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Krupkaite

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Big Photo

Sedl, Leckbachgraben (Leckbachrinne), Nasenkopf, Habach valley, Hohe Tauern, Salzburg, Austria
© Richard Bayerl

Show Krupkaite Photos (17)



Formula:
PbCuBi
 
3
S
 
6
System:OrthorhombicColour:steel-grey
Lustre:MetallicHardness:3½ - 4
Name:Named for the type locality.


Aikinite-Bismuthinite Series.

Classification of Krupkaite

IMA status:Approved 1974
Strunz 8th edition ID:2/E.30-50
Nickel-Strunz 10th (pending) edition ID:2.HB.05a

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
B : With Cu, Ag, Fe, Sn and Pb
Dana 8th edition ID:3.4.5.2

3 : SULFOSALTS
4 : ø = 3
Hey's CIM Ref.:5.7.6

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
7 : Sulpharsenites etc. of Pb and other metals
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Type Occurrence of Krupkaite

Type Locality:Barbora adit, Knöttel (Knötel; Knödel; Knödlberg) area, Krupka (Graupen), Krušné Hory Mts (Erzgebirge), Ústí Region, Bohemia (Böhmen; Boehmen), Czech Republic
Year of Discovery:1974

Physical Properties of Krupkaite

Lustre:Metallic
Diaphaneity (Transparency):Opaque
Colour:steel-grey
Streak:black
Hardness (Mohs):3½ - 4

Crystallography of Krupkaite

Crystal System:Orthorhombic
Cell Parameters:a = 4Å, b = 11.2Å, c = 11.56Å
Ratio:a:b:c = 0.357 : 1 : 1.032
Unit Cell Volume:V 517.89 ų (Calculated from Unit Cell)

Chemical Properties of Krupkaite

Formula:
PbCuBi
 
3
S
 
6
Essential elements:Bi, Cu, Pb, S
All elements listed in formula:Bi, Cu, Pb, S
Common Impurities:Se

Relationship of Krupkaite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
2.HB.05aAikinite
PbCuBiS
 
3
2.HB.05aFriedrichite
Pb
 
5
Cu
 
5
Bi
 
7
S
 
18
2.HB.05aGladite
PbCuBi
 
5
S
 
9
2.HB.05aHammarite
Pb
 
2
Cu
 
2
Bi
 
4
S
 
9
2.HB.05cJaskólskiite
Pb
 
2+x
Cu
 
x
(Sb,Bi)
 
2-x
S
 
6
 (x = 0.2)
2.HB.05aLindströmite
Pb
 
3
Cu
 
3
Bi
 
7
S
 
15
2.HB.05bMeneghinite
Pb
 
13
CuSb
 
7
S
 
24
2.HB.05aPekoite
PbCuBi
 
11
(S,Se)
 
18
2.HB.05aEmilite
Pb
 
2.7
Cu
 
2.7
Bi
 
5.3
S
 
12
2.HB.05UM2000-46-S:BiCuPb
Cu
 
0.33
Pb
 
0.33
Bi
 
7.67
S
 
12
2.HB.05aSalzburgite
Pb
 
1.6
Cu
 
1.6
Bi
 
6.4
S
 
12
2.HB.05UM1990-54-Se:BiCuPb
CuPb(Ni,Co)
 
0.3
Bi
 
3
Se
 
6
2.HB.05aPaarite
Pb
 
1.7
Cu
 
1.7
Bi
 
6.3
S
 
12
2.HB.10cEclarite
(Cu,Fe)Pb
 
9
Bi
 
12
S
 
28
2.HB.10bGiessenite
Pb
 
27
Cu
 
2
(Bi,Sb)
 
19
S
 
57
2.HB.10bIzoklakeite
Pb
 
27
(Cu,Fe,Ag)
 
2
(Sb,Bi)
 
19
S
 
57
2.HB.10aKobellite
Pb
 
22
Cu
 
4
(Bi,Sb)
 
30
S
 
69
2.HB.10aTintinaite
Pb
 
22
Cu
 
4
(Sb,Bi)
 
30
S
 
69
2.HB.15Benavidesite
Pb
 
4
(Mn,Fe)Sb
 
6
S
 
14
2.HB.15Jamesonite
Pb
 
4
FeSb
 
6
S
 
14
2.HB.20dBerryite
Cu
 
3
Ag
 
2
Pb
 
3
Bi
 
7
S
 
16
2.HB.20bBuckhornite
AuPb
 
2
BiTe
 
2
S
 
3
2.HB.20aNagyágite
Pb
 
5
Au(Te,Sb)
 
4
S
 
5-8
2.HB.20eWatkinsonite
Cu
 
2
PbBi
 
4
(Se,S,Te)
 
8
2.HB.20cMuseumite
[Pb
 
2
(Pb,Sb)
 
2
S
 
8
][(Te,Au)
 
2
]
2.HB.20eLitochlebite
Ag
 
2
PbBi
 
4
Se
 
8
Related Minerals - Hey's Index Grouping:

- +
5.7.1Seligmannite
PbCuAsS
 
3
5.7.2Bournonite
PbCuSbS
 
3
5.7.3Meneghinite
Pb
 
13
CuSb
 
7
S
 
24
5.7.4Gladite
PbCuBi
 
5
S
 
9
5.7.5Lindströmite
Pb
 
3
Cu
 
3
Bi
 
7
S
 
15
5.7.7Hammarite
Pb
 
2
Cu
 
2
Bi
 
4
S
 
9
5.7.8Friedrichite
Pb
 
5
Cu
 
5
Bi
 
7
S
 
18
5.7.9Aikinite
PbCuBiS
 
3
5.7.10Nuffieldite
Pb
 
2
Cu(Pb,Bi)Bi
 
2
S
 
7
5.7.11Jaskólskiite
Pb
 
2+x
Cu
 
x
(Sb,Bi)
 
2-x
S
 
6
 (x = 0.2)
5.7.12Tintinaite
Pb
 
22
Cu
 
4
(Sb,Bi)
 
30
S
 
69
5.7.13Kobellite
Pb
 
22
Cu
 
4
(Bi,Sb)
 
30
S
 
69
5.7.14Proudite
CuPb
 
7.5
Bi
 
9.33
(S,Se)
 
22
5.7.15Nordströmite
CuPb
 
3
Bi
 
7
(Se
 
4
S
 
10
)
5.7.16Watkinsonite
Cu
 
2
PbBi
 
4
(Se,S,Te)
 
8
5.7.17Pekoite
PbCuBi
 
11
(S,Se)
 
18
5.7.18Petrovicite
Cu
 
3
HgPbBiSe
 
5
5.7.19Eclarite
(Cu,Fe)Pb
 
9
Bi
 
12
S
 
28
5.7.20Marrite
AgPbAsS
 
3
5.7.21Baumhauerite-2a
Pb
 
11
Ag(As,Sb)
 
18
S
 
36
5.7.22Andorite
PbAgSb
 
3
S
 
6
5.7.23Ramdohrite
(Cd,Mn,Fe)Ag
 
5.5
Pb
 
12
Sb
 
21.5
S
 
48
5.7.24Roshchinite
Ag
 
19
Pb
 
10
Sb
 
51
S
 
96
5.7.25Ourayite
Ag
 
3
Pb
 
4
Bi
 
5
S
 
13
5.7.26Eskimoite
Ag
 
7
Pb
 
10
Bi
 
15
S
 
36
5.7.27Fizélyite
Ag
 
5
Pb
 
14
Sb
 
21
S
 
48
5.7.28Owyheeite
Ag
 
3+x
Pb
 
10-2x
Sb
 
11+x
S
 
28
, -0.13 < x > +0.20
5.7.29Freieslebenite
AgPbSbS
 
3
5.7.30Diaphorite
Ag
 
3
Pb
 
2
Sb
 
3
S
 
8
5.7.31Sterryite
Ag
 
2
Pb
 
10
(Sb,As)
 
12
S
 
29
5.7.32Vikingite
Ag
 
5
Pb
 
8
Bi
 
13
S
 
30
5.7.33Zoubekite
AgPb
 
4
Sb
 
4
S
 
10
5.7.34Schirmerite
PbAgBi
 
3
S
 
6
 - Pb
 
3
Ag
 
1.5
Bi
 
3.5
S
 
9
5.7.36Gustavite
Ag
 
3
Pb
 
5
Bi
 
11
S
 
24
5.7.37Kitaibelite
Ag
 
10
PbBi
 
30
S
 
51
5.7.38Treasurite
Ag
 
7
Pb
 
6
Bi
 
15
S
 
32
5.7.39Benjaminite
(Ag,Cu)
 
3
(Bi,Pb)
 
7
S
 
12
5.7.40Lengenbachite
(Ag,Cu)
 
2
Pb
 
6
As
 
4
S
 
13
5.7.41Berryite
Cu
 
3
Ag
 
2
Pb
 
3
Bi
 
7
S
 
16
5.7.42Neyite
Ag
 
2
Cu
 
6
Pb
 
25
Bi
 
26
S
 
68
5.7.43Larosite
(Cu,Ag)
 
21
(Pb,Bi)
 
2
S
 
13
5.7.44Cupropavonite
AgCu
 
2
PbBi
 
5
S
 
10
5.7.45Padĕraite
Cu
 
5.9
Ag
 
1.3
Pb
 
1.6
Bi
 
11.2
S
 
22
5.7.46Rayite
Pb
 
8
(Ag,Tl)
 
2
Sb
 
8
S
 
21
5.7.47Rathite
Pb
 
8
Pb
 
4-x
(Tl
 
2
As
 
2
)
 
x
(Ag
 
2
As
 
2
)As
 
16
S
 
40
5.7.48Hatchite
AgTlPbAs
 
2
S
 
5

Other Names for Krupkaite

Synonyms:
IMA1974-020
Other Languages:
German:Krupkait
Russian:Крупкаит
Simplified Chinese:库辉铋铜铅矿
Spanish:Krupkaita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Krupkaite

Reference List:

- +
Syneček, V. and Hybler, J. (1974) The crystal structure of krupkaite, CuPbBi3S6, and of gladite, CuPbi5S9, and the classification of superstructures in the bismuthinite-aikinite group. Neues Jahrbuch für Mineralogie, Monatshefte 1974: 541-560.

Mumme, W.G. (1975) The crystal structure of krupkaite, CPbBi3S6, from the Juno mine at Tennant Creek, Northern Territory, Australia. American Mineralogist: 60: 300-308.

Neues Jahrbuch für Mineralogie, Monatshefte (1974): 541-560.

Bulletin of the Czech Society of Mineralogy and Geology, Prague (1983): 28: 62.

Pring, A. (1989) Structural disorder in aikinite and krupkaite. American Mineralogist: 74: 250-255.

Topa, D., et al. (2008): Simultaneous structure refinement of two components of an exsolution intergrowth: crystal structures of the lindstromite-krupkaite pair. Canadian Mineralogist, 46, 525-539.


Internet Links for Krupkaite

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    • Localities for Krupkaite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Argentina
     
    • Chubut
    		Brodtkorb, Milka K. de (2002) Las Especies Minerales de la República Argentina. Tomo I. (Asociación Mineralógica Argentina)
    • Salta
      • Organullo Mining District
    		Milka K. de Brodtkorb (2002) Las Especies Minerales de la Republica Argentina. Vol. 1 (elements, sulphides and sulphosalts). (Asociacion Mineralogica Argentina); DE BRODTKORB, Milka K. Precious metaltellurides and other Te-bearing minerals in different paragenesis of Argentina: A review. Rev. Asoc. Geol. Argent. [online]. 2009, vol.64, n.3, pp. 365-372.
    Australia
     
    • Northern Territory
      • Tennant Inlier
        • Tennant Creek
    		No reference listed
    • Western Australia
      • Kalgoorlie-Boulder Shire
        • Kalgoorlie-Boulder
    		Mueller, Andreas G.; Lawrance, Louisa M.; Muhling, Janet; Pooley, Gregory D. (2012): Mineralogy and PTX relationships of the Archean Hannan South Au-Cu (Co-Bi) deposit, Kalgoorlie, Western Australia: thermodynamic constraints on the formation of a zoned intrusion-related skarn. Economic Geology 107, 1-24.
    Austria
     
    • Carinthia
      • Hohe Tauern
        • Goldberg group
          • Innerfragant
            • Wurten
              • Alteck
    		G. Niedermayr, I. Praetzel: Mineralien Kärntens, 1995
    Paar, W.H., and Niedermayr, G. (1998): Mitteilungen der Österreichischen Mineralogischen Gesellschaft 143, 425-435.
    Bergbau in Westkärnten
          • Zirknitz
            • Große Zirknitz valley
    		G. Niedermayr, I. Praetzel: Mineralien Kärntens, 1995
            • Kleine Zirknitz valley
              • Kluidscharte
    		G. Niedermayr, I. Praetzel: Mineralien Kärntens, 1995
    • Salzburg
      • Hohe Tauern
        • Felben valley
          • Scheelite deposit
    		MinRec 33:352; Kolitsch, U. (2009): 1585) Gustavit und andere Pb-Bi-Sulfosalze vom Westfeld des Scheelitbergbaues Felbertal, Salzburg. P. 207 in: Niedermayr, G. et al. (2009): Neue Mineralfunde aus Österreich LVIII. Carinthia II, 199/119, 189-236.
        • Gastein valley
    		Makovicky, E., Paar, W.H., Putz, H., Zagler, G. (2010): Dantopaite, Ag5Bi13S22, the 6P natural member of the pavonite homologous series, from Erzwies, Austria. Canadian Mineralogist, 48, 467-481.
          • Naßfeld valley
            • Sportgastein
    		Kolitsch et al., in prep. (SXRD); KOLITSCH, U. et al. (2008), in: Niedermayr, G. et al. (2008): Neue Mineralfunde aus Österreich LVII. Carinthia II, 198./118., 223-274.
        • Habach valley
          • Nasenkopf
            • Leckbachgraben (Leckbachrinne)
    		Bayerl, R. (2004): Krupkait, ein Erstfund aus dem Habachtal. Lapis 29 (7-8), 54-56. (in German)
      • Lungau
        • Murwinkel
          • Rotgülden
            • Lower Rotgülden lake
    		Miner.Arch.Salzb., vol.14 (297)
    Bolivia
     
    • Potosí Department
      • Sud Lípez Province
        • Cerro Bonete
    Bulgaria
     
    • Pazardzhik Oblast (Pazardjik Oblast)
      • Panagyurishte (Panagurishte) Obshtina
        • Levski
    		Bogdanov, K., Tsonev, D., Popov, K. (2004): Mineral assemblages and genesis of the Cu-Au epithermal deposits in the southern part of the Panagyurishte ore district, Bulgaria. In: Proceedings of the 10th International Congress, Thessaloniki, April 2004.
    Canada
     
    • New Brunswick
      • Gloucester Co.
        • Bathurst Parish
    		Jambor, J. L. (1982): McMaster, an allogenic massive sulfide copper deposit, Bathurst area, New Brunswick. CANMET Report 83-2E, 12 pp.
    China
     
    • Henan Province
      • Sanmenxia Prefecture
        • Lingbao Co.
          • Qinling Mine
    		Zhenkuan Luo, Kang Guan, and Manzhi Wang (1992): Geology and Prospecting 28(2), 31-35
    • Hunan Province
      • Chenzhou Prefecture
        • Yizhang Co.
          • Dongpo ore field
    		Yingchen Ren (1999): Contributions to Geology and Mineral Resources Research 14(1), 1-12, 38
    • Jiangsu Province
      • Nanjing Prefecture
        • Jiangning District
    		Xiangping, G., Watanabe, M., Ohkawa, M., Hoshino, K., Shibata, Y., and Desong, C. (2001): Canadian Mineralogist 39(6), 1641-1652.
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Ústí Region
        • Krušné Hory Mts (Erzgebirge)
          • Krupka (Graupen)
            • Knöttel (Knötel; Knödel; Knödlberg) area
    		Lapis 23(4), 18-34 (1998)
    Germany
     
    • North Rhine-Westphalia
      • Siegerland
        • Eiserfeld
          • Kohlenbach Valley
    		Wittern: "Mineralfundorte in Deutschland", 2001
        • Eisern
    		Wittern: "Mineralfundorte in Deutschland", 2001
    Greece
     
    • Attikí Prefecture (Attica; Attika)
      • Lavrion District (Laurion; Laurium)
        • Lavrion District Mines
          • Agios Konstantinos [St Constantine] (Kamariza)
    		No reference listed
    Iran
     
    • Markazi Province
      • Astaneh
    		Nezafatis, N. (2006): Au-Sn-W-Cu Mineralization in the Astaneh-Sarband Area, West Central Iran. PhD thesis, University of Tübingen (Germany), 116 pp.
    Japan
     
    • Honshu Island
      • Chubu Region
        • Gifu Prefecture
          • Shirakawamura
    		Matsubara, S. & Miyawaki, R. (2006) Catalogue of Japanese Minerals (National Science Museum)
      • Chugoku Region
        • Yamaguchi Prefecture
          • Hagi City
            • Asahi-son
    		Nakajima et al (1981) Sanko-Gakkai Kou'en-Youshi, 92.
      • Tohoku Region
        • Yamagata Prefecture
          • Mogami
    		Yokoro, Y. and Nakashima, K. (2010): Ag-Cu-Pb-Bi-S Minerals Newly Discovered from the Ohori Base Metal Deposit, Yamagata Prefecture, NE Japan: Implications for Bi-metallogenesis in the Green-Tuff Region. Resource Geology, 60, 1-17.
    Kazakhstan
     
    Spiridonov, E. M. (1982): Mineralogy of the Ichkeul'mes skarn copper deposit, central Kazakhstan. Novye Dannye o Mineralakh 30, 208-226.
    • Karagandy Province (Qaragandy Oblysy; Karaganda Oblast')
      • Akchatau (Aqshatau; Akschatau; Akchataul; Akshatau)
    		Efimov A.V. Bismuthian mineralisation of tin and wolfram deposits, 1993
    Peru
     
    • Huancavelica Department
      • Angaraes Province
    		Min.Rec. 28, no.4 (1997)
    Hyrsl & Rosales (2003) Mineralogical Record, 34, 241-254.; Hyrsl & Rosales (2003) Mineralogical Record, 34, 241-254.
    Poland
     
    • Lower Silesia (Dolnośląskie)
      • Rudawy Janowickie Mts
        • Czarnów
          • Rędziny
    		Gołębiowska B., Pieczka A., Parafiniuk J. 2006: Cu(Ag)-Pb-Bi(Sb) sulphosalts from Rędziny (Western Sudetes, Poland). Mineralogia Polonica - Special Papers, vol. 28, 78-80
    Romania
     
    • Bihor Co.
      • Nucet
        • Băiţa Mining District (Baita Bihor; Rézbánya)
    		Zajzon, N., Szentpéteri, K., Fehér, B., Szakáll, S. & Kristály, F. (2012): Krupkaite from Avram Iancu mine, Băiţa (Bihor) metallogenic district, Romania [http://www.mineral.hermuz.hu/acta_07/pdf/159-Zajzon.pdf]
    • Maramureș Co.
      • Baia Borsa
    		Nigel G. Cook : "Bismuth Sulphosalts from Hydrothermal Vein Deposits of Neogen Age, N.W. Romania, Mitt. Österr. Miner. Ges. , 143, 1998 / Lecture to the Austrian Mineralogical Society, 23rd June 1997, Salzburg.
    Slovakia
     
    • Banská Bystrica Region
    		Ďuďa R.,Kotuľak P., Káňa R., 1993: Bergbau und Mineralien von Banská Štiavnica (Schemnitz), Slowakei. Emser Hefte, 14, 3, 1-70, Haltern
      • Brezno Co.
        • Bystrá
    		Pršek J.,2004: Štruktžúra a kryštalochémia sulfosolí zo sulfidických mineralizácií Západných Karpát (Kandid. dizert. práca),Manuskript, archív Kated. miner. a petrológie PFUK Bratislava, 135 p.; - Pršek, J., Ozdín, D. & Sejkora, J. (2008): Eclarite and associated Bi sulfosalts from the Brezno-Hviezda occurrence (Nízke Tatry Mts, Slovak Republic). Neues Jahrbuch für Mineralogie - Abhandlungen, 185, 117-130.
    • Košice Region
      • Rožňava Co.
        • Dobšiná (Dobschau) Mining District
    		Koděra et all.,1990: Topografická mineralógia Slovenska, I-III, 1590p
    Žák, L. & Hybler, J. (1981): Krupkaite (x=1,3) from Dobšiná CSSR. N. Jb. Miner. Mth. 5, 206-214.
      • Spišská Nová Ves Co.
    		Pršek J.,2004: Štruktžúra a kryštalochémia sulfosolí zo sulfidických mineralizácií Západných Karpát (Kandid. dizert. práca),Manuskript, archív Kated. miner. a petrológie PFUK Bratislava, 135 p.
    • Žilina Region
      • Liptovský Mikuláš Co.
    		Chovan M., Michálek J., 1988: Bismutín a tetradymit na Sb ložisku Dúbrava. Min.Slovaca, Bratislava, 20, 2, 161-168
    Ozdin D., Chovan M., 1999: New mineralogical and paragenetic knowledge about siderite veins in the vicinity of Vyšná Boca, Nízke Tatry Mts. Slov. Geol. Magazine, Bratislava, 5, 4, 255-271
    Ozdín D. (2003): Mineralógia a genéza sideritovej mineralizácie Ďumbierskych Tatier. Dissertation thesis, Comenius University, 194 p.
    Sweden
     
    • Småland
      • Västervik
    		CanMin 25, 393
    Switzerland
     
    • Grischun (Grisons; Graubünden)
      • Bregaglia Valley (Bergell)
        • Albigna Valley
    		Schweizer Strahler, Vol. 9 Nr. 11 Aug. 1993
        • Bondasca Valley
    		Stalder, H. A., Wagner, A., Graeser, S. and Stuker, P. (1998): "Mineralienlexikon der Schweiz", Verlag Wepf & Co. (Basel), p. 80
    • Wallis (Valais)
      • Anniviers Valley
        • Saint-Luc
    		Ansermet, S. (2012): Mines et minéraux du Valais - II. Anniviers et Tourtemagne. With contributions by N. Meisser, Ed. Porte-plumes (Ayer)
    Ansermet, S. (2012): Mines et minéraux du Valais - II. Anniviers et Tourtemagne. With contributions by N. Meisser, Ed. Porte-plumes (Ayer)
    UK
     
    • England
      • Cumbria
        • North and Western Region (Cumberland)
          • Caldbeck Fells
            • Carrock Fell
    		BMS Database
    Ukraine
     
    • Odessa Oblast'
      • Dnister-Bug domain
        • Savran-Sinistovska ore zone
    USA
     
    • California
      • Inyo Co.
        • Darwin District
          • Darwin
    		Mineral News: 16 (9):1; Gail E. Dunning, Yves MoÎlo, and Joseph F. Cooper, Jr. (2000) Ag-Cu-Pb-Bi Sulfosalts New to Darwin, Inyo County, California
    • Colorado
      • Clear Creek Co.
        • Alice District
    		Minerals of Colorado (1997) Eckel, E. B.
    • Montana
      • Jefferson Co.
        • Whitehall District (Cardwell District)
    		Spry, P.G., Foster, F., Truckle, J.S., and Chadwick, T.H. (1997): Mineralogy and Petrology 59, 143-164.; Economic Geology,(1996) Vol. 91-3, pp.507-526
    • Nevada
      • Esmeralda Co.
        • Tule Canyon District
    		NBMG Spec. Pub. 31 Minerals of Nevada
    • Utah
      • Salt Lake Co.
        • Wasatch Mts
          • Little Cottonwood District (Alta District)
    		Alan Pring (1989). Structural disorderln aikinite and krupkaite. American Mineralogist, 74, 250-255.
    Mineral and/or Locality
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