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Motukoreaite

Big Photo

Stradner Kogel Mt., Wilhelmsdorf, Bad Gleichenberg, Styria, Austria
© Thomas Witzke

Show Motukoreaite Photos (13)
Formula:
NaMg
 
19
Al
 
12
(CO
 
3
)
 
6.5
(SO
 
4
)
 
4
(OH)
 
54
·28H
 
2
O
System:Trigonal


Partial dehydration readily occurs.

Classification of Motukoreaite

IMA status:Approved
Strunz 8th edition ID:6/D.14-20
Nickel-Strunz 10th (pending) edition ID:7.DD.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
Dana 8th edition ID:17.1.7.1

17 : COMPOUND CARBONATES
1 : Miscellaneous
Hey's CIM Ref.:12.2.4

12 : Carbonates with other anions
2 : Carbonates with sulphate
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Type Occurrence of Motukoreaite

Type Locality:Browns Island (Motukorea), Auckland City, Auckland, North Island, New Zealand
Year of Discovery:1977

Crystallography of Motukoreaite

Crystal System:Trigonal
Class (H-M):3m (3 2/m) - Hexagonal Scalenohedral
Space Group:R3m {R3 2/m}
Cell Parameters:a = 9.172(2) Å, c = 33.51(1) Å
Ratio:a:c = 1 : 3.654
Unit Cell Volume:V 2,441.37 ų (Calculated from Unit Cell)
Z:3
X-Ray Powder Diffraction:
d-spacingIntensity
11.32 (vvs)
5.58 (s)
4.59 (s)
3.72 (s)
2.578 (s)
2.386 (s)

Optical Data of Motukoreaite

Type:Uniaxial
RI values: nα = 1.510 nβ = 1.510
Maximum Birefringence:δ = 1.510

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low

Chemical Properties of Motukoreaite

Formula:
NaMg
 
19
Al
 
12
(CO
 
3
)
 
6.5
(SO
 
4
)
 
4
(OH)
 
54
·28H
 
2
O
Essential elements:Al, C, H, Mg, Na, O, S
All elements listed in formula:Al, C, H, Mg, Na, O, S

Relationship of Motukoreaite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
7.DD.05Felsőbányaite
Al
 
4
[(OH)
 
10
|SO
 
4
] · 4H
 
2
O
7.DD.10Langite
Cu
 
4
[(OH)
 
6
|SO
 
4
] · 2H
 
2
O
7.DD.10Posnjakite
Cu
 
4
[(OH)
 
6
|SO
 
4
] · H
 
2
O
7.DD.10Wroewolfeite
Cu
 
4
[(OH)
 
6
|SO
 
4
] · 2H
 
2
O
7.DD.15Spangolite
Cu
 
6
Al[(OH)
 
12
|Cl|SO
 
4
] · 3H
 
2
O
7.DD.20Ktenasite
Zn(Cu,Zn)
 
4
[(OH)
 
6
|(SO
 
4
)
 
2
] · 6H
 
2
O
7.DD.25Christelite
Cu
 
2
Zn
 
3
[(OH)
 
6
|(SO
 
4
)
 
2
] · 4H
 
2
O
7.DD.30Campigliaite
Mn
2+
 
Cu
 
4
[(OH)
 
6
|(SO
 
4
)
 
2
] · 4H
 
2
O
7.DD.30Devilline
CaCu
 
4
(SO
 
4
)
 
2
(OH)
 
6
·3H
 
2
O
7.DD.30Orthoserpierite
Ca(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
·3H
 
2
O
7.DD.30Serpierite
Ca(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
·3H
 
2
O
7.DD.30Niedermayrite
CdCu
 
4
[(OH)
 
6
|(SO
 
4
)
 
2
] · 4H
 
2
O
7.DD.35Carrboydite
(Ni,Cu)
 
14
Al
 
9
[(OH)
 
43
|(SO
 
4
,CO
 
3
)
 
6
] · 7H
 
2
O
7.DD.35Glaucocerinite
(Zn,Cu)
 
10
Al
 
6
[(OH)
 
32
|(SO
 
4
)
 
3
] · 18H
 
2
O
7.DD.35Honessite
Ni
 
6
Fe
3+
2
[(OH)
 
16
|SO
 
4
] · 4H
 
2
O
7.DD.35Hydrohonessite
Ni
 
6
Fe
3+
2
[(OH)
 
16
|SO
 
4
] · 7H
 
2
O
7.DD.35Mountkeithite
(Mg,Ni)
 
11
(Fe
3+
 
,Cr
3+
 
,Al)
 
3
[(OH)
 
24
|(SO
 
4
,CO
 
3
)
 
3.5
] · 11H
 
2
O
7.DD.35Shigaite
Al
 
4
Mn
 
7
(SO
 
4
)
 
2
(OH)
 
22
·8H
 
2
O
7.DD.35Wermlandite
Mg
 
7
(Ca,Mg)(Al,Fe)
 
2
(SO
 
4
)
 
2
(OH)
 
18
(H
 
2
O)
 
12
7.DD.35Woodwardite
Cu
 
4
Al
 
2
[(OH)
 
12
|SO
 
4
] · 2-4H
 
2
O
7.DD.35Zincaluminite
Zn
 
6
Al
 
6
[(OH)
 
13
|SO
 
4
]
 
2
 · 5H
 
2
O
7.DD.35Hydrowoodwardite
Cu
 
1-x
Al
 
x
[(OH)
 
2
|(SO
 
4
)
 
x/2
] · nH
 
2
O
7.DD.35Zincowoodwardite
Zn
 
1-x
Al
 
x
(SO
 
4
)
 
x/2
(OH)
 
2
·nH
 
2
O (?)
7.DD.35Natroglaucocerinite
[(Zn,Cu)
 
5
Al
 
3
(OH)
 
16
][(SO
 
4
)
 
1.5
Na
 
1.5
(SO
 
4
)
 
0.75
(H
 
2
O)
 
9
]
7.DD.35Nikischerite
[AlFe
 
2
(OH)
 
6
]
 
3
(SO
 
4
)
 
2
Na(H
 
2
O)
 
6
·6H
 
2
O
7.DD.40Lawsonbauerite
(Mn
2+
 
,Mg)
 
9
Zn
 
4
[(OH)
 
11
|SO
 
4
]
 
2
 · 8H
 
2
O
7.DD.40Torreyite
(Mg,Mn
2+
 
)
 
9
Zn
 
4
[(OH)
 
11
|SO
 
4
]
 
2
 · 8H
 
2
O
7.DD.45Mooreite
(Mg,Zn,Mn
2+
 
)
 
15
[(OH)
 
13
|SO
 
4
]
 
2
 · 8H
 
2
O
7.DD.50Namuwite
(Zn,Cu)
 
4
[(OH)
 
6
|SO
 
4
] · 4H
 
2
O
7.DD.55Bechererite
(Zn,Cu)
 
6
Zn
 
2
[(OH)
 
12
|(SO
 
4
,HSiO
 
4
)
 
2
]
7.DD.60Ramsbeckite
(Cu,Zn)
 
15
[(OH)
 
22
|(SO
 
4
)
 
4
] · 6H
 
2
O
7.DD.65Vonbezingite
Ca
 
6
Cu
 
3
[(OH)
 
12
|(SO
 
4
)
 
3
] · 2H
 
2
O
7.DD.70Redgillite
Cu
 
6
[(OH)
 
10
|SO
 
4
] · H
 
2
O
7.DD.75Chalcoalumite
CuAl
 
4
[(OH)
 
12
|SO
 
4
] · 3H
 
2
O
7.DD.75Nickelalumite
(Ni,Cu)Al
 
4
[(OH)
 
12
|{SO
 
4
,(NO
 
3
)
 
2
}] · 3H
 
2
O
7.DD.75Kyrgyzstanite
ZnAl
 
4
(SO
 
4
)(OH)
 
12
·3H
 
2
O
7.DD.80Guarinoite
(Zn,Co,Ni)
 
6
[(OH,Cl)
 
10
|SO
 
4
] · 5H
 
2
O
7.DD.80Schulenbergite
(Cu,Zn)
 
7
[(OH)
 
10
|(SO
 
4
,CO
 
3
)
 
2
] · 3H
 
2
O
7.DD.80Thérèsemagnanite
(Co,Zn,Ni)
 
6
(SO
 
4
)(OH,Cl)
 
10
·8H
 
2
O
7.DD.80UM1992-30-SO:CCuHZn
(Zn,Cu)
 
7
[(SO
 
4
,CO
 
3
)
 
2
](OH)
 
10
 · 3H
 
2
O
7.DD.85Montetrisaite
Cu
 
6
(SO
 
4
)(OH)
 
10
·2H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
12.2.1Burkeite
Na
 
6
CO
 
3
(SO
 
4
)
 
2
12.2.2Hanksite
Na
 
22
K(SO
 
4
)
 
9
(CO
 
3
)
 
2
Cl
12.2.3Tychite
Na
 
6
Mg
 
2
SO
 
4
(CO
 
3
)
 
4
12.2.5Ferrotychite
Na
 
6
(Fe,Mn,Mg)
 
2
SO
 
4
(CO
 
3
)
 
4
12.2.6Nakauriite
Cu
 
8
[(OH)
 
6
|CO
 
3
|(SO
 
4
)
 
4
] · 48H
 
2
O
12.2.7Carbonatecyanotrichite
Cu
 
4
Al
 
2
[(OH)
 
12
|(CO
 
3
,SO
 
4
)] · 2H
 
2
O
12.2.8Rapidcreekite
Ca
 
2
[CO
 
3
|SO
 
4
] · 4H
 
2
O
12.2.9Tatarskite
Ca
 
6
Mg
 
2
(SO
 
4
)
 
2
(CO
 
3
)
 
2
Cl
 
4
(OH)
 
4
·7H
 
2
O
12.2.10Schulenbergite
(Cu,Zn)
 
7
[(OH)
 
10
|(SO
 
4
,CO
 
3
)
 
2
] · 3H
 
2
O
12.2.11Leadhillite
Pb
 
4
SO
 
4
(CO
 
3
)
 
2
(OH)
 
2
12.2.12Macphersonite
Pb
 
4
SO
 
4
(CO
 
3
)
 
2
(OH)
 
2
12.2.13Susannite
Pb
 
4
SO
 
4
(CO
 
3
)
 
2
(OH)
 
2
12.2.14Wherryite
Pb
 
7
Cu
 
2
(SO
 
4
)
 
4
(SiO
 
4
)
 
2
(OH)
 
2
12.2.15Caledonite
Cu
 
2
Pb
 
5
[(OH)
 
6
|CO
 
3
|(SO
 
4
)
 
3
]
12.2.16Nasledovite
PbMn
 
3
Al
 
4
(CO
 
3
)
 
4
SO
 
4
O
 
5
·5H
 
2
O
12.2.17Jouravskite
Ca
 
6
Mn
3+
2
[(OH)
 
4
|(SO
 
4
,CO
 
3
)]
 
3
 · 26H
 
2
O
12.2.18Schröckingerite
NaCa
 
3
(UO
 
2
)[F|(CO
 
3
)
 
3
|SO
 
4
] · 10H
 
2
O
12.2.19Manganotychite
Na
 
6
Mn
 
2
SO
 
4
(CO
 
3
)
 
4
12.2.20Hauckite
Fe
3+
3
(Mg,Mn
2+
 
)
 
24
Zn
 
18
[(OH)
 
81
|(CO
 
3
)
 
2
|(SO
 
4
)
 
4
]
12.2.21Paraotwayite
Ni(OH)
 
2-x
(SO
 
4
,CO
 
3
)
 
0.5x
12.2.22Carrboydite
(Ni,Cu)
 
14
Al
 
9
[(OH)
 
43
|(SO
 
4
,CO
 
3
)
 
6
] · 7H
 
2
O
12.2.23Mountkeithite
(Mg,Ni)
 
11
(Fe
3+
 
,Cr
3+
 
,Al)
 
3
[(OH)
 
24
|(SO
 
4
,CO
 
3
)
 
3.5
] · 11H
 
2
O
12.2.24Camerolaite
Cu
 
4
Al
 
2
[(OH)
 
10
|CO
 
3
|(HSbO
 
4
,SO
 
4
)] · 2H
 
2
O

Other Names for Motukoreaite

Synonyms:
IMA1976-033
Other Languages:
German:Motukoreait
Russian:Мотукореаит
Spanish:Motukoreaita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Motukoreaite

Reference List:Rodgers, K.A., J.E. Chisholm, R.J. Davis, and C.S. Nelson (1977): Motukoreaite, a new hydrated carbonate, sulphate, and hydroxide of Mg and Al from Auckland, New Zealand. Mineral. Mag., 41, 389–390.

American Mineralogist (1978): 63: 598-599.

Rius, J. and F. Plana (1986): Contribution to the superstructure resolution of the double layer mineral motukoreaite. Neues Jahrb. Mineral., Monatsh., 263–272.

Zamarreno, I., F. Plana, A. Vazquez, and D.A. Clague (1989): Motukoreaite: a common alteration product in submarine basalts. Am. Mineral., 74, 1054–1058.

Bryner, V., K.A. Rodgers, S.F. Courtney, and W. Postl (1991): Motukoreaite from Brown’s Island, New Zealand, and Stradner Kogel, Austria: a scanning electron microscope study. Neues Jahrb. Mineral., Abh., 163, 291–304.

Internet Links for Motukoreaite

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    Localities for Motukoreaite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Austria
     
    • Styria
      • Bad Gleichenberg
        • Wilhelmsdorf
    		R. Exel: Die Mineralien und Erzlagerstätten Österreichs (1993)
    Italy
     
    • Veneto
      • Vicenza Province
        • Crespadoro
          • Chiampo valley
    		Daleffe, A., & Boscardin, M. (2008): Motukoreaite. Primo ritrovamento in Italia. Rivista Mineralogica Italiana, 1/2008, 22-23
    New Zealand
     
    • North Island
      • Auckland
        • Auckland City
    		Min.Mag.(1977) 41, 389-390 and M21
    Mineral and/or Locality
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    Copyright © Jolyon Ralph and Ida Chau 1993-2009. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them.Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. If you would like to add information to improve the quality of our database, then click here to register. Current server date and time: 18th Oct 2009 02:27:27