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Kampf, A. R., Mills, S. J., Housley, R. M. (2010) The crystal structure of munakataite, Pb2Cu2(Se4+O3)(SO4)(OH)4, from Otto Mountain, San Bernardino County, California, USA. Mineralogical Magazine, 74 (6) 991-998 doi:10.1180/minmag.2010.074.6.991

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Reference TypeJournal (article/letter/editorial)
TitleThe crystal structure of munakataite, Pb2Cu2(Se4+O3)(SO4)(OH)4, from Otto Mountain, San Bernardino County, California, USA
JournalMineralogical Magazine
AuthorsKampf, A. R.Author
Mills, S. J.Author
Housley, R. M.Author
Year2010 (December)Volume74
Page(s)991-998Issue6
PublisherMineralogical Society
Download URLhttps://rruff.info/rruff_1.0/uploads/MM74_991.pdf+
DOIdoi:10.1180/minmag.2010.074.6.991Search in ResearchGate
Classification
Not set		LoC
Not set
Mindat Ref. ID244125Long-form Identifiermindat:1:5:244125:6
GUID85305c45-facd-443d-af34-deaae90b71f5
Full ReferenceKampf, A. R., Mills, S. J., Housley, R. M. (2010) The crystal structure of munakataite, Pb2Cu2(Se4+O3)(SO4)(OH)4, from Otto Mountain, San Bernardino County, California, USA. Mineralogical Magazine, 74 (6) 991-998 doi:10.1180/minmag.2010.074.6.991
Plain TextKampf, A. R., Mills, S. J., Housley, R. M. (2010) The crystal structure of munakataite, Pb2Cu2(Se4+O3)(SO4)(OH)4, from Otto Mountain, San Bernardino County, California, USA. Mineralogical Magazine, 74 (6) 991-998 doi:10.1180/minmag.2010.074.6.991
In(2010, December) Mineralogical Magazine Vol. 74 (6) Mineralogical Society
Abstract/NotesAbstractMunakataite, Pb2Cu2(Se4+O3)(SO4)(OH)4, has been found in association with a variety of rare secondary Te minerals at Otto Mountain, San Bernardino County, California, USA. It is very rare and occurs as subparallel bundles of blue needles up to 1 mm long. Electron microprobe analyses provided the empirical formula Pb1.96Cu1.60[(Se0.894+S0.11)βˆ‘1O3](SO4)[(OH)3.34(H2O)0.66]βˆ‘4- Munakataite is mono-clinic, space group P21/m, with cell parameters a = 9.8023(26), b = 5.6751(14), c = 9.2811(25) Γ…, Ξ² = 102.443(6), V = 504.2(2) Γ…3 and Z = 2. The crystal structure, solved by direct methods and refined to R1 = 0.0308 for 544 Fo > 4ΟƒF reflections, consists of Jahn-Teller-distorted Cu2+O6 square bipyramids. which form chains along b by sharing trans edges across their square planes. The chains are decorated by SO4 tetrahedra and Se4+O3 pyramids, which bond to apical corners of adjacent bipyramids. The chains are linked to one another via bonds to two different PbO9 polyhedra, only one of which exhibits one-sided coordination typical of Pb2+ with a stereochemically active 6s2 lone-electron-pair. Munakataite is isostructural with schmiederite and the structure is closely related to that of linarite.

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Locality Pages

LocalityCitation Details
Aga Mine, Otto Mountain, Baker, Soda Mountains, Silver Lake Mining District, San Bernardino County, California, USA
Bird Nest drift, Otto Mountain, Baker, Soda Mountains, Silver Lake Mining District, San Bernardino County, California, USA

Mineral Pages

MineralCitation Details
Munakataite

Mineral Occurrences

LocalityMineral(s)
Otto Mountain, Baker, Soda Mountains, Silver Lake Mining District, San Bernardino County, California, USAβ“˜ Acanthite, β“˜ Anglesite, β“˜ Atacamite, β“˜ Boleite, β“˜ Brochantite, β“˜ Burckhardtite, β“˜ Calcite, β“˜ Caledonite, β“˜ Celestine, β“˜ Cerussite, β“˜ Chalcopyrite, β“˜ Chlorargyrite, β“˜ Chrysocolla, β“˜ Devilline, β“˜ Diaboleite, β“˜ Fluorite, β“˜ Fornacite, β“˜ Galena, β“˜ Goethite, β“˜ Gold, β“˜ Hessite, β“˜ Housleyite, β“˜ Iodargyrite, β“˜ Jarosite, β“˜ Khinite, β“˜ Kuranakhite, β“˜ Linarite, β“˜ Malachite, β“˜ Markcooperite, β“˜ Mimetite, β“˜ Mottramite, β“˜ Munakataite, β“˜ Murdochite, β“˜ Muscovite, β“˜ Ottoite, β“˜ Paratimroseite, β“˜ Perite, β“˜ Phosphohedyphane, β“˜ Plumbojarosite, β“˜ Pyrite, β“˜ Quartz, β“˜ Schieffelinite, β“˜ Telluroperite, β“˜ Thorneite, β“˜ Timroseite, β“˜ Vanadinite, β“˜ Vauquelinite, β“˜ Wulfenite
Aga Mine, Otto Mountain, Baker, Soda Mountains, Silver Lake Mining District, San Bernardino County, California, USAβ“˜ Munakataite

See Also

These are possibly similar items as determined by title/reference text matching only.

Kampf, A. R., Mills, S. J., Nash, B. P. (2016) Pauladamsite, Cu4(SeO3)(SO4)(OH)4Β·2H2O, a new mineral from the Santa Rosa mine, Darwin district, California, USA. Mineralogical Magazine, 80 (6) 949-958 doi:10.1180/minmag.2016.080.032
Kampf, Anthony R., Housley, Robert M., Mills, Stuart J., Rossman, George R., Marty, Joe (2020) Hagstromite, Pb8Cu2+(Te6+O6)2(CO3)Cl4, a new lead–tellurium oxysalt mineral from Otto Mountain, California, USA. Mineralogical Magazine, 84 (4) 517-523 doi:10.1180/mgm.2020.30
Kampf, Anthony R., Cooper, Mark A., Mills, Stuart J., Housley, Robert M., Rossman, George R. (2016) Lead-tellurium oxysalts from Otto Mountain near Baker, California, USA: XII. Andychristyite, PbCu2+Te6+O5(H2O), a new mineral with hcp stair-step layers. Mineralogical Magazine, 80 (6) 1055-1065 doi:10.1180/minmag.2016.080.042
Kampf, A. R., Mills, S. J., Housley, R. M., Rossman, G. R., Marty, J., Thorne, B. (2013) Lead-tellurium oxysalts from Otto Mountain near Baker, California: X. Bairdite, Pb2Cu2+4Te6+2O10(OH)2(SO4)(H2O), a new mineral with thick HCP layers. American Mineralogist, 98 (7) 1315-1321 doi:10.2138/am.2013.4389
Christy, Andrew G., Mills, Stuart J., Kampf, Anthony R., Housley, Robert M., Thorne, Brent, Marty, Joe (2016) The relationship between mineral composition, crystal structure and paragenetic sequence: the case of secondary Te mineralization at the Bird Nest drift, Otto Mountain, California, USA. Mineralogical Magazine, 80 (2) 291-310 doi:10.1180/minmag.2016.080.001
Kampf, A. R., Mills, S. J., Housley, R. M., Marty, J., Thorne, B. (2010) Lead-tellurium oxysalts from Otto Mountain near Baker, California: V. Timroseite, Pb2Cu2+5(Te6+O6)2(OH)2, and paratimroseite, Pb2Cu2+4(Te6+O6)2(H2O)2, two new tellurates with Te-Cu polyhedral sheets. American Mineralogist, 95 (10) 1560-1568 doi:10.2138/am.2010.3514
Mills, S. J., Kampf, A. R., Christy, A. G., Housley, R. M., Rossman, G. R., Reynolds, R. E., Marty, J. (2014) Bluebellite and mojaveite, two new minerals from the central Mojave Desert, California, USA. Mineralogical Magazine, 78 (5) 1325-1340 doi:10.1180/minmag.2014.078.5.15
Kampf, A. R., Mills, S. J., Housley, R. M., Williams, P. A., Dini, M. (2012) Alcaparrosaite, K3Ti4+Fe3+(SO4)4O(H2O)2, a new hydrophobic Ti4+ sulfate from Alcaparrosa, Chile. Mineralogical Magazine, 76 (4) 851-861 doi:10.1180/minmag.2012.076.4.03
Flynn, Shields, Barton, Isabel F., Feinglos, Mark (2016) Munakataite, Pb2Cu2(Se4+O3)(SO4)(OH)4, and Other Selenium Minerals from Tsumeb, Namibia. Rocks & Minerals, 91 (6) 548-553 doi:10.1080/00357529.2016.1217470
Mills, S. J., Kampf, A. R., Housley, R. M., Favreau, G., Pasero, M., Biagioni, C., Merlino, S., Berbain, C., Orlandi, P. (2012) Omsite, (Ni,Cu)2Fe3+(OH)6[Sb(OH)6], a new member of the cualstibite group from Oms, France. Mineralogical Magazine, 76 (5) 1347-1354 doi:10.1180/minmag.2012.076.5.16
Kampf, A. R., Mills, S. J., Housley, R. M., Rossman, G. R., Nash, B. P., Dini, M., Jenkins, R. A. (2013) Joteite, Ca2CuAl[AsO4][AsO3(OH)]2(OH)2Β·5H2O, a new arsenate with a sheet structure and unconnected acid arsenate groups. Mineralogical Magazine, 77 (6) 2811-2823 doi:10.1180/minmag.2013.077.6.08
 
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