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Dutrowite

A valid IMA mineral species
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05429840017088788145565.jpg
Dutrowite, etc.

Fornovolasco metarhyolite formation, Fornovolasco, Vergemoli, Lucca Province, Tuscany, Italy
05429840017088788145565.jpg
Dutrowite, etc.

Fornovolasco metarhyolite formation, Fornovolasco, Vergemoli, Lucca Province, Tuscany, Italy
05429840017088788145565.jpg
Dutrowite, etc.

Fornovolasco metarhyolite formation, Fornovolasco, Vergemoli, Lucca Province, Tuscany, Italy
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About DutrowiteHide

06560220017059440569804.jpg
Barbara L Dutrow
Formula:
Na(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3O
Colour:
brown
Lustre:
Vitreous
Hardness:
7 - 7½
Specific Gravity:
3.203 (Calculated)
Crystal System:
Trigonal
Name:
Named in honor of Barbara L. Dutrow (1956-), professor at Louisiana State University, former president of the Mineralogical Society of America and past President of the Geological Society of America (2021), and governor of the Gemological Institute of America (GIA), for her research into the tourmaline group.
Isostructural with:
Magnesio-dutrowite
The first tourmaline group member with essential titanium. The Fe2+-analogue of magnesio-dutrowite. Unique combination of elements.

A Mg-dominant analogue, probably magnesio-dutrowite, is reported from Zlatá Idka, Slovakia (Bačík et al., 2022).

Most likely a late-stage phase resulting from replacement of "biotite" during a late-magmatic/hydrothermal event at high temperature but low pressure.



Unique IdentifiersHide

Mindat ID:
54240
Long-form identifier:
mindat:1:1:54240:5
GUID
(UUID V4):
89baa363-84d2-40c9-b1d0-104711264920

IMA Classification of DutrowiteHide

IMA status:
Approved
IMA Formula:
Na(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3O
Approval year:
2019

Classification of DutrowiteHide

Strunz-mindat (2024):
9.CK.

9 : SILICATES (Germanates)
C : Cyclosilicates
K : [Si6O18]12- 6-membered single rings, with insular complex anions

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
DtwIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of DutrowiteHide

Lustre:
Vitreous
Transparency:
Transparent
Colour:
brown
Streak:
light brown
Hardness:
7 - 7½ on Mohs scale
Comment:
by analogy with other members of the tourmaline supergroup
Tenacity:
Brittle
Fracture:
Irregular/Uneven
Density:
3.203 g/cm3 (Calculated)

Optical Data of DutrowiteHide

Type:
Uniaxial
Pleochroism:
Visible
Comments:
ω = dark brown and ε = light brown.
Comments:
the mean refractive index, calculated according to the Gladstone–Dale relation is 1.800.

Chemistry of DutrowiteHide

Mindat Formula:
Na(Fe2+2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3O
Elements listed:
Al, B, Fe, H, Na, O, Si, Ti - search for minerals with similar chemistry

Chemical AnalysisHide

Empirical formulas:
Sample IDEmpirical Formula
1X(Na0.81Ca0.20K0.01)YΣ1.02(Fe2+1.43Mg1.00Ti0.56)ZΣ3.00(Al5.13Fe3+0.27V3+0.02Mg0.58)TΣ6.00[(Si5.82Al0.18)Σ6.00O18](BO3)(OH)W3[O0.59(OH)0.41]Σ1.00
Sample references:
IDLocalityReferenceNotes
1Fornovolasco metarhyolite formation, Fornovolasco, Vergemoli, Lucca Province, Tuscany, Italy
Biagioni et al. (2023)
from electron microprobe and Mössbauer spectroscopy, recast from structural empirical formula to fullfill the requirements of the tourmaline classification

Crystallography of DutrowiteHide

Crystal System:
Trigonal
Class (H-M):
3m - Ditrigonal Pyramidal
Space Group:
R3m
Cell Parameters:
a = 15.9864(8) Å, c = 7.2187(4) Å
Ratio:
a:c = 1 : 0.452
Unit Cell V:
1,597.68 ų (Calculated from Unit Cell)
Z:
3

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.40 Å(42)
4.61 Å(18)
4.24 Å(52)
4.00 Å(60)
2.971 Å(61)
2.585 Å(100)
2.048 Å(41)
1.925 Å(24)
Comments:
From Type Description.

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
23 : Subaerial aqueous alteration by non-redox-sensitive fluids (see also #47)
Stage 4b: Highly evolved igneous rocks>3.0
34 : Complex granite pegmatites
Stage 5: Initiation of plate tectonics<3.5-2.5
40 : Regional metamorphism (greenschist, amphibolite, granulite facies)

Type Occurrence of DutrowiteHide

Type Locality:
ⓘ Fornovolasco metarhyolite formation, Fornovolasco, Vergemoli, Lucca Province, Tuscany, Italy
General Appearance of Type Material:
chemically homogeneous domains, up to 0.5 mm in diameter, within prismatic crystals (anhedral to subhedral) up to 1 mm in size
Place of Conservation of Type Material:
Type material is deposited in the mineralogical collections of the Museo di Storia Naturale, Università di Pisa, Via Roma 79, Calci (PI), Italy, catalogue number 19890
Geological Setting of Type Material:
metarhyolite formation
Associated Minerals at Type Locality:
ZirconRutileQuartzOxy-draviteMuscovite
IlmeniteClinochloreApatiteAnnite

Synonyms of DutrowiteHide

Relationship of Dutrowite to other SpeciesHide

Member of:
Tourmaline Group
Other Members of this group:
AdachiiteCaFe3Al6(Si5AlO18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Alumino-oxy-rossmanite◻Al3Al6(Si5AlO18)(BO3)3(OH)3OTrig. 3m : R3m
BosiiteNaFe3+3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Celleriite◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Chromium-draviteNaMg3Cr3+6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Chromo-alumino-povondraiteNaCr3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
DarrellhenryiteNa(Al2Li)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
DraviteNaMg3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Ferro-bosiiteNaFe3+3(Al4Fe2+2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
FeruviteCaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Fluor-buergeriteNaFe3+3Al6(Si6O18)(BO3)3O3FTrig. 3m : R3m
Fluor-draviteNaMg3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-elbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-liddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-rossmanite◻(Al2Li)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m (3 2/m) : R3m
Fluor-schorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-tsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Fluor-uviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
Foitite◻(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
LiddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
LucchesiiteCaFe2+3 Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Magnesio-dutrowiteNa(Mg2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Magnesio-foitite◻(Mg2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Magnesio-lucchesiiteCaMg3Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
MaruyamaiteK(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
OleniteNaAl3Al6(Si6O18)(BO3)3O3(OH)Trig. 3m : R3m
Oxy-chromium-draviteNaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
Oxy-draviteNa(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Oxy-foitite◻(Fe2+Al2)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m (3 2/m) : R3m
Oxy-rossmanite◻(Li0.5Al2.5)Al6(Si6O18)(BO3)3(OH)3O
Oxy-schorlNa(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Oxy-uviteCaMg3Al6(Si6O18)(BO3)3(OH)3O
Oxy-vanadium-draviteNaV3(V4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
PovondraiteNaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
PrincivalleiteNa(Mn2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
Rossmanite◻(LiAl2)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
SchorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
TsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
UM2000-64-SiO:BFeHKMg(K,Na)Fe3+3(Mg2Fe3+4)Si6O18(BO3)3(OH)3O
UM2008-52-SiO:AlBCaFFeHLiMgNa(Ca,Na,◻)(Al,Li,Fe,Mg)3Al6[Si6O18](BO3)3(OH,O)3(F,O)
Unnamed (F analogue of feruvite)CaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3F
Unnamed (Pb-analogue of Fluor-liddicoatite)Pb(Li2Al)Al6(Si6O18)(BO3)3(OH)3F
UviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
Vanadio-oxy-chromium-draviteNaV3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
Vanadio-oxy-draviteNaV3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m

Common AssociatesHide

Associated Minerals Based on Photo Data:
1 photo of Dutrowite associated with Oxy-draviteNa(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3O
1 photo of Dutrowite associated with ApatiteCa5(PO4)3(Cl/F/OH)
1 photo of Dutrowite associated with BiotiteK(Fe2+/Mg)2(Al/Fe3+/Mg/Ti)([Si/Al/Fe]2Si2O10)(OH/F)2
1 photo of Dutrowite associated with K Feldspar

Related Minerals - Strunz-mindat GroupingHide

9.CK.Fluor-schorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.DarrellhenryiteNa(Al2Li)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.AdachiiteCaFe3Al6(Si5AlO18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.BosiiteNaFe3+3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Celleriite◻(Mn2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.PrincivalleiteNa(Mn2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Alumino-oxy-rossmanite◻Al3Al6(Si5AlO18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Ferro-bosiiteNaFe3+3(Al4Fe2+2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.Magnesio-dutrowiteNa(Mg2.5Ti0.5)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-buergeriteNaFe3+3Al6(Si6O18)(BO3)3O3FTrig. 3m : R3m
9.CK.05Chromium-draviteNaMg3Cr3+6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05DraviteNaMg3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05ElbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05FeruviteCaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Foitite◻(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05LiddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05OleniteNaAl3Al6(Si6O18)(BO3)3O3(OH)Trig. 3m : R3m
9.CK.05PovondraiteNaFe3+3(Mg2Fe3+4)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05SchorlNaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Magnesio-foitite◻(Mg2Al)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Rossmanite◻(LiAl2)Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05TsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Oxy-vanadium-draviteNaV3(V4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Oxy-draviteNa(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Oxy-rossmanite◻(Li0.5Al2.5)Al6(Si6O18)(BO3)3(OH)3O
9.CK.05Luinaite-(OH)NaFe2+3Al6(Si6O18)(BO3)3(OH)3(OH)Mon. m : Bm
9.CK.05Fluor-elbaiteNa(Li1.5Al1.5)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Chromo-alumino-povondraiteNaCr3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-draviteNaMg3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Oxy-schorlNa(Fe2+2Al)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Fluor-liddicoatiteCa(Li2Al)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Unnamed (F analogue of feruvite)CaFe2+3(Al5Mg)(Si6O18)(BO3)3(OH)3F
9.CK.05UM2000-64-SiO:BFeHKMg(K,Na)Fe3+3(Mg2Fe3+4)Si6O18(BO3)3(OH)3O
9.CK.05Oxy-chromium-draviteNaCr3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
9.CK.05Fluor-tsilaisiteNaMn2+3Al6(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Vanadio-oxy-chromium-draviteNaV3(Cr4Mg2)(Si6O18)(BO3)3(OH)3O Trig. 3m : R3m
9.CK.05Fluor-uviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3FTrig. 3m : R3m
9.CK.05Vanadio-oxy-draviteNaV3(Al4Mg2)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05MaruyamaiteK(Al2Mg)(Al5Mg)(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05LucchesiiteCaFe2+3 Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05Oxy-foitite◻(Fe2+Al2)Al6(Si6O18)(BO3)3(OH)3OTrig. 3m (3 2/m) : R3m
9.CK.05Oxy-uviteCaMg3Al6(Si6O18)(BO3)3(OH)3O
9.CK.05Magnesio-lucchesiiteCaMg3Al6(Si6O18)(BO3)3(OH)3OTrig. 3m : R3m
9.CK.05UviteCaMg3(Al5Mg)(Si6O18)(BO3)3(OH)3(OH)Trig. 3m : R3m
9.CK.05Fluor-rossmanite◻(Al2Li)Al6(Si6O18)(BO3)3(OH)3FTrig. 3m (3 2/m) : R3m
9.CK.10Abenakiite-(Ce)Na26Ce6(Si6O18)(PO4)6(CO3)6(SO2)OTrig. 3 : R3
9.CK.15ScawtiteCa7(Si3O9)2CO3 · 2H2OMon. 2/m
9.CK.20Steenstrupine-(Ce)Na14Mn2+2Fe3+2Ce6Zr(Si6O18)2(PO4)6(PO3OH)(OH)2 · 2H2OTrig. 3m (3 2/m) : R3m
9.CK.20Thorosteenstrupine(Ca,Th,Mn)3Si4O11F · 6H2O

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for DutrowiteHide

References for DutrowiteHide

Localities for DutrowiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Italy (TL)
 
  • Tuscany
    • Lucca Province
      • Vergemoli
        • Fornovolasco
Miyawaki et al. (2020) +1 other reference
Slovakia
 
  • Košice Region
    • Košice-okolie District
      • Zlatá Idka
Bačík et al. (2022)
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