Motukoreaite
A valid IMA mineral species - questionable
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About Motukoreaite
Formula:
Mg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O
Colour:
Colorless, white, yellow
Lustre:
Dull
Hardness:
1 - 1½
Specific Gravity:
1.48 - 1.53
Crystal System:
Trigonal
Member of:
Name:
Named by K.A. Rodgers, J.E. Chisholm, R.J. Davis, and C.S. Nelson in 1977 for the Maori name of the type locality, Motukorea, meaning 'island of cormorants'.
Type Locality:
Partial dehydration readily occurs.
As part of the recent re-evaluation of the nomenclature of the hydrotalcite supergroup (Mills et al., 2012), motukoreaite was identified as a questionable species which needs further investigation. The range of composition currently ascribed to motukoreaite may represent more than one species.
As part of the recent re-evaluation of the nomenclature of the hydrotalcite supergroup (Mills et al., 2012), motukoreaite was identified as a questionable species which needs further investigation. The range of composition currently ascribed to motukoreaite may represent more than one species.
Unique Identifiers
Mindat ID:
2793
Long-form identifier:
mindat:1:1:2793:5
GUID
(UUID V4):
(UUID V4):
4a02cac0-82a5-40c2-854e-7c625e635d90
IMA Classification of Motukoreaite
Approved, Questionable
IMA Formula:
Mg6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O
First published:
1977
Classification of Motukoreaite
7.DD.35
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
17.1.7.1
17 : COMPOUND CARBONATES
1 : Miscellaneous
17 : COMPOUND CARBONATES
1 : Miscellaneous
12.2.4
12 : Carbonates with other anions
2 : Carbonates with sulphate
12 : Carbonates with other anions
2 : Carbonates with sulphate
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.
Symbol | Source | Reference |
---|---|---|
Mtu | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Mtu | Warr (2020) | Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30 |
Physical Properties of Motukoreaite
Dull
Transparency:
Translucent
Colour:
Colorless, white, yellow
Streak:
White
Hardness:
1 - 1½ on Mohs scale
Density:
1.48 - 1.53 g/cm3 (Measured) 1.478 g/cm3 (Calculated)
Optical Data of Motukoreaite
Type:
Uniaxial
RI values:
nα = 1.510 nβ = 1.510
Max Birefringence:
δ = 1.510
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Low
Chemistry of Motukoreaite
Mindat Formula:
Mg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O
Chemical Analysis
Oxide wt%:
1 | |
---|---|
Na2O | 1.6 % |
MgO | 16 % |
Al2O3 | 20 % |
SO3 | 15 % |
CaO | 0 % |
Rest | 48 % |
Total: | 100.6 % |
Sample references:
ID | Locality | Reference | Notes |
---|---|---|---|
1 | Motukoreaite occurrence, Hoyo Azul, Playa Blanca, Yaiza, Lanzarote, Las Palmas Province, Canary Islands, Spain | average of 2 semiquantitative point analyses performed by Joy Desor. |
Crystallography of Motukoreaite
Crystal System:
Trigonal
Class (H-M):
3m (3 2/m) - Hexagonal Scalenohedral
Space Group:
R3m
Cell Parameters:
a = 9.172(2) Å, c = 33.51(1) Å
Ratio:
a:c = 1 : 3.654
Unit Cell V:
2,441.37 ų (Calculated from Unit Cell)
Z:
3
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0014801 | Motukoreaite | Rius J, Plana F (1986) Contribution to the superstructure resolution of the double layer mineral motukoreaite Neues Jahrbuch fur Mineralogie, Monatshefte 1986 263-272 | 1986 | the Emile Baudot bank, western Mediterranean | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
11.32 Å | (vvs) |
5.58 Å | (s) |
4.59 Å | (s) |
3.72 Å | (s) |
2.578 Å | (s) |
2.386 Å | (s) |
2.158 Å | (s) |
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 3a: Earth’s earliest Hadean crust | >4.50 |
8 : Mafic igneous rocks | |
10 : Basalt-hosted zeolite minerals |
Type Occurrence of Motukoreaite
General Appearance of Type Material:
White, clay-like. A box-work of plate-like crystals with a hexagonal form in which individuals measured about 3 × 3 × 0.02 microns.
Place of Conservation of Type Material:
University of Auckland, Auckland, New Zealand.
The Natural History Museum, London, England, 1977,422.
National Museum of Natural History, Washington, D.C., USA, 142971.
The Natural History Museum, London, England, 1977,422.
National Museum of Natural History, Washington, D.C., USA, 142971.
Geological Setting of Type Material:
Clay-like cement in both beach-rock and basaltic volcanic tuffs.
Reference:
Rodgers, K.A., Chisholm, J.E., Davis, R.J., Nelson, C.S. (1977) Motukoreaite, a new hydrated carbonate, sulphate, and hydroxide of Mg and Al from Auckland, New Zealand. Mineralogical Magazine: 41: 389–390.
Synonyms of Motukoreaite
Other Language Names for Motukoreaite
Relationship of Motukoreaite to other Species
Member of:
Other Members of this group:
Erssonite | Mg7Fe3+2(OH)18[Ca(H2O)6](SO4)2 · 12H2O | Trig. 3m (3 2/m) : P3c1 |
Natroglaucocerinite | Zn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O | Hex. |
Nikischerite | Fe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O | Trig. 3 : R3 |
Shigaite | Mn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O | Trig. 3 : R3 |
Wermlandite | Mg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2O | Trig. 3m (3 2/m) : P3c1 |
Common Associates
Associated Minerals Based on Photo Data:
29 photos of Motukoreaite associated with Phillipsite-K | (K,Na,Ca0.5,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2O |
17 photos of Motukoreaite associated with Calcite | CaCO3 |
12 photos of Motukoreaite associated with Phillipsite Subgroup | |
3 photos of Motukoreaite associated with Gismondine Subgroup | |
2 photos of Motukoreaite associated with Smectite Group | A0.3D2-3[T4O10]Z2 · nH2O |
1 photo of Motukoreaite associated with Nordstrandite | Al(OH)3 |
1 photo of Motukoreaite associated with Pyroxene Group | ADSi2O6 |
1 photo of Motukoreaite associated with Aegirine | NaFe3+Si2O6 |
Related Minerals - Strunz-mindat Grouping
7.DD. | Asagiite | NiCu4(SO4)2(OH)6 · 6H2O |
7.DD.05 | Felsőbányaite | Al4(SO4)(OH)10 · 4H2O |
7.DD.07 | Llantenesite | Cu6Al[SeO4](OH)12Cl · 3H2O |
7.DD.10 | Langite | Cu4(SO4)(OH)6 · 2H2O |
7.DD.10 | Posnjakite | Cu4(SO4)(OH)6 · H2O |
7.DD.10 | Wroewolfeite | Cu4(SO4)(OH)6 · 2H2O |
7.DD.10 | Gobelinite | CoCu4(SO4)2(OH)6 · 6H2O |
7.DD.10 | Fehrite | MgCu4(SO4)2(OH)6 · 6H2O |
7.DD.15 | Spangolite | Cu6Al(SO4)(OH)12Cl · 3H2O |
7.DD.15 | Kobyashevite | Cu5(SO4)2(OH)6 · 4H2O |
7.DD.15 | Unnamed (Dimorph of Devilline) | CaCu4(SO4)2(OH)6 · 3H2O |
7.DD.20 | Ktenasite | ZnCu4(SO4)2(OH)6 · 6H2O |
7.DD.25 | Christelite | Cu2Zn3(SO4)2(OH)6 · 4H2O |
7.DD.30 | Campigliaite | Mn2+Cu4(SO4)2(OH)6 · 4H2O |
7.DD.30 | Devilline | CaCu4(SO4)2(OH)6 · 3H2O |
7.DD.30 | Orthoserpierite | Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O |
7.DD.30 | Serpierite | Ca(Cu,Zn)4(SO4)2(OH)6 · 3H2O |
7.DD.30 | Niedermayrite | CdCu4(SO4)2(OH)6 · 4H2O |
7.DD.30 | Edwardsite | Cu3Cd2(SO4)2(OH)6 · 4H2O |
7.DD.35 | Carrboydite | (Ni1-xAlx)(SO4)x/2(OH)2 · nH2O |
7.DD.35 | Glaucocerinite | (Zn1-xAlx)(OH)2(SO4)x/2 · nH2O |
7.DD.35 | Honessite | (Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2O |
7.DD.35 | Hydrohonessite | (Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2O |
7.DD.35 | Mountkeithite | [(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2O |
7.DD.35 | Shigaite | Mn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
7.DD.35 | Wermlandite | Mg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2O |
7.DD.35 | Woodwardite | Cu1-xAlx(OH)2(SO4)x/2 · nH2O |
7.DD.35 | Zincaluminite | Zn6Al6(SO4)2(OH)16 · 5H2O |
7.DD.35 | Hydrowoodwardite | (Cu1-xAlx)(OH)2[SO4]x/2 · nH2O |
7.DD.35 | Zincowoodwardite | Zn1-xAlx(OH)2[SO4]x/2 · nH2O |
7.DD.35 | Natroglaucocerinite | Zn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
7.DD.35 | Nikischerite | Fe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O |
7.DD.40 | Isselite | Cu6(SO4)(OH)10 · 5H2O |
7.DD.40 | Lawsonbauerite | (Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2O |
7.DD.40 | Torreyite | (Mg,Mn2+)7◻2Mn2+2Zn4(SO4)2(OH)22 · 8H2O |
7.DD.45 | Mooreite | Mg9◻2Mn2Zn4(SO4)2(OH)26 · 8H2O |
7.DD.45 | Hodgesmithite | (Cu,Zn)6Zn(SO4)2(OH)10 · 3H2O |
7.DD.47 | Lahnsteinite | Zn4(SO4)(OH)6 · 3H2O |
7.DD.50 | Namuwite | Zn4(SO4)(OH)6 · 4H2O |
7.DD.50 | Minohlite | (Cu,Zn)7(SO4)2(OH)10 · 8H2O |
7.DD.52 | Lauraniite | Cu6Cd2(SO4)2(OH)12 · 5H2O |
7.DD.55 | Bechererite | Zn7Cu(OH)13[(SiO(OH)3(SO4)] |
7.DD.60 | Ramsbeckite | (Cu,Zn)15(SO4)4(OH)22 · 6H2O |
7.DD.65 | Vonbezingite | Ca6Cu3(SO4)3(OH)12 · 2H2O |
7.DD.70 | Redgillite | Cu6(SO4)(OH)10 · H2O |
7.DD.75 | Chalcoalumite | CuAl4(SO4)(OH)12 · 3H2O |
7.DD.75 | Nickelalumite | NiAl4(SO4)(OH)12(H2O)3 |
7.DD.75 | Kyrgyzstanite | ZnAl4(SO4)(OH)12 · 3H2O |
7.DD.80 | Guarinoite | Zn6(SO4)(OH)10 · 5H2O |
7.DD.80 | Schulenbergite | (Cu,Zn)7(SO4)2(OH)10 · 3H2O |
7.DD.80 | Thérèsemagnanite | NaCo4(SO4)(OH)6Cl · 6H2O |
7.DD.80 | UM1992-30-SO:CCuHZn | (Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2O |
7.DD.85 | Montetrisaite | Cu6(SO4)(OH)10 · 2H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Motukoreaite
mindat.org URL:
https://www.mindat.org/min-2793.html
Please feel free to link to this page.
Please feel free to link to this page.
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References for Motukoreaite
Reference List:
Rodgers, K. A., Chisholm, J. E., Davis, R. J., Nelson, C. S. (1977) Motukoreaite, a new hydrated carbonate, sulphate, and hydroxide of Mg and Al from Auckland, New Zealand. Mineralogical Magazine, 41 (319) 389-390 doi:10.1180/s0026461x00038147
Fleischer, Michael, Cabri, Louis J. (1978) New mineral names. American Mineralogist, 63 (5-6) 598-600
Hawthorne, Frank C., Jambor, John L., Bladh, Kenneth W., Burke, Ernst A. J., Grice, Joel D., Phillips, Don, Roberts, Andrew C., Schedler, Robert A., E., James (1987) New mineral names. American Mineralogist, 72 (9-10) 1023-1028
Localities for Motukoreaite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Australia | |
| Clissold (2007) |
Austria | |
| Alker et al. (1981) +3 other references |
Italy | |
| Daleffe et al. (2008) |
New Zealand (TL) | |
| Rodgers et al. (1977) |
Poland | |
| Wachowiak et al. (2016) |
Spain | |
| Van Opstal (2021) +2 other references |
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Stradner Kogel, Wilhelmsdorf, Bad Gleichenberg, Südoststeiermark District, Styria, Austria