Freudenbergite
A valid IMA mineral species
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About Freudenbergite
Formula:
Na2(Ti,Fe)8O16
Colour:
Black; deep brown to light yellowish brown in transmitted light
Hardness:
5
Specific Gravity:
3.956
Crystal System:
Monoclinic
Name:
Named in honor of Wilhelm Freudenberg (17 May 1881 Weinheim, German Empire - 28 January 1960, Weinheim, Baden-Wurttemberg, West Germany), palaeontologist at the University of Tübingen and the University of Göttingen, and curator for mineralogy and geology at the National Collections of Natural History in Karlsruhe. He studied Katzenbuckel rocks.
Unique Identifiers
Mindat ID:
1608
Long-form identifier:
mindat:1:1:1608:3
GUID
(UUID V4):
(UUID V4):
c9cab628-2ca0-4f64-b007-5c84e7d107ee
IMA Classification of Freudenbergite
Approved
IMA Formula:
Na(Ti4+3Fe3+)O8
First published:
1961
Classification of Freudenbergite
4.CC.10
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
C : With large and medium-sized cations
4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
C : Metal: Oxygen = 2: 3,3: 5, and similar
C : With large and medium-sized cations
7.9.3.1
7 : MULTIPLE OXIDES
9 : AB8X16
7 : MULTIPLE OXIDES
9 : AB8X16
7.9.19
7 : Oxides and Hydroxides
9 : Oxides of Ti
7 : Oxides and Hydroxides
9 : Oxides of Ti
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference |
|---|---|---|
| Fdb | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Freudenbergite
Transparency:
Opaque
Colour:
Black; deep brown to light yellowish brown in transmitted light
Streak:
Pale yellow-brown
Hardness:
5 on Mohs scale
Comment:
< 5
Cleavage:
Distinct/Good
{001}, and another prismatic, good.
{001}, and another prismatic, good.
Density:
3.956 g/cm3 (Measured) 3.97 g/cm3 (Calculated)
Optical Data of Freudenbergite
Type:
Biaxial (+)
Dispersion:
r < v
Internal Reflections:
yellow-brown
Pleochroism:
Visible
Comments:
Deep brown to pale yellow-brown.
Comments:
n = ∼2.37–2.42
Chemistry of Freudenbergite
Mindat Formula:
Na2(Ti,Fe)8O16
Elements listed:
Crystallography of Freudenbergite
Crystal System:
Monoclinic
Cell Parameters:
a = 12.3 Å, b = 3.82 Å, c = 6.5 Å
β = 107.3°
β = 107.3°
Ratio:
a:b:c = 3.22 : 1 : 1.702
Unit Cell V:
291.59 ų (Calculated from Unit Cell)
Z:
4
Comment:
Point Group: 2/m, m,or 2. Space Group: C2/m, Cm,or C2.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
| ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
|---|---|---|---|---|---|---|---|
| 0009624 | Freudenbergite | Ishiguro T, Tanaka K, Marumo F, Ismail M G M U, Hirano S, Somiya S (1978) Freudenbergite Acta Crystallographica B34 255-256 |  | 1978 | synthetic | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 3.627 Å | (very strong) |
| 1.911 Å | (strong to very strong) |
| 5.81 Å | (strong) |
| 3.101 Å | (strong) |
| 3.015 Å | (strong) |
| 2.731 Å | (strong) |
| 2.712 Å | (strong) |
| 2.069 Å | (strong) |
| 2.049 Å | (strong) |
| 1.596 Å | (strong) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 3a: Earth’s earliest Hadean crust | >4.50 |
| 7 : Ultramafic igneous rocks | |
| Stage 4b: Highly evolved igneous rocks | >3.0 |
| 35 : Ultra-alkali and agpaitic igneous rocks | |
| Stage 5: Initiation of plate tectonics | <3.5-2.5 |
| 41 : Mantle metasomatism |
Type Occurrence of Freudenbergite
General Appearance of Type Material:
Irregularly shaped grains, to 0.15 mm.
Place of Conservation of Type Material:
No designated type material.
Geological Setting of Type Material:
Apatite-rich alkali syenite. Of late magmatic origin.
Associated Minerals at Type Locality:
Reference:
Frenzel, G. (1961) Ein neues mineral: Freudenbergit (Na2Fe2Ti7O18). Neues Jahrbuch für Mineralogie, Monatshefte: 1961: 12-22.
Other Language Names for Freudenbergite
Varieties of Freudenbergite
| Ferrous freudenbergite | Freudenbergite containing Fe. |
Common Associates
Associated Minerals Based on Photo Data:
| 9 photos of Freudenbergite associated with Rutile | TiO2 |
| 2 photos of Freudenbergite associated with Plagioclase | (Na,Ca)[(Si,Al)AlSi2]O8 |
Related Minerals - Strunz-mindat Grouping
| 4.CC. | Xuite | Ca3Fe3+2[(AlO3(OH)]3 |
| 4.CC. | Allendeite | Sc4Zr3O12 |
| 4.CC. | Bitikleite | Ca3(Sb5+Sn4+)[AlO4]3 |
| 4.CC. | Yttriaite-(Y) | Y2O3 |
| 4.CC. | Chlorkyuygenite | Ca12Al14O32[(H2O)4Cl2] |
| 4.CC. | Anzaite-(Ce) | Ce3+ 4Fe2+Ti6O18 (OH)2 |
| 4.CC. | Heamanite-(Ce) | (K0.5Ce0.5)TiO3 |
| 4.CC. | Priscillagrewite-(Y) | (Ca2Y)Zr2(AlO4)3 |
| 4.CC. | Saranovskite | SrCaFe2+2(Cr4Ti2)Ti12O38 |
| 4.CC. | Botuobinskite | SrFe2+Mg2(Cr3+6Ti4+12)[O36(OH)2] |
| 4.CC. | Mirnyite | SrZr4+Mg2(Cr3+6Ti4+12)O38 |
| 4.CC. | Haitaite-(La) | LaU4+Fe3+2(Ti13Fe2+4Fe3+)O38 |
| 4.CC. | Shagamite | KFe11O17 |
| 4.CC.05 | Chrombismite | Bi3+16Cr6+O27 |
| 4.CC.10 | Fluormayenite | Ca12Al14O32F2 |
| 4.CC.10 | Fluorkyuygenite | Ca12Al14O32[(H2O)4F2] |
| 4.CC.15 | Grossite | CaAl4O7 |
| 4.CC.17 | Goldschmidtite | KNbO3 |
| 4.CC.20 | Chlormayenite | Ca12Al14O32[◻4Cl2] |
| 4.CC.20 | Unnamed (HBU UK-4) | NaFe2+Zn2(Ti,Fe3+,Nb)6Ti12O38 |
| 4.CC.20 | Paseroite | PbMn2+(Mn2+,Fe3+)2(V5+,Ti,◻)18O38 |
| 4.CC.20 | Mianningite | (◻,Pb,Ce,Na)(U4+,Mn,U6+)Fe3+2 (Ti,Fe3+)18O38 |
| 4.CC.20 | UM1987-03-O:FePbTiU | ~(U,Pb)(Ti,Fe3+,Fe2+,Mn)21O38 |
| 4.CC.22 | Kahlenbergite | KAl11O17 |
| 4.CC.22 | Gorerite | CaAlFe3+11O19 |
| 4.CC.25 | Yafsoanite | Ca3Te6+2(ZnO4)3 |
| 4.CC.25 | Nixonite | Na2Ti6O13 |
| 4.CC.30 | Latrappite | Ca2NbFe3+O6 |
| 4.CC.30 | Lueshite | NaNbO3 |
| 4.CC.30 | Natroniobite | NaNbO3 |
| 4.CC.30 | Perovskite | CaTiO3 |
| 4.CC.30 | Barioperovskite | BaTiO3 |
| 4.CC.30 | Lakargiite | Ca(Zr,Sn,Ti)O3 |
| 4.CC.30 | Megawite | CaSnO3 |
| 4.CC.32 | Usturite | Ca3(Sb5+Zr)[Fe3+O4]3 |
| 4.CC.32 | Elbrusite | Ca3(U6+0.5Zr1.5)[Fe3+O4]3 |
| 4.CC.32 | Dzhuluite | Ca3(Sb5+Sn4+)[Fe3+O4]3 |
| 4.CC.32 | Monteneveite | Ca3Sb5+2(Fe3+2Fe2+)O12 |
| 4.CC.35 | Loparite-(Ce) | (Na,REE)2Ti2O6 |
| 4.CC.35 | Macedonite | PbTiO3 |
| 4.CC.35 | Tausonite | SrTiO3 |
| 4.CC.35 | Isolueshite | (Na,La)NbO3 |
| 4.CC.35 | Panguite | (Ti,Al,Sc,Mg,Zr,Ca)1.8O3 |
| 4.CC.37 | Pauloabibite | NaNbO3 |
| 4.CC.40 | Crichtonite | Sr(Mn,Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH)38 |
| 4.CC.40 | Davidite-(Ce) | Ce(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38 |
| 4.CC.40 | Davidite-(La) | La(Y,U)Fe2(Ti,Fe,Cr,V)18(O,OH,F)38 |
| 4.CC.40 | Davidite-(Y) | (La,Ce,Na,Ca,Pb)(Y,Fe2+,◻)(Fe2+,Mn2+)2(Ti,Fe3+,Nb,Zr)18O38 (hypothetical) |
| 4.CC.40 | Landauite | NaMnZn2(Ti,Fe)6Ti12O38 |
| 4.CC.40 | Lindsleyite | (Ba,Sr)(Zr,Ca)(Fe,Mg)2(Ti,Cr,Fe)18O38 |
| 4.CC.40 | Loveringite | (Ca,Ce,La)(Zr,Fe)(Mg,Fe)2(Ti,Fe,Cr,Al)18O38 |
| 4.CC.40 | Mathiasite | (Mg,Cr,Fe,Ca,K)2(Ti,Zr,Cr,Fe)5O12 |
| 4.CC.40 | Senaite | Pb(Mn,Y,U)(Fe,Zn)2(Ti,Fe,Cr,V)18(O,OH)38 |
| 4.CC.40 | Uhligite | Ca3(Ti,Al,Zr)9O20 ? |
| 4.CC.40 | Dessauite-(Y) | (Sr,Pb)(Y,U)(Ti,Fe3+)20O38 |
| 4.CC.40 | Cleusonite | (Pb,Sr)(U4+,U6+)(Fe2+,Zn)2(Ti,Fe2+,Fe3+)18(O,OH)38 |
| 4.CC.40 | Gramaccioliite-(Y) | (Pb,Sr)(Y,Mn)Fe3+2(Ti,Fe3+)18O38 |
| 4.CC.45 | Diaoyudaoite | NaAl11O17 |
| 4.CC.45 | Hawthorneite | BaMgTi3Cr4Fe2+2Fe3+2O19 |
| 4.CC.45 | Hibonite | CaAl12O19 |
| 4.CC.45 | Lindqvistite | Pb2Mn2+Fe16O27 |
| 4.CC.45 | Magnetoplumbite | (Pb,Mn)(Fe,Mn)12O19 |
| 4.CC.45 | Plumboferrite | Pb2(Fe3+,Mn2+,Mg)11O19 |
| 4.CC.45 | Yimengite | K(Cr,Ti,Fe,Mg)12O19 |
| 4.CC.45 | Haggertyite | BaFe2+4Fe3+2Ti5MgO19 |
| 4.CC.45 | Nežilovite | PbZn2Mn4+2Fe3+8O19 |
| 4.CC.45 | Batiferrite | BaTi2Fe3+8Fe2+2O19 |
| 4.CC.45 | Chihuahuaite | FeAl12O19 |
| 4.CC.45 | Barioferrite | BaFe3+12O19 |
| 4.CC.45 | Kangite | (Sc,Ti,Al,Zr,Mg,Ca,◻)2O3 |
| 4.CC.45 | Mizraite-(Ce) | Ce(Al11Mg)O19 |
| 4.CC.50 | Jeppeite | (K,Ba)2(Ti,Fe)6O13 |
| 4.CC.55 | Zenzénite | Pb3Fe3+4Mn4+3O15 |
| 4.CC.60 | Mengxianminite (of Huang et al.) | (Ca,Na)3(Fe,Mn)2Mg2(Sn,Zn)5Al8O29 |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Freudenbergite
mindat.org URL:
https://www.mindat.org/min-1608.html
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External Links:
References for Freudenbergite
Reference List:
IMA (1967) International Mineralogical Association: Commission on New Minerals and Mineral Names. Mineralogical Magazine and Journal of the Mineralogical Society, 36 (277) 131-136 doi:10.1180/minmag.1967.036.277.20
Localities for Freudenbergite
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Botswana | |
| Anashkin et al. (2013) +1 other reference |
Canada | |
| Anzolini et al. (2019) |
Germany | |
| Lippolt et al. (1976) +5 other references |
| Am. Min. et al. (1961) +1 other reference |
Russia | |
| maurice.strahlen.org (2003) +1 other reference |
| Mikhailova et al. (2015) +1 other reference |
| Am Min (97) +1 other reference |
South Africa | |
| Patchen et al. (1997) |
| Kamenetsky et al. (2014) |
| Giuliani et al. (2012) |
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Kaskasnyunchorr Mountain, Khibiny Massif, Murmansk Oblast, Russia