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Clinoptilolite-Ca

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Formula:
(Ca,Na,K)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
System:MonoclinicLustre:Vitreous
Hardness:3½ - 4
Member of:Zeolite Group
Name:From the Greek klino - "oblique" ptylon - "feather" and lithos - "stone." The Ca-dominant member of the clinoptilolite series.

Classification of Clinoptilolite-Ca

IMA status:Approved
Strunz 8th edition ID:8/J.23-22
Nickel-Strunz 10th (pending) edition ID:9.GE.05

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
E : Chains of T10O20 Tetrahedra
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Type Occurrence of Clinoptilolite-Ca

Type Locality:Kuruma Pass, Fukushima Prefecture, Tohoku Region, Honshu Island, Japan

Physical Properties of Clinoptilolite-Ca

Lustre:Vitreous
Hardness (Mohs):3½ - 4

Crystallography of Clinoptilolite-Ca

Crystal System:Monoclinic
Cell Parameters:a = 17.66Å, b = 17.963Å, c = 7.4Å
β = 116.47°
Ratio:a:b:c = 0.983 : 1 : 0.412
Unit Cell Volume:V 2,101.39 ų (Calculated from Unit Cell)

Optical Data of Clinoptilolite-Ca

Type:Biaxial (+/-)
RI values: nα = 1.476 - 1.491 nβ = 1.479 - 1.493 nγ = 1.479 - 1.497
2V:Measured: 31° to 48°
Maximum Birefringence:δ = 0.003 - 0.006

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r > v to r < v strong

Chemical Properties of Clinoptilolite-Ca

Formula:
(Ca,Na,K)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
Simplified for copy/paste:(Ca,Na,K)2-3Al3(Al,Si)2Si13O36·12H2O
Essential elements:Al, Ca, H, O, Si
All elements listed in formula:Al, Ca, H, K, Na, O, Si

Relationship of Clinoptilolite-Ca to other Species

Series:Forms a series with Heulandite-Ca (see here)
Member of:Zeolite Group
Other Members of Group:

- +
Alflarsenite
NaCa
 
2
Be
 
3
Si
 
4
O
 
13
(OH) · 2H
 
2
O
Amicite
K
 
2
Na
 
2
Al
 
4
Si
 
4
O
 
16
· 5H
 
2
O
Ammonioleucite
(NH
 
4
,K)(AlSi
 
2
O
 
6
)
Analcime
Na
 
2
(Al
 
2
Si
 
4
O
 
12
) · 2H
 
2
O
Barrerite
(Na,K,Ca
 
0.5
)
 
2
[Al
 
2
Si
 
7
O
 
18
] · 7H
 
2
O
Beaumontite (of Lévy)
Bellbergite
(K,Ba,Sr)
 
2
Sr
 
2
Ca
 
2
(Ca,Na)
 
4
[Al
 
3
Si
 
3
O
 
12
]
 
6
· 30H
 
2
O
Bikitaite
LiAlSi
 
2
O
 
6
· H
 
2
O
Boggsite
Ca
 
8
Na
 
3
(Si,Al)
 
96
O
 
192
· 70H
 
2
O
Brewsterite
Brewsterite-Ba
(Ba,Sr)[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
Brewsterite-Sr
(Sr,Ba,Ca)[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
Chabazite-Ca
(Ca,K
 
2
,Na
 
2
)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
· 12H
 
2
O
Chabazite-K
(K
 
2
,Ca,Na
 
2
,Sr,Mg)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
· 12H
 
2
O
Chabazite-Levyne Subgroup
Chabazite-Mg
(Mg
 
0.7
K
 
0.5
Ca
 
0.5
Na
 
0.1
)[Al
 
3
Si
 
9
O
 
24
]·10H
 
2
O
Chabazite-Na
(Na
 
2
,K
 
2
,Ca,Sr,Mg)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
· 12H
 
2
O
Chabazite-Sr
Sr
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
· 12H
 
2
O
Chiavennite
CaMnBe
 
2
Si
 
5
O
 
13
(OH)
 
2
· 2H
 
2
O
Clinoptilolite-K
(K,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
Clinoptilolite-Na
(Na,K,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
Cowlesite
CaAl
 
2
Si
 
3
O
 
10
· 6H
 
2
O
Dachiardite-Ca
(Ca,Na
 
2
,K
 
2
)
 
5
Al
 
10
Si
 
38
O
 
96
· 25H
 
2
O
Dachiardite-Na
(Na
 
2
,Ca,K
 
2
)
 
5
Al
 
10
Si
 
38
O
 
96
· 25H
 
2
O
Direnzoite
NaK
 
6
MgCa
 
2
(Al
 
13
Si
 
47
O
 
120
) · 36H
 
2
O
Edingtonite
Ba[Al
 
2
Si
 
3
O
 
10
] · 4H
 
2
O
Epistilbite
CaAl
 
2
Si
 
6
O
 
16
· 5H
 
2
O
Erionite-Ca
(Ca,K
 
2
,Na
 
2
)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Erionite-K
(K
 
2
,Ca,Na
 
2
)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Erionite-Na
(Na
 
2
,K
 
2
,Ca)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Faujasite Subgroup
Faujasite-Ca
(Ca,Na
 
2
,Mg)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
Faujasite-Mg
(Mg,Na
 
2
,Ca)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
Faujasite-Na
(Na
 
2
,Ca,Mg)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
Ferrierite
Ferrierite-K
(K
 
2
,Na
 
2
,Mg,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
] · 18H
 
2
O
Ferrierite-Mg
(Mg,Na
 
2
,K
 
2
,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
] · 18H
 
2
O
Ferrierite-Na
(Na
 
2
,K
 
2
,Mg,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
] · 18H
 
2
O
Ferrochiavennite
Ca
 
1-2
Fe[(Si,Al,Be)
 
5
Be
 
2
O
 
13
(OH)
 
2
]•2H
 
2
O
Flörkeite
(K
 
3
Ca
 
2
Na)[Al
 
8
Si
 
8
O
 
32
] · 12H
 
2
O
Garronite
Na
 
2
Ca
 
5
Al
 
12
Si
 
20
O
 
64
· 27H
 
2
O
Gaultite
Na
 
4
Zn
 
2
Si
 
7
O
 
18
· 5H
 
2
O
Gismondine
Gismondine-Ba
Ba
 
2
Al
 
4
Si
 
4
O
 
16
· 4-6H
 
2
O
Gismondine-Ca
CaAl
 
2
Si
 
2
O
 
8
· 4H
 
2
O
Gmelinite
Gmelinite-Ca
(Ca,Na
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Gmelinite-K
(K
 
2
,Na
 
2
,Ca)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Gmelinite-Na
(Na
 
2
,Ca)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Gobbinsite
Na
 
4
(Ca,Mg,K
 
2
)Al
 
6
Si
 
10
O
 
32
· 12H
 
2
O
Gonnardite
(Na,Ca)
 
2
(Si,Al)
 
5
O
 
10
· 3H
 
2
O
Goosecreekite
Ca[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
Gottardiite
Na
 
3
Mg
 
3
Ca
 
5
Al
 
19
Si
 
117
O
 
272
· 93H
 
2
O
Harmotome
(Ba
 
0.5
,Ca
 
0.5
,K,Na)
 
5
[Al
 
5
Si
 
11
O
 
32
] · 12H
 
2
O
Heulandite-Ba
(Ba,Ca,K,Na,Sr)
 
5
Al
 
9
Si
 
27
O
 
72
· 22H
 
2
O
Heulandite-Ca
(Ca,Na)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
Heulandite-K
(K,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
Heulandite-Na
(Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
Heulandite-Sr
(Sr,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
Hsianghualite
Ca
 
3
Li
 
2
(Be
 
3
Si
 
3
O
 
12
)F
 
2
Kirchhoffite
Cs(BSi
 
2
O
 
6
)
Laumontite
CaAl
 
2
Si
 
4
O
 
12
· 4H
 
2
O
Leucite
K(AlSi
 
2
O
 
6
)
Lévyne
Lévyne-Ca
(Ca,Na
 
2
,K
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Lévyne-Na
(Na
 
2
,Ca,K
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Lovdarite
K
 
2
Na
 
6
Be
 
4
Si
 
14
O
 
36
•9H
 
2
O
Maricopaite
Pb
 
7
Ca
 
2
(Si,Al)
 
48
O
 
100
· 32H
 
2
O
Mazzite-Mg
(Mg,K,Ca)
 
5
(Si
 
26
Al
 
10
)O
 
72
· 28H
 
2
O
Mazzite-Na
Na
 
8
[Al
 
4
Si
 
14
O
 
36
]
 
2
· 30H
 
2
O
Merlinoite
(K,Na)
 
5
(Ca,Ba)
 
2
Al
 
9
Si
 
23
O
 
64
· 23H
 
2
O
Mesolite
Na
 
2
Ca
 
2
Si
 
9
Al
 
6
O
 
30
· 8H
 
2
O
Montesommaite
(K,Na)
 
9
Al
 
9
Si
 
23
O
 
64
· 10H
 
2
O
Mordenite
(Na
 
2
,Ca,K
 
2
)Al
 
2
Si
 
10
O
 
24
· 7H
 
2
O
Mutinaite
Na
 
3
Ca
 
4
Si
 
85
Al
 
11
O
 
192
· 60H
 
2
O
Nabesite
Na
 
2
BeSi
 
4
O
 
10
· 4H
 
2
O
Natrolite
Na
 
2
Al
 
2
Si
 
3
O
 
10
· 2H
 
2
O
Natrolite Subgroup
Offretite
KCaMgAl
 
5
Si
 
13
O
 
36
· 16H
 
2
O or near
Pahasapaite
Li
 
8
(Ca,Li,K)
 
10.5
Be
 
24
(PO
 
4
)
 
24
· 38H
 
2
O
Paranatrolite
Na
 
2
Al
 
2
Si
 
3
O
 
10
· 3H
 
2
O
Parthéite
CaAl
 
2
Si
 
2
O
 
8
· 2H
 
2
O
Paulingite
Paulingite-Ca
(Ca,K
 
2
,Na
 
2
,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
Paulingite-K
(K
 
2
,Ca,Na
 
2
,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
Paulingite-Na
(Na
 
2
,K
 
2
,Ca,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
Perlialite
K
 
9
Na(Ca,Sr)[Al
 
2
Si
 
4
O
 
12
]
 
6
· 15H
 
2
O
Phillipsite-Ca
(Ca
 
0.5
,K,Na,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
.
 
12H2O
Phillipsite-K
(K,Na,Ca
 
0.5
,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
]
.
 
12H
 
2
O
Phillipsite-Na
(Na,K,Ca
 
0.5
,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
] · 12H
 
2
O
Pollucite
(Cs,Na)
 
2
(Al
 
2
Si
 
4
O
 
12
) · 2H
 
2
O
Roggianite
Ca
 
2
Be(OH)
 
2
Al
 
2
Si
 
4
O
 
13
· 2.5H
 
2
O
Scolecite
CaAl
 
2
Si
 
3
O
 
10
· 3H
 
2
O
Stellerite
Ca[Al
 
2
Si
 
7
O
 
18
] · 7H
 
2
O
Stilbite-Ca
NaCa
 
4
[Al
 
9
Si
 
27
O
 
72
] · nH
 
2
O
Stilbite-Na
(Na,Ca,K)
 
6-7
[Al
 
8
Si
 
28
O
 
72
] · nH
 
2
O
Strontiohurlbutite
SrBe
 
2
(PO
 
4
)
 
2
Terranovaite
(Na,Ca)
 
8
(Si
 
68
Al
 
12
)O
 
160
· 29H
 
2
O
Tetranatrolite
Thomsonite-Ca
NaCa
 
2
[Al
 
5
Si
 
5
O
 
20
] · 6H
 
2
O
Thomsonite-Sr
Na(Sr,Ca)
 
2
[Al
 
5
Si
 
5
O
 
20
] · 7H
 
2
O
Tschernichite
(Ca,Na
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 4-8H
 
2
O
Tschörtnerite
Ca
 
4
(Ca,Sr,K,Ba)
 
3
Cu
 
3
[(OH)
 
2
|Al
 
3
Si
 
3
O
 
12
]
 
4
· nH
 
2
O
Wairakite
Ca(Al
 
2
Si
 
4
O
 
12
) · 2H
 
2
O
Weinebeneite
CaBe
 
3
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
Wenkite
(Ba,K)
 
4
(Ca,Na)
 
6
[(SO
 
4
)
 
3
|(Si,Al)
 
20
O
 
39
(OH)
 
2
] · 0.5H
 
2
O
Willhendersonite
KCa[Al
 
3
Si
 
3
O
 
12
] · 5H
 
2
O
Yugawaralite
CaAl
 
2
Si
 
6
O
 
16
· 4H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
9.GE.05Clinoptilolite-K
(K,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
9.GE.05Clinoptilolite-Na
(Na,K,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
9.GE.05Heulandite-Ca
(Ca,Na)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
9.GE.05Heulandite-K
(K,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
9.GE.05Heulandite-Na
(Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
9.GE.05Heulandite-Sr
(Sr,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
· 12H
 
2
O
9.GE.05Heulandite-Ba
(Ba,Ca,K,Na,Sr)
 
5
Al
 
9
Si
 
27
O
 
72
· 22H
 
2
O
9.GE.10Stilbite-Ca
NaCa
 
4
[Al
 
9
Si
 
27
O
 
72
] · nH
 
2
O
9.GE.10Stilbite-Na
(Na,Ca,K)
 
6-7
[Al
 
8
Si
 
28
O
 
72
] · nH
 
2
O
9.GE.15Barrerite
(Na,K,Ca
 
0.5
)
 
2
[Al
 
2
Si
 
7
O
 
18
] · 7H
 
2
O
9.GE.15Stellerite
Ca[Al
 
2
Si
 
7
O
 
18
] · 7H
 
2
O
9.GE.20Brewsterite-Ba
(Ba,Sr)[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
9.GE.20Brewsterite-Sr
(Sr,Ba,Ca)[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O

Other Names for Clinoptilolite-Ca

Other Languages:
German:Klinoptilolith-Ca
Russian:Клиноптилолит-Ca

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Clinoptilolite-Ca

Reference List:

- +
Tschermaks Mineralogische und Petrographische Mitteilungen: 18: 129-146.

Zeitschrift für Kristallographie: 145: 216-239.

Armbruster, T. (1993), Dehydration mechanism of clinoptilolite and heulandite: Single-crystal X-ray study of Na-poor, Ca-, K-, Mg-rich clinoptilolite at 100K: American Mineralogist: 78: 260-264.

Fahri Esenli and Isik Kumbasar (1998) X-Ray Diffraction Intensity Ratios I(111)//(311) of Natural Heulandites and Clinoptilolites, Clays and Clay Minerals, Vol. 46, No. 6, 679-686, 1998.


Snellings, R.A., Gualtieri, A.F., Elsen, J. (2009): The Rietveld structure refinement of an exceptionally pure sample of clinoptilolite from Ecuador and its Na-, K-, and Ca-exchanged forms. Zeitschrift für Kristallographie Supplements, 30, 395-40

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  • Localities for Clinoptilolite-Ca

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Argentina
     
    • Neuquén
    Pablo Rodrigo Leal, María Elena Vattuone, and Carlos Oscar Latorre (2011) Zeolite assemblages from Northern Patagonian Andes, Argentina: A review. Revista Mexicana de Ciencias Geológicas, v.28, núm. 2, 2011, p. 212-225
    Armenia
     
    • Tavuš Province (Tavush)
      • Idzhevan
    Pavel M. Kartashov data
    Austria
     
    • Lower Austria
      • Waldviertel
        • Maria Laach am Jauerling
          • Zintring
    Kolitsch, U. & Löffler, E. (2012): 1759) Apatit, Klinoptilolith-Ca, Meionit, Prehnit, Titanit, Zirkon und weitere Mineralien aus einem Steinbruch bei Zintring, Maria Laach am Jauerling, Waldviertel, Niederösterreich. Pp. 161-162 in Niedermayr, G. et al. (2012): Neue Mineralfunde aus Österreich LXI. Carinthia II, 202./122., 123-180.
    Canada
     
    • Nova Scotia
      • Cumberland Co.
        • Parrsboro
    PE-PIPER, G. and MILLER, L. (2002) Zeolite minerals from the North Shore of the Minas Basin, Nova Scotia, Atlantic Geology, 38, 1, 11-28. (Sample W180)
      • Kings Co.
    PE-PIPER, G. and MILLER, L. (2002) Zeolite minerals from the North Shore of the Minas Basin, Nova Scotia, Atlantic Geology, 38, 1, 11-28.
        • Bay of Fundy
    Can. Min. 38, 1215.
    Canadian Mineralogist Vol 38 pp. 1215-1232 (2000)
    • Québec
      • Laurentides
        • Argenteuil RCM
          • Wentworth
            • Laurel
    Van Velthuizen et al. (2006) Mineral. Record 37, 283 [locality 48]
    Cyprus
     
    • Larnaca District (Larnaka District; İskele District)
    Prüfer, P. (2010): Mineralien der Insel Zypern. Der Aufschluss 61, 97-106. (in German)
    Germany
     
    • Bavaria
      • Lower Bavaria
        • Bavarian Forest
          • Waldkirchen
            • Röhrnbach
    Habel, M. (2009): Der Granodioritbruch der Fa. Josef Uhrmann OHG, Steinerleinbach bei Röhrnbach. Mineralien-Welt 20 (2), 66-86.
    Hungary
     
    • Heves Co.
      • Mátra Mtns
        • Kisnána
    GEODA, 2000
    • Veszprém Co.
      • Bakony Mtns
    Szakáll-Gatter-Szendrei: Mineral Species of Hungary, 2005
    Indian Ocean
     
    • Ninety East Ridge (90° E Ridge; Indian Ridge)
      • D.S.D.P.
        • Leg 26
    D. Besse et al. , Bell. Minéral. , 1981, 104, pp. 56-63.
    Japan
     
    • Honshu Island
      • Tohoku Region
        • Fukushima Prefecture
    Z. Kristallogr. 145, 216; Can. Mineral. (1997) 35, 1571
    • Kyushu Region
      • Fukuoka prefecture
    Nendo Kagaku v.30, no.1 (1990)
    New Zealand
     
    • North Island
      • Waikato
        • Thames-Coromandel
          • Whitianga
    S. J. Mills, Museum Victoria
    • South Island
      • Canterbury
    S. J. Mills, Museum Victoria
    Spain
     
    • Canary Islands
      • Las Palmas Province
    various added photos
          • La Aldea de San Nicolás
    various added photos
    UK
     
    • England
      • Cornwall
        • St Just District
          • St Just
            • Botallack
              • Botallack Mine
    J.Russell Socierty 2006, 68-71
    USA
     
    • Oregon
      • Clackamas Co.
    RRUFF database specimen no. RO61098
      • Malheur Co.
    Altaner,Stephan P. and Grim,Ralph E.(1990) Mineralogy,Chemistry,And Diagenesis Of Tuffs In The Sucker Creek Formation (Miocene) Eastern Oregon: Clays and Clay Minerals,Vol.38,No.6,pp 561-572,pg 562. RRUFF database specimen No.RO60662
      • Tillamook Co.
    Wise, W.S. and Tschernich, R.W. (1976): Dachiardite-bearing zeolite assemblages in the Pacific Northwest, in: Sand, L.B. and Mumpton, F. (eds.): Natural Zeolites Occurrence, Properties, Use. Pergamon Press (Oxford, New York), pp. 105-111.
    • Washington
      • Douglas Co.
    Tschernich (1991): Zeolites of Washington State. Rock & Minerals, 66(4); American Mineralogist, Volume 67, pages 799-803, 1982
      • Wahkiakum Co.
        • Altoona
    Cannon, B. (1975): Minerals of Washington, p.75; Micro Probe Volume IX Number 3 Spring 2001
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