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Motukoreaite

A valid IMA mineral species - questionable
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About MotukoreaiteHide

Formula:
Mg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O
Colour:
Colorless, white, yellow
Lustre:
Dull
Hardness:
1 - 1½
Specific Gravity:
1.48 - 1.53
Crystal System:
Trigonal
Name:
Named by K.A. Rodgers, J.E. Chisholm, R.J. Davis, and C.S. Nelson in 1977 for the Maori name of the type locality, Motukorea, meaning 'island of cormorants'.
Partial dehydration readily occurs.

As part of the recent re-evaluation of the nomenclature of the hydrotalcite supergroup (Mills et al., 2012), motukoreaite was identified as a questionable species which needs further investigation. The range of composition currently ascribed to motukoreaite may represent more than one species.


Unique IdentifiersHide

Mindat ID:
2793
Long-form identifier:
mindat:1:1:2793:5
GUID
(UUID V4):
4a02cac0-82a5-40c2-854e-7c625e635d90

IMA Classification of MotukoreaiteHide

Classification of MotukoreaiteHide

7.DD.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
17.1.7.1

17 : COMPOUND CARBONATES
1 : Miscellaneous
12.2.4

12 : Carbonates with other anions
2 : Carbonates with sulphate

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

Please only use the official IMA–CNMNC symbol. Older variants are listed for historical use only.

SymbolSourceReference
MtuIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43
MtuWarr (2020)Warr, L.N. (2020) Recommended abbreviations for the names of clay minerals and associated phases. Clay Minerals, 55, 261–264 doi:10.1180/clm.2020.30

Physical Properties of MotukoreaiteHide

Transparency:
Translucent
Colour:
Colorless, white, yellow
Streak:
White
Hardness:
1 - 1½ on Mohs scale
Density:
1.48 - 1.53 g/cm3 (Measured)    1.478 g/cm3 (Calculated)

Optical Data of MotukoreaiteHide

Type:
Uniaxial
RI values:
nα = 1.510 nβ = 1.510
Max Birefringence:
δ = 1.510
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Low

Chemistry of MotukoreaiteHide

Mindat Formula:
Mg6Al3(OH)18[Na(H2O)6][SO4]2 · 6H2O

Chemical AnalysisHide

Oxide wt%:
 1
Na2O1.6 %
MgO16 %
Al2O320 %
SO315 %
CaO0 %
Rest48 %
Total:100.6 %

Crystallography of MotukoreaiteHide

Crystal System:
Trigonal
Class (H-M):
3m (3 2/m) - Hexagonal Scalenohedral
Space Group:
R3m
Cell Parameters:
a = 9.172(2) Å, c = 33.51(1) Å
Ratio:
a:c = 1 : 3.654
Unit Cell V:
2,441.37 ų (Calculated from Unit Cell)
Z:
3

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014801MotukoreaiteRius J, Plana F (1986) Contribution to the superstructure resolution of the double layer mineral motukoreaite Neues Jahrbuch fur Mineralogie, Monatshefte 1986 263-2721986the Emile Baudot bank, western Mediterranean0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
11.32 Å(vvs)
5.58 Å(s)
4.59 Å(s)
3.72 Å(s)
2.578 Å(s)
2.386 Å(s)
2.158 Å(s)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Stage 3a: Earth’s earliest Hadean crust>4.50
8 : Mafic igneous rocks
10 : Basalt-hosted zeolite minerals

Type Occurrence of MotukoreaiteHide

General Appearance of Type Material:
White, clay-like. A box-work of plate-like crystals with a hexagonal form in which individuals measured about 3 × 3 × 0.02 microns.
Place of Conservation of Type Material:
University of Auckland, Auckland, New Zealand.
The Natural History Museum, London, England, 1977,422.
National Museum of Natural History, Washington, D.C., USA, 142971.
Geological Setting of Type Material:
Clay-like cement in both beach-rock and basaltic volcanic tuffs.
Reference:
Rodgers, K.A., Chisholm, J.E., Davis, R.J., Nelson, C.S. (1977) Motukoreaite, a new hydrated carbonate, sulphate, and hydroxide of Mg and Al from Auckland, New Zealand. Mineralogical Magazine: 41: 389–390.

Synonyms of MotukoreaiteHide

Other Language Names for MotukoreaiteHide

Relationship of Motukoreaite to other SpeciesHide

Other Members of this group:
ErssoniteMg7Fe3+2(OH)18[Ca(H2O)6](SO4)2 · 12H2OTrig. 3m (3 2/m) : P3c1
NatroglaucoceriniteZn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OHex.
NikischeriteFe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig. 3 : R3
ShigaiteMn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig. 3 : R3
WermlanditeMg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : P3c1

Common AssociatesHide

Associated Minerals Based on Photo Data:
29 photos of Motukoreaite associated with Phillipsite-K(K,Na,Ca0.5,Ba0.5)4-7[Al4-7Si12-9O32] . 12H2O
17 photos of Motukoreaite associated with CalciteCaCO3
12 photos of Motukoreaite associated with Phillipsite Subgroup
3 photos of Motukoreaite associated with Gismondine Subgroup
2 photos of Motukoreaite associated with Smectite GroupA0.3D2-3[T4O10]Z2 · nH2O
1 photo of Motukoreaite associated with NordstranditeAl(OH)3
1 photo of Motukoreaite associated with Pyroxene GroupADSi2O6
1 photo of Motukoreaite associated with AegirineNaFe3+Si2O6

Related Minerals - Strunz-mindat GroupingHide

7.DD.AsagiiteNiCu4(SO4)2(OH)6 · 6H2OMon. 2/m : P21/b
7.DD.05FelsőbányaiteAl4(SO4)(OH)10 · 4H2OMon. 2 : P21
7.DD.07LlantenesiteCu6Al[SeO4](OH)12Cl · 3H2OTrig. 3m : P3 1c
7.DD.10LangiteCu4(SO4)(OH)6 · 2H2OMon. m
7.DD.10PosnjakiteCu4(SO4)(OH)6 · H2OMon. m : Pm
7.DD.10WroewolfeiteCu4(SO4)(OH)6 · 2H2OMon. m : Pm
7.DD.10GobeliniteCoCu4(SO4)2(OH)6 · 6H2OMon. 2/m : P21/m
7.DD.10FehriteMgCu4(SO4)2(OH)6 · 6H2OMon. 2/m : P21/b
7.DD.15SpangoliteCu6Al(SO4)(OH)12Cl · 3H2OTrig. 3m : P3 1c
7.DD.15KobyasheviteCu5(SO4)2(OH)6 · 4H2OTric. 1 : P1
7.DD.15Unnamed (Dimorph of Devilline)CaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
7.DD.20KtenasiteZnCu4(SO4)2(OH)6 · 6H2OMon. 2/m : P21/b
7.DD.25ChristeliteCu2Zn3(SO4)2(OH)6 · 4H2OTric. 1 : P1
7.DD.30CampigliaiteMn2+Cu4(SO4)2(OH)6 · 4H2OMon. 2 : B2
7.DD.30DevillineCaCu4(SO4)2(OH)6 · 3H2OMon. 2/m : P21/b
7.DD.30OrthoserpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OOrth. mm2 : Pca21
7.DD.30SerpieriteCa(Cu,Zn)4(SO4)2(OH)6 · 3H2OMon. 2/m : B2/b
7.DD.30NiedermayriteCdCu4(SO4)2(OH)6 · 4H2OMon. 2/m : P21/m
7.DD.30EdwardsiteCu3Cd2(SO4)2(OH)6 · 4H2O Mon. 2/m : P21/b
7.DD.35Carrboydite(Ni1-xAlx)(SO4)x/2(OH)2 · nH2OHex.
7.DD.35Glaucocerinite(Zn1-xAlx)(OH)2(SO4)x/2 · nH2OHex.
7.DD.35Honessite(Ni1-xFe3+x)(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35Hydrohonessite(Ni1-xFe3+x)(OH)2(SO4)x/2 · nH2OHex.
7.DD.35Mountkeithite[(Mg1-xFe3+x)(OH)2][SO4]x/2 · nH2OHex.
7.DD.35ShigaiteMn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig. 3 : R3
7.DD.35WermlanditeMg7Al2(OH)18[Ca(H2O)6][SO4]2 · 6H2OTrig. 3m (3 2/m) : P3c1
7.DD.35WoodwarditeCu1-xAlx(OH)2(SO4)x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincaluminiteZn6Al6(SO4)2(OH)16 · 5H2O
7.DD.35Hydrowoodwardite(Cu1-xAlx)(OH)2[SO4]x/2 · nH2OTrig. 3m (3 2/m) : R3m
7.DD.35ZincowoodwarditeZn1-xAlx(OH)2[SO4]x/2 · nH2OTrig.
7.DD.35NatroglaucoceriniteZn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OHex.
7.DD.35NikischeriteFe2+6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2OTrig. 3 : R3
7.DD.40IsseliteCu6(SO4)(OH)10 · 5H2OOrth. mm2 : Pmn21
7.DD.40Lawsonbauerite(Mn2+,Mg)9Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.40Torreyite(Mg,Mn2+)72Mn2+2Zn4(SO4)2(OH)22 · 8H2OMon. 2/m : P21/b
7.DD.45MooreiteMg92Mn2Zn4(SO4)2(OH)26 · 8H2OMon. 2/m : P2/b
7.DD.45Hodgesmithite(Cu,Zn)6Zn(SO4)2(OH)10 · 3H2OTrig. 3 : P3
7.DD.47LahnsteiniteZn4(SO4)(OH)6 · 3H2O Tric. 1 : P1
7.DD.50NamuwiteZn4(SO4)(OH)6 · 4H2OTrig. 3 : P3
7.DD.50Minohlite(Cu,Zn)7(SO4)2(OH)10 · 8H2OHex.
7.DD.52LauraniiteCu6Cd2(SO4)2(OH)12 · 5H2OMon. 2/m : P21/b
7.DD.55BechereriteZn7Cu(OH)13[(SiO(OH)3(SO4)]Trig. 3 : P3
7.DD.60Ramsbeckite(Cu,Zn)15(SO4)4(OH)22 · 6H2OMon. 2/m
7.DD.65VonbezingiteCa6Cu3(SO4)3(OH)12 · 2H2OMon. 2/m : P21/b
7.DD.70RedgilliteCu6(SO4)(OH)10 · H2OMon. 2/m : P21/b
7.DD.75ChalcoalumiteCuAl4(SO4)(OH)12 · 3H2OMon. 2 : P21
7.DD.75NickelalumiteNiAl4(SO4)(OH)12(H2O)3Mon. 2/m
7.DD.75KyrgyzstaniteZnAl4(SO4)(OH)12 · 3H2OMon. 2/m
7.DD.80GuarinoiteZn6(SO4)(OH)10 · 5H2OHex.
7.DD.80Schulenbergite(Cu,Zn)7(SO4)2(OH)10 · 3H2OTrig. 3
7.DD.80ThérèsemagnaniteNaCo4(SO4)(OH)6Cl · 6H2OTrig. 3 : P3
7.DD.80UM1992-30-SO:CCuHZn(Zn,Cu)7(SO4,CO3)2(OH)10 · 3H2OTrig. 3 : P3
7.DD.85MontetrisaiteCu6(SO4)(OH)10 · 2H2OOrth. mm2 : Cmc21

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for MotukoreaiteHide

References for MotukoreaiteHide

Reference List:

Localities for MotukoreaiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Western Australia
    • Coolgardie Shire
      • Widgiemooltha
Clissold (2007)
Austria
 
  • Styria
    • Südoststeiermark District
      • Bad Gleichenberg
        • Wilhelmsdorf
Alker et al. (1981) +3 other references
Italy
 
  • Veneto
    • Vicenza Province
      • Crespadoro
        • Chiampo Valley
Daleffe et al. (2008)
New Zealand (TL)
 
  • Auckland Region
Rodgers et al. (1977)
Poland
 
  • Greater Poland Voivodeship
    • Koło County
      • Gmina Kłodawa
Wachowiak et al. (2016)
Spain
 
  • Canary Islands
    • Las Palmas Province
      • Lanzarote
        • Yaiza
          • Playa Blanca
            • Hoyo Azul
Van Opstal (2021) +2 other references
 
Mineral and/or Locality  
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