Shcherbakovite to other SpeciesHide

Member of:

Batisite Group

Other Members of this group:

Batisite	BaNaNaTi₂(Si₄O₁₂)O₂	Orth. mmm (2/m 2/m 2/m) : Imma
Noonkanbahite	BaKNaTi₂(Si₄O₁₂)O₂	Orth. mmm (2/m 2/m 2/m) : Imma

Common AssociatesHide

Associated Minerals Based on Photo Data:

2 photos of Shcherbakovite associated with Aegirine

NaFe³⁺Si₂O₆

Related Minerals - Strunz-mindat Grouping Hide

9.DH.	Gageite-2M	(Mn,Mg,Zn)₄₂Si₁₆O₅₄(OH)₄₀	Mon. 2/m
9.DH.	Bavsiite	Ba₂V₂O₂[Si₄O₁₂]	Tet. 4/m : I4/m
9.DH.	Devilliersite	Ca₄Ca₂Fe³⁺₁₀O₄[(Fe³⁺₁₀Si₂)O₃₆]	Tric. 1 : P1
9.DH.	Yuzuxiangite	Sr₃Fe³⁺(Si₂O₆)₂(OH) · 3H₂O	Mon. 2/m : P2₁/m
9.DH.	Louisfuchsite	Ca₂(Mg₄Ti₂)(Al₄Si₂)O₂₀	Tric. 1 : P1
9.DH.05	Leucophanite	NaCaBeSi₂O₆F	Orth. 2 2 2 : P2₁ 2₁ 2₁
9.DH.10	Ohmilite	Sr₃(Ti,Fe³⁺)(Si₄O₁₂)(O,OH) · 2-3H₂O	Mon. 2/m : P2₁/m
9.DH.15	Haradaite	SrVSi₂O₇	Orth. mmm (2/m 2/m 2/m)
9.DH.15	Suzukiite	BaVSi₂O₇	Orth.
9.DH.20	Batisite	BaNaNaTi₂(Si₄O₁₂)O₂	Orth. mmm (2/m 2/m 2/m) : Imma
9.DH.20	Noonkanbahite	BaKNaTi₂(Si₄O₁₂)O₂	Orth. mmm (2/m 2/m 2/m) : Imma
9.DH.25	Taikanite	Sr₃BaMn²⁺₂(Si₄O₁₂)O₂	Mon. 2 : B2
9.DH.30	Krauskopfite	BaSi₂O₅ · 3H₂O	Mon. 2/m : P2₁/b
9.DH.35	Balangeroite	(Mg,Fe²⁺,Fe³⁺,Mn²⁺)₄₂Si₁₆O₅₄(OH)₄₀	Mon. 2/m
9.DH.35	Gageite	Mn₂₁(Si₄O₁₂)₂O₃(OH)₂₀	Mon. 2/m
9.DH.40	Aenigmatite	Na₄[Fe²⁺₁₀Ti₂]O₄[Si₁₂O₃₆]	Tric. 1 : P1
9.DH.40	Dorrite	Ca₄(Mg₃Fe³⁺₉)O₄(Si₃Al₈Fe³⁺O₃₆)	Tric.
9.DH.40	Høgtuvaite	Ca₄[Fe²⁺₆Fe³⁺₆]O₄[Si₈Be₂Al₂O₃₆]	Tric. 1 : P1
9.DH.40	Krinovite	Na₂Mg₄Cr³⁺₂(Si₆O₁₈)O₂	Tric. 1 : P1
9.DH.40	Makarochkinite	(Ca,Na)₄[Fe²⁺₈Fe³⁺₂Ti₂]O₄[Si₈Be₂Al₂O₃₆]	Tric. 1 : P1
9.DH.40	Rhönite	Ca₄[Mg₈Fe³⁺₂Ti₂]O₄[Si₆Al₆O₃₆]	Tric. 1 : P1
9.DH.40	Serendibite	Ca₄[Mg₆Al₆]O₄[Si₆B₃Al₃O₃₆]	Tric. 1 : P1
9.DH.40	Welshite	Ca₄Mg₉Sb₃O₄[Si₆Be₃AlFe₂O₃₆]	Tric. 1 : P1
9.DH.40	Wilkinsonite	Na₂Fe²⁺₄Fe³⁺₂(Si₆O₁₈)O₂	Tric. 1 : P1
9.DH.40	Leucorhönite	Ca₂(Mg,Fe³⁺,Al)₆(Si,Al)₆O₂₀	Tric.
9.DH.40	Kuratite	Ca₂(Fe²⁺₅Ti)O₂[Si₄Al₂O₁₈]	Tric. 1 : P1
9.DH.40	Khesinite	Ca₄(Mg₃Fe³⁺₉)O₄(Fe³⁺₉Si₃)O₃₆	Tric. 1 : P1
9.DH.40	UM1991-29-SiO:FeMgNa	Na₄(Mg₅Fe³⁺₇)O₄[Si₉Fe³⁺₃O₃₆]
9.DH.45	Sapphirine	Mg₄(Mg₃Al₉)O₄[Si₃Al₉O₃₆]	Mon. 2/m : P2₁/b
9.DH.50	Khmaralite	(Mg,Al,Fe)₁₆[(Al,Si,Be)₁₂O₃₆]O₄	Mon. 2/m : P2₁/b
9.DH.55	Surinamite	(Mg,Fe)₃Al₄BeSi₃O₁₆	Mon. 2/m
9.DH.55	UM1988-26-SiO:AlMg	Mg₄Al₂O[Si₃Al₂O₁₅]
9.DH.60	Deerite	(Fe,Mn)₆(Fe,Al)₃[Si₆O₁₇]O₃(OH)₅	Mon. 2/m : P2₁/b
9.DH.65	Howieite	Na(Fe,Mn)₁₀(Fe,Al)₂Si₁₂O₃₁(OH)₁₃	Tric.
9.DH.65	Taneyamalite	(Na,Ca)(Mn,Mg,Fe)₁₂Si₁₂(O,OH)₄₄	Tric.
9.DH.70	Johninnesite	Na₂Mn²⁺₉Mg₇(OH)₈[AsO₄]₂[Si₆O₁₇]₂	Tric.
9.DH.75	Agrellite	NaCa₂Si₄O₁₀F	Tric. 1 : P1

Other InformationHide

Notes:

Insoluble in HNO3 and HCl, partly soluble in H2SO4 on heating.

Health Risks:

No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for ShcherbakoviteHide

mindat.org URL:

https://www.mindat.org/min-3635.html
Please feel free to link to this page.

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External Links:

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Raman and XRD data at RRUFF project

References and PDF downloads at RRUFF project

American Mineralogist Crystal Structure Database

Handbook of Mineralogy page PDF

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References for ShcherbakoviteHide

Reference List:

Es'kova, E.M., Kazakova, M.E. (1954) Shcherbakovite - a new mineral. Doklady Akademii Nauk SSSR: 99: 837-840.

Fleischer, M. (1955) New mineral names. American Mineralogist: 40: 787-788.

Mitchell, Roger H. (1990) Shcherbakovite in leucite phlogopite lamproites from the Leucite Hills, Wyoming. Mineralogical Magazine, 54 (377) 645-646 doi:10.1180/minmag.1990.054.377.18

Uvarova, Y. A., Sokolova, E., Hawthorne, F. C., Liferovich, R. P., Mitchell, R. H. (2003) The crystal chemistry of shcherbakovite from the Khibina massif, Kola Peninsula, Russia. The Canadian Mineralogist, 41 (5) 1193-1201 doi:10.2113/gscanmin.41.5.1193

Jambor, J.L., Roberts, A.C. (2004) New mineral names. American Mineralogist: 89: 1826-1834.

Krivovichev, S.V., Yakovenchuk, V.N., Pakhomovsky, Y.A. (2004) Topology and symmetry of titanosilicate framework in the crystal structure of shcherbakovite, Na(K,Ba)2(Ti,Nb)2[Si4O12]. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva: 133: 55-63.

Piilonen, P.C., Ercit, T.S., Roberts, A.C. (2005) New mineral names. American Mineralogist: 90: 768-773.

(2023) Shcherbakovite. Handbook of Mineralogy. Mineralogical Society of America

Localities for ShcherbakoviteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the

symbol to view information about a locality. The

symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed.

- This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality.

- Good crystals or important locality for species.

- World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). ~~Struck out~~ - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.


Australia
Western Australia Derby-West Kimberley Shire Noonkanbah Station ⓘ ~~Walgidee Hills~~	Mineralogical Magazine 1984 48 : 263-266 +2 other references

Canada
Nunavut Qikiqtaaluk Region Baffin Island ⓘ Napoleon Bay	multistage proterozoic lamproites. ... +1 other reference

Russia
Murmansk Oblast Khibiny Massif Eveslogchorr Mt ⓘ Fersman Gorge	Men'shikov Yu.P. et al. (2003)
ⓘ Wadeite point	Arzamastsev et al. (2008)
ⓘ Koashkar Mt	Pekov (1998)
Koashva Mt ⓘ IGC Stop 2-3	Arzamastsev et al. (2008)
ⓘ IGC Stop 2-4	Arzamastsev et al. (2008)
ⓘ Koashva Open Pit	[World of Stones 95:5-6 +2 other references
ⓘ Kukisvumchorr Mt	Pekov (1998) +1 other reference
ⓘ Kirovskii apatite mine	Pekov (1998)
ⓘ Rasvumchorr Mt	Am Min 79:1011 +1 other reference
Rasvumchorr Mine ⓘ Apatitovyi Tsirk (TL)	World of Stones 95: 5-6 +2 other references
ⓘ Tsentral'nyi Mine	Pekov I.V. et al. (2010) +1 other reference
The Carbonatite Stock in the vicinity of Tul'ilukht Bay ⓘ Olenii Ruchei (Olenii Creek; Oleny Ruchei)	[Mandarino +1 other reference
ⓘ Vuonnemiok River Valley	Pekov (1998)
ⓘ Yukspor Mt	Pavel.M. Kartashov (n.d.) +2 other references
ⓘ Material'naya Adit	Khomyakov et al. (1983) +1 other reference
Kovdor Massif ⓘ Kovdor Phlogopite mine	Moiseev et al. (2007)
Kovdorsky District ⓘ Mokhnatye Roga	Akimenko et al. (2014, September)
ⓘ Niva alkaline intrusion	Arzamastseva et al. (1999) +1 other reference
ⓘ Sakha	[World of Stones 12:49]

USA
Montana Chouteau County Highwood Mountains ⓘ Lamproitic dike	Kuehner et al. (2003, June)
Wyoming Sweetwater County ⓘ ~~Leucite Hills Mining District~~	Hausel et al. (2001)
ⓘ ~~Emmons Mesa~~	Mitchell R.H. and Bergman S.C. (1991)
ⓘ ~~South Table Mountain~~	Mitchell (1990)
ⓘ ~~Zirkel Mesa~~	Mitchell (1990)

Shcherbakovite

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