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Hematolite

A valid IMA mineral species - grandfathered
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About HematoliteHide

Formula:
(Mn,Mg,Al,Fe3+)15(As5+O4)2(As3+O3)(OH)23
Cation requirements for charge balance suggest that there about two 3+ cations per formula unit. The original 3+ cations determined by Moore and Araki (1978) were Al-dominant. Polytypic stacking may be present resulting in formula variations.
Colour:
Brown-red, blood-red, nearly black; reddish orange to yellowish brown in transmitted light.
Lustre:
Vitreous, Sub-Vitreous, Resinous, Pearly, Sub-Metallic
Hardness:
Specific Gravity:
3.49
Crystal System:
Trigonal
Name:
Named as aimatolit (Swedish) in 1884 by Lars Johan Igelstrom from the Greek αίμα for "blood" and λίθος for "stone", in allusion to its red pyrope-like colour.
Dark blood-red platy crystals (< 1 mm) and crusts.


Unique IdentifiersHide

Mindat ID:
1857
Long-form identifier:
mindat:1:1:1857:5
GUID
(UUID V4):
8b74320d-24c9-422a-97aa-cd4e93e1a9cf

IMA Classification of HematoliteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA Formula:
(Mn,Mg,Al)15(AsO4)2(AsO3)(OH)23

Classification of HematoliteHide

8.BE.45

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
E : With only medium-sized cations, (OH, etc.):RO4 > 2:1
43.4.6.1

43 : COMPOUND PHOSPHATES, ETC.
4 : Anhydrous Compound Phosphates, etc·, Containing Hydroxyl or Halogen
20.8.21

20 : Arsenates (also arsenates with phosphate, but without other anions)
8 : Arsenates of Mn

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
HmtIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of HematoliteHide

Vitreous, Sub-Vitreous, Resinous, Pearly, Sub-Metallic
Transparency:
Translucent
Comment:
Pearly to sub-metallic on cleavage surfaces.
Colour:
Brown-red, blood-red, nearly black; reddish orange to yellowish brown in transmitted light.
Streak:
Light chocolate-brown to reddish brown
Hardness:
3½ on Mohs scale
Tenacity:
Brittle
Cleavage:
Perfect
On {0001}, perfect
Fracture:
Irregular/Uneven
Density:
3.49 g/cm3 (Measured)    3.48 g/cm3 (Calculated)

Optical Data of HematoliteHide

Type:
Uniaxial (-)
RI values:
nω = 1.733 nε = 1.714
Birefringence:
0.019
Max Birefringence:
δ = 0.019
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
High
Pleochroism:
Non-pleochroic
Comments:
The crystals are divided into differently oriented, anomalously biaxial sectors at times.

Chemistry of HematoliteHide

Mindat Formula:
(Mn,Mg,Al,Fe3+)15(As5+O4)2(As3+O3)(OH)23

Cation requirements for charge balance suggest that there about two 3+ cations per formula unit. The original 3+ cations determined by Moore and Araki (1978) were Al-dominant. Polytypic stacking may be present resulting in formula variations.

Crystallography of HematoliteHide

Crystal System:
Trigonal
Class (H-M):
3 - Rhombohedral
Space Group:
R3
Cell Parameters:
a = 8.275 Å, c = 36.60 Å
Ratio:
a:c = 1 : 4.423
Unit Cell V:
2,170.44 ų (Calculated from Unit Cell)
Z:
3
Morphology:
Crystals thick tabular {0001} with large {0115}, or rhombohedral with {0115} alone. The rhombohedral faces are striated horizontally.
Comment:
Basic repeat distance of 12.2 A of a five-layer structure found

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0000610HematoliteMoore P B, Araki T (1978) Hematolite: A complex dense-packed sheet structure American Mineralogist 63 150-15919780293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
6.12 Å(80)
5.63 Å(30)
5.20 Å(50)
4.14 Å(80)
3.40 Å(40)
4.22 Å(40)
2.60 Å(40)
2.39 Å(100)
1.562 Å(90)
Comments:
Berry and Graham (1948)

Geological EnvironmentHide

Paragenetic Mode(s):
Geological Setting:
Unnamed, possible ferric analog of hematolite occurs at Ogdensburg, New Jersey (Dunn and Peacor, 1983). The mineral occurs in fractures of red willemite-franklinite-calcite ore as well as on friedelite-magnetite rock.

Type Occurrence of HematoliteHide

Geological Setting of Type Material:
Veinlets or cavities in crystalline limestone of a stratabound Mn-Fe ore deposit.
Associated Minerals at Type Locality:

Synonyms of HematoliteHide

Other Language Names for HematoliteHide

Relationship of Hematolite to other SpeciesHide

Other Members of this group:
Arakiite(Zn,Mn2+)(Mn2+,Mg)12(Fe3+,Al)2(As5+O4)2(As3+O3)(OH)23Mon. m : Bb
DixeniteCuMn2+14Fe2+(SiO4)2(As5+O4)(As3+O3)5(OH)6Trig. 3 : R3
KraissliteZn3(Mn,Mg)25(Fe3+,Al)(As3+O3)2[(Si,As5+)O4]10(OH)16Orth. 2 2 2 : C2 2 21
McgoverniteMn19Zn3(AsO4)3(AsO3)(SiO4)3(OH)21Trig. 3m (3 2/m)
SynadelphiteMn2+9(As5+O4)2(As3+O3)(OH)9 · 2H2OOrth. mmm (2/m 2/m 2/m) : Pnma
Turtmannite(Mn,Mg)22.5Mg3-3x((V5+,As5+)O4)3(As3+O3)x(SiO4)3O5-5x(OH)20+xTrig.

Common AssociatesHide

Associated Minerals Based on Photo Data:
5 photos of Hematolite associated with AllactiteMn2+7(AsO4)2(OH)8
4 photos of Hematolite associated with SynadelphiteMn2+9(As5+O4)2(As3+O3)(OH)9 · 2H2O
4 photos of Hematolite associated with CalciteCaCO3
4 photos of Hematolite associated with MagnetiteFe2+Fe3+2O4
4 photos of Hematolite associated with PyrochroiteMn(OH)2
3 photos of Hematolite associated with DolomiteCaMg(CO3)2
1 photo of Hematolite associated with JacobsiteMn2+Fe3+2O4
1 photo of Hematolite associated with Akrochordite(Mn2+,Mg)5(AsO4)2(OH)4 · 4H2O
1 photo of Hematolite associated with BaryteBaSO4

Related Minerals - Strunz-mindat GroupingHide

8.BE.05AugeliteAl2(PO4)(OH)3Mon. 2/m : B2/m
8.BE.10GrattarolaiteFe3+3(PO4)O3Trig. 3m : R3m
8.BE.15CornetiteCu3(PO4)(OH)3Orth. mmm (2/m 2/m 2/m) : Pbca
8.BE.20ClinoclaseCu3(AsO4)(OH)3Mon. 2/m : P21/b
8.BE.25ArhbariteCu2Mg(AsO4)(OH)3Tric. 1 : P1
8.BE.25GilmariteCu3(AsO4)(OH)3Tric. 1 : P1
8.BE.30AllactiteMn2+7(AsO4)2(OH)8Mon. 2/m : P21/b
8.BE.30FlinkiteMn2+2Mn3+(AsO4)(OH)4Orth. mmm (2/m 2/m 2/m) : Pnma
8.BE.30RaadeiteMg7(PO4)2(OH)8Mon. 2/m
8.BE.30ArganditeMn7(VO4)2(OH)8Mon. 2/m : P21/m
8.BE.35Chlorophoenicite(Mn,Mg)3Zn2(AsO4)(OH,O)6Mon. 2/m : B2/m
8.BE.35Magnesiochlorophoenicite(Mg,Mn)3Zn2(AsO4)(OH,O)6Mon. 2/m : B2/m
8.BE.35Mineral E (of Dunn, et. al., 1982)Orth. mmm (2/m 2/m 2/m)
8.BE.40Gerdtremmelite(Zn,Fe)(Al,Fe)2(AsO4)(OH)5Tric.
8.BE.45DixeniteCuMn2+14Fe2+(SiO4)2(As5+O4)(As3+O3)5(OH)6Trig. 3 : R3
8.BE.45KraissliteZn3(Mn,Mg)25(Fe3+,Al)(As3+O3)2[(Si,As5+)O4]10(OH)16Orth. 2 2 2 : C2 2 21
8.BE.45McgoverniteMn19Zn3(AsO4)3(AsO3)(SiO4)3(OH)21Trig. 3m (3 2/m)
8.BE.45Arakiite(Zn,Mn2+)(Mn2+,Mg)12(Fe3+,Al)2(As5+O4)2(As3+O3)(OH)23Mon. m : Bb
8.BE.45Turtmannite(Mn,Mg)22.5Mg3-3x((V5+,As5+)O4)3(As3+O3)x(SiO4)3O5-5x(OH)20+xTrig.
8.BE.45CarlfrancisiteMn2+3(Mn2+,Mg,Fe3+,Al)42[As3+O3]2(As5+O4)4[(Si,As5+)O4]6[(As5+,Si)O4]2(OH)42 Trig. 3m (3 2/m) : R3c
8.BE.50SynadelphiteMn2+9(As5+O4)2(As3+O3)(OH)9 · 2H2OOrth. mmm (2/m 2/m 2/m) : Pnma
8.BE.55Holdenite(Mn2+,Mg)6Zn3(AsO4)2(SiO4)(OH)8Orth. mmm (2/m 2/m 2/m) : Ccca
8.BE.60KoliciteMn2+7Zn4(AsO4)2(SiO4)2(OH)8Orth. mmm (2/m 2/m 2/m) : Cmca
8.BE.65Sabelliite(Cu,Zn)2Zn(AsO4,SbO4)(OH)3Trig. 3 : P3
8.BE.70JarosewichiteMn2+3Mn3+(AsO4)(OH)6Orth. 2 2 2
8.BE.75TheisiteCu5Zn5(AsO4,SbO4)2(OH)14Orth.
8.BE.80CoparsiteCu4(AsO4,VO4)O2ClOrth. mmm (2/m 2/m 2/m) : Pbcm
8.BE.85WaterhouseiteMn2+7(PO4)2(OH)8Mon. 2/m : P21/b
8.BE.90VasilseverginiteCu9O4(AsO4)2(SO4)2Mon. 2/m

Fluorescence of HematoliteHide

Not fluorescent in UV

Other InformationHide

Notes:
Readily soluble in acids.

Alters to Manganite.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for HematoliteHide

References for HematoliteHide

Reference List:

Localities for HematoliteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Sweden
 
  • Värmland County
    • Filipstad
      • Långban Ore District
Holtstam et al. (1999)
Natural History Museum
Österberg (2003)
Gatedal (n.d.) +1 other reference
Moore (1978)
Nysten (1987)
Igelström (1884) +3 other references
      • Persberg ore district
        • Pajsberg
Nysten (2004)
 
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