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Vaterite

Formula:
CaCO
 
3
System:HexagonalColour:Colourless
Hardness:3
Name:Named after Heinrich Vater, Professor of Mineralogy and Chemistry, Tharandt, Saxony (Germany).
Polymorph of:Aragonite, Calcite


A rare CaCO3 modification that is metastable below approx. 400°C.

Classification of Vaterite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:5/B.02-10
Nickel-Strunz 10th (pending) edition ID:5.AB.20

5 : CARBONATES (NITRATES)
A : Carbonates without additional anions, without H2O
B : Alkali-earth (and other M2+) carbonates
Dana 8th edition ID:14.1.2.1

14 : ANHYDROUS NORMAL CARBONATES
1 : A(XO3)
Hey's CIM Ref.:11.4.3

11 : Carbonates
4 : Carbonates of Ca
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Physical Properties of Vaterite

Diaphaneity (Transparency):Transparent
Colour:Colourless
Streak:White
Hardness (Mohs):3
Density (calculated):2.645 g/cm3

Crystallography of Vaterite

Crystal System:Hexagonal
Class (H-M):6/mmm (6/m 2/m 2/m) - Dihexagonal Dipyramidal
Space Group:P63/mmc (P63/m 2/m 2/c)
Cell Parameters:a = 4.13Å, c = 8.49Å
Ratio:a:c = 1 : 2.056
Unit Cell Volume:V 125.41 ų (Calculated from Unit Cell)
Z:6
Morphology:Thin fibres, spherulitic aggregates.
X-Ray Powder Diffraction:
d-spacingIntensity
3.57 (55)
3.30 (100)
2.73 (95)
2.065 (60)
1.858 (25)
1.823 (70)

Optical Data of Vaterite

Type:Uniaxial (+)
RI values: nω = 1.550 nε = 1.650
Maximum Birefringence:δ = 0.100

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate

Chemical Properties of Vaterite

Formula:
CaCO
 
3
Essential elements:C, Ca, O
All elements listed in formula:C, Ca, O

Relationship of Vaterite to other Species

Related Minerals - Nickel-Strunz Grouping):
5.AB.05Calcite
CaCO
 
3
5.AB.05Gaspéite
(Ni,Mg,Fe)CO
 
3
5.AB.05Magnesite
MgCO
 
3
5.AB.05Otavite
CdCO
 
3
5.AB.05Rhodochrosite
MnCO
 
3
5.AB.05Siderite
FeCO
 
3
5.AB.05Smithsonite
ZnCO
 
3
5.AB.05Spherocobaltite
CoCO
 
3
5.AB.10Ankerite
Ca(Fe
2+
 
,Mg,Mn
2+
 
)(CO
 
3
)
 
2
5.AB.10Dolomite
CaMg(CO
 
3
)
 
2
5.AB.10Kutnohorite
Ca(Mn,Mg,Fe)(CO
 
3
)
 
2
5.AB.10Minrecordite
CaZn(CO
 
3
)
 
2
5.AB.15Aragonite
CaCO
 
3
5.AB.15Cerussite
PbCO
 
3
5.AB.15Strontianite
SrCO
 
3
5.AB.15Witherite
BaCO
 
3
5.AB.25Huntite
CaMg
 
3
(CO
 
3
)
 
4
5.AB.30Norsethite
BaMg(CO
 
3
)
 
2
5.AB.35Alstonite
BaCa(CO
 
3
)
 
2
5.AB.40Olekminskite
Sr(Sr,Ba)(CO
 
3
)
 
2
5.AB.40Paralstonite
BaCa(CO
 
3
)
 
2
5.AB.45Barytocalcite
BaCa(CO
 
3
)
 
2
5.AB.50Carbocernaite
(Ca,Na)(Sr,Ce,Ba)(CO
 
3
)
 
2
5.AB.55Benstonite
(Ba,Sr)
 
6
(Ca,Mn)
 
6
Mg(CO
 
3
)
 
13
5.AB.60Juangodoyite
Na
 
2
Cu(CO
 
3
)
 
2
Related Minerals - Hey's Index Grouping:
11.4.1Calcite
CaCO
 
3
11.4.2Aragonite
CaCO
 
3
11.4.4Monohydrocalcite
CaCO
 
3
·H
 
2
O
11.4.5Ikaite
CaCO
 
3
·6H
 
2
O
11.4.6Dolomite
CaMg(CO
 
3
)
 
2
11.4.7Huntite
CaMg
 
3
(CO
 
3
)
 
4
11.4.8Sergeevite
Ca
 
2
Mg
 
11
(CO
 
3
)
 
13
·10H
 
2
O

Other Names for Vaterite

Synonyms:
μ-CalciteVaterite-B
German names:
Vaterit
Russian names:
Фатерит
Simplified Chinese names:
球文石
Spanish names:
Vaterita

Other Information

Thermal Behaviour:Dry crystals convert to calcite when heated to about 440°.
Other Information:Converts to aragonite or calcite when boiled in water. Converts to calcite when boiled in NaCl solution.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Vaterite

Reference List:Doelter, C. (1911) Handbuch der Mineral-chemie (in 4 volumes divided into parts): 1: 113.

Meigen, W. (1911): Über kohlensauren Kalk. Verhandl. Ges. Deut. Naturforscher u. Ärtzte, 82, 120-124.

Johnston, Merwin, and Williamson (1916) American Journal of Science: 41: 473.

Gibson, Wyckoff, and Merwin (1925) American Journal of Science: 10: 325 (as Vaterite-B).

Heide (1925) Centralblatt für Mineralogie, Geologie und Paleontologie, Stuttgart: 198.

Hintze, Carl (1926) Handbuch der Mineralogie. Berlin and Leipzig. 6 volumes: 1 [3B]: 2883.

Yoshimura (1930) Japanese Journal of Geology and Geography: 7: 3.

American Mineralogist (1931): 16: 770-772.

Donnay (1936) Société géologique de Belgique, Liége, Bulletin: 59: 215.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged: 181-182.

McConnel, J.D.C. (1960): Vaterite from Ballycraigy, Larne, Northern Ireland. Mineralogical Magazine: 32: 534-544.

American Mineralogist (1960): 45: 1316.

Zeitschrift für Kristallographie (1969): 128: 183.

Internet Links for Vaterite

Search Engines:
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  • External Links:
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  • Look for Vaterite on Wikipedia
  • Look for Vaterite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Vaterite in the Natural History Museum (London) online catalogue
  • Vaterite details from Handbook of Mineralogy (PDF)
  • Mineral Dealers:
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    Localities for Vaterite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • Tasmania
      • Central Plateau
    Bottrill & Baker (in prep) Catalogue of minerals of Tasmania
    Austria
     
    • Salzburg
      • Hohe Tauern Mts
        • Obersulzbach valley
          • Hopffeld area
    A. Strasser: Die Minerale Salzburgs (1989)
    Canada
     
    • Québec
      • Rouville Co.
        • Mont Saint-Hilaire
    No reference listed
    China
     
    • Zhejiang Province
      • Hangzhou Prefecture
        • Yuhang District
    Acta Mineralogica Sinica 21(2), 153-157 (2001)
    Germany
     
    • Baden-Württemberg
      • Black Forest
        • Wolfach
          • Oberwolfach
            • Rankach valley
    WALENTA, K. (1995): Neue Mineralfunde von der Grube Clara. 6. Folge, 2. Teil. - Lapis 20 (6), 41 und 46-49.
    • Lower Saxony
      • Harz Mts
        • Clausthal-Zellerfeld
          • Oberschulenberg
    Schnorrer-Köhler, G. (1991): Mineralogische Notizen V, Der Aufschluss, Vol. 42, 155-171
    • Rhineland-Palatinate
      • Eifel Mts
        • Daun
          • Üdersdorf
    Schüller, W., Betz, V., Die Mineralien vom Emmelberg, Lapis 12/1986
        • Hillesheim
          • Zilsdorf
    Hentschel. G., Die Mineralien der Eifelvulkane, Weise Verlag München, 1983
        • Mayen
          • Ettringen
    [Hentschel, G., Seltene Minerale in Calcium-reichen Auswürflingen vom Bellerberg bei Mayen/Eifel, Aufschluß 29, 77-83, 1978] [Lapis, 15 (5), 9-36]
        • Mendig
          • Niedermendig
    Hentschel, G., Die Mineralien der Eifelvulkane, Weise Verlag München, 1983
    Hungary
     
    • Somogy Co.
    Szakáll & Gatter: Hun. Min. Spec., 1993
    Israel
     
    Gross, S. (1977): The Mineralogy of the Hatrurim Formation, Israel. Geological Survey of Israel, Bulletin no. 70, 80 pp.
    Japan
     
    • Hokkaido Island
    Ito et al. (1999) Ganseki-Koubutsu-Koshogaku Zasshi, 94, 176-182.
    Palestine
     
    • West Bank
    Shulamit Gross (1977) The mineralogy of the Hatrurim Formation, Israel. Geol. Surv. of Israel, bull. # 70.
    Poland
     
    • Upper Silesia (Śląskie)
      • Upper Silesian Coal Basin
        • Katowice area
          • Siemianowice Śląskie
    Kruszewski L. 2006: Oldhamite-periclase-portlandite-fluorite assemblage and coexisting minerals of burnt dump in Siemianowice Śląskie - Dąbrówka Wielka area (Upper Silesia, Poland) - preliminary report. Mineralogia Polonica Special Papers, vol.28, 118-120
    Russia
     
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
    www.koeln.netsurf.de/~w.steffens/khib.htm
    www.koeln.netsurf.de/~w.steffens/vuori.htm
    South Africa
     
    • Northern Cape Province
      • Kalahari manganese fields
        • Hotazel
    Minerals of South Africa
    USA
     
    • Arizona
      • Maricopa Co.
    Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 412.
    • Michigan
      • Houghton Co.
        • Osceola
    Mineralogy of Michigan (E. W. Heinrich & G. W. Robinson)
    • New Mexico
      • Otero Co.
        • Cornudas Mountains
    XRD - Laszlo Horvath collection
    • Tennessee
      • Smith Co.
        • Central Tennessee Ba-F-Pb-Zn District
          • Carthage
    www.excaliburmineral.com
    Mineral and/or Locality
    Google
     
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