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Orthoserpierite

Big Photo

Chessy-les-Mines, Rhône, Rhône-Alpes, France
© jm.CLAUDE

Show Orthoserpierite Photos (11)
Formula:
Ca(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
·3H
 
2
O
System:Orthorhombic


Devilline Group.

A species very hard to distinguish from devilline and bladed serpierite.

Classification of Orthoserpierite

IMA status:Approved
Strunz 8th edition ID:6/D.19-30
Nickel-Strunz 10th (pending) edition ID:7.DD.30

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
Dana 8th edition ID:31.6.7.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
6 : (AB)5(XO4)2Zq·xH2O
Hey's CIM Ref.:25.5.8

25 : Sulphates
5 : Sulphates of Zn and Hg
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Type Occurrence of Orthoserpierite

Type Locality:Chessy-les-Mines, Rhône, Rhône-Alpes, France
Year of Discovery:1985

Crystallography of Orthoserpierite

Crystal System:Orthorhombic
Cell Parameters:a = 22.1Å, b = 6.2Å, c = 20.39Å
Ratio:a:b:c = 3.565 : 1 : 3.289
Unit Cell Volume:V 2,793.84 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
d-spacingIntensity
10.21 (100)
5.10 (90)
3.400 (90)
3.184 (50)
2.610 (50)
2.558 (50)

Optical Data of Orthoserpierite

Type:Biaxial (-)
RI values: nα = 1.586 nβ = 1.645 nγ = 1.650
2V:Measured: 32° , Calculated: 30°
Maximum Birefringence:δ = 0.064

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:small

Chemical Properties of Orthoserpierite

Formula:
Ca(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
·3H
 
2
O
Essential elements:Ca, Cu, H, O, S
All elements listed in formula:Ca, Cu, H, O, S, Zn
Empirical Formula:
Ca1.08(Cu3.54Zn0.58)Sum=4.12(SO4)1.71(OH)6.98 •3.18H2O

Relationship of Orthoserpierite to other Species

Member of Group:
Devilline Group:
Related Minerals - Nickel-Strunz Grouping):

- +
7.DD.05Felsőbányaite
Al
 
4
[(OH)
 
10
|SO
 
4
] · 4H
 
2
O
7.DD.10Langite
Cu
 
4
[(OH)
 
6
|SO
 
4
] · 2H
 
2
O
7.DD.10Posnjakite
Cu
 
4
[(OH)
 
6
|SO
 
4
] · H
 
2
O
7.DD.10Wroewolfeite
Cu
 
4
[(OH)
 
6
|SO
 
4
] · 2H
 
2
O
7.DD.15Spangolite
Cu
 
6
Al[(OH)
 
12
|Cl|SO
 
4
] · 3H
 
2
O
7.DD.20Ktenasite
Zn(Cu,Zn)
 
4
[(OH)
 
6
|(SO
 
4
)
 
2
] · 6H
 
2
O
7.DD.25Christelite
Cu
 
2
Zn
 
3
[(OH)
 
6
|(SO
 
4
)
 
2
] · 4H
 
2
O
7.DD.30Campigliaite
Mn
2+
 
Cu
 
4
[(OH)
 
6
|(SO
 
4
)
 
2
] · 4H
 
2
O
7.DD.30Devilline
CaCu
 
4
(SO
 
4
)
 
2
(OH)
 
6
·3H
 
2
O
7.DD.30Serpierite
Ca(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
·3H
 
2
O
7.DD.30Niedermayrite
CdCu
 
4
[(OH)
 
6
|(SO
 
4
)
 
2
] · 4H
 
2
O
7.DD.35Carrboydite
(Ni,Cu)
 
14
Al
 
9
[(OH)
 
43
|(SO
 
4
,CO
 
3
)
 
6
] · 7H
 
2
O
7.DD.35Glaucocerinite
(Zn,Cu)
 
10
Al
 
6
[(OH)
 
32
|(SO
 
4
)
 
3
] · 18H
 
2
O
7.DD.35Honessite
Ni
 
6
Fe
3+
2
[(OH)
 
16
|SO
 
4
] · 4H
 
2
O
7.DD.35Hydrohonessite
Ni
 
6
Fe
3+
2
[(OH)
 
16
|SO
 
4
] · 7H
 
2
O
7.DD.35Motukoreaite
NaMg
 
19
Al
 
12
(CO
 
3
)
 
6.5
(SO
 
4
)
 
4
(OH)
 
54
·28H
 
2
O
7.DD.35Mountkeithite
(Mg,Ni)
 
11
(Fe
3+
 
,Cr
3+
 
,Al)
 
3
[(OH)
 
24
|(SO
 
4
,CO
 
3
)
 
3.5
] · 11H
 
2
O
7.DD.35Shigaite
Al
 
4
Mn
 
7
(SO
 
4
)
 
2
(OH)
 
22
·8H
 
2
O
7.DD.35Wermlandite
Mg
 
7
(Ca,Mg)(Al,Fe)
 
2
(SO
 
4
)
 
2
(OH)
 
18
(H
 
2
O)
 
12
7.DD.35Woodwardite
Cu
 
4
Al
 
2
[(OH)
 
12
|SO
 
4
] · 2-4H
 
2
O
7.DD.35Zincaluminite
Zn
 
6
Al
 
6
[(OH)
 
13
|SO
 
4
]
 
2
 · 5H
 
2
O
7.DD.35Hydrowoodwardite
Cu
 
1-x
Al
 
x
[(OH)
 
2
|(SO
 
4
)
 
x/2
] · nH
 
2
O
7.DD.35Zincowoodwardite
Zn
 
1-x
Al
 
x
(SO
 
4
)
 
x/2
(OH)
 
2
·nH
 
2
O (?)
7.DD.35Natroglaucocerinite
[(Zn,Cu)
 
5
Al
 
3
(OH)
 
16
][(SO
 
4
)
 
1.5
Na
 
1.5
(SO
 
4
)
 
0.75
(H
 
2
O)
 
9
]
7.DD.35Nikischerite
[AlFe
 
2
(OH)
 
6
]
 
3
(SO
 
4
)
 
2
Na(H
 
2
O)
 
6
·6H
 
2
O
7.DD.40Lawsonbauerite
(Mn
2+
 
,Mg)
 
9
Zn
 
4
[(OH)
 
11
|SO
 
4
]
 
2
 · 8H
 
2
O
7.DD.40Torreyite
(Mg,Mn
2+
 
)
 
9
Zn
 
4
[(OH)
 
11
|SO
 
4
]
 
2
 · 8H
 
2
O
7.DD.45Mooreite
(Mg,Zn,Mn
2+
 
)
 
15
[(OH)
 
13
|SO
 
4
]
 
2
 · 8H
 
2
O
7.DD.50Namuwite
(Zn,Cu)
 
4
[(OH)
 
6
|SO
 
4
] · 4H
 
2
O
7.DD.55Bechererite
(Zn,Cu)
 
6
Zn
 
2
[(OH)
 
12
|(SO
 
4
,HSiO
 
4
)
 
2
]
7.DD.60Ramsbeckite
(Cu,Zn)
 
15
[(OH)
 
22
|(SO
 
4
)
 
4
] · 6H
 
2
O
7.DD.65Vonbezingite
Ca
 
6
Cu
 
3
[(OH)
 
12
|(SO
 
4
)
 
3
] · 2H
 
2
O
7.DD.70Redgillite
Cu
 
6
[(OH)
 
10
|SO
 
4
] · H
 
2
O
7.DD.75Chalcoalumite
CuAl
 
4
[(OH)
 
12
|SO
 
4
] · 3H
 
2
O
7.DD.75Nickelalumite
(Ni,Cu)Al
 
4
[(OH)
 
12
|{SO
 
4
,(NO
 
3
)
 
2
}] · 3H
 
2
O
7.DD.75Kyrgyzstanite
ZnAl
 
4
(SO
 
4
)(OH)
 
12
·3H
 
2
O
7.DD.80Guarinoite
(Zn,Co,Ni)
 
6
[(OH,Cl)
 
10
|SO
 
4
] · 5H
 
2
O
7.DD.80Schulenbergite
(Cu,Zn)
 
7
[(OH)
 
10
|(SO
 
4
,CO
 
3
)
 
2
] · 3H
 
2
O
7.DD.80Thérèsemagnanite
(Co,Zn,Ni)
 
6
(SO
 
4
)(OH,Cl)
 
10
·8H
 
2
O
7.DD.80UM1992-30-SO:CCuHZn
(Zn,Cu)
 
7
[(SO
 
4
,CO
 
3
)
 
2
](OH)
 
10
 · 3H
 
2
O
7.DD.85Montetrisaite
Cu
 
6
(SO
 
4
)(OH)
 
10
·2H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
25.5.1Zinkosite
ZnSO
 
4
25.5.2Goslarite
ZnSO
 
4
·7H
 
2
O
25.5.3Namuwite
(Zn,Cu)
 
4
[(OH)
 
6
|SO
 
4
] · 4H
 
2
O
25.5.4Ktenasite
Zn(Cu,Zn)
 
4
[(OH)
 
6
|(SO
 
4
)
 
2
] · 6H
 
2
O
25.5.5Ramsbeckite
(Cu,Zn)
 
15
[(OH)
 
22
|(SO
 
4
)
 
4
] · 6H
 
2
O
25.5.6Boyleite
(Zn,Mg)SO
 
4
·4H
 
2
O
25.5.7Serpierite
Ca(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
·3H
 
2
O
25.5.9Zincaluminite
Zn
 
6
Al
 
6
[(OH)
 
13
|SO
 
4
]
 
2
 · 5H
 
2
O
25.5.10Glaucocerinite
(Zn,Cu)
 
10
Al
 
6
[(OH)
 
32
|(SO
 
4
)
 
3
] · 18H
 
2
O
25.5.11Gunningite
(Zn,Mn)SO
 
4
·H
 
2
O
25.5.12Chaidamuite
ZnFe(SO
 
4
)
 
2
(OH)·4H
 
2
O
25.5.13Bianchite
(Zn,Fe)SO
 
4
·6H
 
2
O
25.5.15Zincmelanterite
(Zn,Cu,Fe)SO
 
4
·7H
 
2
O
25.5.16Zincobotryogen
(Zn,Mg,Mn
2+
 
)Fe
3+
 
[OH|(SO
 
4
)
 
2
] · 7H
 
2
O
25.5.17Schuetteite
Hg
2+
3
[O
 
2
|SO
 
4
]
25.5.18Gianellaite
[Hg
 
2
N]
+
2
SO
 
4

Other Names for Orthoserpierite

Synonyms:
IMA1983-022a
Other Languages:
German:Orthoserpierit
Spanish:Orthoserpierita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Orthoserpierite

Reference List:Schweizerische mineralogische und petrographische Mitteilungen (1985): 65: 1-7.

American Mineralogist (1987): 72: 1026.

Krause, W. & Täuber, H. (1992): Zum Kenntnisstand der Minerale Serpierit, Orthoserpierit und Devillin. Aufschluss 43, 1-25. (in German)

Internet Links for Orthoserpierite

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  • Look for Orthoserpierite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Orthoserpierite in the Natural History Museum (London) online catalogue
  • Orthoserpierite details from Handbook of Mineralogy (PDF)
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    Localities for Orthoserpierite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • South Australia
      • Mt Lofty Ranges
        • South Mt Lofty Ranges
          • Clarendon
    		Kolitsch, U. and Elliott, P. (1999): Mineralogy of the Mount Malvern Mine near Clarendon, South Australia. Australian J. Mineral. 5, 3-17.
    Austria
     
    • Tyrol
      • North Tyrol
        • Inn valley
          • Brixlegg - Schwaz area
            • Brixlegg - Rattenberg
              • Geyer - Silberberg District
                • Silberberg Mt.
    		Schnorrer, G. and Poeverlein, R. (2002) Schwaz-Brixlegg-Fundstellen: 2. Die Minerale des Stockerstollens bei Brixlegg in Tirol. Aufschluss, 53, 209-228.
    Lapis 19(7/8):13-78 (1994); Schnorrer, G. & Poeverlein, R. (2008): Schwaz-Brixlegger Fundstellen. 6. Die Minerale des Gratlspitz bei Brixlegg in Tirol. Aufschluss 59, 7-28.
            • Schwaz
              • Ringenwechsel District
                • Weißer Schrofen
    		Schnorrer, G., Poeverlein, R. (2007): Die Minerale des Martinstollens am Weißen Schrofen, Der Aufschluss, Vol. 58, 27-40
    Chile
     
    • Atacama Region
      • Huasco Province
        • Vallenar
          • Sierra Bolsico area
    		maurizio dini - analysed with EDX, Pdf and microprobe (by dr. Jochen Scluter)
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Central Bohemia Region
        • Příbram
          • Březové Hory (Birkenberg)
            • Black pits deposit
    		No reference listed
    [Der Aufschluss 1996:6 p.267-287]
    France
     
    • Rhône-Alpes
      • Rhône
    		Schweiz.Min.Petr.Mitt.(1985) 65, 1-7
    Germany
     
    • Lower Saxony
      • Harz Mts
        • Clausthal-Zellerfeld
          • Oberschulenberg
    		No reference listed
        • Goslar
          • Grane Reservoir
    		No reference listed
    • North Rhine-Westphalia
      • Sauerland
        • Meschede
    		Wittern: "Mineralfundorte in Deutschland", 2001
    • Rhineland-Palatinate
      • Lahn valley
        • Bad Ems District
          • Frücht
    		Möhn, G., Frohwein, J. & Blaß, G. (2009): Neue Mineralfunde von der Grube Friedrichssegen bei Bad Ems. Lapis 34 (5), 35-40; 58.
    • Saxony
      • Erzgebirge
    		Lapis 30(7/8):78-80 (2005)
    Greece
     
    • Attikí (Attica; Attika) Prefecture
      • Lavrion (Laurion; Laurium) District
        • Lavrion District Mines
          • Agios Konstantinos [St Constantine] (Kamariza)
    		No reference listed
          • Lavrion (Laurion; Laurium)
            • Lavrion Mines
    		No reference listed
          • Sounion area
            • Sounion Mines
    		Lapis, 24, 7/8 (1999)
    Ireland
     
    • Co. Galway
      • Killimor
    		Sarp, H.; Perroud, P.; DeHaller, A. (1987): Second occurrence of orthoserpierite in the Tynagh mine (Ireland). Arch. Sci. Genève, 40, 47-50. (in French)
    • Co. Wicklow
      • Glendasan
    		XRD of specimens from nos. 3 & 4 levels by Dr Green, Manchester Museum.
    Switzerland
     
    • Wallis (Valais)
      • Martigny
        • Mont Chemin
    USA
     
    • Arizona
      • Pinal Co.
        • Galiuro Mts
          • Bunker Hill District (Copper Creek District)
    		T. Kennedy collection
              • Copper Creek
    		Shannon, David (1996) Orthoserpierite from the Copper Creek District, Pinal County, Arizona. Mineralogical Record: 27: 189-190. Grant, Raymond W., Bideaux, R.A., and Williams, S.A. (2006) Minerals Added to the Arizona List 1995-2005: 7.
        • Mammoth District
    		Grant, Raymond W., Bideaux, R.A., and Williams, S.A. (2006) Minerals Added to the Arizona List 1995-2005: 7.
    • New Jersey
      • Sussex Co.
        • Franklin Mining District
          • Ogdensburg
            • Sterling Hill
    		Jenkins, R.E., II: The Picking Table:33(2):12-13 (1992); Dunn(1995):Pt5:639.
    • Utah
      • Piute Co.
        • Tushar Mts
          • Cottonwood Creek
            • Mount Baldy District
    		Collected by and in the collection of Brent Thorne.
      • Tooele Co.
        • Oquirrh Mts
          • Ophir District
            • Ophir Hill area
    		Rocks & Minerals 83:1 pp 52-62
    Rocks & Minerals 83:1 pp 52-62
    Mineral and/or Locality
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