Korobitsynite
A valid IMA mineral species
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About Korobitsynite
Formula:
Na2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2O
Colour:
Colorless
Lustre:
Vitreous
Hardness:
5
Specific Gravity:
2.72
Crystal System:
Orthorhombic
Member of:
Name:
Named after Mikhail Fedorovich Korobitsyn (Михаил Федорович Коробицин) (1928-1996), amateur mineralogist and collector who made significant contributions to mineralogical investigations of the Lovozero alkaline complex.
Unique Identifiers
Mindat ID:
7141
Long-form identifier:
mindat:1:1:7141:9
GUID
(UUID V4):
(UUID V4):
569a55c4-a0c0-47c6-8bf0-fabc7dadb99b
IMA Classification of Korobitsynite
Approved
IMA Formula:
(Na,◻)4Ti2(Si4O12)(O,OH)2 · 4H2O
First published:
1999
Type description reference:
Classification of Korobitsynite
9.CE.30a
9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Kbi | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Korobitsynite
Vitreous
Transparency:
Transparent
Colour:
Colorless
Streak:
White
Hardness:
5 on Mohs scale
Tenacity:
Brittle
Cleavage:
Imperfect/Fair
(001)
(001)
Density:
2.72 g/cm3 (Measured) 2.69 g/cm3 (Calculated)
Optical Data of Korobitsynite
Type:
Biaxial (+)
RI values:
nα = 1.646 nβ = 1.654 nγ = 1.763
Max Birefringence:
δ = 0.117
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Moderate
Dispersion:
weak
Chemistry of Korobitsynite
Mindat Formula:
Na2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2O
Crystallography of Korobitsynite
Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pbam
Setting:
Pbam
Cell Parameters:
a = 7.349(2) Å, b = 14.164(2) Å, c = 7.130(1) Å
Ratio:
a:b:c = 0.519 : 1 : 0.503
Unit Cell V:
742.2 ų
Morphology:
Needle-like crystals. Forms include {110}, {001}, {010}, {100}, and {021}.
Crystal Structure
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0012492 | Korobitsynite | Rastsvetaeva R K, Chukanov N V, Pekov I V (1997) Crystal structure of a new mineral - titanium analog of orthorhombic nenadkevichite Doklady Akademii Nauk SSSR 357 364-367 | 1997 | 0 | 293 |
CIF Raw Data - click here to close
Epitaxial Relationships of Korobitsynite
Epitaxial Minerals:
Elpidite | Na2ZrSi6O15 · 3H2O |
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
3.262 Å | (100) |
6.53 Å | (85) |
7.09 Å | (79) |
2.075 Å | (57) |
2.553 Å | (56) |
3.180 Å | (52) |
2.649 Å | (45) |
1.457 Å | (45) |
2.512 Å | (42) |
1.307 Å | (40) |
1.060 Å | (40) |
1.271 Å | (35) |
5.02 Å | (34) |
1.591 Å | (32) |
1.122 Å | (30) |
Comments:
Lovozero massif, Kola Peninsula, Russia. The data are from the type description.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Stage 4b: Highly evolved igneous rocks | >3.0 |
35 : Ultra-alkali and agpaitic igneous rocks |
Type Occurrence of Korobitsynite
Co-Type Localities:
General Appearance of Type Material:
Prismatic crystals uр to 2 сm.
Place of Conservation of Type Material:
A. E. Fersman Mineralogical Museum, Moscow, Russia, number 89457 (type).
Geological Setting of Type Material:
In miarolitic cavities in pegmatite.
Associated Minerals at Type Locality:
Reference:
Pekov, I.V., Chukanov, N.V., Khomyakov, A.P., Rastsvetaeva, R.K., Kucherinenko, Y.V., Nedel'ko, V.V. (1999) Korobitsynite, Na3-x(Ti,Nb)2[Si4O12](OH,O)2·3-4H2O, a new mineral from Lovozero massif, Kola Peninsula. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva: 128: 72-79.
Synonyms of Korobitsynite
Other Language Names for Korobitsynite
Relationship of Korobitsynite to other Species
Member of:
Other Members of this group:
Nenadkevichite | (Na,◻)8Nb4(Si4O12)2(O,OH)4 · 8H2O | Orth. mmm (2/m 2/m 2/m) : Pbam |
UM2000-63-SiO:BaHKNaNbSrTi | (H3O)4Na2K[Sr0.4Ba0.3(H2O)0.8]{[Ti4.5Nb3.5](OH)4.5O3.5)[Si4O12]4} · 4.2H2O | Mon. m : Bm |
Unnamed (Ca-Na-ordered analogue of Korobitsynite) | (Ca,Na)2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2O | Orth. 2 2 2 : P21 21 2 |
Common Associates
Associated Minerals Based on Photo Data:
6 photos of Korobitsynite associated with Aegirine | NaFe3+Si2O6 |
4 photos of Korobitsynite associated with Albite | Na(AlSi3O8) |
2 photos of Korobitsynite associated with Calcioancylite | |
2 photos of Korobitsynite associated with Unnamed (Fe-analogue of Zakharovite) | Na4Fe5Si10O24(OH)6 · 6H2O |
2 photos of Korobitsynite associated with Smectite Group | A0.3D2-3[T4O10]Z2 · nH2O |
2 photos of Korobitsynite associated with Natrolite | Na2Al2Si3O10 · 2H2O |
1 photo of Korobitsynite associated with Sazhinite-(Ce) | Na2CeSi6O14 · 6H2O |
1 photo of Korobitsynite associated with Unnamed (Sazhinite-related mineral I) | Na, La, Si, O, H |
1 photo of Korobitsynite associated with Tuperssuatsiaite | Fe3+Fe3+2(Na◻)◻2Si8O20(OH)2(H2O)4 · 2H2O |
1 photo of Korobitsynite associated with Fluorapatite | Ca5(PO4)3F |
Related Minerals - Strunz-mindat Grouping
9.CE. | Dutkevichite-(Ce) | NaZnBa2Ce2Ti2Si8O26F · H2O |
9.CE. | Niobobaotite | Ba4(Ti2.5Fe2+1.5)Nb4Si4O28Cl |
9.CE.05 | Papagoite | CaCu[H3AlSi2O9] |
9.CE.10 | Verplanckite | Ba4Mn2+2Si4O12(OH,H2O)3Cl3 |
9.CE.15 | Baotite | Ba4(Ti,Nb,W)8O16(SiO3)4Cl |
9.CE.20 | Nagashimalite | Ba4(V,Ti)4B2Si8O27(O,OH)2Cl |
9.CE.20 | Taramellite | Ba4(Fe3+,Ti,Fe2+,Mg)4(B2Si8O27)O2Clx |
9.CE.20 | Titantaramellite | Ba4(Ti,Fe3+,Fe2+,Mg)4(B2Si8O27)O2Clx |
9.CE.25 | Bario-orthojoaquinite | (Ba,Sr)4Fe2Ti2[Si4O12]2O2 · H2O |
9.CE.25 | Byelorussite-(Ce) | NaBa2Ce2MnTi2[Si4O12]2O2(F,OH) · H2O |
9.CE.25 | Joaquinite-(Ce) | NaBa2Ce2FeTi2[Si4O12]2O2(OH,F) · H2O |
9.CE.25 | Orthojoaquinite-(Ce) | NaBa2Ce2FeTi2[Si4O12]2O2(O,OH) · H2O |
9.CE.25 | Strontiojoaquinite | Sr2Ba2(Na,Fe)2Ti2[Si4O12]2O2(O,OH)2 · H2O |
9.CE.25 | Strontio-orthojoaquinite | (Na,Fe)2Sr2Ba2Ti2[Si4O12]2O2(O,OH)2 · H2O |
9.CE.25 | Orthojoaquinite-(La) | NaBa2La2Fe2+Ti2[Si4O12]2O2(O,OH) · H2O |
9.CE.30a | Unnamed (Ca-Na-ordered analogue of Korobitsynite) | (Ca,Na)2(Ti,Nb)2(Si4O12)(OH,O)2 · 3-4H2O |
9.CE.30e | Labuntsovite-Mn | Na4K4(Ba,K)2Mn2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10-12H2O |
9.CE.30a | Nenadkevichite | (Na,◻)8Nb4(Si4O12)2(O,OH)4 · 8H2O |
9.CE.30d | Lemmleinite-K | K2(Ti,Nb)2(Si4O12)(OH,O)2 · 4H2O |
9.CE.30c | Kuzmenkoite-Mn | K2Mn2+(Ti,Nb)4(Si4O12)2(OH,O)4 · 5-6H2O |
9.CE.30b | Vuoriyarvite-K | K2(Nb,Ti)2(Si4O12)(O,OH)2 · 4H2O |
9.CE.30b | Tsepinite-Na | Na2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O |
9.CE.30c | Karupmøllerite-Ca | (Na,Ca,K)2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 7H2O |
9.CE.30e | Labuntsovite-Mg | Na4K4(Ba,K)2Mg(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2O |
9.CE.30e | Labuntsovite-Fe | Na4K4(Ba,K)2Fe2+(Ti,Nb)8(Si4O12)4(O,OH)8 · 10H2O |
9.CE.30d | Lemmleinite-Ba | Na2K2Ba(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2O |
9.CE.30c | Gjerdingenite-Fe | K2Fe2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O |
9.CE.30h | Neskevaaraite-Fe | K3Na2Fe2+(Ti,Nb)4(Si4O12)2(O,OH)4 · 5-6 H2O |
9.CE.30b | Tsepinite-K | K2(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O |
9.CE.30b | Paratsepinite-Ba | Ba4(Ti,Nb)8(Si4O12)4(OH,O)8 · 8H2O |
9.CE.30b | Tsepinite-Ca | Ca(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O |
9.CE.30h | Alsakharovite-Zn | NaSrKZn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2O |
9.CE.30c | Gjerdingenite-Mn | K2Mn2+(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O |
9.CE.30c | Lepkhenelmite-Zn | (Ba,K)2Zn(Ti,Nb)4(Si4O12)2(O,OH)4 · 7H2O |
9.CE.30b | Tsepinite-Sr | Sr(Ti,Nb)2(Si4O12)(OH,O)2 · 3H2O |
9.CE.30b | Paratsepinite-Na | (Na,Sr,K,Ca)7(Ti,Nb)8(Si4O12)4(O,OH)8 · nH2O n ~ 8 |
9.CE.30f | Paralabuntsovite-Mg | Na8K8Mg4Ti16(Si4O12)8(OH,O)16 · 20-24H2O |
9.CE.30c | Gjerdingenite-Ca | K2Ca(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O |
9.CE.30c | Gjerdingenite-Na | K2Na(Nb,Ti)4(Si4O12)2(OH,O)4 · 5H2O |
9.CE.30h | Gutkovaite-Mn | K2CaMn(Ti,Nb)4(Si4O12)2(O,OH)4 · 5H2O |
9.CE.30c | Kuzmenkoite-Zn | K2Zn(Ti,Nb)4(Si4O12)2(OH,O)4 · 6-8H2O |
9.CE.30g | Organovaite-Mn | K2Mn(Nb,Ti)4(Si4O12)2(O,OH)4 · 5-7H2O |
9.CE.30g | Organovaite-Zn | K2Zn(Nb,Ti)4(Si4O12)2(O,OH)4 · 6H2O |
9.CE.30g | Parakuzmenkoite-Fe | (K,Ba)4Fe(Ti,Nb)8(Si4O12)4(O,OH)8 · 14H2O |
9.CE.30c | Burovaite-Ca | (Na,K)4Ca2(Ti,Nb)8(Si4O12)4(OH,O)8 · 12H2O |
9.CE.45 | Komarovite | (Ca,Mn)(Nb,Ti)2[Si2O7](O,F)3 · 3.5H2O |
9.CE.45 | Natrokomarovite | (Na,Ca,H)2Nb2Si2O10(OH,F)2 · H2O |
Other Information
IR Spectrum:
The infrared spectrum has absorption bands at 3500, 3390, 3250, 1633, 1118, 959, 919, 750, 667, and 454 cm–1 .
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Korobitsynite
mindat.org URL:
https://www.mindat.org/min-7141.html
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References for Korobitsynite
Reference List:
Pekov, I. V., Chukanov, N. V., Khomyakov, A. P., Rastsvetaeva, R. K., Kucherinenko, Y. V., Nedel'ko, V. V. (1999) Korobitsynite, Na3-x(Ti,Nb)2[Si4O12](OH,O)2·3-4H2O, a new mineral from Lovozero massif, Kola Peninsula. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 128 (3) 72-79
Jambor, John L., Pertsev, Nikolai N., Roberts, Andrew C. (2000) New Mineral Names. American Mineralogist, 85. 1321-1325
Localities for Korobitsynite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Canada | |
| HORVÁTH (2001) |
Namibia | |
| Niedermayr et al. (2002) +1 other reference |
Russia | |
| Belovitskaya et al. (2004) |
| [AmMin 84:195] |
| Pekov et al. (1999) +3 other references |
Sorokhtina N.V. et al. (2004) | |
| Pekov et al. (1999) +2 other references |
Pekov (2000) |
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Shomiokitovoe pegmatite, Umbozero mine, Alluaiv Mountain, Lovozersky District, Murmansk Oblast, Russia